CZ309869B6 - A device for variable application of printing powder - Google Patents
A device for variable application of printing powder Download PDFInfo
- Publication number
- CZ309869B6 CZ309869B6 CZ2022-541A CZ2022541A CZ309869B6 CZ 309869 B6 CZ309869 B6 CZ 309869B6 CZ 2022541 A CZ2022541 A CZ 2022541A CZ 309869 B6 CZ309869 B6 CZ 309869B6
- Authority
- CZ
- Czechia
- Prior art keywords
- plate
- powder
- printing
- block
- removal
- Prior art date
Links
- 239000000843 powder Substances 0.000 title claims abstract description 53
- 238000007639 printing Methods 0.000 title claims abstract description 48
- 230000017525 heat dissipation Effects 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 238000005192 partition Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 description 5
- 238000010146 3D printing Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C19/00—Apparatus specially adapted for applying particulate materials to surfaces
- B05C19/06—Storage, supply or control of the application of particulate material; Recovery of excess particulate material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/10—Auxiliary heating means
- B22F12/17—Auxiliary heating means to heat the build chamber or platform
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/20—Cooling means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
- B29C64/205—Means for applying layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
- B29C64/227—Driving means
- B29C64/232—Driving means for motion along the axis orthogonal to the plane of a layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
- B29C64/295—Heating elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Printing Plates And Materials Therefor (AREA)
Abstract
Description
Zařízení pro variabilní nanášení tiskového práškuDevice for variable application of printing powder
Oblast technikyField of technology
Technickým řešením je zařízení pro variabilní nanášení tiskového prášku sestávající z nanášecího pravítka, umístěného v nanášecím rameni, zásobníku prášku a desky pro odvod prášku, kdy mezi zásobník prášku a desku pro odvod prášku je včleněna tisková platforma uložená v rámu zařízení.The technical solution is a device for variable application of printing powder consisting of an application ruler located in the application arm, a powder container and a powder removal plate, where a printing platform stored in the device frame is incorporated between the powder container and the powder removal plate.
Dosavadní stav technikyCurrent state of the art
Při aditivní výrobě kovových součástí metodou DMLS dochází k nanášení vrstvy tiskového prášku pomocí nanášecího elementu, který je umístěn do nanášecího ramene. Prášek je nanášen na celou plochu desky pro tisk tiskové platformy, což znamená, že určitá jeho část zůstane nevyužitá, a navíc vzhledem ke kontaminaci ztrácí požadované vlastnosti. Pokud se má tento prášek využít pro další tisk, tak musí projít další úpravou, jako je prosévání nebo čištění, což celý tento proces prodražuje. Ze stavu techniky je známo řešení, kdy je tisková platforma konstruována tak, aby bylo možné co nejjednodušeji zmenšit její pracovní prostor a použít menší objem prášku při tisku. V procesu, kdy se provádí tisk na malou tiskovou platformu, se velká platforma nahrazuje tzv. redukčním rámečkem, který je určen k vyplnění nevyužitého prostoru platformy. Vyjmutím redukčního rámečku a pístu, na kterém je umístěna zmenšená deska pro tisk. Nevýhodou tohoto řešení ovšem je, že se prášek nanáší po celé desce tiskové platformy, a tudíž část prášku spadá do odpadního zásobníku. Tuto nevýhodu vykazuje i řešení, kdy je prášek ze zásobního válce nanášen pomocí stěrače na stavební paletu, nevyužitý prášek opět putuje do přepadové nádrže. Eliminace plýtvání tiskového prášku je prováděna tak, že se kovový prášek nenahrne do prostoru desky pro tisk přes celou délku komory, ale jen poměrově méně. Šířka nanesení prášku podél nanášeče zůstává stejná. Ze stavu techniky je rovněž známo zařízení s pohyblivou tiskovou platformou popsané v US 2018065321 A1.During the additive manufacturing of metal parts using the DMLS method, a layer of printing powder is applied using an application element that is placed in the application arm. The powder is applied to the entire surface of the plate for printing the printing platform, which means that a certain part of it remains unused, and moreover, due to contamination, it loses the desired properties. If this powder is to be used for further printing, it must undergo further treatment, such as sieving or cleaning, which makes the whole process more expensive. A solution is known from the state of the art, where the printing platform is constructed in such a way that it is possible to reduce its working space as simply as possible and to use a smaller volume of powder during printing. In the process of printing on a small printing platform, the large platform is replaced by a so-called reduction frame, which is designed to fill the unused space of the platform. By removing the reduction frame and piston on which the reduced printing plate is placed. However, the disadvantage of this solution is that the powder is applied over the entire plate of the printing platform, and therefore part of the powder falls into the waste container. This disadvantage is also shown by the solution where the powder from the storage cylinder is applied to the building pallet using a wiper, the unused powder goes back into the overflow tank. The elimination of the waste of printing powder is carried out in such a way that the metal powder does not accumulate in the space of the plate for printing over the entire length of the chamber, but only proportionally less. The width of the powder application along the applicator remains the same. A device with a movable printing platform described in US 2018065321 A1 is also known from the state of the art.
Podstata vynálezuThe essence of the invention
Vynálezem je zařízení pro variabilní nanášení tiskového prášku sestávající z nanášecího pravítka, umístěného v rameni, zásobníku prášku a desky pro odvod prášku, kdy mezi zásobník prášku a desku pro odvod prášku je včleněna tisková platforma, která je uložena v rámu. Tisková platforma obsahuje základní desku, na které je uložen blok pro odvod tepla, ke kterému shora přiléhá deska pro tisk, kdy plocha základní desky je větší než plocha bloku pro odvod tepla, přičemž k bloku přiléhá rozpínací mechanismus, který je shora opatřen deskou, která výškově nepřesahuje desku pro odvod prášku.The invention is a device for variable application of printing powder consisting of an application ruler located in the arm, a powder container and a powder removal plate, where a printing platform is incorporated between the powder container and the powder removal plate, which is stored in the frame. The printing platform includes a base plate on which a heat sink block is placed, to which a printing plate adjoins from above, where the area of the base plate is greater than the area of the heat sink block, and an expansion mechanism adjoins the block, which is provided with a plate from above it does not exceed the powder discharge plate in height.
Výhodné je, pokud je blok pro odvod tepla směrem k desce opatřen výstupky, mezi které jsou vloženy akumulátory mechanické energie, přičemž akumulátory mechanické energie jsou zvnějšku opásány těsněním. Tím je zajištěna potřebná izolace zařízení a je zamezeno vniknutí nanášeného prášku do prostoru základní desky.It is advantageous if the block for heat removal towards the plate is provided with protrusions between which the mechanical energy accumulators are inserted, the mechanical energy accumulators being surrounded by a seal on the outside. This ensures the necessary insulation of the device and prevents the intrusion of applied powder into the area of the base plate.
Pro vymezení pracovního prostoru mezi rozpínacím mechanismem a blokem pro odvod tepla a deskou pro tisk je včleněna přepážka.A partition is incorporated to define the working space between the expansion mechanism and the block for heat dissipation and the printing plate.
Mezi blok pro odvod tepla a desku pro tisk je včleněn kovový kryt. Nejčastěji se nabízí alternativa s kovovým plechovým krytem vzhledem k jeho tloušťce. Důvodem je zvýšení bezpečnosti zařízení při potenciální manipulaci s deskou pro tisk, její výměnu za jinou s ohledem na procesní parametry 3D tisku či při rutinní údržbě zařízení.A metal cover is incorporated between the heat dissipation block and the printing plate. The alternative with a metal sheet cover is most often offered due to its thickness. The reason is to increase the safety of the device during potential handling of the printing plate, its replacement with another one with regard to the process parameters of 3D printing or during routine maintenance of the device.
Zásobník prášku je vertikálně přestavitelný, což umožňuje alternativní nanášení tiskového práškuThe powder magazine is vertically adjustable, which enables alternative application of printing powder
- 1 CZ 309869 B6 o variabilním množství s ohledem na procesní parametry 3D tisku.- 1 CZ 309869 B6 about variable quantity with regard to process parameters of 3D printing.
Rovněž je výhodné, pokud je deska pro odvod prášku vertikálně přestavitelná z důvodu usnadnění manipulace s odpadním práškem.It is also advantageous if the powder discharge plate is vertically adjustable to facilitate the handling of waste powder.
Přepažením pracovního prostoru tiskové platformy dochází k možnosti implementace různého množství desek pro tisk, je však samozřejmě požadováno, aby desky pro tisk byly snadno vyměnitelné.By partitioning the working space of the printing platform, it is possible to implement a different number of printing plates, but of course it is required that the printing plates are easily replaceable.
Objasnění výkresůClarification of drawings
Na obr. 1 a na obr. 2 je znázorněn izometrický pohled na zařízení pro variabilní nanášení tiskového prášku. Na obr. 3 je znázorněn pohled na základní desku. Na obr. 4 je znázorněn pohled na desku pro tisk. Na obr. 5 je znázorněn blok pro odvod tepla. Na obr. 6 je znázorněn pohled na kryt bloku pro odvod tepla. Na obr. 7 a na obr. 8 je znázorněn izometrický pohled na tiskovou platformu.Fig. 1 and Fig. 2 show an isometric view of a device for variable application of printing powder. Fig. 3 shows a view of the base plate. Fig. 4 shows a view of the printing plate. Fig. 5 shows the block for heat dissipation. Fig. 6 shows a view of the block cover for heat dissipation. Fig. 7 and Fig. 8 show an isometric view of the printing platform.
Příklad uskutečnění vynálezuAn example of the implementation of the invention
Zařízení pro variabilní nanášení tiskového prášku sestává z nanášecího pravítka N, které je umístěno do nanášecího ramene Rý. Součástí zařízení je dále zásobník Z prášku a deska O pro odvod prášku. Mezi zásobník Z prášku a desku O pro odvod prášku je včleněna tisková platforma P. Tisková platforma P je uložena v opláštěném rámu R zařízení. Tisková platforma P sestává ze základní desky 1, na které je uložen hliníkový blok B pro odvod tepla. Na základní desku 1 jsou natištěny ustavovací elementy pro přesnou pozici bloku B pro odvod tepla. K bloku B pro odvod tepla shora přiléhá deska D, na kterou je realizován 3D tisk. Blok B pro odvod tepla je směrem k desce D opatřen po obvodu výstupky V. V hliníkovém bloku jsou vyfrézovány otvory pro ustavení na základní platformě a po obvodu je vyfrézovaná drážka pro těsnění a drážky pro inbus k upínání k základní desce 1 pro případné dotažení upnutí k základní desce 1. Mezi výstupky V jsou vloženy akumulátory A mechanické energie v podobě pružin, přičemž ty jsou zvnějšku opásány pryžovým těsněním T. Plocha S1 základní desky 1 je větší než plocha S2 bloku B pro odvod tepla, čímž je vytvořen nevyužitý pracovní prostor. K bloku B pro odvod tepla tudíž přiléhá rozpínací mechanismus r na principu heveru. Rozpínací mechanismus je shora opatřen deskou 3. Konce rozpínacích ramen rozpínacího mechanismu r jsou opatřeny vložkami Vý, aby nedocházelo k otlačení nebo poničení pracovní stěny rámu zařízení. Deska 3 výškově nepřesahuje desku O pro odvod prášku, aby nedocházelo při přejíždění nanášecího pravítka N k zadrhávání či úplnému zaseknutí. Mezi rozpínacím mechanismem r a blokem B pro odvod tepla, ke kterému shora přiléhá deska D pro tisk, je včleněna přepážka Pý. Přepážka Pý výškově nepřesahuje desku D. Přepážka Pý je smontována pomocí jednoduchých šroubových spojení, které jsou snadno demontovatelné a lze tak jednotlivé části relativně rychle upravit či zcela vyměnit. Mezi blok B pro odvod tepla a desku D je zároveň včleněn kovový kryt K. Zásobník Z prášku je vertikálně přestavitelný. Deska O pro odvod prášku je rovněž vertikálně přestavitelná. Deska D pro tisk je vyměnitelná.The device for variable application of printing powder consists of an application ruler N, which is placed in the application arm Rý. The device also includes a powder container Z and a plate O for powder removal. A printing platform P is incorporated between the powder container Z and the powder discharge plate O. The printing platform P is housed in the sheathed frame R of the device. The printing platform P consists of a base plate 1 on which an aluminum block B is placed for heat dissipation. Setting elements for the exact position of block B for heat dissipation are printed on base plate 1. Plate D, on which 3D printing is carried out, is adjacent to block B for heat removal from above. Block B for heat dissipation is provided with protrusions V around the perimeter towards the plate D. Holes are milled in the aluminum block for setting on the base platform, and there is a groove milled around the perimeter for a seal and grooves for an allen key to clamp to the base plate 1 for possible tightening of the clamp to base plate 1. Accumulators A of mechanical energy in the form of springs are inserted between the protrusions V, while these are surrounded from the outside by a rubber seal T. The area S1 of the base plate 1 is larger than the area S2 of block B for heat dissipation, which creates an unused working space. Therefore, the expansion mechanism r on the hever principle is attached to block B for heat removal. The expansion mechanism is equipped with a plate 3 from above. The ends of the expansion arms of the expansion mechanism r are equipped with inserts Vy, so that the working wall of the device frame is not crushed or damaged. The height of the plate 3 does not exceed the plate O for the discharge of the powder, so that there is no tripping or complete jamming when passing the application ruler N. Between the expansion mechanism r and the block B for heat removal, to which the plate D for printing adjoins from above, a partition Pý is incorporated. The height of the partition Pý does not exceed the plate D. The partition Pý is assembled using simple screw connections, which are easily dismantled and the individual parts can thus be modified or completely replaced relatively quickly. At the same time, a metal cover K is incorporated between block B for heat dissipation and plate D. The powder container Z is vertically adjustable. The powder discharge plate O is also vertically adjustable. The printing plate D is replaceable.
Průmyslová využitelnostIndustrial applicability
Zařízení je využitelné zejména v konstrukci 3D tiskáren pro variabilní tisk součástí z tiskového prášku.The device can be used especially in the construction of 3D printers for variable printing of components from printing powder.
Claims (6)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CZ2022-541A CZ2022541A3 (en) | 2022-12-20 | 2022-12-20 | A device for variable application of printing powder |
PCT/CZ2022/000052 WO2024132000A1 (en) | 2022-12-20 | 2022-12-27 | Device for variable application of printing powder |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CZ2022-541A CZ2022541A3 (en) | 2022-12-20 | 2022-12-20 | A device for variable application of printing powder |
Publications (2)
Publication Number | Publication Date |
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CZ309869B6 true CZ309869B6 (en) | 2023-12-27 |
CZ2022541A3 CZ2022541A3 (en) | 2023-12-27 |
Family
ID=89321386
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CZ2022-541A CZ2022541A3 (en) | 2022-12-20 | 2022-12-20 | A device for variable application of printing powder |
Country Status (2)
Country | Link |
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CZ (1) | CZ2022541A3 (en) |
WO (1) | WO2024132000A1 (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180236557A1 (en) * | 2017-02-22 | 2018-08-23 | General Electric Company | Method of manufacturing turbine airfoil and tip component thereof |
US20180236549A1 (en) * | 2017-02-21 | 2018-08-23 | General Electric Company | Additive manufacturing using a recoater with in situ exchangeable recoater blades |
DE102020106516A1 (en) * | 2020-03-10 | 2021-09-16 | Universität Paderborn | Sensor-integrated manufacturing system for additive manufacturing |
EP3912816A1 (en) * | 2020-05-18 | 2021-11-24 | Daido Steel Co., Ltd. | Metal powder |
WO2022134250A1 (en) * | 2020-12-24 | 2022-06-30 | 华中科技大学 | Rapid ultra-high temperature heating device of 3d printing powder bed |
EP4052905A1 (en) * | 2021-03-05 | 2022-09-07 | Ricoh Company, Ltd. | Object forming liquid and object producing method |
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2022
- 2022-12-20 CZ CZ2022-541A patent/CZ2022541A3/en unknown
- 2022-12-27 WO PCT/CZ2022/000052 patent/WO2024132000A1/en unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180236549A1 (en) * | 2017-02-21 | 2018-08-23 | General Electric Company | Additive manufacturing using a recoater with in situ exchangeable recoater blades |
US20180236557A1 (en) * | 2017-02-22 | 2018-08-23 | General Electric Company | Method of manufacturing turbine airfoil and tip component thereof |
DE102020106516A1 (en) * | 2020-03-10 | 2021-09-16 | Universität Paderborn | Sensor-integrated manufacturing system for additive manufacturing |
EP3912816A1 (en) * | 2020-05-18 | 2021-11-24 | Daido Steel Co., Ltd. | Metal powder |
WO2022134250A1 (en) * | 2020-12-24 | 2022-06-30 | 华中科技大学 | Rapid ultra-high temperature heating device of 3d printing powder bed |
EP4052905A1 (en) * | 2021-03-05 | 2022-09-07 | Ricoh Company, Ltd. | Object forming liquid and object producing method |
Also Published As
Publication number | Publication date |
---|---|
WO2024132000A1 (en) | 2024-06-27 |
CZ2022541A3 (en) | 2023-12-27 |
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