CZ315599A3 - Composition for fine fabric or paper articles containing humidity controllers - Google Patents

Abstract

Fabric or paper products, which comprises moisture regulators, further comprising 1 to 1 15 wt. % preferably 2 to 20 wt. %, based on the whole composition, at least one special nonionic, superficial an active substance (surfactant) selected from at least one amine oxide and / or hydroxyacid esters and / or at least one amphotenside. Fabric, respectively. paper product and method production of fine fabric and paper products.

Description

Compositions for fine fabric or paper products containing moisture regulators

Technical field

The present invention relates to a composition comprising moisture regulators for tissue paper products, to a method of making such products, to the use of the composition for treating such tissue paper products, and to flat support materials containing fine fabric or paper products in a wet-laid form. wetlaid including TAD method or airlaid, non-waven fibers mainly based on cellulose fibers.

The invention relates to both a care and a softness improving composition for processing or treating fine tissue or paper products, which can be used, for example, in tissue paper products such as tissue paper, cosmetic scarves, toilet paper, kitchen towels and the like.

Paper tissue, paper glazes or webs or pulp (webs), in the area of sanitary paper at low basis weights also mentioned fine tissue or cosmetic paper, event. fabric, can no longer be thought of as a consumer product in modern society. Fine paper products such as handkerchiefs, cosmetic scarves, make-up scarves, towels, and toilet paper account for a substantial share of the volume of trade, with a trend towards care products. For fine paper products with special treatment character> ·>

4 4 4 4 4 4 4 4 4 4 4 4 4

4 4 4 · 444445

4 4 · 4

4 4444444 44 44, in addition to the treatment aspect, the extreme softness aspect of these handkerchiefs, scarves or towels is also at the center of consumer interests. With regard to the care properties, in addition to the increased softness of the products and the associated passive care, in particular chemical substances which can be applied as components of the composition to a given fine fabric or paper product are meant. The term " active care " should further be understood to mean that a composition which, when used, is applied to the skin or skin. Thus, on the one hand, the skin should not be further irritated by the use of a soft scarf or handkerchief, and on the other hand, with a sufficient amount of application, it must be treated and the redness of the skin must be prevented or minimized. The treatment ingredients of the composition are those which act to soothe the skin, soothe, anti-inflammatory (prevent or inhibit any inflammation) or moisture-producing effect, etc., as are known from the skin cosmetics as lotion lotions, creams, ointments, shampoos, etc.

By "passive care" is meant the softness of a fine tissue or tissue paper product conditioned by extreme softness; high surface smoothness / softness combined with high crease softness. This softness can be further improved by the composition and morphology of the paper product, by mechanical measures such as smoothing or roughening, as well as by the addition of suitable chemical excipients.

BACKGROUND OF THE INVENTION ······························ 99 99

Generally, 'softness' for delicate fabric or paper products means the subjective touch experience of the consumer when he takes the product in his hand and rubs it against the skin, eventually. it crumpled in his hand. For more details on softness, respectively. For the manufacture of these fine products, reference is made to the earlier patent application WO96 / 08601.

^r The use of chemicals to increase the softness of these products from soft tissue is also known. Most of these chemicals are cationic surfactants as described in German Patent Specification 4334367 or EP-A 0688901 or glucose-glutamate as disclosed in U.S. Pat. No. 4,882,221. Another possibility to obtain soft tissue paper is to use nonionic surfactants as described in European Patent Application 347177, respectively. the use of siloxane poles, which are discussed in more detail in, inter alia, European Patent Applications 347353 and 347354.

Furthermore, DE-C 3447499 discloses a non-drying cleaning cloth in which an emulsion comprising at least one moisture regulator, preferably ethylene glycol poles, and at least one other liquid substance is applied to the carrier material.

in

Furthermore, WO96 / 08601 discloses compositions for tissue paper products containing polysiloxanes containing 25-95% by weight of at least one polyhydroxy compound, 575% by weight of polysiloxanes, as well as in proportion to 100 parts by weight of this mixture. -35 wt.% Water. In this application it could be shown that said combination has a synergistic effect on softness. The prior art set out the task of preparing fine fabrics in which fabric or paper products with increased softness are not adversely affected by the mechanical properties.

US-A-4,786,367 relates to a cellulosic fiber network comprising 0.1-2% by weight of lauroamphoglycinate relative to the fibrous network. However, this form does not contain any information to indicate whether or not the fiber network contains moisture regulators or recommends them.

German Patent Specification 3237574 relates to the use of special amine oxides, as further defined by the general formula (I), as auxiliaries in the production of hunting, paper or special hygiene products to reduce mechanical strength and improve wetting ability, respectively. absorbability. These amine oxides are usually added in amounts of from 0.02-2.0%, preferably 0.01-1%, based on the dry weight of the cellulose. Again, the addition of moisture regulators to such compositions for fine paper products or directly to the fine paper products themselves is neither described nor recommended in this form.

EP-A-0 347 1 76 relates to a fine paper having a basis weight of 1065 g per m ² and a density of not less than 0.6 grams per cm ³ , which paper contains at least 0.01% by weight of non-cationic surfactant in addition to cellulose fibers, based on the weight of the dry fibers of the paper, said non-cationic surfactant being deposited on a damp fabric or paper web. Said non-cationic surfactant means, inter alia, a water-soluble amine oxide having an alkyl group of 10-15 carbon atoms and 2 (hydroxy) alkyl groups having 1-3 carbon atoms. Not even from this. CHANGED SHEET '• · · ·

It is not possible to assume the addition of the corresponding surfactant-containing composition, the moisture regulator, and the mixture to be applied to the appropriate fabric or paper products. , nor is it recommended.

EP-A-0 347 177 defines said product in EP-A-0 347 176 as a corresponding manufacturing process. Here too, the currently claimed subject is not pre-described or recommended.

EP-A-0 688 901 relates to a tissue paper product to which has been added 3-35% by dry weight of an aqueous softness providing composition, said softness imparting composition comprising 20-98 wt% glycerin and 0.2-5% by weight of a quaternary ammonium compound, which is generally understood to mean a cationic and no nonionic or amphionic surfactant. Neither this form nor described or recommended the use of certain amounts of a special non-ionic Jew. The replacement of a cationic surfactant by a nonionic surfactant is also not suggested or recommended, as the two classes of substances are usually not comparable to each other due to the different application spectrum.

DE-C-34 47 499 relates to a non-drying cleaning cloth consisting of a flat carrier material to which a respective emulsion comprising water and a moisture regulator has been applied, wherein fine, inorganic and / or organic dispersible solids have been applied to the carrier material. Even from this form it is not possible to detect the addition of special amounts of a special nonionic surfactant to the corresponding composition for fine fabric or paper products. CHANGED UST · · ♦ · · · · · US US US Or to the products themselves without adding the corresponding fine, inorganic and / or organic dispersible solids.

EP-A-0 282 289 relates to a skin care composition containing up to 35% by weight of the monoalkyl citrate ester salt. Paraffin oil or vegetable oil is used as carrier for this composition. Here too, it is not prescribed or recommended to be used as an additional component of a hydrophilic moisture regulator, as an additional component, especially based on polyols, especially with respect to fine fabric or paper products.

German Patent Specification 2622571 relates to wet toilet paper impregnated with cleaning, degreasing and bacteriostatic substances, wherein the carrier is impregnated with a solution of the following composition: 0.2-2.0 wt.% Of fatty acid amidoalkyl, 0.2-2.0 wt. % saturated fatty acids ethoxylated with a partial glycerin ester, 0-20 wt.% aliphatic alcohols having 2-4 carbon atoms, 0.5-5 wt.% organic acids, 0-5 wt.% perfume oil and water as a residue. Depending on the proportion of acids possibly added, a pH of 5 is reached. 6. What is to be considered individually for a given component of aliphatic alcohols is also intended to be disinfectant and preservative components, which usually means lower alkyl monoalcohols, especially in the file ethanol and isopropanol. Again, the addition of moisture controllers to this composition is not described or recommended.

DE-U-8 5 12 083 relates to wet toilet paper, characterized in that it consists of paper impregnated with glycol or glycol ester. Neither from this document can it be ascertained or recommended to add additional components to a given wet toilet paper which would have both a softness promoting and a curing effect for the user.

AT-358 741 relates to a pulp or skin cleansing web impregnated with a cleaning emollient in which the web has a wiping surface and a lower density wiping zone, the wiping surface being a wiping zone limit where the wiping zone has a mean cavity index of at least 68; a minimum cavity index of at least 10, and wherein the wiping zone is impregnated with 10-150% lipophilic cleaning plasticizer based on the web weight. However, the present invention is not described or recommended, since the composition of the invention is not lipophilic with respect to the hydrophilic main component of the moisture regulator.

However, it is almost unknown to prepare a corresponding fine fabric or paper product which not only exhibits improved softness but also has an active treatment effect due to the applied composition.

SUMMARY OF THE INVENTION

Thus, an object of the present invention is a composition for fine fabric or paper products comprising appropriate moisture regulators and having both a softness promoting and a curing effect for the user.

The present invention thus relates to a composition comprising moisture regulators for fine fabric or paper products, characterized in that it further comprises 1-25 wt.%, Preferably 7-20 wt.

4 4

4 «444 4444 • 4 4 4444 ·

4 4 4 4 4 444445

4 4 4 4 4

% By weight, in particular 5-13% by weight, based on the total composition, of at least one non-ionic surfactant selected from amine oxide and / or hydroxy acid esters and / or at least one amphotenside.

It is a further object of the present invention to provide a process for manufacturing fine fabric or paper products in which such a composition is applied continuously or discontinuously to a fiber web or fabric path either within the sieve, press, TAD, and Yankee rolls and / or dry parts, ie. at a fiber density of from 20 to 97%, based on the dry fiber weight of a given lane, in an amount of from 0.1 to 59% by weight, on or in the lane, and the lane is subjected to supercooling after said application. Alternatively, the invention provides a basis for the preparation of a process for producing fine fabric or paper products, wherein the above application is carried out behind the dry portion on a webbing machine, back machine and / or in a processing machine by the above method.

(non-woven) fibers on containing, planar,

A further object of the present invention is a fine fabric product in the form of a wetlaid (including TAD method) and / or airlaid or nonwoven based predominantly cellulosic fibers of at least one-layer carrier materials, further characterized in that it further comprises 5 to 20 wt. %, preferably 7-13 wt.%, based on the total product, of at least one special, nonionic surfactant selected from amine oxide and / or hydroxy acid esters and / or at least one amphotenside.

• 9 · 9 · 9 · 9 · 9 · 9 · 9 · 9 ·

9 9 9 99999999

9

999 99 9999999 99 99

Finally, it is an object of the present invention to use the aforementioned composition for processing or treating fabric or paper products, in particular handkerchiefs, cosmetic scarves, facial tampons or napkins, toilet paper and kitchen towels.

According to a preferred embodiment of the composition according to the invention, said nonionic surfactant is an amine oxide of the general formula

R ₂

R - N ⊕ - ^Ο θ R _{3 X} wherein _R} R ₂ and R ₃ independently of each other represents an optionally substituted aliphatic, linear or branched alkyl radical having 1 to 25 carbon atoms, preferably 1 to 17 carbon atoms, possibly substituted, cyclic alkyl radical of 3 to 25 carbon atoms, preferably 3 to 17 C-atoms, optionally substituted aliphatic, linear or branched amidoalkyl radical of 3 to 22 C-atoms, preferably 7 to 17 Cats in the alkyl moiety or optionally substituted cyclic amidoalkyl radical with 3 to 10 carbon atoms, preferably 5 to 8 carbon atoms in the alkyl moiety.

For these amine oxides, it is preferred that in the above formula R 1 and R _{2 are} C 1 -C 4 alkyl, preferably methyl, and R ₃ is an amidoalkyl group of formula (CH ₂ ) _and N (H) C (O) R ₄ (II), wherein a is 1 to 5 and R ₄ is a fatty acid residue derived from natural oils or fats having 7 to 25 carbon atoms, preferably 7 to 17 carbon atoms.

According to a further preferred embodiment, the compositions according to the invention comprise a hydroxy acid ester, which may be, for example, a glucose ester, lactic acid ester, mandelic acid ester, malic acid ester, tartaric acid ester, citric acid ester or ricinoleic acid ester having at least one. from natural oils or fats, a fatty acid residue having 1 to 25 carbon atoms, preferably 7 to 17 carbon atoms, which, if desired, further has at least one polar group, such as a hydroxyl group. Particularly preferred in this connection are at least one fatty acid residue comprising citric acid ester and salts thereof.

According to another preferred embodiment, the composition according to the invention has an amphoteric in the form of an ampholyte or betaine.

When the component included in the composition of the invention is betaine, it should be derived from natural or synthetic sources and selected from alkyl betaines of the formula R ₅ (CH ₃ ) N ^T (CH ₃ ) CH ₂ COO '(III), wherein R 5 is optionally substituted linear or branched alkyl having 1 to 25 carbon atoms, preferably 7 to 17 carbon atoms; alkylamidobetaines of the general formula R 6 (CO (NH) (CH 2) O (CH 3) N ⁺ (CH 3) CH ₂ COO '(IV), wherein R ₆ is an optionally substituted linear or branched alkyl group having 1 to 25 Cats, preferably 7 to 17 C - atoms having from 1 to 5 sulfobetaines of the general formula R ₇ (CH ₃ ) N ⁺ (CH ₃ ) -X-SO ₃ (VI), wherein R ₇ is an optionally substituted C 1 -C 25 alkyl group, Preferably 4 to 17 C-atoms and X is optionally substituted alkylene having 1 to 5 methyl units; alkylpolyamphopolycarboxyglycinates of the formula

COO® Na® COO® Na® (XI) wherein R ₂₈ is a C ₇ -C ₁₇ fatty acid and is equal to 2 or 3 or a glycine ester of the formula

HIM

II / ^N \ z ^c h ₃ c ^x ch / (Xii)

O-R 29 wherein R ₂₉ is C ₇ -C ₁₇ -alkyl, preferably C ₁₂ H ₂₅ .

In the composition according to the invention, it is further preferred that the moisture regulator is present in an amount of 40 to 90 wt.%, Preferably 50-80 wt.%, Based on the total composition, and at the same time selected in particular from polyols. Polyols as defined herein are in particular glycerin, polyalkylene glycol, 1,3-butylene glycol (butylene glycol), propylene glycol and sugar alcohols, with particular preference given to glycerine, butylene glycol and / or propylene glycol.

• A A A A A A A A A A A A A A A A A A AAAAAAAA

9

998 9 AAA 9999 99 99

According to a further preferred embodiment, the compositions according to the invention comprise 0.01 to 50% by weight, preferably 0.1 to 40% by weight, of at least one natural, naturally identical or synthetic cosmetic composition. Vitamin-based cosmetics or plant extracts such as horse chestnut, birch, arnica, chamomile or bisabolol, respectively can be mentioned here. azulene alone, St. John's wort, cucumber, aloe vera, hops, allantoin or hamamelis and linden, which are also partly known for their astringency and healing-promoting effect. Provitamin B5 = D-panthenol is particularly well suited as it also serves as a humectant and thus partially replaces glycine / propylene glycol. In the case of bisabolol and azulene, an addition of from 0.5 to 1% to the composition already shows a corresponding effect. Other active ingredients that can be incorporated into the composition are glycyrrhetinic acid, the active ingredient from the root of the sweetwood bush, which acts bacteriostatically and inhibits inflammation, as well as its salts and phytosterol (even ethoxylated) Generol® (Henkel KGaA), produced from soybean oil, which also has anti-inflammatory effects (R. Wachter, B. Salka and A. Magnet, Perfumery und Kosmetik 75 (1994) 755). The composition may contain 1 to 5% by weight of these active ingredients. Other active ingredients include sorbitan fatty acid ester or ethoxylated (oxethylated) homologous glycerin compounds, oxethylated fatty alcohol esters, fatty alcohol alkanolamides, oxethylated fatty alcohols, oxethylated sheep wool alcohols, glycerin monostearate, sulfuric acid, cetylstearyl alcohol. Vaseline and lanolin. In addition to lanolin alone, derivatives thereof, such as lanolininal or sheep's wax alcohols, which are sold under the name Amerchol by Union may also be used. 9 9 9 9 8 «·« ··· «

9 8 · · «

999 9 999 999 «» 8 ··

Carbide lne. in conjunction with mineral oils. Other lanolin derivatives are acetylated lanolin as well as hydrophilic derivatives of lanolin, e.g. As logical additional treatment ingredients, the composition may further comprise jojoba oil, avocado oil, tea tree oil and lime extract or rice flower oil in an amount of between 1 and 40 wt%, in particular 10 to 20 wt%.

As a possible component of the cosmetic composition, the polysiloxane component used may be any water-soluble and / or water-dispersible compound that exists at room temperature (20 ° C) in liquid, pasty or waxy form. The polysiloxane component used for the purposes of the present invention includes polymeric, oligomeric, copolymeric and other multiple monomeric siloxanes. In the following, the term polysiloxane is to be understood to mean any polymer, oligomer, or other multiple monomeric siloxane material. Further, the polysiloxane material may have both a linear and branched or cyclic structure.

According to a preferred embodiment of the composition, the polysiloxane component in the cosmetic composition comprises monomers of the siloxane unit having the following composition:

Re (VI) -Si-O-

R ₉ • 44 • 4 44 4 4 4 4 4 4 4 • 4 • 444 • 444 4 · 4 · 4 ··· 4 444 4444 44 44 wherein R _g and R ₉ are each monomeric siloxane units of the same or different and in each case an alkyl, aryl, alkenyl, alkylaryl, arylalkyl, cycloalkyl, halogenated hydrocarbon or other group. Each of these groups may be substituted or unsubstituted. The R _g - and R ₉ groups of each individual monomer unit may differ from the corresponding functional groups of the other pendant monomer unit. Further, these groups may be both straight chain and branched or may be cyclic. R _g group, and R ₉ may be further independently of one another other silicon groups, but they are not limited to siloxanes, polysiloxanes, and polysilanes. The groups R _g and R ₉ may further comprise a large number of organic functional groups, e.g., alcoholic, carboxyl, and amino functional groups.

The degree and method of substitution cause the relative degree of softness, tissue feel and hydrophilicity that is provided to the tissue paper structure. In general, the degree of softness and the silky feel that is caused, inter alia, by the poles of siloxane increases with decreasing hydrophilicity of the substituted polysiloxane component. Aminofunctional polysiloxanes and polyetherpolysiloxanes are particularly preferred as the polysiloxane component in the processing composition of the invention.

Preferred skin-friendly polysiloxanes in the composition of the invention include linear organopoly siloxane compounds of the following formula:

R ₁₀ I R16 1 Rie AND R-I3 AND AND Ru-Si-1 1 -Si -0 1 AND Si -0 AND - Si - R14 AND AND R12 1 R17 and AND R19 L_ - b Rl5

(VII)

99 99 • 9 9 9 9 9 9 9 9 9 9 • 9 9 9 9 9 999999 9 9 9 9 9

Wherein each of the R ₁₀ to R ₁₈ radicals are independently C 1 -C ₁₀ unsubstituted alkyl or aryl groups, and R ₁₉ is an optionally substituted C 1 -C ₁₀ alkyl or aryl radical. Preferably each R ₀ - R _g -group to independently C o to C unsubstituted alkyl group. One skilled in the art it is known that there is no great difference if e.g. R or _{1 S} R _J9 is substituted. Preferably, the molar ratio b: (a + b) is between 0 and 20%, preferably between 0 and 10% and especially between 1 and 5%.

According to a particularly preferred embodiment of compositions of the invention for the poly siloxane-tolerant good complexion, R ₀ and Rib methyl and R ₁₉ is a substituted or unsubstituted alkyl, aryl or alkenyl. Materials of this kind are generally referred to herein as dimethylsiloxanes, which have a particular functionality, as used herein. Examples of such dimethylsiloxanes poles may be: polysiloxanes such as Dow Corning® 200 Fluid, polydimethylcyclosiloxanes such as Dow Corning® 344 and 345, polydimethylsiloxane with an R ₁₀ -alkylcarbon group, and polysiloxanes with one or more amino, carboxyl, hydroxy, , polyether, aldehyde, ketone, amide, ester, thiola and / or other R ₁₉ functional groups, including alkyl and alkenylanalogues of such functional groups. E.g. aminofunctional alkyl as R ₉ may be an aminofunctional polydimethylsiloxane or aminoalkylfunkční. The exemplary enumeration of these polydimethylsiloxanes does not mean that other polydimethylsiloxanes not specifically mentioned here are excluded.

4 4 4 • 4 ·· ··

4 4 ···· 4 4 4 4 • · 4 4 4 4 4 • 4 4 · 444444

4 4 4 4 4

444 4,444 4444 44 · 4

The viscosity of the polysiloxanes used as the skin-tolerant component in the composition of the invention may vary over a wide range as long as the siloxane remains fluid (liquid) and may be liquefied for use in the tissue composition of the invention. This means, for example, viscosities from 25.10 ⁶ m ² / s to 20,000,000.10 ⁶ m ² / s or even higher. Preferred here are viscosities from 15,000 x ^{10 6} m ² / s to 3,340,000 x ¹⁰ m ² / s. Highly viscous polysiloxanes that are not able to flow themselves can be effectively applied to the tissue paper as part of the composition of the invention, for example, when the poles of the siloxane component of the invention are dissolved in a polyol or propylene glycol, respectively. glycerol, optionally water, or a mixture thereof together with an emulsified surfactant or polysiloxane, if insoluble in propylene glycol or glycerin, optionally water, is dissolved with an appropriate solvent such as hexane. Special methods of applying polysiloxane components to cosmetic products are discussed below.

The aforementioned skin-friendly polysiloxane components are described, for example, in US-A-2826551, US-A-3964550, US-A-4364837, US-A-4395454, US-A-4950545, US-A- 4921 895 and British Patent Specification 849433. The monograph "Silicon Corapounds", pp. 181-217, published in Petrarch Systems, 1984, further provides a detailed listing and description of such polysiloxanes.

According to a further preferred embodiment, the skin-friendly polysiloxane components may be in the form of a skin-friendly polysiloxane component.

9 · 9 9 9 9 999

99 • · 9 · 9 9

999 999 ·

99 polvétersiloxanes of the general average formula are used in 99 compositions according to the invention:

ch ₃ I r CH ₃ 1 R _CH3 - I ch ₃ I 1 R20 - SiO - | 1 Hundred- AND and SiO - AND AND Si-R20 AND ch ₃ 1 R12 I CH ₃ _ I ch ₃

(VIII) in which R ₂ s are given molecule the same or different alkyl group having 1 to 12 carbon atoms or a polyether group _(CnH2n O) _{X 2} R 1, wherein R ₂ l is a hydrogen, hydroxyl, alkyl or acyl group 1 and n is from 2 to 2.7 and x is from 2 to 200, with at least one of the R ₂₀ groups in the average molecule being a polyether group; a has a numerical value of from 0 to 98, b has a numerical value of from 0 to 98 and a + b is from 8 to 98. R ₂₀ can be an alkyl group having 1 to 12 carbon atoms or a polyether group. However, it must be satisfied that at least one _R20 in an average molecule is a polyether group. Preferably, 2 to 5 R ₂₀ groups are polyether and the remaining R ₂₀ groups have the meaning of an alkyl group, with methyl being particularly preferred. However, the alkyl group may also have up to 12 carbon atoms. In this way, it is possible to alter the properties of the processing composition and thus to improve the handling of the tissue paper products. The polyether groups correspond to the formula (C _n H 2 _n O) _x R ₂₁ . The index n has a numerical value from 2 to 2.7. Generally, the ether group consists mostly of oxy ethylene and possibly oxypropylene groups. If the index is 2, the polyether group consists exclusively of oxyethylene units. If the numeric value of n increases, then it increases ..................

The proportion of oxypropylene groups is also present. A numerical value of n = 2.7 means that 70% of the polyether groups are xypropylene groups.

Index x represents the number of oxyalkyl units. This value is an average numeric value since a mixture of products of different chain lengths is usually obtained in the synthesis of polyethers. The index x has a numerical value of from 2 to 200 and is preferably from 10 to 50. Polyether groups having an average molecular weight of from 600 to 4,000 are preferred. The index a represents the number of methylsiloxane units carried by the R ₁₂ -group. Index b corresponds to the number of dimethylsiloxane units. While a and b can have a value from 0 to 98, the condition that the sum of a + b have a value from 8 to 98 must be met. If a = 0, the polyether group or groups are bound at the end of the chain. The siloxanes with positive values for a are modified by _R12 -bočními chain. Preferred are the siloxanes, for which R ₂₀ -group arranged in the side chain. The group R ₂₁ can be hydrogen, hydroxyl, alkyl or also acyl. Preferably, R ₃ is a hydrogen atom. When R _{21 is an} alkyl group, small alkyl groups having 1 to 4 carbon atoms are preferred. A preferred acyl group is acetyl.

According to a particularly preferred embodiment, the skin-tolerant poles of the siloxane component in the composition of the invention have the following formula:

CH;

Ru-SiO CH;

CH;

SiO CH;

CH;

- Si - R 22

I c CH ₃ (IX) wherein R ₂ is a group of formula

- R23 - N - R26 · Y ~

AND

R 25 and therein R ₂₃ is a bivalent hydrocarbon group whose carbon chain is interrupted by an oxygen atom, R _24, R _25, R ₂₆ are identical or different and represent alkyl groups having 1 to 18 carbon atoms, one of R _24, R ₂ 5> R26 is - (CH 2) ₃ NHCOR ₁₉ - wherein R ₂₉ is -alkyl groups having 7 to 17 carbon atoms, and Y 'is a monovalent anion and c has a numerical value from 5 to 100. R ₂₃ is a divalent hydrocarbon group, e.g. a group of the formula -CH ₂ -C (OH) H-CH ₂ -O- (CH ₂ ) ₃ -. The groups R ₂₄ , R 25, R ₂₆ may be the same or different and are alkyl groups having 1 to 18 carbon atoms. However, one of the abovementioned groups R ₂₄ , R 25, R 20 may also have the meaning of the CH ₂ N ₃ -COR 27 group.

When R ₂₄ , R ₂ , R 26 are alkyl, they have 1 to 18 carbon eh atoms. Particularly preferred are Ri4-group in which two of said R ₂₄ -, R ₂ i, R ₂ O- group having 1 to 4 carbon atoms and the third group has up to 18 carbon atoms. If one of R ₂₄ -, R25-, R ₂ O- group is (CH _{2) 3} NHCOR ₂₇ -group, and Ri9 is alkyl group with 7-17 carbon atoms. Y 'is a monovalent anion, usually an acetate group. Y, however, may also be an inorganic group, such as e.g. The index "c" indicates the number of dimethylsiloxane units in linear siloxanes and has a numerical value of from 5 to 100 and preferably from 10 to 80. In particular, such a Preferred among said siloxanes are polydimethylsiloxanes, such as polyether alkyl, as well as quaternary or betaine groups, especially nitrogen modified polydimethylsiloxanes.

Particularly preferred siloxanes are Tegopren (R) by Th. Goldschmidt AG sold organomodified siloxanes with significant surface and boundary activity in aqueous and organic systems. These are polyethersiloxanes as listed in the undated company form "Tegopren® Informativ" and sold under the trade names Tegopren® 3012, Tegopren® 3020, Tegopren® 3021, Tegopren® 3022, Tegopren® 3070, Tegopren® 5840,

Tegopren® 5842, Tegopren® 5843, Tegopren® 5847, Tegopren® 5851, Tegopren® 5852, Tegopren® 5863, Tegopren® 5873,

Tegopren® 5878, Tegopren® 5884 and Tegopren® 7006, which typically have mean cloud points ranging from 25 ° C to 71 ° C, as well as modified siloxanes in the form of quaternary and betaine compounds of tegoprenes with silicones as sold under the designations Tegopren® 6920, Tegopren® 6922 and Tegopren® 6950.

Nonionic and / or cationic surfactants can also be used in the compositions according to the invention in amounts of from 0 to 20% by weight, preferably from 0 to 10% by weight, as other customary auxiliaries and additives. Such types of surfactants are, for example, quaternary ammonium compounds, but especially quaternary ammonium salts, as described, for example, in U.S. Patents 5,312,522, 5,474,435, 5405,501. «·« ··

5427696 and further in patent applications EP-A 688901, WO95 / 1 1344, WO95 / 1 1343, WO95 / 01478, WO95 / 01479,

WO94 / 29521, WO94 / 29520, WO94 / 16143 and WO94 / 19381.

In addition, the compositions of the present invention may contain fragrances of the conventional type selected from natural, nature-identical or artificial fragrances (see definition in RMPMP, 9th ed. 1992, pp. 3887 and d.), With the corresponding aromatic fragrances being preferred. substances. E.g. agronomic oils such as lemon essential oil, bergamot essential oil, orange essential oil, petitgraine essential oil, coniferous essential oil, Foin Coupé fragrance compositions or flower essential oils such as roses, jasmine, lilac, lavender, as well as synthetic fragrances menthol base. Ullmann, Enzyklopadie der technischen Chemie, Vol. 20, p. 190285.

In addition, inorganic pigments or organic dyes which are used in the manufacture of cosmetics or nonwoven paper can also be added to the composition of the invention. Physiologically harmless and non-irritating dyes, in particular the corresponding natural and respiratory dyes, are preferred, especially for ecological reasons. Natural dyes. All of the above-mentioned additives and auxiliaries may be present both individually and in combination.

4 • · 3 ·

In addition, inorganic and / or organic fillers which are commonly used in the manufacture of products such as talc, bentonite and other clays or clays may also be included in the composition of the invention.

The amount of fillers thus added is generally 1-50% by weight, but preferably 1-10% by weight.

If desired, gelling agents or hydrogels, such as those known in the form of naturally occurring polymers, e.g. based on polysaccharides, lignin, natural rubber, proteins and / or natural resins, may also be added to the composition. When polysaccharides are used herein, this refers to film-forming materials obtained from rural field plants or herbs, marine plants or microorganisms. Appropriate polysaccharide gel-forming agents from rural plants are usually understood to include starch and starch products, e.g., corn, wheat and rice starch as well as potato and manioc starch. Other polysaccharides derived from rural plants are galactomannans, such as carob meal and guar, dipectins and pectic substances, exydate gum such as acacia or acacia gum, as well as tragacanth, cellulose derivatives, etc. Polysaccharides derived from marine plants are primarily alginates and agar, carrageenans and polysaccharides from algae. Finally, the polysaccharides obtained from the microorganisms are dextran and xanthan. The gelling agents which may be used in the compositions of the present invention are mainly gelatin, which are commercially available as Type A and Type A; . »·» ·; ··· ··· of ··· ···· ·· **

B. Synthetically modified, naturally occurring polymers that can be used as thickeners in the compositions of the invention are understood to be the corresponding cellulose ethers and starch ethers and esters and mixtures thereof. Finally, synthetic polymers can also be used in the compositions of the invention, which are selected from vinyl polymers, preferably polyvinyl alcohol, polyvinylpyrrolidone or polyvinyl butyral, polyacrylic compounds, preferably polymethacrylic acid ester copolymers. These components may be added to the composition in amounts of from 0 to 40 wt%, preferably from 1 to 20 wt%. %.

An overview of the water-soluble polymers thus used can be found in the Encyclopedia of Polymer Science and Engineering, Vol. 17 (1989), pp. 730-784.

The above composition of the invention usually has a pH in the range of from 3 to 8, but preferably from 3.5 to 5.

The composition according to the invention usually exhibits a viscosity of 1-700 mPas, preferably 5-600 mPas at spray application temperatures of 10 to 90 ° C, preferably 15-80 ° C, spray application, and a roller viscosity of 5 to 600 mPas, and a viscosity of 5 -2,000 mPas, preferably 10-1,500 mPas.

tttt ·················· 24

In a preferred embodiment, the composition of the invention comprises the following components in the following amounts: 3090 wt%, preferably 50-80 wt%, of at least one moisture regulator, especially glycerin and / or propylene glycol, 0-20 wt%, preferably 2-10 wt%, at least one nonionic and / or cationic surfactant, 1-25 wt%, preferably 2-20 wt%, at least one special nonionic surfactant selected from amine oxides and / or hydroxy acid esters, as well as at least one amphotenside, 0.01-40 wt.%, Preferably 0.01-20 wt.%, Of at least one cosmetic composition, 0-70 wt.%, Preferably 0-40 wt.%, Of at least one natural, naturally modified or synthetic gelling agent, and water as the rest.

The present invention further provides a method for producing fine fabric or paper products of the above-mentioned type, characterized in that the respective composition of the above-mentioned kind is applied continuously or discontinuously to the fibrous web or fabric (paper) path within the screen section, press part, Yankee rollers and / or dry parts, i.e. at a fiber density of 20-9 7%, based on the dry weight of the fibers of the pathway, in an amount of from 0.1 to 40%, preferably from 1 to 20%, on or in the pathway, and the pathway is optionally quenched after application.

According to an alternative embodiment, the present invention relates to a method for producing fine paper or fabric products, characterized in that the respective composition is applied continuously or discontinuously on or in a given path on a fibrous web. A web or web of fine fabric or fine paper behind the dry portion on a webbing machine, back machine and / or processing machines in an amount of 0.1 to 40 wt. %, preferably from 1 to 20 wt.%, and this trajectory is optionally smoothed after application.

According to a preferred embodiment of the process according to the invention, the composition is applied in an amount of from 0.2 to 50%, preferably from 1 to 20%, at a fiber density of from 30 to 97%, based on the dry weight of the fibers of the monolayer path.

According to a further preferred embodiment of the method according to the invention, the fine fabric or paper path is a multilayer path and the composition is applied at a fiber density of more than 90%, based on dry fiber weight, on and / or into at least one of the outer layers of the multilayer path. from 0.001 to 50%, as shown as a single component, eg by means of an air interlayer gas chromatography, preferably from 0.01 to 30%, or even more preferably from 0.1 to 25% and particularly preferably from 0.5 to 25%; 20%.

According to a further preferred embodiment of the method, the composition is applied to and / or into a multilayer fine fabric or paper path on both outer layers in an amount of from 0.001 to 50%, preferably from 0.01 to 30%.

According to a further preferred embodiment of the method according to the invention, the application of the composition is carried out in a machine for producing the composition. By spraying onto the appropriate roll (Pope-Roller), forming a film of the sprayed composition, which is then transferred to the path of the respective fabric or paper during the winding process, or the application is carried out with trowels or brushes or with blades, resp. blades. The application can also be carried out by rolling, spraying or spraying, spreading with spreading knives or by means of blades or blades.

Alternatively, the application of the composition, but in particular of the cosmetic composition, can be applied to the fabric or fabric path. The tissue paper may be in a microencapsulated form, impregnated in microtampons or in the form of liposomes.

According to a further preferred embodiment of the method according to the invention, in cases where there is no application in the microencapsulated form, impregnated in microtampons and in the form of liposomes on / into the given layers, smoothing through at least one pass of the fabric or fine paper path through the gap between two rolls. wherein the steel surface cylinder is associated with an opposing lei with a steel, plastic, paper or rubber surface, preferably a plastic surface. In this modification of the method, it is advantageous to perform smoothing by passing the path or nonwoven portion twice through the respective slot between the rollers, whereby one steel surface roll is first assigned to the plastic surface counter-roll and then mirror-like the plastic surface roll is assigned to the steel surface roll.

9 4

«4 · ♦ ·· · · · · · · ·

4,444 444 ♦ 4 4

999 99 99

According to a further preferred embodiment of the method according to the invention, the aforementioned composition is applied to a fibrous web or nonwoven part in a conventional fiber production or nonwoven laying process. Alternatively, the composition can be applied to the fibrous web also as a part of a flow-drying process. of the TAD method.

It is also an object of the present invention to use the above composition for processing or handling cosmetic products, in particular handkerchiefs, cosmetic wipes, facial wipes, toilet paper and kitchen towels.

Another object of the present invention is a fabric or paper product in the form of a wetlaid (including TAD method) and / or airlaid or nonwoven fibers based primarily on cellulosic fibers containing flat, at least the bottom of the layer of carrier materials characterized in that it further contains 0.05 to 50% by weight, preferably 130% by weight, based on the total product, of at least one special nonionic surfactant selected from amine oxide and / or hydroxy acid esters and / or at least one amphoteric surfactant.

Said fine fabric or paper product according to the invention may be one at least one layer, preferably two to four layers or multilayer, unsampled, patterned or partially patterned, e.g.

AAA

A A

AAA

AND

AA edge patterned soft tissue paper. Instead of pure cellulosic fibers, tissue paper with uncoated or unsampled middle layers or with a middle layer of CTMP may also be used. If multilayer cosmetic paper is used, the corresponding adhesive adhesion of the layers can be achieved by glue-gluing, partial glue-gluing, for example by spot gluing according to a predetermined pattern, by compression using two steel cylinders under pressure, mechanical adhesion of the individual layers above surfaces. screening, edge stamping, longitudinal grooving, etc. Such a cosmetic product may be a bulky carrier material of sufficiently high strength and as soft as possible, which may be achieved, for example, using the appropriate tissue or nonwoven or a combination of both . In the case of cosmetic or paper products, products having a basis weight of about 15 to 75 g / m @ ^{2 are used} . Nonwoven products are based on a basis weight of from 18 to 120 g / m ² . Either fabric and nonwoven products alone or combinations of both products with different basis weights can be used. The use of non-woven materials can guarantee a given compressibility.

If desired, the corresponding support material can be wet strengthened using conventional, non-toxic wetting agents such as urea and melamine resins as well as crosslinked cationic polyalkenylamines, etc.

·· · i ·. ···:. ·. ♦ · ··: ··:

.:. : ...........

According to a preferred embodiment, the fabric or paper cosmetic product will have at least a portion of its surface, on its outer sides, on the inner sides of the outer layers, only on the inner layers, or on all layers, an appropriate composition of the above type.

According to a further preferred embodiment of the fine fabric or paper product according to the invention, it is present on at least a part of the above composition as a coating or coating in microencapsulated form, embedded in microtampons or liposomes, on or in layers, The species is found in microencapsulated form, embedded in microtampons or in the form of liposomes. in given layers.

The above-mentioned composition has, as a basic component, in addition to the Jew according to the invention, moisture regulators and water as the remainder. Polyols, such as polyethylene glycol or sorbitol, or other skin and mucosal compatible substances, act as such moisture regulators. The use of propylene glycol and / or glycerin is preferred.

As regards the cosmetic composition, the use of provitamin B5, called D-panthenol, is particularly preferred because of its very good moisture retention capacity. Other particularly preferred cosmetic ingredients are allantoin and the allantoin addition compound on D-panthenol, tocopherol acetate, jojoba.

444 444

4

44 special esters from Merck AG oil, rice flower oil, avocado oil of fatty alcohols and lactic acid, e.g.

dispensing product CeraphyT ^s 28 H _(CH3) C (OH) C (O) OC ₆ H _33, phytosterol acid glycyrrhitinová and its salts, Nordmann & Rassmann issued isopropyl esters of fatty acids from a wool wax, e.g. under the trademark Amerlate ® P emitted isopropyl myristate, bisabolol and azulene, plant proteins such as wheat proteins and algen extracts, as well as plant extracts, optionally. active substances from hops, St. John's wort, melissa, arnica, hibiscus, elderberry, sage, mallow, hamamelis, mango, papaya and linden.

As representatives of amine oxides, hydroxyacid esters and amphoteric surfactants of the particularly preferred classes of compounds of the invention, amine oxides of the formula

R ₂

AND

R ₁ - N ® - O ®

R ₃ (i) wherein R ₍ and R ₂ is methyl and R _{3 is an} amidoalkyl group of formula (CH ₂ ) ₃ N (H) C (O) R ₄ , wherein R ₄ is a C ₇ -C ₁₇ fatty acid residue. Other particularly preferred amphotensides are the so-called alkylamphoacetates of the general formula R ₈ (O) C (H) N (CH ₂ ) ₂ (H) NCH ₂ (OH) CCH ₂ COO ', where R ₈ represents a fatty residue. 99 ·· ··

9 9 0 9 9 9 • 9 9

0 9 999999 9 99 acids with 7-17 carbon atoms. Further preferred are alkyl polyamphopolycarboxyglycinates (APAC),

C00® Na® C00® Na® where R ₂ s ⁼ C ₇ -C ₁₇ -fatty acid and n = 2,3.

Furthermore, trimethylglycine having the general formula (CH ₃ ) ₃ N ⁺ CH ₂ COO ', coconut amidopropybetain or citric acid monoglyceride with a C ₇ -C ₁₇ fatty acid residue in which one of the two free carboxylic acid groups is mentioned lemon has in the β-position SO ₃ -group.

Further, glycine esters of the general composition may be mentioned: 9 9 9 9999 9999 9

Η Ο

I II / z \ z ^c \ h ₃ c ch ₂ ο - r ₂₉

R ₂₉ ⁼ C ₇ -C ₁₇ => -C ₁₂ H ₂₅ (specifically: Medialan® LD. Example 5).

The aforementioned composition, when applied, partially penetrates the tissue of a given pulp and thus affects the softness and feel of the product, e.g. When applied exclusively to the outer layers, a sufficient amount of lotion remains adhering to the topsheet and is transferred to the skin when the products so treated are sufficiently used to develop their effect.

The so-called handheld tests were performed to assess the improved / changed hand against the relevant standards. This is done by a panel test of trained persons based on a manual on sensory test methods (ISTN, Special Technical Publication 434, p. 22, Testform de-ranking methods, rank order elevents printings, February 1993). Accordingly, increasing softness, defined herein as the sum of surface softness and crease softness, is evaluated by a group of four trained persons according to the following procedure:

Tissues to be tested were folded twice in such a way that the identification of the sample could not be recognized by the investigator and in any case the same external side would be considered.

Handkerchiefs prepared in this way are then tested for their softness by rubbing and squeezing between the thumbs, fingers and toes.

· · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · defined standards. While "zero sample", ie. untreated handkerchief from standard production, showed a handheld value of only 72 handheld points on a scale of 0 to 100, the values in the laboratory of the appropriately treated handkerchiefs are always above this value. The following table gives an overview of the softnesses obtained.

The present invention is now explained in more detail by the following examples.

DETAILED DESCRIPTION OF THE INVENTION

He did

To the stock solution with 40 wt% glycerin, 30 wt% propylene glycol and 20 wt% water was added 10 wt% disodium salt of alkyl polyglycol ester sulfosuccinate (Rewopol SB CS 50 from REWO GmbH). The addition takes place with stirring, while ensuring good mixing. A clear lotion composition is formed which is applied to a four-layer, patterned, fine paper paper with a basis weight of 60 g / m ² and a 6% coating on the edges. After conditioning for 24 hours, the scarves, wipes or handkerchiefs are smoothed and subjected to a panel test against other samples in a row. The treated (lotioned) cosmetic product has always been classified as softer than the untreated (unrotated) sample, both smoothed and un smoothed.

····

44 ·· «4 4 4 * • 4 · 9 · 4 4 ··· ·· * • 4 4 ·

4 * «* 4 t · ··

Example 2

To the base solution (lotion) with 40 wt.% Glycerin, 30 wt.% Propylene glycol and 20 wt.% Water, 10 wt.% Coconut amidoalkyldimethylamine oxide, which is sold by Th. Goldschmidt AG under the designation Tegotain WS 35. The addition takes place with stirring, while ensuring good mixing. A clear lotion composition is formed which is applied to a 4-ply, edge-patterned cosmetic paper as described in Example 1 at 6% application. After 24-hour conditioning, the scarves or handkerchiefs are additionally smoothed and subjected to paneling. test against other samples in a row. The treated (lotion) cosmetic product is in any case cut off better than untreated, whether smoothed or not smoothed.

Example 3

To the base product (lotion) with 50 wt.% Propylene glycol, and 20 wt.% Water, 10 wt.% Of the amine oxides of Example 2 were added with mixing well. Then 20 wt% D-panthenol (BASF AG) was added. The addition is carried out with vigorous stirring to ensure good mixing. After formation of a uniform solution (lotion), this product is applied to a 4-ply, edge-patterned cosmetic paper as described in Example 1 at 6% deposition. After 24 hours conditioning, the scarf or cloth is cooled and then also subjected to panel tests. . Treated (lotion) cosmetic or tissue paper is again classified as superior to an untreated cosmetic product (not smoothed or smoothed).

9 9 9 9 999999 9 9 9 999999 9 9 9 999999

9

. 9 9999999 99 99

Example 4

To the stock solution containing 30 wt.% Glycerin, 20 wt.% Propylene glycol and 29.75 wt.% Water, 5.25 wt.% Amine oxides according to Example 2 were added with stirring. Then 15 wt.% Phytosterol was added ( Henkel KGaA). After good mixing, the solution was applied to a 4-ply, edge-patterned tissue paper as described in Example 1 at 6% deposition. After 24 hours conditioning and smoothing, the treated cosmetic product was always better classified in the panel test than the untreated product.

Example 5

To the stock solution with 46 wt.% Propylene glycol propylene and 20 wt.% Water, 2 wt.% Of the amine oxides of Example 2 as well as 2 wt.% Medialan ® LD and 3 wt.% Tocopherol acetate are added under stirring. pot. % of rice flower oil and 15% by weight of jojoba oil. After good mixing, the composition (lotion) is applied in a 6% coating onto the four-layered, edge-patterned cosmetic paper of Example 1. After 24 hours conditioning and cooling, the treated paper in the panel test was always better classified than the untreated product.

Example 6

Example 2 was repeated, but instead of amine oxides, 10 wt.% Rewoteric AM 2C NM alkylamfoacetate was added.

• 0 ························

Witco Reactants). In the otherwise similar treatment, a panel test was performed after application, conditioning and smoothing, which showed that the treated (lotioned) tissue was in any case cut better than the correspondingly untreated tissue.

R = C ₇ -C ₁₇ -fatty acid

Example 7

To the stock solution with 69 wt.% Propylene glycol and 20 wt.% Water, 10 wt.% Of the amine oxides of Example 2 were added and mixed well. Thereafter, 1 wt.% Of glycerin acid (Midas Pharma GmbH, Ingelheim) was added while heating to about 60 ° C with vigorous stirring. After dissolution and subsequent cooling to 20 ° C, the composition (lotion) at 6% application is applied to the four-layered, edge-patterned cosmetic paper of Example 1. After 24 hours conditioning and smoothing, the treated cosmetic product (cloth) was better in the panel test. classified as an untreated product.

• 44

4

4 4 4 4 4 4 4

Example 8

Example 2 was repeated except that 10 wt% trimethylglycine (WITCO) was added instead of amine oxide. Otherwise, the same experiment resulted in a clear lotion, which was applied in a 6% coating to the four-ply, edge-patterned, fine paper of Example 1. After 24 hours conditioning and smoothing, the treated tissue was classified better than untreated in a panel test. cloth or tissue.

Example 9

To the stock solution consisting of propylene glycol, glycerin and water (30:45:25 quantity ratio) was added 4% bentonite (Optigel® SH, Sed-Chemie AG). The viscosity of the treated lotion was increased to about 840 mPas to allow appropriate deposition by film presses. This solution was applied as a 6% solution on both sides by spraying, and a hand-held 77 value of ± 5 was found.

• »· o ··· fr · · · · · · · · · · ·

C. composition (lotion) Lotion composition Value HF N Zero sample, untreated (non-lotioned) 72 WITH Glycerin + propylene glycol (PG) poles + water = 45 + 30 + 25 76 Ex. 1 Rewopol SB CS 50 + glycerin + PG + water - 10 + 40 + 30 + 20 76 Ex. 2 Amine oxide WS3 5 + glycerin + PG + water = 10 + 40 + 30 + 20 77 Ex. 3 D-panthenol + WS amine oxide 35 + PG + water = 20 + 10 + 50 + 20 75 Ex. 4 Glycerin + PG + H ₂ O + WS 35 + Phytostyrol Generol® +122 E 25 (Henkel) = 30 + 20 + 29.75 + 5.25 + 15 78 Ex. 5 PG + H ₂ O + WS 35 + Medialan® LD + tocopher acetate + rice flower oil + j ojob oil = 46 + 20 + 2 + 2 + 3 + 12 + 15 76 Ex. 6 Rewoteric AM 2C NM + glycerin + PG + water = 10 + 40 + 30 + 20 76 Ex. 7 Glycyrrhitinic acid + amine oxide WS35 + PG + water = 1 + 10 + 69 + 20 75 Ex. 8 Trimethylglycine + glycerin + PG + water = 10 + 40 + 30 + 20 7 6 Ex. 9 Glycerin + PG + H ₂ O + bentonite = 45 + 30 + 25 + 4 77

* Dodecyl ~ dimethylamine oxide (Th. Goldschmidt AG)

.........

• 4 · 4 · 4 4 ₉ 4 · 444 9999 · »

Claims (27)

P A T Ε N T E C O R T E R T C A T Composition for fine fabric or paper products comprising moisture control agents, characterized in that it further comprises 1-2 5 wt%, preferably 2-2 0 wt%, based on the total composition, of at least one special nonionic surfactant ( surfactant) selected from at least one amine oxide and / or hydroxy acid esters and / or at least one amphoteric. F Composition according to claim 1, characterized in that said amine oxide has the general formula r ₂ i R, _n®-O® I R ₃ wherein Ri, R ₂ and R ₃ independently represent optionally substituted aliphatic linear or branched alkyl radical having 1 to 25 carbon atoms, optionally substituted cyclic alkyl residue with 3 to 22 carbon atoms, an optionally substituted aliphatic linear or branched • AA ⁴⁰ amidoalkyl radical having 3 to 22 carbon atoms in the alkyl group or an optionally substituted cyclic amidoalkyl moiety having 3 to 10 carbon atoms in the alkyl moiety. Composition according to claim 2, characterized in that the amine oxide has the general formula (I) in which R 1 and R ₂ represent an optionally substituted C 1 -C 4 alkyl group, preferably methyl, and R ₃ is an amidoalkyl radical of formula (CH) ₂ ) ₃ N (H) C (O) R, (II) wherein a is 1 to 5 and R. _t is a fatty acid residue derived from natural oils and fats having 7 to 25 carbon atoms, preferably 7 to 17 C -atomy. Composition according to claim 1, characterized in that the hydroxyalkyl ester is a (semi) ester of a fruit acid, a lactic acid ester, a ricinoleic acid ester or a gluconic acid ester, preferably a mono-, di- or triester of citric acid, containing at least one fatty acid residue derived from natural oils and fats and having 1 to 25 carbon atoms, preferably 7 to 17 carbon atoms, optionally further comprising a single polar group. The composition of claim 1, wherein the amphoteric is an ampholyte or betaine. Composition according to claim 5, characterized in that said betaine is derived from natural or synthetic sources and is selected from alkyl betaines of the general formula 9 9 9999 · 9 9 · 9 9 99999 9 9 9 9 99999999 9 9 9 9 9 999 9 9999999 9 · 99 R ₅ (CH ₃ ) N ⁺ (CH ₃ ) CH ₂ COO- (III) wherein R ₅ represents an optionally substituted linear or branched alkyl group having 1 to 25 carbon atoms, alkylamidobetaines of the general formula R ₆ (CO) NH (CH ₂ ) ₀ (CH ₃ ) N ⁺ (CH ₃ ) CH ₂ COO '(IV) wherein R ₆ is an optionally substituted linear or branched alkyl group having 1 to 25 C-atoms, and ₀ is equal to 1 to 5, sulfobetaines of the general formula R ₈ (CH ₃ ) N ⁺ (CH ₃ ) -X-SO ₃ '(V) wherein R ₈ represents an optionally substituted linear or branched alkyl group having 1 to 25 C-atoms and X an optionally substituted alkylene group having 1 to 5 methyl units , alkyl polyamphopolycarboxyglycinates of formula n (XI) 42 • · · · · • · * • · • · · • · • · · · • ·· ·· ·· • · · · · · · · · • · · · · · • 9 · ··· • · · · ····· · · · »·· wherein R ₂₈ is C ₇ -C, ₇ -mastnou acid and n is e or 2 3, or glycinesters with general pattern Η Ο I II / ^Ν \ z ^C \ H ₃ c CH ₂ ο - _R29 (XII) where R ₂₉ is C ₇ -C ₁₇ -alkyl, preferably C ₁₂ H _2j. Composition according to the preceding claims, characterized in that the moisture regulator is present in an amount of 40 to 90% by weight, preferably 50 to 80% by weight, based on the total composition, and is selected in particular from polyols. Composition according to the preceding claims, characterized in that said polyol is selected from glycerin, propylene glycol, butylene glycol, polyalkylene glycol and sugar alcohols. Composition according to the preceding claims, characterized in that it further comprises 0.01 to 50% by weight, preferably 0.1 to 40% by weight, of at least one natural, naturally identical or synthetic cosmetic composition, preferably on a natural vegetable basis . Composition according to the preceding claims, characterized in that it further comprises customary auxiliaries and additives, such as 4 · 4 · 4 · 4 · 4 4 Non-ionic and / or cationic surfactants, inorganic and / or organic fillers, dyes and / or natural or synthetic gelling agents. Composition according to the preceding claims, characterized in that it has a pH of from 3 to 8, preferably from 3.5 to 5. Composition according to the preceding claims, characterized in that they have a viscosity of from 1 mPas to 700 mPas, preferably from 5 mPas to 600 mPas, when applied at a temperature of from 10 to 90 ° C, by spraying or by paddling. a viscosity of from 5 mPas to 2000 mPas, preferably 10 mPas to 2000 mPas. Composition according to the preceding claims, comprising 30 to 90 wt.%, Preferably 50 to 80 wt.%, At least one moisture regulator, 0 to 20 wt.%, Preferably 2 to 10 wt.%, At least one nonionic and / or cationic. surfactant (surfactant), 1 to 25 wt.%, preferably 2 to 20 wt.%, of at least one special surfactant selected from amine oxide and / or hydroxy acid esters and at least one amphoteric surfactant, 0.01 to 40 wt.%, preferably 0.01 to 20 wt.%, at least one cosmetic composition, 0 to 70 wt.%, preferably 0 to 40 wt.%, at least one gelling agent, and water as a residue. Method for producing fine fabric or paper products, characterized in that the composition according to claims 1 to 13 is applied continuously or in a continuous manner to the fibrous web or fabric path within the screen portion, the press portion, the TAD portion, on a large Yankee rollers and / or inside the dry portion; at density 9 9 9 9 9 · · 9 9 9 9 9 9 9 9 · 9 9 9 9 • 9 99999 9 9 9 9 99999999 9 9 9 9 9 999 9 999 9999 99 99 pulp from 20 to 97%, based on the dry weight of the fibers of a given pathway, in an amount of 0.1 to 50 wt%, preferably 0.2 to 50 wt%, on or in the pathway and pathway eventually undergo additional smoothing after application. Method for producing fine fabric or paper products, characterized in that the composition according to claims 1 to 13 is applied continuously or discontinuously to a fibrous web (web) or a fine fabric path behind the dry part on a webbing machine, back machine and / or processing machine. from 0.1 to 40 wt.%, preferably from 1 to 20 wt.%, on or in a given lane, and optionally the lane is subjected to appropriate smoothing after application. Method according to claim 15, characterized in that the composition is applied in an amount of from 0.2 to 50%, preferably from 1 to 20%, at a fiber density of from 35 to 97%, based on the dry weight of the fiber-forming material of the monolayer path. Method according to claims 14 to 16, characterized in that the fabric path is a multilayer path and the composition is applied to at least one outer layer of the multilayer path at a density of more than 90% by weight of the fibrous fabric, 0.001 to 50%, preferably 0.01 to 30%. Method according to claim 17, characterized in that said composition is applied to the multilayer pathway in an amount of from 0.001 to 50%, preferably from 0.01 to 30%. Method according to claims 14 to 18, characterized in that the application of at least one part of the composition on the given path takes place by spraying, rolling, by means of painting knives 444 4 44 44 443 4 4 44 4 4 4 4 44444 4 4 4 44444444 4 4 4 4 4 5 444 4444 4444 44 44 or in a paddle-like manner, or in and on a given pathway by microencapsulation, embedded in microtampons or in the form of liposomes, in particular as a cosmetic composition. Method according to claims 14 to 19, characterized in that the post-smoothing, except for the method according to claim 19, of the last alternative, is carried out by at least one passage of the fabric or nonwoven path through the nip between the rolls, the steel surface roll being associated with a steel, plastic, paper or rubber or rubber surface, preferably with a plastic surface. Method according to claims 14 to 19, characterized in that the smoothing, except for the method according to claim 19, of the last alternative, takes place through a double passage of the web or nonwoven through a nip between the rollers. surface and then the mirror cylinder with the plastic surface is assigned to the counter surface with the steel surface. Method according to claims 14 to 21, characterized in that the deposition of the composition on the fibrous web takes place in the context of a conventional method for producing the respective fabric. Method according to claims 14 to 21, characterized in that the application of the composition to the fibrous web is carried out by means of a flow-drying (TAD method) or by a nonwoven material non-woven process. Use of the composition according to claims 1 to 13, in particular in the form of a solution or lotion for processing or treating tissue paper products, in particular handkerchiefs, 99 9 9 99 99 99 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 999 999 9 9 9 9 9 Cosmetic wipes, dispensing shampoos, toilet paper and kitchen towels, in particular according to claims 14 to 23. 25. Fine woven or paper fabrics in the form of wet laid, including TAD and / or pneumatic dry laid or nonwoven based on predominantly cellulose-containing, planar, at least monolayer support materials, characterized in that they further contain 5 to 20 wt. %, preferably 7 to 13 wt.%, based on the total product, of at least one special nonionic surfactant (surfactant) selected from amine oxides and / or esters of hydroxycarbonate and / or at least one amphoteric surfactant. The fabric or paper product of claim 25, further comprising a composition according to claims 1 to 13 on at least one portion of its surface, on its outer sides, on the inner sides of the outer layers, on the inner layers only or on all layers. . The tissue or paper product of claims 25 and 26, wherein there is at least one portion of said composition of claims 1 to 13 as a deposit, λ / microencapsulated form, embedded in microtampons or in the form of liposomes on / in said layers, and preferably at least one portion of the cosmetic composition of claim 15 in microencapsulated form, embedded in microtampons or in the form of liposomes on / in said layers.