CS269012B1 - Coapoz1c1a for coated fabric - Google Patents

Coapoz1c1a for coated fabric Download PDF

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Publication number
CS269012B1
CS269012B1 CS865330A CS533086A CS269012B1 CS 269012 B1 CS269012 B1 CS 269012B1 CS 865330 A CS865330 A CS 865330A CS 533086 A CS533086 A CS 533086A CS 269012 B1 CS269012 B1 CS 269012B1
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Czechoslovakia
Prior art keywords
parts
type
fabric
propanediol
weight
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CS865330A
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Czech (cs)
Slovak (sk)
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CS533086A1 (en
Inventor
Stefan Rndr Truchlik
Viera Ing Kabatova
Stanislav Ing Csc Markus
Vladimir Kulich
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Truchlik Stefan
Kabatova Viera
Markus Stanislav
Vladimir Kulich
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Priority to CS865330A priority Critical patent/CS269012B1/en
Publication of CS533086A1 publication Critical patent/CS533086A1/en
Publication of CS269012B1 publication Critical patent/CS269012B1/en

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Abstract

Koapozlcla pre povrstvenle textilii s nu tavltetnýal reolog!cký·I vlastnosta1» I a regulovate(nýa režlaoa xuíenla, ktoré haotnostne na 100 dlelov polyaérnej zložky obsahuje 1 až 70 dlelov aktívnej zložky, ktori je koablněclou 1,2- propéndlolu a/alebo 1,3- propéndollu a alualnos1l1kétu typu Al^Oj.ASIO^.óH^O natrlflkovaného 5 až 12 X haot. bezvodého Na^COj, v haotnostnoa poaere 1:10 až 10:1.Composites for coating textiles with fusible and rheological properties and controllable resins, which usually contain 1 to 70 parts of the active component per 100 parts of the polyaer component, which is a compound of 1,2-propendolol and/or 1,3-propendol and an aluminum alloy of some type Al^Oj.ASIO^.óH^O natrlflced 5 to 12 X haot. of anhydrous Na^COj, in haotnostnoa poaere 1:10 to 10:1.

Description

CS 269012 B1 1

Vynález sa týk» koapozicie pře povrstvenie textilii s nastavitelnými reologickýmivlastnoslaai « regulovaným režiaoa suienia na báze vodných disperzii polymérov, kdehlavnou aonoaérnou jednotkou je ester kyseliny akrylové] a/alebo aetakrylovej, obsahu-jůcej plnívá a připadne zaákíovadlá, aodifikátor a ďaliie pomocné prostriedky, ktoráhaotnostne na 100 dlelov polyaérnej zložky obsahuje 1 až 70 dielov aktivně] zložky, kte-ré je koabinéciou 1,2- propéndiolu a/alebo 1,3- propéndiolu a natrifi kovaného aluaino-silikátu v haotnostnoa poaere 1:10 až 10:1.

Je znéae, že polyaérne dlsperzie na akrylétovej báze aajú za určitých podaienoksklon vykazovat při tepelnoa zpracovaní nad 90 UC výrazný nelineérny priebeh odchoduvody v poslednej fáze suienia, čo vyvolává nežiadůce aakroefekty na povrchu povrstve-nia vo forae bublin a inýeh nehoaogenit. Pře nastavenie požadovaných Teologických vlast-nosti koapozicii pře povrstven-ie textilii sa bežhe použivajů záhustky na báze polyelek-trolytov, derlvátov celulózy a pod., ktoré neaajů zásadný vplyv na reguláciu procesu su-ienia. Prlaae zahustovanle povrstvovacieh zaesi anorganickými plnívaní aá zasa svoje hra-nice vo vlastnostiach výsledného povrstvenia. Pře odstránle nežiadůcich povrchových javov sa najčastejiie použivajů aditiva pre-dlžujúce otvorenů dobu filau ako napr. etylénglykól, dietyléng lykól, glycerin, zaes gly-cerinu a močoviny, polyjacharidy a pod. /Planondon J.E., Alte- welt A.L., Retin Review,23. 3. 1973, Wesfall P.H., Nayfield H. : Text. Chea. Color, 3,1971 /, ktoré viak vie-obecne nepostačujů pře dosiahnutie uspokojivých výsledkov.

Uvedené a ďaliie nevýhody rieii tento vynález, podta ktorého koapozleia pre povrst-venie textilii s nasta v ite(nýai reologiekýai vlastnoslaai a regulovaný» režiaoa suieniana báze vodných disperzii polyaérov, kde hlavnou aonoaérnou jednotkou je ester kyselinyakrylové] a/alebo aetakrylovej, obsahujůca plnívá, připadne zaákčovadl i, aodifikátory adiliie poaocné prostriedky, ktorá haotnostne na 100 dielov polyaérnej zložky obsahuje1 až 70 dielov aktivnej zložky, ktorá je koabináciou 1,2- propéndiolu a/alebo 1,3- pro-pándiolu a natrifi kov»ného aluainos1likátu v haotnostnoa poaere 1:10 až 10:1. Výhoda koapozicie pre povrstvenie textilii podlá uvedeného vynálezu spočívá v tou,že koabináciou uvedených zložiek sa dosiahne kontiauálny priebeh v konečnej fáze odpa-řovaní» vody, za sůčasnej úpravy požadovaných Teologických vlastnosti, čin sa zabránivzniku nežiadůcich efektov- tvorba bublin, presakovania převřitvovacej koapozicie cezitruktúru textilie a pod. Óaliou výhodou je vylůčenie aditiv na úpravu Teologickýchvlastnosti z koapozicie, pričoa koabináciou zložiek podlá vynálezu posobi priaznivo narovnoaernost fileu a jeho itrukturélnu integritu.

Pod pojaoa natr1fi kováný aluai nos111kát typu Al^Oj.ASiO^.ÓH.,0 sa rozuaejů stabili-zované Na katiónoa alua i nos i11káto vé anióny vzniklé v zaysle sehéay:

3 pO-^i-OH 0

O o I 0 -0-S1-0-H-,

> -0-S1-O-Al-OH

J -O-Si-O-H-i 0

+ 2HjO

Vynález je ďalej objasněný, no nie obaedzený nasledujúci a i přikladši 2 CS 269012 Bl Přiklad 1. koapozlcla Λ prt povrstvenle textilii o nasledovnoa zloženl: akrylátová disperzi» η» báze kopolyaérustyrén, butylakrylit a kyselina akryloví > s obsahoa neprchavej zloiky *0 X 100 haot. dlelov anorganické priíkové plniv* 107 haot. dlelov z toho alualnosikát typu AI 2°j·451°2 · 6Hpetrifikovaný 7 X haot. bezvodýa N»2COj 0-12 haot. dlelov A1 Obsah Al2Oj.4S102.6H2O petrifikovaného 7 X bezvodýa N»2COj /haot. dlely/ /Pa.s/ * 1 A1 0 0,12 A2 4 1,14 i A3 8 2,94 A4 12 4,55

Koaoozicia B pre povrstvenle textilii o nasledovnoa zloženl: akrylátová disperzi»- ako v koapozicli A 100 haot. dielovanorganické práškové plnívá 107 haot. dlelovz toho alualnos ikát- ako v kompozleil A 12 haot. dlelov1,2- prooándiol 2-4 haot. dielov

A

Oynaalck* vlakozlta kompozleil pre povrstvenle t»x11111 aerané na Rheoteste typ RV-- XI, iayková rychlost 9,0 s”1 teplota 20 °C.

Podobného účinku sa dosiahne aj pri použiti akrylátových disperzU na báze iných kopolymérov.

Priebeh konečnej fáty odpařovaní» vody z kompozici· A1 a pr1 teplete 140 °cznázorňuje graf na obr. 1.

Označeni»: ·- rec. A- rec. B2 Přiklad 2:

Kompozici» C pre povrstvenle textilii o následovnoa zloienl: akrylátová disperzi» s obsahoa neprchavej zloiky 40 X 100 hBOt. dlelov

CS 269012 B1 1

The present invention relates to a co-coating of a fabric with adjustable rheological properties controlled by the aqueous dispersion of polymers, wherein the main aono-unit is an acrylic ester and / or an aethacrylic-containing filler and optionally a curing agent, an aodifier and other auxiliaries. 100 µl of the polymeric component contains 1 to 70 parts of the active ingredient, which is the co-co-action of 1,2-propene diol and / or 1,3-propene diol and the purified alumina silicate in a temperature range of 1:10 to 10: 1.

It is understood that, on certain acrylic base substrates, they exhibit, under certain conditions, a marked non-linear course of exit in the final phase of drying, resulting in undesirable and surface-defective surface effects in the form of bubbles and inhomogeneity. In order to set the desired rheological properties of the fabric coating, polyelectrolytes, cellulose derivatives and the like, which do not substantially influence the control of the drying process, are commonly used. In addition, the thickened coating composition is coated with inorganic fillers and, in turn, retains its properties in the properties of the resulting coating. In order to remove undesired surface phenomena, filament-prolonging additives such as ethylene glycol, diethylene glycol, glycerin, glycerine and urea, polyjaccharides and the like are most commonly used. Planondon JE, ALWER AL, Retin Review, 23. 3. 1973, Wesfall PH, Nayfield H.: Text. Chea. Color, 3.1971), which in general does not suffice to achieve satisfactory results.

The above and other disadvantages of the present invention are those of the present invention for the coating of textiles with a water-dispersible base and a base of aqueous dispersions of polyaeros where the main aonoaer unit is an acrylic acid ester and / or an aethacrylic ester, alternatively, the admixture and the modifiers of the admixture may contain a composition which contains from 1 to 70 parts by weight of the active ingredient which is coabinating 1,2-propenediol and / or 1,3-propanediol and natrioxide aluainosilicate in 100 parts by weight of the polyether component. The advantage of the coaposition for coating a fabric according to the invention is that the coabination of said components achieves a continuous course in the final phase of evaporation of water, with the simultaneous adjustment of the desired rheological properties, avoiding undesirable effects. bubble formation, leakage of the coagulation c the fabric structure, etc. The advantage is the elimination of additives for the modification of theological property from coaposition, whereby the coabination of the components according to the invention favorably improves the integrity of the file and its structural integrity.

The anions formed in the aluminosilicate and the aluminosilicate anions formed in zaysle seedate are dispersed in the form of an aluminum alloy.

3 pO-i-OH

O o I 0 -0-S1-0-H-,

-O-S1-O-Al-OH

J -O-Si-OH 10

+ 2HjO

The invention is further illustrated by the following, but not by way of example only, with the exception of acrylate dispersion, based on copolymers of styrene, butylacrylate and acrylic acid, with a non-volatile nature. inorganic nail fillers * 107 haot. of which alualnosicate type AI 2 ° j · 451 ° 2 · 6Hpetrified 7 X haot. anhydrous N 2 CO 2 0-12 ha. dlelov A1 Al2O3.4S102.6H2O content of petrified 7X anhydrous N2CO3 / haot. dlely / /Pa.s/ * 1 A1 0 0.12 A2 4 1.14 i A3 8 2.94 A4 12 4.55

Koaoozicia B pre povrstvenle textilii o nasledovnoa composed: acrylate dispersion »- as in A 100 haot. Partial organic powder filling 107 haot. dlelovz of this aluminosity - as in the composition A 12 haot. dlel1,2-proanediol 2-4 haot. parts

AND

Oynaalck * vlakozlta composites for coating x11111 aerated on Rheoteste type RV-- XI, speed 9.0 s ”1 temperature 20 ° C.

A similar effect is obtained when using other copolymer-based acrylate dispersions.

The course of the final water evaporation phase of the composition A1 and pr1 heat 140 ° and shows the graph in Fig. 1.

Marked »: - - rec. A- rec. B2 Example 2:

The composition »C for coated textiles is as follows: acrylate dispersion with a non-volatile crime 40 X 100 hBOt. dlelov

Claims (1)

CS 269012 B1 anorganické práškové plnívá 107 hmot. dlelov natr1f1 kovaný alumí nos111kát typu A l .,0 j. 4S 10^ . óH^O 0,2 hmot. dlelov 1,3-propánd1o l 0,2 hmot. dlelov Dynamická v 1skoz1ta kompozlc1e pre povrstvenle textilii mermné na Rheoteste typ RV-II,Smyková rychlost 9,0 s"1, teplota 20 °C je 4,65 Pa.s. PREDWET VfNÁLEZU Kompozlda pre povrstvenle textilii s nastavitelnými Teologickými vlastnoslaml aregulovatelným režlmom suienla, na báze vodných d1sperz11 polymérov, kde hlavnou mono-mérnou Jednotkou je ester kyseliny akrylovej a/alebo metakrylovej, obsahujúca plnívá apřipadne zmákiovadlá, mod111kátory a ďalšle pomocné prostrledky, vyznaíujuce sa tým, žehmotnostně na 100 dlelov polymérnej zložky obsahuje 1 až 70 dlelov aktlvnej zložky, ktorá je komblnádou 1,2- propándlolu a/alebo 1,3- propándlolu a alum1 nos111kátu typuA120j.4S1 Oj.6HjO natr 1 f1 kováného 5 až 12 Z hmot. bezvodýho Na^CO^, v hmotnostnom pomě-re 1:10 až 10:1. 1 výkresCS 269012 B1 Inorganic Powder Fills 107 wt. The aluminum alumina is of type A 1.0, 4S10. 0.2 wt. of 1.3-propanediol 0.2 wt. dlelov Dynamic in 1-layer composite for Rheoteste type RV-II fabric, shear rate 9.0 s -1, temperature 20 ° C is 4.65 Pa.s PRIOR TO THE INVENTION Composite for fabric coated with adjustable theological properties and controllable based on aqueous d1 spheres of polymers, where the main monomeric unit is an acrylic and / or methacrylic acid ester, comprising fillers and optionally wipers, modifiers and other auxiliaries, characterized in that it has a content of 1 to 70 parts of active ingredient per 100 parts of polymer component. , which is a combination of 1,2-propanediol and / or 1,3-propanedol and alumina noseate of the type Al2O3S1O6H2O10, which is 5 to 12% by weight of anhydrous Na2 CO3, in a ratio of 1:10 by weight. up to 10: 1
CS865330A 1986-07-14 1986-07-14 Coapoz1c1a for coated fabric CS269012B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CS865330A CS269012B1 (en) 1986-07-14 1986-07-14 Coapoz1c1a for coated fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CS865330A CS269012B1 (en) 1986-07-14 1986-07-14 Coapoz1c1a for coated fabric

Publications (2)

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CS533086A1 CS533086A1 (en) 1989-09-12
CS269012B1 true CS269012B1 (en) 1990-04-11

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