CS259255B1 - Non-corrosive flux for melt welding of aluminum - Google Patents

Non-corrosive flux for melt welding of aluminum Download PDF

Info

Publication number
CS259255B1
CS259255B1 CS863857A CS385786A CS259255B1 CS 259255 B1 CS259255 B1 CS 259255B1 CS 863857 A CS863857 A CS 863857A CS 385786 A CS385786 A CS 385786A CS 259255 B1 CS259255 B1 CS 259255B1
Authority
CS
Czechoslovakia
Prior art keywords
aluminum
flux
fluoride
welding
corrosive
Prior art date
Application number
CS863857A
Other languages
Czech (cs)
Slovak (sk)
Other versions
CS385786A1 (en
Inventor
Pavel Guldan
Original Assignee
Pavel Guldan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pavel Guldan filed Critical Pavel Guldan
Priority to CS863857A priority Critical patent/CS259255B1/en
Publication of CS385786A1 publication Critical patent/CS385786A1/en
Publication of CS259255B1 publication Critical patent/CS259255B1/en

Links

Landscapes

  • Nonmetallic Welding Materials (AREA)

Abstract

Riešenie sa týká chemického zloženia nekorozívneho taviva na tavné zváranie hliníka najma plechov a profilov tenkých hrúbok do 5 mm, kyslíkacetýlénovým plameňom. Tavivo je v práškovej formě a je určené hlavně na zváranie hliníkových materiálov v chladiarenskom, potravinárskom a elektrotechnickom priemysle. Je na báze fluoridov a obsahuje 30 až 50 % hmot. fluoridu sodného, ďalej pozostáva z 30 až 39 % hmot. fluoridu lítneho, 5 až 9 % hmot. fluorohlinitanu sodného alebo fluorokremičitanu draselného alebo fluoroboritanu draselného, 3 až 8 % hmot. fluoridu hlinitého, jeho výhodou ije, že nie je korozívne a l'ahko sa odstraňuje zo zvarového kovu.The solution concerns the chemical composition of a non-corrosive flux for fusion welding of aluminum, especially thin sheets and profiles up to 5 mm thick, using an oxyacetylene flame. The flux is in powder form and is intended mainly for welding aluminum materials in the refrigeration, food and electrical industries. It is based on fluorides and contains 30 to 50 wt. % sodium fluoride, further consisting of 30 to 39 wt. % lithium fluoride, 5 to 9 wt. % sodium fluoroaluminate or potassium fluorosilicate or potassium fluoroborate, 3 to 8 wt. % aluminum fluoride, its advantage is that it is non-corrosive and is easily removed from the weld metal.

Description

Riešenie sa týká chemického zloženia nekorozívneho taviva na tavné zváranie hliníka najma plechov a profilov tenkých hrúbok do 5 mm, kyslíkacetýlénovým plameňom. Tavivo je v práškovej formě a je určené hlavně na zváranie hliníkových materiálov v chladiarenskom, potravinárskom a elektrotechnickom priemysle. Je na báze fluoridov a obsahuje 30 až 50 % hmot. fluoridu sodného, ďalej pozostáva z 30 až 39 % hmot. fluoridu lítneho, 5 až 9 % hmot. fluorohlinitanu sodného alebo fluorokremičitanu draselného alebo fluoroboritanu draselného, 3 až 8 % hmot. fluoridu hlinitého. Jeho výhodou ije, že nie je korozívne a Tahko sa odstraňuje zo zvarového kovu. 259255 3 4 259255The solution relates to the chemical composition of a non-corrosive flux for fusion welding of aluminum, in particular to sheets and profiles of thin thicknesses up to 5 mm by an oxygen-acetene flame. The flux is in powder form and is mainly used for welding aluminum materials in the refrigeration, food and electrical industries. It is based on fluorides and contains 30 to 50 wt. % sodium fluoride, further comprising 30 to 39 wt. % lithium fluoride, 5 to 9 wt. sodium fluorohalite or potassium fluorosilicate or potassium fluoroborate, 3 to 8 wt. aluminum fluoride. Its advantage is that it is not corrosive and Tahko is removed from the weld metal. 259255 3 4 259255

Vynález sa týká nekorozívneho taviva v práškovej formě na tavné zváranie hliníkových plechov a profilov tenkých hrúbok do 5 mm kyslík acetylénovým plameňom.BACKGROUND OF THE INVENTION The present invention relates to a non-corrosive flux in powder form for fusion welding of aluminum sheets and thin thickness profiles up to 5 mm oxygen by acetylene flame.

Doteraz známe tavívá na zváranie hliníka sú založené na báze chloridov a fluoridov. Vačšina používaných taviv na tavné zváranie hliníka je založená na báze chloridov s obsahom 90 až 92 % hmot. a zbytok fluoridy. Vysoký obsah chloridov sposobuje hygroskopičnosť taviva, čo vyvolává v praxi nemalé problémy pri jeho skladovatelnosti. Tavívá s vysokým obsahom chloridov majú vlastnost vyvolávat medzikryštalickú koróziu zvarového spoja. Aby sa v praxi tomuto nežiadúcemu aspektu predišlo, musia sa zvyšky taviva odstrániť umytím vodou, mořením v 20 až 40 % kyselině dusičnej alebo 10 %-nej kyselině sírovej a umytím vodou. Tieto operácie zvyšujú prácnosť a tým i nákladnost’ zvárania.So far known fluxes for aluminum welding are based on chlorides and fluorides. Most of the melting fluxes used for aluminum welding are based on chlorides with a content of 90 to 92% by weight. and the remaining fluoride. The high chloride content makes the flux hygroscopicity, which in practice causes considerable problems with its shelf life. High-chloride melts have the property of inducing inter-crystalline corrosion of the weld joint. In order to avoid this undesirable aspect in practice, flux residues must be removed by washing with water, pickling in 20 to 40% nitric acid or 10% sulfuric acid and washing with water. These operations increase the labor and thus the cost of welding.

Tavivo nekorozívneho typu podía čs. patentu č. 112118 má nevýhodu v menšom rozmedzí taviaceho intervalu a vyššie povrchové napatie roztaveného zvarového, kovu a roztavenej trosky, čo má za následok ťažšie a prácne odstráňovanie zvyškov taviva.Non-corrosive flux according to MS. No. 11,1118 has the disadvantage of a smaller melting range and higher surface tension of molten weld, metal and molten slag, resulting in more difficult and laborious removal of flux residues.

Uvedené nevýhody do značnej miery odstraňuje tavivo podlá vynálezu na tavné zváranie hliníka na báze fluoridov s obsahom 30 až 50 % hmot. fluoridu sodného, ktorého podstata spočívá v tom, že pozostáva z 30 až 39 % hmot. fluoridu lítneho, 5 až 9 °/o hmot. fluorohlinitanu sodného alebo fluorokremičitanu draselného alebo fluoroboritanu draselného, 3 až 8 % hmot. fluoridu hlinitého.These disadvantages are largely removed by the flux according to the invention for the fluoride-based welding of aluminum with a content of 30 to 50% by weight. sodium fluoride, which consists in that it consists of 30 to 39 wt. lithium fluoride, 5 to 9% by weight; sodium fluorohalite or potassium fluorosilicate or potassium fluoroborate, 3 to 8 wt. aluminum fluoride.

Tavivo podlá vynálezu dosahuje výborné zváracie vlastnosti. Spoj po zvarení je čistý a kovovo lesklý, prevarenie zvarového spoja je dobré, bez neprievarov a pórov s dobrými mechanickými hodnotami zodpovedajúcimi hliníku Al 99,5—99,8.The flux according to the invention achieves excellent welding properties. The welded joint is clean and metallic shiny, the weld seam welding is good, without non-welds and pores with good mechanical values corresponding to aluminum Al 99.5 - 99.8.

Tavivo v porovnaní s inými typmi vykazuje široký taviaci interval, solidus 520 °C, liqvidus 700 °C, povrchové napatie vzhladom na nižší obsah kovov alkalických zemin je nižšie. Troska je tekutejšia a po reakcii z oxidickou vrstvou stéká do stráň zvarového kovu. Týmto je umožněné zváračovi sledovat ukladanie a odtavovanie přídavného materiálu a formovat zvarový kov tak, aby nemohlo příst k neprevareným miestam v spoji. Po přerušení zvárania je zvar bez zapečených zvyškov taviva a je možné bez ďalších úprav pokračovat v zváraní. U taviva podlá čs. patentu č. 112118 sa zapečené zvyšky taviva musia odstraňovat mechanicky. Zvyšky taviva tvoria nasýtené oxidy hliníka, ktoré pretože majú zvýšenú teplotu tavenia, zabraňujú ďalšiemu bezprostřednému napojeniu zvarového kovu. Tavivo má znížený obsah toxických látok, čím sa zlepšuje pracovně prostredie zváračov.Compared to other types, the flux exhibits a wide melting range, solidus of 520 ° C, liquidity of 700 ° C, and the lower surface alkaline earth content of the surface tension is lower. The slag is more fluid and, after reaction with the oxide layer, flows into the seam of the weld metal. This makes it possible for the welder to monitor the deposition and melting of the additive material and to form the weld metal so that it cannot access the uncured areas in the joint. After the welding is interrupted, the weld is free of baked flux residues and it is possible to continue welding without further treatment. For flux according to MS. No. 11,1118, the baked flux residues must be removed mechanically. The flux residues form saturated aluminum oxides which, because of their increased melting point, prevent further direct welding of the weld metal. Flux has a reduced content of toxic substances, thereby improving the welding environment.

Pri tavnom zváraní chladiacich a mraziacich agregátov do chladničiek a mrazničiek sa ukázalo ako vhodné tavivo nasledovného zloženia, 50 % hmot. fluoridu sodného, 39 % hmot. fluoridu lítneho, 6 % hmot. fluorohlinitanu sodného,, 5 °/o hmot. fluoridu hlinitého. V ďalšom případe tavivo pozostávalo z 50 % hmot. fluoridu sodného, 38 °/o hmot. fluoridu lítneho, 7 % hmot. fluorokremičitanu draselného, 5 % hmot. fluoridu hlinitého.In the fusion welding of refrigeration and freezing units to refrigerators and freezers, a flux of the following composition, 50 wt. sodium fluoride, 39 wt. % lithium fluoride, 6 wt. sodium fluoroaluminate, 5% by weight; aluminum fluoride. In another case, the flux consisted of 50 wt. sodium fluoride, 38% by weight; % lithium fluoride, 7 wt. % potassium fluorosilicate, 5 wt. aluminum fluoride.

Taktiež dobré výsledky sa dosiahli s tavivom, ktoré pozostávalo z 50 % hmot. fluoridu sodného, 33 % hmot. fluoridu lítneho, 9 % hmot. fluoroboritanu draselného a 8 pere. hmot. fluoridu hlinitého.Also, good results have been obtained with a flux consisting of 50 wt. sodium fluoride, 33 wt. % lithium fluoride, 9 wt. potassium fluoroborate and 8 pips. wt. aluminum fluoride.

Tavivo podía vynálezu je vhodné na zváranie najmá tenkých plechov z hliníka a profilov akosti A) 99,5 až 99,8 °/o, najmá materiálov a zariadení v chladiarenskom, mraziarenskom, potravinárskom ako aj v elektrotechnickou! priemysle.The flux according to the invention is suitable for welding in particular thin sheets of aluminum and profiles A) of 99.5 to 99.8%, particularly materials and equipment in refrigeration, freezing, food and electrical engineering! industry.

Claims (1)

Nekorozívně tavivo na tavné zváranie hliníka na báze fluoridov s obsahom 30 až 50 pere. hmot. fluoridu sodného, vyznačujúce sa tým, že ďalej pozostáva z 30 až 39 %Non-corrosive flux for fusion welding aluminum based on fluorides containing 30 to 50 pens. wt. sodium fluoride, characterized in that it further comprises 30 to 39% YNÁLEZU hmot. fluoridu lítneho, 5 až 9 % hmot. fluorohlinitanu sodného alebo fluorokremičitanu draselného· alebo fluoroboritanu draselného, 3 až 8 % hmot. fluoridu hlinitého.YNÁLEZU wt. % lithium fluoride, 5 to 9 wt. % sodium fluoroaluminate or potassium fluorosilicate or potassium fluoroborate, 3 to 8 wt. aluminum fluoride.
CS863857A 1986-05-26 1986-05-26 Non-corrosive flux for melt welding of aluminum CS259255B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CS863857A CS259255B1 (en) 1986-05-26 1986-05-26 Non-corrosive flux for melt welding of aluminum

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CS863857A CS259255B1 (en) 1986-05-26 1986-05-26 Non-corrosive flux for melt welding of aluminum

Publications (2)

Publication Number Publication Date
CS385786A1 CS385786A1 (en) 1988-02-15
CS259255B1 true CS259255B1 (en) 1988-10-14

Family

ID=5379888

Family Applications (1)

Application Number Title Priority Date Filing Date
CS863857A CS259255B1 (en) 1986-05-26 1986-05-26 Non-corrosive flux for melt welding of aluminum

Country Status (1)

Country Link
CS (1) CS259255B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ301554B6 (en) * 1999-10-25 2010-04-14 Solvay Fluor Und Derivate Gmbh Powder flux based on alkaline fluoroaluminate for dry application and process for joining components of aluminium or aluminium alloy

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CZ301554B6 (en) * 1999-10-25 2010-04-14 Solvay Fluor Und Derivate Gmbh Powder flux based on alkaline fluoroaluminate for dry application and process for joining components of aluminium or aluminium alloy

Also Published As

Publication number Publication date
CS385786A1 (en) 1988-02-15

Similar Documents

Publication Publication Date Title
US4010309A (en) Welding electrode
US5171377A (en) Brazing flux
US4940882A (en) Welding flux and welding electrode
US3560702A (en) Composite electrode for consumable electrode arc welding process
US3675310A (en) Soldering method
US3424626A (en) Low silica welding composition
US2686354A (en) Process for coating and uniting metal shapes with aluminum
US3100338A (en) Method of joining
US5728479A (en) Aluminum-lithium-magnesium filler alloy for brazing
US3107176A (en) Nickel-copper alloy welding electrode
US2768893A (en) Brazing alloys
CN111819029B (en) Method for manufacturing flux-cored wire, and method for manufacturing welded joint
CS259255B1 (en) Non-corrosive flux for melt welding of aluminum
US3124479A (en) Copper-nickel alloy welding electrode
Sekulic Brazing of aluminum alloys
US2973428A (en) Arc welding of unalloyed structural steel workpieces such as hull-plates, and arc welding electrodes therefor
US3184345A (en) Submerged arc welding composition
NO145248B (en) PROCEDURE FOR THE PREPARATION OF XYLOSE SOLUTION FROM XYLAN SUSTAINABLE MATERIALS
US2357125A (en) Light metal flux
US2817895A (en) Soldering flux composition and method of soldering with same
SU1706820A1 (en) Flux for soldering steels
RU2243073C2 (en) Flux for argon arc welding of articles of aluminum bronzes at making and repairing them
US3001898A (en) Welding with washing effect
RU2072906C1 (en) Coating composition to protect surface from sticking smelted metal splash
US2458688A (en) Welding cupro-nickel alloys