CS268777B1 - Method of isopropenyl ethers production - Google Patents

Method of isopropenyl ethers production Download PDF

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CS268777B1
CS268777B1 CS857060A CS706085A CS268777B1 CS 268777 B1 CS268777 B1 CS 268777B1 CS 857060 A CS857060 A CS 857060A CS 706085 A CS706085 A CS 706085A CS 268777 B1 CS268777 B1 CS 268777B1
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mac
isopropenyl ethers
peaktop
npmmepe
buxoa
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CS857060A
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CS706085A1 (en
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Oleg N Temkin
Gennadij K Sestakov
Igor V Kalecic
Anatolij M Taber
Ljudmila B Kuprinaja
Natalja I Anochina
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Oleg N Temkin
Gennadij K Sestakov
Igor V Kalecic
Anatolij M Taber
Ljudmila B Kuprinaja
Natalja I Anochina
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Priority to CS857060A priority Critical patent/CS268777B1/en
Priority to DD85281264A priority patent/DD267629A3/en
Publication of CS706085A1 publication Critical patent/CS706085A1/en
Publication of CS268777B1 publication Critical patent/CS268777B1/en

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260 777 -1-260 777 -1-

AaHHoe t/raofSpereni/ie othocmtco k cnocody noayMeHMS, M03onponeHM«osux stupce, Karopue npe«c τοβΛϊΐβτ co<$off iziHTepec msi cnHTeaa nceB«oMOHOHOB-no«ynpo«yxTOB np0 no/iyMeHuii/i XHpOpaCTUOpHMblX BMTaMMHOB, Η3ΠΡ0ΜΒΡ Λ. E 0 Ki .AaHHoe t / raofSpereni / ie othocmtco k cnocody noayMeHMS, M03onponeHM «osux scale, Karopue npe« c τοβΛϊΐβτ what <$ off iziHTepec msi cnHTeaa nceB «oMOHOH-no« ynTOB np0 no / iyMeHuii / i XHpOpaCTUOpHMblX BMTaMMHOB, Ρ3ΠΡ0ΜΒΡ Λ. E 0 Ki.

KpoMe toto. MsonponeHi/iJiOBbie βφριρμ MoryT <«η Mcno/ibsoeaHb) b πρΟΜβοβχβτββ KpaCMTejieří,KpoMe this. MsonponeHi / iJiOBbie βφριρμ MoryT <η Mcno / ibsoeaHb) b πρΟΜβοβχβτββ KpaCMTejieří,

HanpviMep «as, numieeoH. ®apMaueBT0Meci<oří 0 napenMepHott npoMumaeHHOCTH.HanpviMep «as, numieeoH. ®apMaueBT0Meci <report 0 napenMepHott npoMumaeHHOCTH.

MaoecreH cnocoa nouiyMeuMsi MaoriponeHunoaux βφμροβ B3aHMO«eňcTBueM MeT0«aueT0«eHac aa0<taT0MOCK0MM crwpTMW Ct-C b npincyrcTaw» μκογο xa«0 b κβΜβοτββ KaTaaraaTopa. npoueccBB«yT np0 TRMneparype 220-225®C, np0 «ao-nei-iuu 41-42 aT. b τβΜβΗ0β 18 Macos. ‘ Βμχολ «asi 2-MeTOKCMnponeHa - 30%, 2-3TOKC0nponeHa 30, 2% Cl).MaoecreH cnocoa nouiyMeuMsi MaoriponeHunoaux βφμροβ B3aHMO ň ň T B ue T T T w w b b b b b b b b b b b b b b b b b b npoueccBB «yT np0 TRMneparype 220-225®C, np0« a-nei-iuu 41-42 aT. b τβΜβΗ0β 18 Macos. Asi χμχολ «about 2-MeCoCMnponeHa - 30%, 2-3TOKCnponeHa 30, 2% Cl).

Aannwřj cnocoe xapa«Tep03yeTcsi ορββηητβλρηο huskmm bhxo«om ueaeraoro npa«yxTa opu «soabiuoň fnpo«oji*MTejibnocTM npouecca.C apa «03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 03 ej ej ej ej ej ej ej.

Ilíiupoacc ιϊλ/οκμμ k npe««oxenHOMy siaasieTcs, cnocoe noayMeHkisi 03οπροπ0Η0.ποβμχ o®0paeiB3a0MO«efícTB0eM a-n/iena wim aaaeHa b cmscm c ΜβτΜΛβιΐΒΤΜΛεΗΟΜ c C»-Ca ajimaTUMecKHMM criMpTaMMripn TeMnepaTypa 190-240°C 0 naBnetm 41-G2 aT. b τβΜβΗΜβ 2,5-4 Macon b np0cyTCTBiw e«KoHme«OM0 b KanecTBe xaTajiusaTopa. Bwxo« ueaeBoro npo«,yKTa 53,8-93.4%, οβλβκτ0βηοβτρ 85-94% C2>. MBBecTnwfí cnocod Tpe«syeT bhcokmx «aB«en0ň C41-62 aT.) 0 npe«ycMaTp0BaeT nep0o«0MecicoeocymecTB«BH0e npouecca. 03B«BMBH0e Kara«03aTopa . 03 xytsa peKT0®0Kau0eW. Henseexno πρ0Ββ«βτ κ nos®jien0»3arpS13HeHHblX CTOMHMX BO«. lle«bo ΛβΗΗΟΓΟ 03oepeTen05i sio-nsieTcsi ynpomeuxe npouecca. nacraB-neHHas, uojui «ocT0ra®TCS, cnococSOM πολυμβημα 03onponeH0«OBMX e>®0pob ossuieM «opny/iu·Ilíiupoacc ιϊλ / οκμμ to NPE «« oxenHOMy siaasieTcs, cnocoe noayMeHkisi 03οπροπ0Η0.ποβμχ o®0paeiB3a0MO «efícTB0eM and n / Iena wim aaaeHa CMSC b c c C ΜβτΜΛβιΐΒΤΜΛεΗΟΜ» -Ca ajimaTUMecKHMM criMpTaMMripn TeMnepaTypa 190 to 240 ° C 0 41 naBnetm aT-G2. b τβΜβΗΜβ 2.5-4 Macon b np0cyTCTBiw e «KoHme« OM0 b KanecTBe xaTajiusaTopa. Bwxo «ueaeBoro npo«, yKTa 53.8-93.4%, οβλβκτ0βηοβτρ 85-94% C2>. MBBecTnwn cnocod Tpe «sysT bhcokmx« aB «en Cnn C41-62 aT.) 0 npe« ycMaTp0BaeT nep0o «0MecicoeocymecTB« BH0e npouecca. 03B «BMBH0e Kara« 03aTopa. 03 xytsa peKT0®0Kau0eW. Henseexno πρ0Ββ «βτ κ nos®jien0» 3arpS13HeHHblX CTOMHMX BO «. lle «bo» 03oepeTen05i sio-nsieTcsi ynpomeuxe npouecca. nacraB-neHHas, uojui «ocT0ra®TCS, cnococSOM πολυμβημα 03onponeH0« OBMX e> ®0pob ossuieM «opny / iu ·

CH3 - CH - CHa. r«e R - CH3, CaHe. B3a0MO«eřícTB0eM Ci-Ca a/iMtaTiwecKi/ix cnwpTOBCH 3 - CH - CH a. R e R-CH 3, CaH 6. B3a0MO «eTcTB0eM Ci-Ca and / iMtaTiwecKi / ix cnwpTOB

OR c MGT0/iaueT0jieHOM, 0jiw βλλβηομ co CMecb» MeTnaaueTnaena c aMHOH np0 TennepaType 200~275°CB np0cyTCTB00 xaTa«03aTopa ZriCNOa)» na 3ΚΤ0Β0Ροβθηηομ yrae μλμ C0Ji0Karej,e. OTji0M0Tra«bnasi ocoeseHnocTb ηρΒ&amp;ΜΚΗΗΟΓΟ cnocoesa cocto0t b tok. mto o xanecTBeKOTa«03aTopa 0cno«b3yoT ZnCNO3)a na οκτ0Β0ροβ3Ημομ yrae 0.110 c0«0Karejie, 0 npouecc Be«yT np0TeMneparype 200~275°C. Konoepcnsi 87%. βμχολ κοΗβΜΗΟΓα προ«γκτβ 37-59%. npe««oxeHHbiff cnocoes ποββολρθτ oecT0 npouecc np0 βτμοοφβρηομ «aB«en00, mto ynpomaeT »10 yMOHbuiaeT oapuBoonacnocTb npouecca. ·OR c MGT0 / iaueT0jieHOM, 0jiw βλλβηομ what CMecb »MeTnaaueTnaena c aMHOH np0 TennepaType 200 ~ 275 ° CB np0cyTCTB00 xaTa« 03aTopa ZriCNOa »to 3ΚΤ0Β0Ροβθηηομ yrae μλμ C0Ji0Karej, e. OTji0M0Tra «bnasi ocoeseHnocTb ηρΒ &amp; cnocoesa cocto0t b flow. mto o xanecTBeKOTa «03aTopa 0cno« b3yoT ZnCNO3) and to οκτ0Β0ροβ3Ημομ yrae 0.110 c0 «0Carie, 0 npouecc Be« yT np0TeMneparype 200 ~ 275 ° C. Consistently 87%. βμχολ κοΗβΜΗΟΓα προ «γκτβ 37-59%. npe «« oxeHHbiff cnocoes ποββολρθτ oecT0 npouecc np0 βτμοοφβρηομ «aB« en00, mto ynpomaeT »10 yMOHbuiaeT oapuBoonacnocTb npouecca. ·

KpoMe Toro. 0cnozib3OBan0e reTeporenKoro xaTa«03aTopa ne Tpe<syeT cneupambHMX CTa«0dBbi«e«eEi0S, KaraJi03aTapa.KpoMe Toro. 0cNoBe0eReReReReReCoRaTa «03aTop not Tpe <syeT cneupambHMX CTa« 0dBbi «eEi0S, KaraJi03aTapa.

KaTa«03arop λθγκο no««aeTcsi pereHepau00 CnpoKamxa b τοκβ BO3«yxa) 0 moxbt 0cno«b3OBaTbC5iΜΗΟΓΟΚΡβΤΗΟ.KaTa «03arop λθγκο no« «aeTcsi pereHepau00 CnpoKamxa b τοκβ BO3« yxa) 0 moxbt 0cno «b3OBaTbC5iΜΗΟΓΟΚΡβΤΗΟ.

Cnocoňi saK«»MaeTC$, o tom. mto b peaxTop. noMeuieHnuři b τβρΜοατβτ 3arpyxa»T KaTa«03aTop. 3ohu Harpeea coctosit 03 narpeBaTenp, 0cnapMTe«si 0 KaTaji0T0MecKoň Tpy<SKM 03 «oapua «μβμθτρομ25 mm 0 ««0HoW 200 mm. HeT0«aueT0jien 0J10 ajuien. 0Λ0 CMecb MeT0.naueT0.neHa 0 aa^ewa. a Taxxea«H»aT0HecK0ff cnHPT Ci-Ca b B0«e napoo no«a»T b xaTa«0T0MecKyo Tpyesxy. Προ«γκτ np0coe«0neH0si,ox«ax«aeMwCÍ yr«eK0C/ioToM, coeS0pa»T b «oayuixy 0 ana«030pyoT c πομοιιιμ ΓΧΧ.Cnocoňi saK «» MaeTC $, about it. mto b peaxTop. noMeuieHnuři b τβρΜοατβτ 3arpyx »T KaTa« 03aTop. 3ohu Harpeea coctosit 03 narpeBaTenp, 0cnapMTe «si 0 KaTaji0T0MecKoň Tpy <SKM 03« oapua «μbμθτρομ25 mm 0« «0HoW 200 mm. HeT0 «aueT0jien 0J10 ajuien. 0Λ0 CMecb MeT0.naueT0.neHa 0 aa ^ ewa. and Taxxea &quot; H &quot; and T0HecK0ff &quot; cnHPT &quot; Ci-Ca b &quot; Ne si si si si si si ox si si si si si si si si si si si si si si si si si si si si si si K K K an an an an an an an an an an an.

Mam-ioe 03οβρβτβΗ0β 0««»CTp0pyeTcsi ΜΜ>κβπρΜΒβ«βΗΜΗΜ0 npHMepaMH. ΠρΜΜβΡ 1. 8 noMeuieHHbiff b τθρμοοτθτ peaxTop 3arpy*a»T 30 Mac.% ZnCNO3>a Ha yr«e. ΜβτβΗΟΛ0 ΜΘΤ0Λ3Ι4βΤ0ΛβΗ B Β0«β ΠβρΟΒ nonaiUT B peaKTOp . Πρθ«ΥΚΤΜ KOH«eHC0pyOT B ΧΟΛΟ«0ΛΙ>Η0ΚΘ0 aHa«030py»T c noMouib» ΓΧΧ. Oest.eMHasi ckopocti» 150 Mac-1, TeMnepaTypa 200°C. bmxoxΜΒΤΜΛΜ3θπροηβΗ0ΛθΒθτο stupa C ΠΙ4Π3) 49%. npOM3BO«0Te«bHOCTb 19 r/Ji xaT.M. He-neBoC npo«yKTBfawe/isiOT ooumhoCÍ paarrjHKOČí npH P - 1 aT., Τκηπ “ 35-37°C. dr,30 “ 0,770. na,Jr, « 1.3738. ΠρΗΜβρ 2. 8 yc«OB0S,x. on0caHHux o npMMepe 1, b peaKTOp 3arpyxawT Zri(NO3)a na yrae. ΠβτβΗΟΛ0 MeT0«aueT0«en-a/iJieHOBy» ®paxu0o b cocTane 60% MeT0«aueT0jiena 0 40% annena 0 ΜβτβΗΟΛ b Biwenapou no«a»T π ρεβκτορ. Ocn>eMHasi cxopocTb 1 150 Mac-1, TeMnepaTypa 225°C. ouxo« Ρ1Ι4Π3 60%, 260 777 προμ3βοαμτβλι>ηοοτι> 42 γ/λ kčit.m. ΠρΜΜβρ 3. B ycsiOBMHX, onMcaHHMX b npuíMepe 1. b ρββκτορ oarpy*a»T 30 Mac.X Zn<NOs,)a Ha yrjie.rieTmiimern/ien-a?ijieHOo.yio «paKuno h HeTaHoa ηοχββτ b peairrop b bmab napou. Oui.eMtia« CKOpocTb150 Mac"1, TSMnepaTypa 275OC, buxoa Ι4Ι4Γ13 90%, npow3OBiMMrejibHocTb 62 γ/ji κβτ. m. npvtMCp 4. B ,υολοβμϊιχ. onucaHHUX u npuíMepe 1. ΜβτβΗΟΛ n ΜβΤΜΛβιιβτΜΛβΗ u di/iao napou no»a»Tu peaxTCtp. B KanecTBe κατβΑΜΒβτορβ picnoAb3y»T 30 Mac.X Zn(NO3)a na yrjie. Ορι.ομεμη cxopocTb150 Mac"1, TennepaTypa 275°C, buxoa ΓΚ4Π3 38%, npoi43BOAi4TeAbHOCTb 34 γ/ji Kar. m.Mam-ioe 03οβρβτβΗ0β 0 «« »» CTp0pyeTcsi ΜΜ> κβπρΜΒβ «βΗΜΗΜ0 npHMepaMH. ΠρΜΜβΡ 1. 8 noMeuieHHbiff b τθρμοοτθτ peaxTop 3arpy * and »T 30 Mac.% ZnCNO3> and Ha yr e e. ΜβτβΗΟΛ0 ΜΘΤ0Λ3Ι4βΤ0ΛβΗ B Β0 «β ΠβρΟΒ nonaiUT B peaKTOp. Πρθ «OH KOH« eHC0pyOT B ΧΟΛΟ «0ΛΙ> Η0ΚΘ0 aHa« 030py »T c noMouib» ΓΧΧ. Oest.eMHasi »150 Mac-1, TeMnepaType 200 ° C. bmxoxΜΒΤΜΛΜ3θπροηβΗ0ΛθΒθτο stupa C ΠΙ4Π3) 49%. npOM3BO «0Te« bHOCTb 19 r / Ji xaT.M. He-BoBoC / yKTBfawe / isiOT oOmMaCoNHeCoNHP - P - 1 aT., Τκηπ '35-37 ° C. dr, 30 "0.770. on, Jr, «1.3738. ΠρΗΜβρ 2. 8 yc OB OB0S, x. on0caHHux on npMMepe 1, b peaKTOp 3arpyxawT Zri (NO3) and on yrae. ΠβτβΗΟΛ0 MeT0 «aueT0« en-a / iJieHOBy »®paxu0o b cocTane 60% MeT0« aueT0jiena 0 40% annena 0 ΜβτβΗΟΛ b Biwenapou no «a» T π ρεβκτορ. Ocn> eMHasi cxopocTb 1,150 Mac-1, TeMnepaTypa 225 ° C. ouxo «Ρ1Ι4Π3 60%, 260,777 προμ3βοαμτβλι> ηοοτι> 42 γ / λ kčit.m. ΠρΜΜβρ 3. B ycsiOBMHX, onMcaHHMX b npuíMepe 1. b ρββκτορ oarpy * a »T 30 Mac.X Zn <NOs,) and Ha yrjie.rieTmiimern / ien-a? IjieHOo.yio« paKuno h HeTaHoa ηοχββτ b peairrop b bmab napou . Oui.eMtia «CKOpocTb150 Mac» 1, TSMnepaTypes 275OC, buxoa Ι4ΓΓ13 90%, npow3OBiMMrejibHocTb 62 γ / ji κβτ. M. NpvtMCp 4. Here peaxTCtp. B KanecTBe κατβΑΜΒβτορβ picnoAb3y »T 30 Mac.X Zn (NO3) and on yrjie. m.

OpMMUP 5. Q ycaoBi4«x. oriMcannux o npMMepe 1. b peaKTOp aarpyxaioT 32 Mac.X Zri(NO.,)s, na cuoiHKare/ie. '0ρΐ.οΜΗβ·Λ cxopocTb 150 Mac-1. TeMnepaTypa 275eC. buxoa Ι4Ι4Π3 97%, npoMauo/iMTejibnocTb 65. 5 γ/λκπτ. m .OpMMUP 5. Q ycaoBi4 * x. oriMcannux on npMMepe 1. b peaKTOp aarpyxaioT 32 Mac.X Zri (NO.,) s, on cuoiHKare / ie. '0ρΐ.οΜΗβ · Λ cxopocTb 150 Mac-1. TeMnepaTypa 275eC. buxoa Ι4Ι4Π3 97%, npoMauo / iMTejibnocTb 65. 5 γ / λκπτ. m.

[IpMMCp 6. B yc.noBMíix onuicaHHbix b npMMepe 1, b peaKTOp aarpyxaoT 30 Mac.X Zn<NO.»)a na cw*«Kare«.Λλλοη μ ΜβτβκοΛ u BHZie napos oomdt o peaKTOp. OtíbOMHasr cKopocTb 150 Mac-*, TeMnepaTypa275'-'C, BUXOA Γ1Ι4Π3 38%. npOMBBOAMTejlbHOCTb 48 Γ/jl KUT. M. ΠρΜΜβρ 7. B yc/iOBMHX oni/ieaHHHX b npMMepe 1. b peaKTop aarpyxanT 30 Mac.X Zn(NO3)3 no ci/uiMKarojie.ΡΙοτΜΛβιιβτΜΛβΗ μ βτβηολ b bmjio napoe no«a»T b peaxrop. OcsteMnasi CKopocTb 150 Mac-1,TeMnepaTypa 225°. cooTHomeHMe MeTnaaueTM^eH-cniipT = lil. 5, buxoa 3τμλμ30προποημλοβο(ό rj®Mpa(3ΜΠ3) 97X. npoM3BOAt4TeAbHOCTb 25 r/ji κβτ. m. ripkiMep 8. B noMewenHUiži b TepMocTaT peaKTop aurpyxaioi KaTaJiuisaTop 25 Mac.% Zn(NO9)2 na yrae.rieranoA m Μβτΐ4Λβυβτΐ4ΛβΗ-βΛΛβΗθ»γ» «paxuM» πομβτ b peaKTOp. Προμυκτμ KowieHCMpyoTo xawMMbMMKe 14 aMaAM3Mpy»T c rroMOtiib» ΓΧΧ. Oat>eMHaa CKopocTb 150 Mac-1, TeMnepaTypa 275eC,BUXOA ΜβΤΜΛΜ30Πρ0ΠβΗΜΛΟΒΟΓΟ 3®Mpa 0414(13) 78%. nPOM3BOAl4TeAbHOCTb 38 Γ—Λ KOT. M. flpMMep 9. B ycjiOBbtnx οηι/icaHHUX b npMMepe 1. b peaKTOp sarpyxaioT KarajiMaaTOp 30 Mac.% Zn(NO9)2 nayrjie. PleTaHoa m MeTHJiaueTUjien-ajuieHOByn «paKUMD b enae napoe noAaoT b ρβακτορ, Ocsi-eMiianCKopocTb 150 Mac-1, T - 275°C, BUxoAa Ι4Ι4Π3 98%. npoi/iaoaAMTe/ibHOCTb 62,4 γ/λ κατ. m.[IpMMCp 6. B yc.noBMíix onuicaHHbix b npMMepe 1, b peaKTOp aarpyxaoT 30 Mac.X Zn <NO. ») And cw *« Kare «. QuoteMHasr cKopocTb 150 Mac- *, TeMnepaTypa275 '-' C, BUXOA Γ1Ι4Π3 38%. npOMBBOAMTejlbHOCTb 48 Γ / jl KUT. M. ΠρΜΜβρ 7. B yc / iOBMHX they / ieaHHHX b npMMepe 1. b peaKTop aarpyxanT 30 Mac.X Zn (NO3) 3 no ci / uiMKarojie. Find the CKopocTb 150 Mac-1, TeMnepaTypa 225 °. cooTHomeHMe MeTnaaueTM ^ eH-cniipT = lil. 5, buxoa 3τμλμ30προποημλοβο (ό rj®Mpa (3ΜΠ3) 97X. NpoM3BOAt4TeAbHOCTb 25 r / i κβτ. M. RipkiMep 8. B noMewenHUizi b TepMocTaT peaKTop aurpyxaioi Γ »paxuM» πομβτ b peaKTOp. Προμυκτμ KowieHCMpyoTo xawMMbMMKe 14 aMaAM3Mpy »T c rroMOtiib» at. Fl fl fl p p p B B 9. 9. y B B B B b b b b b b b b b b b b b b b b b b b b b b b b b b b Mac-1, T-275 ° C, BUxoAa Ι4Ι4Π3 98%, npoi / iaoaAMTe / ibHOCTb 62.4 γ / λατ. M.

flpMMep 10. X B ycjioewax oni/tcam-iux b npMMepe 1. b ρββκτορ 3arpyxaoT KaTajivraaTop 32 Mac.% Zn(NO9)a w na yrjie. KeTaHOJi m MeTHJiaueTmieH-ajuieHOBy» «paKUM» (Ι4ΑΦ) b βμαθ napos πομβτ b ρβακτορ. |OtíWMHasi CKopocTb 150 Mac-1. T « 275°C, buxoa ΙΊΙ4Π3 98,5%. npovoBOJiwTejibniXTb 63.1 γ/ji Kar . m. flpMMep 11. B ycjiosMíix onwcaHHUX b npMMepe 1. b peaKTOp 3arpyxanT κβταΛΜΒατορ 35 Mac.% Zn(NO9>2 Hayr-ne. HeTano/i m MeTMAaueTMAeH-aAAeHOByo ©paKUMio (Ι4ΑΦ) hoauot b bmac napou b peaKTOp. OoteMHaiacKopocTb 150 Mac-1, buxoa Ι4Ι4Π3 84%. npoi43BOAMTeJibHocTb 44.5 r/Jt κατ. m.flpMMep 10. X B ycjioewax they / tcam-iux b npMMepe 1. b ρ 3arpyxaoT KaTajivraaTop 32 Mac.% Zn (NO9) and w na yrjie. KeTaHOJi m MeTHJiaueTmieH-ajuieHOBy »« paKUM »(Φ4ΑΦ) b βμαθ napos πομβτ b ρβακτορ. | OtíWMHasi CKopocTb 150 Mac-1. T «275 ° C, buxoa ΙΊΙ4Π3 98.5%. npovoBOJiwTejibniXTb 63.1 γ / ji Kar. flpMMep 11. B ycjiosMíix onwcaHHUX b npMMepe 1. b peaKTOp 3arpyxanT 35 Mac.% Zn (NO9> 2 Hayr-no. HeTano / im MeTMAaueTMAeH-aAAeHOByo -1, buxoa Ι4Ι4Π3 84% npoi43BOAMTeJibHocTb 44.5 r / Jt κατ. M.

Claims (1)

* Η PŘEDMĚT VYNALEZU Způsob získávání isopropenyletherů obecného vzorce; CH3 - C - CHg, kde R = CH3 nebo C2H5OR vzájemným působením 0^ až 02 alifatických alkoholů namethylacetylen nebo allen, nebo se směsí methylacetylenus allenem při zvýěené teplotě v přítomnosti katalyzátoru,vyznačující se tím, že se jako katalyzátor používá dusič-nan zinečnatý na aktivním uhlí nebo silikagelu, a processe provádí při teplotě 200 až 275 °C. IOBJECT OF THE INVENTION A method for obtaining isopropenyl ethers of the general formula; CH 3 - C - CH 3, where R = CH 3 or C 2 H 5 OR by the interaction of 0 to 02 aliphatic alcohols methylacetylene or allene, or a mixture of methylacetylenes allen at elevated temperature in the presence of a catalyst, characterized in that zinc nitrate is used as the catalyst activated carbon or silica gel, and the process is carried out at a temperature of 200 to 275 ° C. AND
CS857060A 1985-10-02 1985-10-02 Method of isopropenyl ethers production CS268777B1 (en)

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CS857060A CS268777B1 (en) 1985-10-02 1985-10-02 Method of isopropenyl ethers production
DD85281264A DD267629A3 (en) 1985-10-02 1985-10-02 METHOD FOR OBTAINING DUESOPROPENYL ETHERS

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CS857060A CS268777B1 (en) 1985-10-02 1985-10-02 Method of isopropenyl ethers production
DD85281264A DD267629A3 (en) 1985-10-02 1985-10-02 METHOD FOR OBTAINING DUESOPROPENYL ETHERS

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DE19726666A1 (en) * 1997-06-23 1998-12-24 Basf Ag Process for the addition of compounds containing hydroxyl groups to alkynes or allenes
DE19726667A1 (en) * 1997-06-23 1998-12-24 Basf Ag Process for the preparation of enol ethers
DE19726670A1 (en) * 1997-06-23 1998-12-24 Basf Ag Process for the addition of compounds containing hydroxyl groups to alkynes or allenes
DE19726668A1 (en) * 1997-06-23 1998-12-24 Basf Ag Process for the addition of compounds containing hydroxyl groups to alkynes or allenes
DE19739716A1 (en) * 1997-09-10 1999-03-11 Basf Ag Process for the production of unsaturated ketones
DE19841552A1 (en) * 1998-09-11 2000-03-16 Basf Ag Production of enol ether involves reacting alcohol and/or acetal with alkyne and/or allene compound and then working up by distillation with recycling of acetal and alcohol, possibly after catalytic acetalization

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