CZ278280B6 - Self-hardening suspension - Google Patents

Self-hardening suspension Download PDF

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Publication number
CZ278280B6
CZ278280B6 CS519788A CZ278280B6 CZ 278280 B6 CZ278280 B6 CZ 278280B6 CS 519788 A CS519788 A CS 519788A CZ 278280 B6 CZ278280 B6 CZ 278280B6
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Czechia
Prior art keywords
self
cement
suspension
per cent
weight
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Czech (cs)
Inventor
Marian Ing Racek
Dusan Ing Valenta
Helena Patajova
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Hydrostav
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Priority to CS519788 priority Critical patent/CZ278280B6/en
Priority to SK519788A priority patent/SK277780B6/en
Publication of CS8805197A2 publication Critical patent/CS8805197A2/en
Publication of CZ278280B6 publication Critical patent/CZ278280B6/en

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Abstract

Self-hardening suspension consists of 0,9 to 30,0 per cent weight of cement, 1,5 to 20,0 per cent weight of puzzolane- -siliceous additive with minimum contains of silicon dioxide 80 per cent of weight, 50 to 89,3 per cent weight of bentonite suspension and 0,2 to 2,0 per cent of weight of plasticizing and and retardation additives with advantage on base of alkaline salts of lignosulfonate and sulfonated condensators of monovalent and polyvalent aromatic alcohols.

Description

Vynález sa týká samotvrdnúcej suspenzie používanej v inžinierskom stavitelstve pri budovaní podzemných střen a prvkov.The invention relates to a self-curing suspension used in civil engineering for building underground roofs and elements.

Doteraz používané samotvrdnúce suspenzie sú zložené prevažne z cementového spojiva, ílovej suspenzie a chemických přísad, ktorými sa reguluje najma retardácia, stabilita a reologické vlastnosti suspenzie v tekutom stave. Samotvrdnúce suspenzie sa využívajú najma pri výrobě tesniacich podzemných stien, ktorými sa dosahuje zníženie priesakov vody do stavebných jám álébo prerušenie priepustných vrstiev v zemine. Ako hydraulické spojivo sa v samotvrdnúcich suspenziách používájú obyčajne cementy, najma troskoportlandské, připadne doplněné dalšími zložkami ako napr. popolčekom, hydraulickým vápnom, troskou a podobné. Nevýhodou samotvrdnúcich suspenzií s čisto cementovým spojivom je skutočnost, že v agresívnom prostředí majú zníženú životnost réspektívne sa nemóžu vóbec použit. Pre dosiahnutie najma vyšších pevností sú potřebné poměrně vysoké dávky cementu, čo obyčajne stažuje retardáciu tuhnutia suspenzie a zvyšuje abrazívnost pro- n stredia pre mechanické časti hlbiacich zariadení. Použitie hydraulického vápna ako doplnkovného spojiva k cementu sice zvyšuje pevnosti ale zároveň znižuje odolnost voči agresívnemu I prostrediu. Samotvrdnúce suspenzie s popolčekom a mletou troskou sú vhodné do niektorých typov agresívneho prostredia. Ich nevýhodou je velká variabilita zloženina týchto přísad a ich nedostupnost v požadovanej rovnomernej kvalitě a v případe popolčeku tiež potřeba vysokých dávok na dosiahnutie požadovaných mechanických vlastností. V niektorých prípadoch použitia doteraz známých samotvrdnúcich suspenzií je nevýhodná dlhá doba tvrdnutia pre dosiahnutie predpísaných mechanických vlastností, ktorá bývá 2-5 mesiacov.The self-setting suspensions hitherto used consist mainly of a cement binder, a clay suspension and chemical additives which regulate in particular the retardation, stability and rheological properties of the suspension in the liquid state. Self-hardening suspensions are used, in particular, in the manufacture of sealing underground walls, which achieve a reduction in water leakage into pits or interruption of permeable layers in the soil. As hydraulic binder in self-hardening suspensions, usually cements are used, in particular troscortland, optionally supplemented with other components such as fly ash, hydraulic lime, slag and the like. A disadvantage of self-hardening suspensions with a purely cementitious binder is that in an aggressive environment they have a reduced service life and cannot be used at all. To achieve a particularly high strength are required, relatively high doses of cement, which usually makes it difficult to retard the solidification of the slurry and increasing the abrasivity pro- n centrifugated for mechanical parts hlbiacich device. The use of hydraulic lime as an additional cement binder increases strength but at the same time reduces resistance to aggressive environments. Self-curing suspensions with ash and ground slag are suitable for some types of aggressive environments. Their disadvantage is the high variability of the composition of these additives and their unavailability in the required uniform quality and, in the case of fly ash, also the need for high doses to achieve the desired mechanical properties. In some cases, the use of hitherto known self-curing suspensions is disadvantageous for a long cure time to achieve the prescribed mechanical properties, which is 2-5 months.

Vyššie uvedené nedostatky rieši vynález, ktorého podstatou je, že samotvrdnúca suspenzia pozostáva z 9,0 - 30,0 % hmotn. cementu, 1,5 - 20,0 % hmot, puzzolánovej kremičitej přísady s výhodou Si-úletu alebo Siloxidu s minimálnym obsahom oxidu křemičitého 80,0 % hmotn., 50,0 - 89,3 % hmotn. bentonitovej suspenzie a 0,2 - 2,0 % hmotn. plastifikačných a retardačných přísad s výhodou na báze alkalických solí lignosulfonanov a sulfonovaných kondenzátov jedno a viacmocných aromatických alkoholov. 1 Samotvrdnúca suspenzia podlá vynálezu má vhodné reologické vlastnosti pre paženie hlbených rýh a reguláciou dávkovania jednotli- », vých materiálových zložiek sa dosahuje požadovaná doba retardácie, vyššie pevnosti po zatvrdnutí, kratšia doba tvrdnutia a vyššia odolnost voči posobeniu agresívnych vod v porovnaní s doteraz známými samotvrdnúcimi suspenziami. Ako puzzolánovú kremičitú přísadu možno s výhodou použit odpad z výroby ferosilícia Si-úlet alebo odpad z výroby křemíku Siloxid, ktoré obsahujú minimálně 80,0% oxidu křemičitého. Ako plastifikačné a retardačně přísady sa móžu použit přísady na báze alkalických solí lignosulfonanov v praxi známe pod obchodným označením Ligoplast resp. Plastifikátor S a přísady na báze sulfonovaných kondenzátov jedno a viacmocných aromatických alkoholov (Ralentol). Ako cementová zložka samotvrdnúcej suspenzie podlá vynálezu sa používá s výhodou portlandský a troskoportlandský cement. Postupom podlá vynálezu sa šetří významné množstvo energeticky náročného cementu.The above-mentioned drawbacks are solved by the invention, which is based on the fact that the self-hardening suspension consists of 9.0-30.0% by weight. cement, 1.5 - 20.0 wt.%, a puzzolane silica additive, preferably Si-drift or siloxide having a minimum silica content of 80.0 wt.%, 50.0 - 89.3 wt. % bentonite suspension and 0.2-2.0 wt. plasticizers and retardants, preferably based on alkali salts of lignosulfonates and sulfonated condensates of mono- and polyhydric aromatic alcohols. The self-curing suspension according to the invention has suitable rheological properties for deep-groove sheeting and by controlling the dosage of the individual material components the desired retardation time, higher hardness after curing, shorter curing time and higher resistance to aggressive water resistance are achieved compared to previously known self-curing suspensions. As a puzzolane siliceous additive, it is advantageous to use wastes from the production of ferro-silicon Si-drift or wastes from the production of silicon silicon containing at least 80.0% of silica. As plasticizing and retarding additives, alkali metal salts of lignosulfonates, known in practice under the trade names Ligoplast, respectively, can be used. Plasticizer S and additives based on sulfonated condensates of monovalent and polyvalent aromatic alcohols (Ralentol). Portland cement and troscortortland cement are preferably used as the cement component of the self-curing suspension according to the invention. The process of the invention saves a significant amount of energy-intensive cement.

-1CZ 278280 B6-1GB 278280 B6

Příklad použitia č. 1Application example 1

Samotvrdnúca suspenzia podlá vynálezu na 1 m3:Self-hardening suspension according to the invention per 1 m 3 :

100 kg cement PC 400 kg Si-úlet alebo Siloxid100 kg cement PC 400 kg Si-drift or siloxide

905 1 bentonitová suspenzia905 1 bentonite suspension

1 Ligoplast .1 Ralentol1 Ligoplast .1 Ralentol

Zatvrdnutá suspenzia má po 1 mesiaci tvrdnutia pevnost v prostom tlaku 0,14 MPa a koeficient filtrácie k = 5.10”9 ms“1. Rovnaké parametre sa dosiahnu pri použití cementovej samotvrdnúcej suspenzie o zložení na 1 m3:After 1 month of curing, the hardened suspension has a simple compressive strength of 0.14 MPa and a filtration coefficient k = 5.10 ” 9 ms“ 1 . The same parameters are achieved when using a cement self-hardening slurry with a composition of 1 m 3 :

250 kg cement PC 400250 kg cement PC 400

905 1 bentonitová suspenzia905 1 bentonite suspension

1 Ligoplast1 Ligoplast

1 Ralentol1 Ralentol

Z porovnania vyplývá, že postupom podlá vynálezu sa ušetří 150 kg cementu na 1 m3 samotvrdnúcej suspenzie.The comparison shows that the process according to the invention saves 150 kg of cement per m 3 of self-hardening suspension.

Příklad použitia č. 2Application example 2

Samotvrdnúca suspenzia podlá vynálezu na 1 m3:Self-hardening suspension according to the invention per 1 m 3 :

200 kg cement PC 400200 kg cement PC 400

100 kg Si-úlet alebo Siloxid100 kg Si-drift or Siloxide

885 1 bentonitová suspenzia885 1 bentonite suspension

1 Ligoplast1 Ligoplast

1 Ralentol1 Ralentol

Zatvrdnutá suspenzia má po 1 mesiaci tvrdnutia pevnost v prostom tlaku 1,6 MPa a koeficient filtrácie k = 3.10 ms . Rovnaké parametre sa dosiahnu pri použití cementovej samotvrdnú» cej suspenzie o zložení na 1 m3:After 1 month of curing the hardened suspension has a simple compressive strength of 1.6 MPa and a filtration coefficient k = 3.10 ms. The same parameters are achieved when using a cement self-hardening slurry with a composition per 1 m 3 :

450 kg cement PC 400450 kg cement PC 400

820 1 bentonitová suspenzia820 1 bentonite suspension

1 Ligoplast1 Ligoplast

1 Ralentol1 Ralentol

Z porovnania vyplývá, že postupom podlá vynálezu sa šetří 250 kg cementu ná 1 m3 samotvrdnúcej suspenzie.The comparison shows that the process according to the invention saves 250 kg of cement per 1 m 3 of self-hardening suspension.

Změnou poměru miešania jednotlivých materiálových zložiek samotvrdnúcej suspenzie podlá vynálezu možno dosahovat rožne fyzikálnomechanické vlastnosti zatvrdnutej suspenzie pri značných úsporách cementu. Výplň podzemněj steny vytvořená podlá vynálezu má zároveň vyššiu odolnost voči agresívnemu pósobeniu podzemných vod. Predmet vynálezu je možné využit aj pre přípravu injekčných zmesí, kde sa dosahuje lepšia prenikacia účinnost v porovnaní s cementovými respektívne ílocementovými injekčnými zmesami.By varying the mixing ratio of the individual material components of the self-curing suspension according to the invention, the various physical-mechanical properties of the cured suspension can be achieved with considerable cement savings. At the same time, the underground wall filler according to the invention has a higher resistance to aggressive action of groundwater. The present invention can also be used for the preparation of injectable compositions, where a better penetration efficiency is achieved compared to cement or cement-based injectable compositions.

-2CZ 278280 B6-2GB 278280 B6

Claims (1)

PATENTOVÉ NÁROKYPATENT CLAIMS Samotvrdnúca suspenzia vyznačená tým, že pozostáva z 9,0 - 30,0 hmotn. cementu, 1,5 - 20,0 % hmotn. puzzolánovej kremičitej přísady s výhodou Si-úletu alebo Siloxidu s minimálnym obsahom oxidu křemičitého 80 % hmotn., 50,0 - 89,3 % hmotn. bentonitovej suspenzie a 0,2 - 2,0 % hmotn. plastifikačných a retardačných přísad s výhodou na báze alkalických solí lignosulfonanov a sulfonovaných kondenzátov jedno a viacmocných aromatických alkoholov.A self-curing suspension characterized in that it consists of 9.0-30.0 wt. % cement, 1.5 - 20.0 wt. % of the puzzolane siliceous additive preferably Si-dust or Siloxide with a minimum silica content of 80 wt.%, 50.0-89.3 wt. % bentonite suspension and 0.2-2.0 wt. plasticizers and retardants, preferably based on alkali salts of lignosulfonates and sulfonated condensates of mono- and polyhydric aromatic alcohols. Konec dokumentu ř!End of document ø!
CS519788 1988-07-20 1988-07-20 Self-hardening suspension CZ278280B6 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CS519788 CZ278280B6 (en) 1988-07-20 1988-07-20 Self-hardening suspension
SK519788A SK277780B6 (en) 1988-07-20 1988-07-20 Self-hardening suspension

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CS519788 CZ278280B6 (en) 1988-07-20 1988-07-20 Self-hardening suspension

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CS8805197A2 CS8805197A2 (en) 1991-08-13
CZ278280B6 true CZ278280B6 (en) 1993-11-17

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Publication number Priority date Publication date Assignee Title
RU2553795C2 (en) * 2012-10-30 2015-06-20 Федеральное Государственное Бюджетное Учреждение Науки Институт Машиноведения Им. А.А. Благонравова Российской Академии Наук Complex additive for heavy concrete mixtures

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CS8805197A2 (en) 1991-08-13
SK277780B6 (en) 1995-01-05

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IF00 In force as of 2000-06-30 in czech republic
MM4A Patent lapsed due to non-payment of fee

Effective date: 20000720