CZ27818U1 - Textile nanocomposite - Google Patents
Textile nanocomposite Download PDFInfo
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- CZ27818U1 CZ27818U1 CZ2014-30209U CZ201430209U CZ27818U1 CZ 27818 U1 CZ27818 U1 CZ 27818U1 CZ 201430209 U CZ201430209 U CZ 201430209U CZ 27818 U1 CZ27818 U1 CZ 27818U1
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- textile
- nanofibres
- polymer
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/05—Interconnection of layers the layers not being connected over the whole surface, e.g. discontinuous connection or patterned connection
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
- B32B7/14—Interconnection of layers using interposed adhesives or interposed materials with bonding properties applied in spaced arrangements, e.g. in stripes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
- D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
- D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
- D06M17/06—Polymers of vinyl compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M17/00—Producing multi-layer textile fabrics
- D06M17/04—Producing multi-layer textile fabrics by applying synthetic resins as adhesives
- D06M17/10—Polyurethanes polyurea
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0223—Vinyl resin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0246—Acrylic resin fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0292—Polyurethane fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Textilní nanokompozitTextile nanocomposite
Oblast technikyTechnical field
Řešením je textilní nanokompozit, který sestává z nosné textilní vrstvy, ke které je přiložena vrstva polymemích nanovláken.The solution is a textile nanocomposite, which consists of a carrier textile layer, to which a layer of polymer nanofibres is attached.
Dosavadní stav technikyBACKGROUND OF THE INVENTION
Textilní nanokompozity s uplatněnou vrstvou polymemích nanovláken jsou určené pro různé aplikace, kde splňují mnohdy protichůdné požadavky. Ty, které jsou určeny pro výrobu oblečení, musí být prodyšné, prostupné pro vodní páru vyvíjenou lidským teplem a současně větruodolné a nepropustné pro vodu. Obdobné požadavky jsou na materiály, ze kterých se zhotovují kupříkladu stany, spací pytle nebo filtry. Těchto požadavků se docílí vrstvením různých textilních materiálů v kombinaci s vrstvami nanovláken popřípadě i různou povrchovou úpravou. Taková úprava může být provedena jak na vnějším povrchu např. CZ 24446 U1 nebo na vnitřní ploše nosné textilní vrstvy, se kterou je vrstva polymemích nanovláken pevně spojena. Cílem těchto řešení je zabránit vzájemnému posunu vrstvy polymemích nanovláken a přilehající textilní vrstvy. Tím totiž dochází k narušení rovnoměrného rozprostření nanovláken, které má za následek, že textilní nanokompozit neplní dostatečné požadované funkce v celé ploše. Pokud se jako fixační prostředek uplatní plošné spojení jakýmkoliv adhezním prostředkem, který zajišťuje pevné spojení nosné textilní vrstvy s na ní uložené vrstvy polymemích nanovláken, takový plošný spoj obou vrstev mění průličnost vzniklého textilního kompozitu. Stejně je tomu, pokud se povrch vrstvy polymemích nanovláken opatří hydrofobní látkou. U vrstvy polymemích nanovláken navíc dochází při pohybu textilního nanokompozitu k vzájemnému pohybu nanovláken, což má za následek i jejich vzájemné přemístění v jejich sestavě. Vznikají tak místa s různou hustotou nanovláken a tedy i s různými vlastnostmi v ploše. Tomu se snaží předejít řešení popsané v CZ 27368 Ul, kde je vrstva polymemích nanovláken opatřena soustavou bodových útvarů z polymeru, mezi kterými je vrstva polymemích nanovláken volně přístupná, bodové útvary zabraňují vzájemnému pohybu nanovláken. Pevné spojení nosné textilní vrstvy s vrstvou polymemích nanovláken v ploše vhodným pojivém, zhoršuje však průličnost textilního nanokompozitu a pouhé nanesení bodových útvarů z polymeru na vrstvu polymemích nanovláken narušuje soudržnost vrstvy polymemích nanovláken, protože bodové útvary jsou vytvořeny pouze na vrchní části vrstvy polymemích nanovláken.Textile nanocomposites with applied layer of polymer nanofibres are designed for various applications, where they often meet contradictory requirements. Those designed for the manufacture of clothing must be breathable, permeable to water vapor generated by human heat, and at the same time windproof and impermeable to water. Similar requirements apply to materials such as tents, sleeping bags or filters. These requirements are achieved by laminating various textile materials in combination with layers of nanofibres and possibly different surface finish. Such a treatment can be carried out both on the outer surface of eg CZ 24446 U1 or on the inner surface of the carrier textile layer with which the layer of polymer nanofibres is firmly connected. The aim of these solutions is to prevent mutual displacement of the polymer nanofiber layer and the adjacent textile layer. In this way, the uniform spreading of nanofibres is disrupted, which results in the textile nanocomposite not fulfilling sufficient required functions in the whole area. If a bond is used as a fixing means by any adhesive means that ensures a firm connection of the carrier textile layer to the layer of polymer nanofibres deposited thereon, such a printed bond of both layers changes the transparency of the resulting textile composite. The same is true if the surface of the layer of polymer nanofibres is provided with a hydrophobic substance. Moreover, in the layer of polymer nanofibres the nanofibers move together during the movement of the textile nanocomposite, which results in their mutual displacement in their assembly. There are places with different density of nanofibres and therefore with different properties in the area. This is attempted to avoid the solution described in CZ 27368 U1, where the polymer nanofiber layer is provided with a set of polymer point formations between which the polymer nanofiber layer is freely accessible, the point formations prevent the nanofibers from moving together. The firm bonding of the supporting textile layer with the polymer nanofiber layer in a suitable bonding area, however, deteriorates the transparency of the textile nanocomposite and the mere application of dot polymer formations to the polymer nanofiber layer compromises the cohesion of the polymer nanofiber layer.
Podstata technického řešeníThe essence of the technical solution
Technickým řešením je textilní nanokompozit, který sestává z nosné textilní vrstvy a k ní přiložené vrstvy polymemích nanovláken. Textilní vrstva a vrstva polymemích nanovláken jsou spolu spojeny v ploše obou vrstev rozptýlenými fragmenty alespoň jednoho polymeru. Fragmenty z polymeru se textilní vrstvy dotýkají a vrstvu polymemích nanovláken prostupují, a tím ji k nosné textilní vrstvě fixují. Takto uspořádané fragmenty jednak vrstvu polymemích nanovláken připevňují a rovněž nanovlákna vzájemně k sobě v místě průniku vrstvou fixují a zabraňují jejich vzájemnému přemístění.The technical solution is a textile nanocomposite, which consists of a carrier textile layer and a layer of polymer nanofibres attached to it. The textile layer and the polymer nanofiber layer are joined together in the area of both layers by scattered fragments of at least one polymer. Fragments of polymer touch the textile layer and the polymer nanofiber layer penetrates, thus fixing it to the supporting textile layer. The fragments arranged in this way secure the layer of polymer nanofibres and also fix the nanofibres to each other at the point of penetration of the layer and prevent their mutual displacement.
Pokud k fragmentům prostupujícím vrstvu polymemích nanovláken je přiložena textilní vrstva, která je s fragmenty spojena, pak tato textilní vrstva zabraňuje mechanickému poškození vrstvy polymemích nanovláken nacházející se mezi fragmenty, která je v těchto místech přístupná.If the fragments penetrating the layer of polymer nanofibres is attached a textile layer, which is connected to the fragments, then this textile layer prevents mechanical damage of the layer of polymer nanofibres located between the fragments, which is accessible in these places.
Pro větší variabilitu užitných vlastností výsledného výrobku, může být vrstva polymemích nanovláken složená z více jednotlivých vrstev, které mohou být zhotoveny ze vzájemně různých polymerů.For greater variability of utility properties of the final product, the layer of polymer nanofibres can be composed of several individual layers, which can be made of mutually different polymers.
-1 CZ 27818 U1-1 CZ 27818 U1
Příklady provedení technického řešeníExamples of technical solution
Textilní nanokompozit podle tohoto řešení obsahuje nosnou textilní vrstvu a na ní přiloženou vrstvu polymerních nanovláken. Textilní vrstva a vrstva polymerních nanovláken jsou spolu spojeny v ploše obou vrstev rozptýlenými fragmenty alespoň jednoho polymeru či tavným pojivém ze skupiny polyuretan, polyvinylacetát, polyethylen-vinylacetát, polyakrylát a silikon, případně jejich směsí, které vrstvu polymerních nanovláken prostupují. Takto uspořádané fragmenty jednak prostupují vrstvu polymerních nanovláken k nosné textilní vrstvě a tím vrstvu polymemích nanovláken připevňují k nosné textilní vrstvě a rovněž nanovlákna vzájemně fixují a zabraňují tím jejich vzájemnému přemístění. Vrstvou polymerních nanovláken je na nosnou textilní vrstvu libovolnou laminací protlačen zvolený polymer či jejich směs v rozptýleném uskupení tvořící rozptýlené body, úsečky či mřížku. Mezi takto uspořádanými uskupeními fragmentů polymeruje vrstva polymerních nanovláken přístupná a tím propustná pro páru.The textile nanocomposite according to this solution comprises a carrier textile layer and a layer of polymeric nanofibres attached thereto. The textile layer and the layer of polymer nanofibres are joined together in the area of both layers by scattered fragments of at least one polymer or a hot-melt binder from the group of polyurethane, polyvinyl acetate, polyethylene vinyl acetate, polyacrylate and silicone, or mixtures thereof. Such arranged fragments, on the one hand, penetrate the layer of polymeric nanofibres to the carrier textile layer and thereby attach the layer of polymeric nanofibres to the carrier textile layer, and also the nanofibers fix each other and thus prevent their mutual displacement. Through a layer of polymer nanofibres, the selected polymer or a mixture thereof in an interspersed formation forming scattered points, lines or a grid is extruded onto the carrier textile layer by any lamination. Between these arranged groups of fragments a layer of polymeric nanofibres is accessible and thus permeable to steam.
K fragmentům polymeru prostupujícím vrstvu polymerních nanovláken až k ploše nosné textilní vrstvy jez opačné strany, která vystupuje z vrstvy polymerních nanovláken, přiložena textilní vrstva. Textilní vrstva je s fragmenty spojena. Textilní vrstva tvoří podšívku a zabraňuje mechanickému poškození vrstvy polymerních nanovláken nacházející se mezi fragmenty. Takto sestavený nanokompozit lze bez poškození vrstvy polymerních nanovláken či narušení jejich užitných vlastností opakovaně prát. U takto sestaveného nanokompozitu určeného pro outdoorové oblečení lze pro nosnou textilní vrstvu volit libovolnou textilii ať tkanou, netkanou nebo pletenou a to z přírodních či syntetických vláken či jejich kombinací. Z toho důvodu je výhodné, když nosná textilní vrstva je tvořena z materiálu s vyšší hydrostatickou odolností nebo opatřeného impregnací, která činí zvolený materiál také větruodolný. Vrstva polymerních nanovláken může být složená z více jednotlivých vrstev ať jednodruhového polymeru, nebo jednotlivé vrstvy nanovláken jsou ze vzájemně různých polymerů. Jednotlivé vrstvy nanovláken mohou být opatřeny různými přípravky pro získání požadovaných vlastností. Kupříkladu biologicky aktivní látkou proti nežádoucím mikroorganismům nebo parfémováním, případně hydrofobní nebo hydrofilní látkou podle potřeby.The polymer fragments penetrating the layer of polymeric nanofibres up to the surface of the carrier textile layer are provided with a textile layer attached to the opposite side, which protrudes from the layer of polymeric nanofibres. The textile layer is joined to the fragments. The textile layer forms a lining and prevents mechanical damage of the layer of polymer nanofibres located between the fragments. Such assembled nanocomposite can be repeatedly washed without damaging the layer of polymer nanofibres or impairing their utility properties. With this nanocomposite designed for outdoor clothing, any fabric, whether woven, nonwoven or knitted, made of natural or synthetic fibers or combinations thereof, can be chosen for the carrier textile layer. For this reason, it is preferable that the carrier textile layer is made of a material with higher hydrostatic resistance or impregnated, which makes the selected material also windproof. The layer of polymer nanofibres can be composed of several individual layers of either a single-species polymer, or the individual layers of nanofibres are made of mutually different polymers. Individual layers of nanofibres can be provided with different preparations to obtain the desired properties. For example, a biologically active agent against undesirable microorganisms or perfuming, or a hydrophobic or hydrophilic agent as desired.
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CZ2014-733A CZ2014733A3 (en) | 2014-10-31 | 2014-10-31 | Textile nanocomposite |
Publications (1)
Publication Number | Publication Date |
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CZ27818U1 true CZ27818U1 (en) | 2015-02-16 |
Family
ID=52598515
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CZ2014-30209U CZ27818U1 (en) | 2014-10-31 | 2014-10-31 | Textile nanocomposite |
CZ2014-733A CZ2014733A3 (en) | 2014-10-31 | 2014-10-31 | Textile nanocomposite |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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CZ2014-733A CZ2014733A3 (en) | 2014-10-31 | 2014-10-31 | Textile nanocomposite |
Country Status (2)
Country | Link |
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CZ (2) | CZ27818U1 (en) |
WO (1) | WO2016066149A1 (en) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2846201A1 (en) | 2002-10-23 | 2004-04-30 | Proline Textile | Composite fire-resistant and waterproof textile material e.g. for firefighters' garments has outer layer made from two non-woven layers connected by felted bridges |
CZ2010373A3 (en) * | 2010-05-13 | 2011-11-23 | Elmarco S.R.O. | Method of increasing strength and abrasion resistance of nanofiber layer, composite comprising nanofiber layer and nanofiber layer per se |
CZ2011306A3 (en) * | 2011-05-23 | 2012-12-05 | Technická univerzita v Liberci | Method of increasing hydrophobic properties of flat layer of polymeric nanofibers, a layer of polymeric nanofibers with increased hydrophobic properties and layered textile composite, which comprises such a layer |
CZ24446U1 (en) | 2012-05-18 | 2012-10-22 | Technická univerzita v Liberci | Layer of polymeric nanofibers with increased hydrostatic resistance and multilayer textile composite containing at leas one such layer |
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2014
- 2014-10-31 CZ CZ2014-30209U patent/CZ27818U1/en not_active IP Right Cessation
- 2014-10-31 CZ CZ2014-733A patent/CZ2014733A3/en unknown
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2015
- 2015-10-29 WO PCT/CZ2015/000130 patent/WO2016066149A1/en active Application Filing
Also Published As
Publication number | Publication date |
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CZ2014733A3 (en) | 2016-05-11 |
WO2016066149A1 (en) | 2016-05-06 |
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