CS259045B1 - Method of d-glucose's and starch hydrolysis products' production - Google Patents

Description

Cnoco6 ΠΟΛΥΊβΗΗΗ D-rJIKNKO9H H ΠρΟΑΥΚΤΟΒ ri «pOJIH3a KpaxMana

06jiaCTb ΠρΗΜβΗβΗΗΗ H3O6pgTeHHH Η3θ6ρβτβΗΗβ KacaeTCH cnocoCa nonyneHHH D rmoKosw at προαυκτοβ rHAPonHsa KpaxMana Ή3 KpaxMana h cojjepacamero xpaxMan cbtpba πγτβΜ rnflponn3a KaTajiH3npoBaH-ΗΟΓΟ KHCJIOTOň h / hJ1H 3H3HMOM.

XapaxTepHCTKKa HgBecTi ^ x TgxHHMecKHx pemeHH D-r-moKoaa h nponyxTU rMflpojiHaa KpaxMana hbjihwtch oCnaropoxeH-HblMH npOflyKTaMH B KpaXManO-naTOHHOfl npOMbmUieHHOCTH. Bí M n n G n n n ony ony n n n n n n n H H H H H H H H H H H H H H H H H H.

OflHaKO YWE ahbho nasecTHO, ητο πρκ κηοιοτηομ rnAponuse, npexne Ečer πρκΠΟΠΚΟΜ rnflponH3e KpaxMana and D h rntoKoau ocoCeHHo πρκ nepepafioTKe aepHOBoroKpaxMana, βοβΗΗκβιοτ eucoKne rtorepu b Bbixoge b'pesynbTare oČpasoBaHHH peeep-CHOHHblX npOAyKTOB, ΓγΜΗΗΟΠΟΑΟβΗΜΧ BenjeCTB and ΤβΚΧβ 3a cMet OCpaSOBaHHB NPO-AykTOB peaKiiHň rraoKoau c βΜΗΗΟΚΗαποτβΜΗ. Bmcokhx pacxoflOB TpeCyeT φκπι, τρθ-Ahh h KpHCTajinnaaijHH npoflyKTOB κηοΛοτηογο ΓΗΑροπΗ3β, npiweM, b KauecTBe ot-xoflaiuero npoflyKTa bmxoaht Tax HaabiBaeMbion rHAPonb. 3HaHHTejibHoro nporpecca b STOE ofinacTH aoCkahcb b pesynbTaT © ΒΒβΑβΗΗΒ shsh-Hbtx cnocoCoB, onpeAenaioDtHX B HacToamee BpeMH TexHOJiornnecKHň craHAapT.HeAocTaTOK khcjiotho-βηβημηογο κπη αβοΗηογο βηβημηογο cnocoCoB COCTOHT b'no-Tepe npHpoAHbix 3H3hmos nocne OAHoxpaTHoro HcnonbsoBaHHH η b ConbmoM BpeMeHHpeaxuHň Ha aMnnorJiwKO3HflHoň 4> ase πρκ ποαηομ rHAPOJinse h CBHsaHHue c sthm He-oCxoAHMbie Conbinae pasMepm ρββκτοροΒ. <PnKCHpoBaHHeM pacmennHioiUHX KpaxMan shshmob Ha CHγτρβΗΗβΜ HOCHTene npecneAo-Banoch ycTpaHeHne cymecTBeHHbix ηθαοοτβτκοβ 3Η3Ημηογο cnocoCa ηρβΑοςτβΒΠΛ-Jiacb BOSMOXHOCTb ΜΗΟΓΟΚρβΤΗΟΓΟ HCnOnh3OBaHHH 3H3HMOB.

Hec mot pa Ha to, hto HaA mtuoGiumaaafieen ananas paGoTaur npnGnn3HTsnbHo c 1970 roAa, noxa b MHpe no cymecTByeT npOMbunneHHoro Hcnonb3OBariHH φκκοκροΒβΗ-

Hbix aMHJiorjuoKosHAaa ηπη anb $ a-aMHna3 b npoMbnnneHHOCTH no rHAponusy KpaxMana. MHoroHHcneHHbie πρηηηημ hbjihwtch pemawmuMH ajih ctojiL · 3aMeftneHHoro npoMbnaneH- ΗΟΓΟ HCnOJlh3OB 3HHH, TaK XapTManep. B. "HMMoCHJIH3OBaHHhie shshmu ΑΠΗ Hcnonbso-, 2 259 045 B B3HHH TeXHOJIOTHHX ΓΒΗηβΒΟή npOMbffiJJieHHOCTn" B Γορ Η8Ηβ # 77 (1977), Ν '7-9, πρΗΒο, ΠΗτ voltage c HeaocTaTOUHoň TepMoycToňHHBOCTbio, npexcfle Bcero, skohomh-necKHe coo6pa »ehhh.

He3HaHHTejIbHaa TepMOyCTOÍÍHHBOCTb φΗΚΟΗρΟΒβΗΙΟιΙΧ Ha HOCHTejie 3H3HMOB BefleT this purpose, HTO npn npoBeaeHHH onbiTOB C <&amp; Ha HKcnpoB3HHoň HocHTene rnioKoaMHjiaaoňHa aMHJiorjnoK03H «Hori <fra3e ποηηογο mupojmaa TeMnepaTypa Peak nh o6mhho coc-TaBjíaeT 308-318 K. Πρκ cTojib hh3khx TeMnepaTypax oratroMepw KpaxMajt and upes- BbIWaHHO nOflBepWeHbl BO3fleCTBH! 0 BHemHHX ΗΗφβΚΗΗ #, Ηβ ΓΟΒΟρΗ O CHHWeHHH ΗΚΤΗΒ “HOCTH 3H3HMOB. OCycnoBJíeHHaH TexHOJiorHeií Ββ / χβΗΗΗ npouecca ηη3κβη TeMnepaTypa peaKUHň πρκBBefleHHH φΗΚΟΗρΟΒβΗΗΜΧ Ha HOCHTeJie pacmeΠΠΗΜΒΡΙΧ KpaXMajl 3H3HMOB b peaKTopaxC HacbtnHHM, BHXpeBblM CJIOeM HB TpyĎHaTblX peaKTOpaX BefleT K HH3KOÉ CTenéHHBbixoaa, Tax HTO 3a CNET npHMeHeHHH Φηκοηροβηηημχ Ha HocHTene 3H3hmob He 6bi-south flocTHrHyTbi cymecTBeHHbie 3KOHOMHnecKHe npeuMymecTBa no cpaBHeHHto C oGbiq-HblMH CnOCO6aMH ΓΗ «ρθΠΗ33 KpaXMaJia npHpOflHblMH 3Η3ΗΜΜΗ.

Ifejib H3o6peTeHHH

UejlbH) Η3θ6ρβΤβΗΗΗ HBJIHeTCH OCymeCTBHTb ΠρΟΜΜΠΙΠβΗΗΟβ ΠρΗΜβΗβΗΗβ φΗΚΟΗρΟΒΘΗ-HblX Ha HOCHTejie 3H3HMOB NPH HCnOJIh3OBaHHH HMerontHXCH TeXHHHeCKHX yCTaHOBOKh b pe3yjibTaTe STOT chh3htb yflejibHbrii pacxofl 3H3hmob h yflejibHbiň pacxofl xpax-Man and Taras chh3htb pacxoflbí Ha onncTKy b npoyecce nojiyneHHH h nepepaÓOTKHnpoflyxTOB rHflpojiH3a 3a Cueto yMeHbineHHH BpeMeHH peaxuiHH h ycTaHOBjíeHHH not NPEPT> iBHoro xofla npoiiecca, ποβεβηθημη Bbixofla b eflHmmy BpeMeHH HC eflHHHflwoSbeMa rHnpojiH3Hbix ycTaHOBOK and Taras rivet noBbnueHHH Bbixofla KpHCTaJinHwec-khx npoflyxTOB hjih npHMbix rpaHynHTOB c pa36pbi3rHBarauHx ycTaHOBOK hjih ycTaHo-BOK C BHXpeBblM CJIOeM flo6HTbCH CymeCTBeHHOrO CHHXCeHHH CeSeCTOHMOCTH Η Ηβοβχο-ΛΗΜωχ KanHTanoBJíoaceHHň.

HajioaceHHe cynpiocTH Η3ο6ρβτβΗΗΗ B ocHoey Η3θ6ρβτβΗΗ «nojioaceHa 3aflana co3flaTb Taxyio TexHOJiornio cnocoóa nojiy-ηθηηη D-rjii0KO3bi h npoflyKTOB rHflpojiH3a xpaxMajia, ητο6η 3Η3 * ιητθιιβηο cHH3HJiaqbOnaCHOCTb 3arpH3HeHHH HJIH ΠΟΒΤΟρΗΟΓΟ 3βΓρΗ3ΗβΗΗΗ HCXOflHbIX HJIH npOMejKyTOHHbIXnpoflyKTOB nojiHoro rnflpojiH3a, τβΜ HTO 3a CNET coaflaHHH onTHMajibHbix ycjiOBHňnpoflecca Μοκβτ noBbicHTbCH TepMoycToífriHBOCTb 3Η3ημοβ h npeflOTBpaTHTbca 3aMeT * · Hoe CHHweHHe HaqajibHoft 3H3hmob φΗκεκροΒβΗΗΜχ Ha HocHTene. B C COOTBeTCTBHH Η3θ6ρβΤβΗΗβΜ 38flaHa pemaeTCH nOCpeflCTBOM ΤΟΓΟ, ΗΤΟ OHHUteH-Hbiň npoflyKT nacTHHHoro rHflpoJiH3a what 3HaneHHeM DE paBHbíM 15-35% CTepHJinsy etch b xofle xpaTKOBpeMeHHoň BbicoKOTeMnepaTypHoň οβρββοτκκ, κ npoflyKTy nacTHHHoro riwpojiHaa floSaBJíHeTCH CBOčoflHbiří 3H3HM BHfle and b ^ a-aMHnasbi, 6eTa-aMHJia3bI HJIH HMHJIOrjH0KO3Hfla3bI B KOJIHHecTBe 2-8 U Ha RPAM npOflyKTa ΓΗΛΡΟ-JIH3a, aKTHBHpOBaHHblň CBOSOflHblM 3Η3ΗΜΟΜ CyČCTpaT BBOflHTCH B peaKflHOHHblft CO ~ cyfl B KOTOpOM 06bIHH0 HMeeTCH KOMIUieKC 3H3HM3 φΗΚΟΗρΟΒΗΗΗΟΓΟ Ha HOCHTejie BφορΜβ He npenHTCTBywmeň ΑΗφΦν3ΗΗ, npoBOflHTCH rHňpojiH3 npOflyxTa nacTHHHororHflP0JIH3a B npHCyTCTBHH CBOÓOflHOrO HO φΗΚΟΗρΟΒβΗΗΟΓΟ Ha HOCHTeJie 3H3HM3 ΠρΗTennepaType 326 - 338 K flo floTHTHeHHH sHaqeHHH DE 35 - 80%, npoMeYeTOHHbiiinPOflyKT BMeCTe C HMeWIUHMCH B ΗβΜ φΗΚΟΗρΟΒβΗΗΜΜ Ha HOCHTeJie 3H3HMOM B φορΜβHe npenHTCTBywme ò ΑΗφφγ3ΗΗ H3BJieKawTCH H3 nepBoro peaKijHOHHoro Coca "ah not pesoflHTCH b nocjienyioDiHe, nponojiscaeTCH noJiHbiň rHflpojina πρκ TeMnepaType 326 -338 K npeflnoHTHTejibHo 329-335 K biuiotb λο 3Η3ηθηηη DE 95-99% aaTeMCBo6o« Hbiň 3H3HM «eaaKTHBHpyeTCH BHE peaKHHOHHoro cocyfla rivet τερΜΗΗβεκοήoCpafioTKH , fle3aKTHBHpoBaHHbn npoflyKT nojiHoro rHflpojinaa onumaeTca h nepepa- 259045 6aTbiBaeTCH nocpeflCTBOM KpHCTajuiHsaiiHH npH oxnasweHHH hjih rpaHyjiauHH lip pac-nbineHHH hjih b BHxpeBOM cjioe. CneiiHajibHbi BapHaHT cooTBeTCTByromero. Η3ο6ρβτβ-HHK) peiueHHH 3aKJiiowaeTCH b that HTO to npoflyKTy ηθοτηηηογο rHflpojiH3a what 3Hane-ηηθμ DE 15-35% floSaBjíHeTCH CBoCoflHbiíi 3H3HM (Ajiba <i> a-aMHJia3a, aMHJiorJHOKOSH-fla3a) aKTHBHpoBanHbiň shshmom npoflyxT nacTHHHoro runpojiHaa προχοηητ ο6ρβ6οτ-xy B HeCKOJIhKHX ΠΟβΚΠΙΟΗβΗΗΜΧ nOCJieflOBaTeJIbHO flpyr 38 flpyroM peaKJJHOHHblX co-CYP ax b KOTOpbix HMeeTca KOMiuiexc No Φηκοηροββηημμ Ha HOCHTejie shshmom β φορ Me He npenHTCTByromeft βπφφγ3ΗΜ, πρΗΗβΜ npn CTaynoHapHOM ΒβββΗΗΗ npoijeccacKoruieEiie h BbigepjKKa npoflyKTa ocymecTBjunoTca t3khm oOpaaoM, HTO b nepsoMcocyfle peaKUHH NPW TeMnepaType 326 - 338 ycTaHaBJíHBaeTCH SHanenne DE PAB-Hoe 40 to 80%, b nocjieflyioiUHX »e peaxiiHOHHbix cocypiax ποβ fteňcTBHeM floCaBJíeHHO-ΓΟ SH3HM8 φΗΚΩΗρΟΒβΗΗΟΓΟ Ha HOCHTejie nOJIHblň rHflpOJIHS npOflOJPKaeTCH no 3HaHe DE-hhh paBHoro 95-99% b saxjiioMeHHH rivet TepMHHecxoň o6pa6oTKH CB o6oflHbiň3H3HM fleaaKTHBupyeTcfl and ββββκτΗΒΗροββΗΗωβ npoflyxT ποληογο rHflpojiHsa omnua-eTca h nepepaĎaTbiBaeTCH nocpeflCTBOM KpHCTajuiHsaijHH NPH oxnaoKfleHHH hjih rpariy-ΙΙΗβΗΗ NPH pacribineHHH HJIH ΒΗΧρβΒΟΜ Cjioe.

CneflyiomHň cneynanbHbift BapHaHT cooTBeTCTByramero Η3θ6ρβτβΗΗκ> pemeHHH saxmoHa-b eTca the MTO κ npoflyKTy HacTHHHoro rnflpojiHaa c 3HaHeHHeM DE ρθβημμ 15% -35 Λθ3ΗρθΒκοή flo6aBJiHWT cBoOojXHbiň 3Η3ΗΜ H3 rpynn pacmeruiflioiHHX KpaXMan HJIHΟΠΗΓΟΜβρω KpaXMaaia, aKTHBHpOBaHHMit 3H3HM0M npOítyKT HaCTHHHOrO ΓΗΑΡΟΠΗ33 ΓΗβ ~ pojiHsyioT b peaKHHOHHOM cocyfle, BHyTpH hjih CHapyjKH κοτοροτο pacrtojioacen κομπ-jiexc c φΗκεπροΒβΗΗΗΜ Ha HocHTejie shshmom NPN TeMnepaType 308 to 338 K no 3ha-ΗβΗΗΗ DE paBHoro 35-80% h SATE BeflyT nojiHbiťl γηλροπη3 b peaKTope-xojioHHenpn TeMnepaType peaxHHH 318-338 K πρββΠΟΗΤΗΤβιίΒΗΟ 326-329 of no 3Hane-hhh DE paBHoro 50-96%.

CneflyromHň cneiiHajibHbiň BapHaHT cnocoóa saxinonaeTCH b that the HTO npoflyxTy NAC-THHHoro raflpojiHaa what 3Η3ΗβΗΗβΜ DE paBHbíM 15-35% floDaBnaeTCH CBOÓoflHbiň3Η3ΗΜ (ar ^ a-aMHJiaaa, aMHHorjiWKoaHrtasa) aKTHBHpoBaHHMft shshmom npoflyKT NAC-τημηογο rHflpojiHsa HenpepbiBHO HaxanJiHBaioT β oahom hjih HecxojibKHX nocjieáOBa- TejibHo noflKjHoueHHbix ffpyr 3a rtpyroM. paaKHHOHHbíX cocypax, BHyTpH hjih CHapyjKHKOTOpbix pacnojio »eH KOMiuiexc c Φηκοηροββηημμ Ha nocHTejie 3H3hmom, NPH-dark paType 326-338 Κ προβοβητ b HHX THRpojmo well 3HaqeHHH paBHoro 38 DE * - .70%»: 3aTeM rivet TepMHHecxoň o6pa6oTXH fleaaKTHBHpytoT cBoCoflHbiň shsh, fleaaxTHBH- HHaaHyAnTiOnHyAaTiTiOnTHyAnTiOnHHaaoToToBoToBoToToBoToBaToToBoMaToBoToBoToBoToBoToBoToBoToBoTaToBe 80%. B pe3yjibTaTe sToro sapHaHTa ΒβββΗΗΗ cnocoSa nojiynaior xpaxMajib-HbIH CHpOn C BblCOKHM COflepW3HHeM rJHOKOSbl,

CneflyroniHň cneuHajibHbiň BapHaHT cnocofia saxjHonaeTCH β that ητο to npOflyxTy UAC-ΤΗΗΗΟΓΟ rHflpOJIH3a CO 3Η8ΗβΗΗβΜ DE paBHbíM 15-35% B KaneCTBe CBOČOflHOrO 3H-3HM3 fl06aBJIHK) T 6eTa ~ aMHJia3y, aKTHBHpOBaiIHblň SHSHMOM npOflyKT HaCTHHHOro ΓΗβ-pojiHsa HenpepbiBHO HaxanjiHBaiOT b oahom hjih HecxojibKHX nocjieflOBaTenbHO noflicjiio-neHHbix flpyr 3a flpyroM peaxHHOHHbix cocyflax, BHyTpH hjih CHapyjKH κοτορκχ pACN-jiosceH KOMiuiexc c Φηκοηροβ8ΗΗμμ Ha HOCHTejie shshmom, προΒΟβΗτ b HHX rnupojiHano 3HaueHHH DE paBHoro 40-65% NPH TeMnepaType 328-343 Κ, 3βτβΜ nyTeMTepMHHecKoň o6pa6oTKH fleaaxTHBHpywT cBo6oflHuň sh3hm, AeaaxTHBHpoBaHHbiň NPO -flyxT rHflpojiHaa OHHmaiOT, ynapHBaiOT βο coflepxaHHH cyxoro BemecTBa nopaflxa 80% .B peayjibTaTe 3Toro BapnaHTa ΒβββΗΗΗ cnocoCa nojiynaiOT o6orameHHbi MaJibToaottcHpon. ΠρΗ προΒβββΗΗΗ cooTBeTCTByioniero Η3θ6ρετβΗΗΐο cnocoSa npHMeHjnoTca annapaTM c

MemajixaMH, HBJiHioiuHecH cTaHflapTHMMH b XHMHMecKon h SHOXHMHHecKoň peaxTOpHOň

TexHHxe h pacnpocTpaHeHHHMH aiNHyHHnHHHHHHHHHHHHHHHHHpHnMHpHMHnHHHM8MH. 259045 <I> HKcnpoBaHHMn Ha HocHTejie 3H3HMHbnnkCmKnkKkKKk ~ HJiH noflBHXHO pacnojiaraeTch b annapaTe c MeiuajiKoň. / lna stack ncnonb3yioTCH πβρφορκροΒ3ΗΗΜβ Tpy6whjih ceTaaTbie mnaHrn H3 οητο-τιοηη, τβκ mto, ηηΦΦυβηη He aaTpyflHHeTCfl. Tpy6bihjih ceTaaTbie nuiaurn ycTaHaBjíHBaioTCH b MecTax HanOonbrain TypeSyneHTHocTH. ΠρΗ ΒΗβπΐΗβΜ pacnojiojKeHHH Kaxnbiň OTflejiBHbiň annapaT paGoTaeT b pexHMe ΑΗφφβ-peHUHajibHoro προτοηηογο peaKTopa. B τηκομ cjiynae 3H3HMHbiň KOMiuiexc φκκοιρο-BaHHbi Ha Ha HOCHTejie xecTKo 3aKpenjiHeTca b Tpy6e jihhhh nepeKanxH MeJKfly flByMHCHTHaTbiMH TapejiKaMH. ΠρβΛΜβτοΜ cooTBeTCTByromero H3o6peTeHHK> cnocoča κροΜβ npovero HBJíaeTCHyMeHbraeHHe cnafla HaHajihHoň ηκτηβηοοτη Φηκοηροββηηογο Ha HOCHTejie 3H3HMa (Φκιπβρ β. "HccjieflOBaHHe bjihhhhh cHHTeTHnecKHx HocHTejieň Ha reTeporeHHwe SH SHMHbie peaKHHH ** flOKTopcKan flHccepTayHH ,, φ3κγπι> τβτ ecTecTBeHHo-MaTeMaraíec-khx Hayx, MJIY rajine- BHTTeHóepr 1980). flo6aBKoft cpaBHHTejibHO He3HannTeJibHO ~ ro KoumecTBa 3H3HMa npeflOTBpamaeTcn npexHHň HeflocTaTox b npHMeHeHHH φΜκ «τ-poBaHHbix Ha HOCHTejie 3H3hmob. fljiH cooTBeTCTByKmiero Η3θ6ρετεΗΗΐο cnoco6a bKanecTBe tfocHTejieň 3H3hm3 Ballad κροΜβ npoqero Hcnojib30BaTbcH MaKponopHCTbieCTeKna, cHjiHKarejib, npeAeapHTenbHo o6pa6oTaHHbie nejttirojio3bi, ^ aKponopHCTbiňnOJIHCTHpOJI, ΠΟ, ΠΗΒΗΗΜΠΗΒΗΗΜ. B KHHeCTBe HOCHTejlH ΠρββΠΟΗΤΗΤβΠΒΗΟ ΠρΗΜβΗΗβΤ ”CH φοφβΤΗΤ y 58 (npO ^ yKT ΧΗΜΗΗβΟΚΟΓΟ Κ0μ6ηΗ3Τ3 B ββφβΛΒΑβ ). B cjiyaae ncnojib3OBaHna cooTBeTCTByromero Η3θ6ρβτβΗΗΐο cnoco6a epoxy cjiyxBw φπκ CHpOBaHHOrO Ha-Hoch 3H3HMa ΠρΗ HCnOJIb3OBHHHH flJIH flO3HpOBKH ΠρΗρΟβΗΟΓΟ3H3HM3 nOJIOCbl DIHpHHOň 2-8 U / RPAM rnnpOJIH3aTa HCHHCJIHeTCH B 2 MeCHIja HC-KJironaa cymecTBeHHoe cHWKeHHe HanajibHoii ηκτηβηοοτη.

CneflyiOIUHNpeflMeT Η3θ6ρβΤβΗΗΗ no CpaBHGHHtO C H3BeCTHbIM ypOBHeM TeXHHKH sa-KmoHaeTCH b co3flaHHH 6onee 3φφκτΗΒΗωχ ycjiOBHn 3H3HMHbix peaKijHft.

Ebino ycTaHOBJíeHO, hto 3a cneT BbicoKoň HanajibHoň KOHneHTpaijHH μοηομθρημχρημχχμhjHAHMepHbix κομποηθητοβ cyÓcTpaTa ynymnaeTCH TepMoycHo HocHTene shshmob. OflHOBpeMeHHo, 6ojiee BbicoKoe coflepacamie mohom6phux hjihflHMepHbix κοΜπΰΗβΗτοΒ cyČcTpaTa o6ycnaBHHBaeT ycTaHOBjíeHHe 6ojiee BbicoKoroocMOTunecKoro flasjíeHHH, κοτοροε οοηθτηηηη b c cooTBeTCTByromeň Η3θ6ρετβΗΗΐοBbicoKoň TeMnepaTypoň peaKijHH HcronronaeT o6pa3OBaHHe h pa3MHO3KeHHe MHKpoopra-HH3MOB. BcnejmcTBHe nero ocymecTBjíaeTCH HenpepbiBHbien xofl npoiiecca h H36e-ra »TCH oco6bie npeflocTopoacHocrá. ΟοοτΒβτοτΒβΗΗΟ KOJiHHecTBy h sejiHHHHe cocyflOB and Taxation HeoSxoflHMOMy cpeflHeMyBpeMeHH npeSbiBaHHH b xajKflOM annapaTe c Memajixoň pa3MemaeTCH ctojibko "CBH-aaHHoň aKTHBHOCTH" HTO b coHeTaHHH what οβο6οληβιμ 3H3HMOM o6ecnenHBaeTca online THManbHbift rHflponH3. PeryjiHpoBaHHe KOHenHoro 3HaneHHH rnflponH3a HenpepbiB NPH-hom xofle npouecca μοκθτ ocymecTBjíHTbCH πγτβΜ υοτβηοβκη noflann βμχοηηογοcy6cTpaTa, peryjiHpoBKH noflaHHoň cBoSoflHoň h CBH3aHHoň 3H3hmhoh βκτηβηοοτη aa CNet ycTáHOBKH TeMnepaTypbi rHflpojiHaa. B cooTBeTCTByromeM Η3θ6ρβτβΗΗcno-ω 3HaqeHHe pH Bbi6npaeTca b HHTepBane 4.0-4.7, bt cjiynae, ecjm pa6-TaioT cMMaa-aMHna3aMH. Π Η c Η o H H - H r r 5 5 5 5 5 5 5 5 5 75 75 75 75 75 75 75 75 75 75 75 75 75-80%.

Even flanee bo3mojkho b cooTBeTcTByJomeM Η3θ6ρβτβΗΗ «> cnoco6e HcriojihsoBaTb ocTaBrnnii CH B OSeflHeHHOM paeTBOpe 3H3HM3 npeflHa3HaneHHOM flJlH φΗΚ03ΗΗΗ CBO6o # ~ hora 3H 3HMa Ha Hoche 3H3HM B ΚβΗβΟΤΒβ CBOÓOflHOrO 3H3HM3. MβΜ caMblM flOCTHraeT-ch flanbHenan skohomhh 3H3HMOB. CoraacHO Η3θ6ρβτβΗΗΐο oHHCTxa h cTepHnHaaixHHnpoflyxTOB nacTHHHoro rnflpoJiHaa b 33bhchmocth ot HMewmeňcH TexHonorHH Φηπβτ-panHH, Μθ »βτ npOH3BOflHTbca taxxi nocne floSaBKH npHponHoro 3H3HMa npn snāna-hhh DE paBHOM 35 '80% b that cnynae, ecnH o6ecnennBaeTCH KaTanuTHnecKoe 259045 BO3fleňc_TBne npupoRHoro 3H3HMá 3a CNET npeRBKJWHeHHH annapaTa c MewajiKOn, bkotopom coBepuieHHo He HMeeřen Φηκοηροβηηηογο 3H3HMa. 0co6oe 3HaMeHne πρκοβρβτββτ το ο6οτολτ &amp; πβοτβο, ητο β cooTBeTCTByionieM H3o6pe-τβΗΗΐο cnocoGe mowho Hcnonb3OBaTb oCbniHbie annapaTbi c MemajiKoň. B pesyjibraTe3ΤΟΓΟ BO3MO3KHO 3HaHHTeRbHO nOBblCHTb npOH3BORH'renbHOCTb ΤΗΚΗΧ yCTaHOBOK co-TopBio RO HaCTOHmerO ΒρβΜβΗΗ paĎOTajlH CO CBOSORHblM 3H3HM0M ΠΟ nepHORHnecKOMymin HenpepbiBHOMy pejKHMy, Tax HTO npn one hundred meters Ballad oTnacTb HeoSxoRHMbie pacxoRbiHa Hobbie KanuTajioBjíoHceHHH, 5E22 Eíí_2SZ322Z2í £! 21ííí2..íí22! 2E2ISÍí25 '

OcymecTBjíeHHe cooTBeTCTByranero HsoOpeTeHmo cnoco6a 6onee noRpoČHo noncHHeT-ch c noMomwo HHaecneflyjoiHHx npHMepoB ocýmecTBneHHH: ΠρΗΜβρ 1 rionyneHHe MOHOrnRpaTa D-rniOKoabi

CycneH3HH KpaxMajia c cyxoft Maccoň nopHRxa 35% conHo rnoToň roborhtch ro3ΗβΗβΗΗΗ pH 2.2 h pa3naraeTCH b HenpepbiBHOM κοΗΒβρτερβ npw TeMnepaType 403 KRo BejiHHHHbí DE 10%. The pH of the pH 5.5 to 6.0 h of the pH of the sample is 358 ° C. Ha orhh κγ KpaxMana flo3HpoBKoN npHCaBJiHeTCH ot 1500 ro 2500eRHHHR SKB. IIpeflBapHTejibHbiň npoflyKT rHRponH3a, nonyneHHwň khcjimm Ajiba <i> aaMiinoJiHTHHecKHMo6pa3OM roborhtch ro sHaqeHHH pH 4.5 b h OHHqaeTca nepBHHHoň ReHTpHtfcyre not npephiBHoro ReňcTBHH, mnaMOBOM cenaparope Taiotce HenpepbiBHoro ReňcTBHH h <J) HJIhTpyeTCH HaMblBHblM ΦηΑβτρομ. nOJiyHeHHbLi H OHHiqeHHblH KHCROTHO-aRblI> a - aMHRORHTHlibe npeRBapHT & RbHblft npORyKTrnRponn3a CTepnjiH3yeTca nyTeM οδρββοτΚΗ b nnacTHHnaTOM τβπποοβΜβΗΗΗΚβ ho6orpeBaeMOM pypyÓMaTOM HarpeBaTejie. T T n K K K K K K K K K K K K K K K K K K K K K K K K K K K K K HR HR HR HR HR HR HR HR

PaccMaTpHBaeTca tojihko cTaRHQHapnwň pesoiM ReňcTBHH cnocoCa. nonwň rHRpORHSnpoRyxTa nacTHHHoro rHflpojra3a npoBORHTca nyTeM ο6ρβ6οτκη cornacno οοοτΒβτατ-ByioweMy Η3θ6ρβτβΗηιο pemeHnio. flnn npoBeRennH, raRojinranecKoň ο6ρβ6οτκη ope-RycMOTpeH RecHTHCTyneHnaTwň xacxaR H3 pnfla nocneROBaTejibno noRKjnoneHHbixo6orpesaeMbix pe3epByapoB c MemanKaMH eMKOCTbio 40 m3 KaaBbi. THR of the npBO-rHnHNHnHnHNHNHNHNHNHNHNHNHNHHHHHHH pH 4.1-4.7 h coRepxcaHnn 35% cyxoroBeinecTBa b cyScTpaTe. flnn o6pa6oTKH κ CTepnjihHOMy n onnmeHHOMy npoRyTs nac-τηηηογο rnRpoRH3a RosnpoBKoft Ro6aBRH »T aMHRornwKOSHRaay H3 Aspergillus ni-ger b KonnnecTBe 5 - 8 U Ha rpaMM cyxoro BemecTBa. AKTHBHpoBaHHUn shshmomnpoRyxT nacTHHHoro rnRponnaa noRaeTCH b 1 — go pe3epeyap rrh o6pa6oTKH. B neppbom peaKRHOHHOM cocyRe pacnojno «eH 3H3HMHMň κομππθκο φηκοΗροΒβΗΗΗή Ha HocnTe-jie. CpeRHee 3HaneHne DE cycopara b 1-m peaKTope ji b b ene ene 60 - 60 - 60 60 60 60 60 60 60 60 60 art art art art Bo 2-MpeaKTope naxoflHTcn 150 ΚΓ aKTHBHpoBaHo 3H3HMOM cMojibi-HocHTenn. CpeRHee '3HaneHHe DE bo 2-m peaKRHOHHOM cocyfle bear τ b oSjiacTH 70 - 75%. C 3thm 3Ha-ηθηηθμ DE npoMexyTouHbi. npoRyxT H3 BToporo peaKTOpa nocrynaeT Β τρβτρή. B 3. ro 10. peaxTopax coRepatHTCH 300 xr ro 350 g cMOHH-HOCHTenH. CMona-HocHTenh pacnonoHceHa b cocyRax c MemanKaMH b oĎnacTHX HaHoHBmeň Typ6yneHT-HOCTH. 3 φ β 6 6 KT KT KT KT H H H H H H H H KT KT KT KT KT KT KT KT KT KT c c c c c c c c 259045 JIponycKHaH cnocoGnocTb xacKana jwhht b npenene 7.3 M3 / nac, hto cooTBeTCTBy-er roflOBOMy BbinycKy npoflyKHHH okojio 23,000 τ npoHyKTa ποπηογο rnflponH3a.

Zina flajibnefiiueíí ο6ρ »6οτκιι προπγκτ ποπηογο rHflponH3a n3BJieKaeTca 10 H3 ~ ro an-steamed MeiuajiKoň c,; ie3aKTHBnpyeTca rivet τβρΜΗπεοκοή oÓpaGoTKH, OHMiuaerca, KoimeHTpnpyeTCH non fleňcrBHeM τβΜΠβρβτγρω h BbicyniHBaeTcn npn pacnbinennH.IIpHMep 2 ílonyaeHne KpaxManbHoro cHpona. I ony bi ň ac ň p p p p p p p p p p p p p p p p p p p ac ac ac ac ac ac ac ac ac ac ac b b b b b 06pa6oTKa προη3βο, π; ητοη b cocyfle c Mem.aJl ~ koći eMKOcTb »32 m3. 06orpeBaeMbiři cocyn c MemaJiKoft oSopynosaH HMnennepnoňMemajiKoň, flna npoBeneHHH cooTBeTCTByrauero Η3ο6ρβτβΗΗκ> cnocoQa προπγκτ NAC-τηηηογο ra n; pojiH3a hobohhtch it 3HaneHnH pH 4.2 h flo3HpoBKoň RPAM npoflyK Ha-ra rn apoHH3a HoSaBnaeTcn rnwKoaMHnaabi 2U. ΑκτΗΒΗροΒβΗΗΜϊί 3Ηημομ προπγκτuacraHHoro rnnpojin3a 3areM bbohhtch b pe3epByap nnn o6pa6oTT í. B pesepsyapeΗΠΗ S K ec ec ec ec ec ec ec ec ec ra ra ra ra ra ra ra ra ra ra ne ne 150 150 150 150 150 150 150 150 150 150 150

H3 HOCHTeie 3H ~ 3HMa πρΟΛγκτ nacTHHHoro rHflpoHH3a pa3JiaraeTca aj κ 3 3 3 3 h3 cocyna cMemajiKoň 42%. IIponycKHaa cnocoSHOCTb cocTaBnaeT οκοπο 2 τ b nac. IIpoflyKT rHflponH3a ftesaKTHBHpyeTCH πγτβΜ M M ň 6 6 6 6 pa pa pa pa pa pa pa pa fle fle fle fle fle fle fle fle fle%%%%%%%%%%%% IIpHMep 3 nonyneHHe cHpona, o6orameHHoro ManbTO3Oii

nonyneHHbn cornacHo npHMepy 1 προπγκτ nacTHUHoro rHflponHaa cooTBeTCTseHiioΗ3ο6ρβτβΗΗΐο nepepaSarbinaeTca b KpaxMajibHbi cnpon c bwcokhm coflepxaHHeM M & Jib “TO3bI. C 3TOň HejlblO nPOflYKT HaCTHUHOrO 5.4ΠΗ3β flOBOflHTCH flO 3Η3ΠβΗΗΗ pH 5.4 - 5.8 h flO3HpoBKo He flo My My My My B B B B B B CH CH CH asa asa. Akthbh-'poBaHHbi 3H3HMOM προπγκτ HacTHHHoro rn.qpo.nn3a HenpepbiBHo BBOflHTCH b pesep · ”Byap c MemajiKoň 15 μ3. B peeepByape flna o6pa6oTKH acecrKO yKpenneHO350 ΚΓ CMOJlbl — HOCHT6JIH. B ΙΟΗβΟΤΒβ CMOJIbl — HOCHT &amp; SOUTH e e e ΗΤΗΤ ΗΤΗΤ .C .C .C .C .C ona 58.CMona-HocHTejib KT BH H BH p iac iac 3 3 3 3 3 3 3 3 3. TeMnepaTypa cy6cTpaTa ycraHaBnHBaeTCH to 332 K. oρΗ BecoBOM pacxone 1 τ nonynawT oSorameHHon ManbTO3O &amp; cnpon c conepacanHeM50% ManbTO3bi b cyxoM BemecTBe. IIpHMep 4 ΠοΠΥΗβΗΗβ MaJIbTO3HOrO CHpona Προπγκτ qacTHHHoro rHHponHsa, nojiyqeHHbiň cornacHo npHMepy 1 rfle b p aanoMcjiyqae Moxhe npeHeSpenb cTepHjiH3aHHeň h nonojiHHTejibHoň ancopSnHOHHoň ohhct "κοβ, cooTBeTCTBeHno H3o6peTeHH» nepepaGaTbisaeTca KpaxManbHbiň cnpon b-c bmco KHM conepacaHHeM ManbTO3bi. C 3T0ň nbio προπγκτ qacTHHHoro runponHaa hobohhtch ho sHaweHHH pH 5.2 - 5.5 η κ HeMy ποβΗροΒκοή no6aBjiHeTca npHponHan an ^ a-aMunaaa.

AKTHBHPOBHHblbl 3H3HMOM ΠρΟΗΥΚΤ Η30ΤΗΗΗΟΓΟ rHHpOJIH3a HenpepbIBHO BBOflHTCH B oSorpeBaeMbion pe3epByap c Mentanxoň ofíbeMOM 40 m3. B peaKHHOHHOM pe3epByape HaxoflHTCH 200 κγ CMOjihi-HocHTejia. 259045 B KauecTBe cMOJibi — ηοοητθπη πρκΜβΗΗβτοΗ Βοφβτκτ y 58. CMona-HocHTenb hkthbh — pee-rcH 6eTa-aMHna3on H3 Bacillus subtilis.

TeMneparypa cyScTpaTa ycTaHaBHHBaeTcn Ha 333 K. lime neoBOM pacxofle 5 τ / nac nonynaioT ManbToaHbi Chpon c conepxaHHeM οκοπο65% Mani> TO3bi b cyxoM BemecTBe. ΠρΗΜβρ 5 nonyneHHe MonorHflpaTa Ο-γπιοκΟβμ IIpoflyKT HacTHHHoro rHflponH3a nonyneHHbiň cornacHo npHMepy 1 RNE b αβηηομcnynae mojkho npeHeCpenb cTepnnH3au (HEN Η ΛοηοπΗΗτβπΒΗοίί aacopČUHOHHoft ohhct-κοή, οοοτΒβτοτΒβΗΗΟ Η3θ0ρβτβΗΗΐο nepepaSaTbisaeTCH b npoflyKT ποπηογο γηαροπη-3a as 3HaneHHeM DE pasHbíM 97-99%. Fljia rnflponHTHHecKoň o6pa6oTKn NPE «Ha3HaHaeTCH oflHHHawaTHCTyneHHaTMň xacxaflnoflKnmeHHbrx bp" fl oGorpeBaeMbix pesepByapos c MenianKoň θμκοοτβ »no 40 m * K» flbiň. Γκπ; ροπΗ3 ocymecTBnneTcn NPH TeMnepaType 328-333 K SHaneHHH pH4,1 - 4.7 h eoflepwaHHH cyxoro BemecTBa b cy6cTpaTe οκοπο 35 %. C uenbio o6pa6oTKH Ha κεοκηωή RPAM OHHineHHoro προρ, γκτβ nacTWHHoro ΓΗ # ροπΗ3βfloaupOBKoň flobaBnaioT 0,020 PUN nynnynaHaabi (npoMoijHM 200 L). AKTHBHpOBaHHblň 3H3HMOM npOflyKT HaCTHUHOTO ΓΗΠΡΟΠΗ33 BBOflHTC «b Kacxafl ρβ3βρ ByapoB ~ c MemanKaMH b Ka f φ β h b β b b b b b b b b b b b b b b b b b b b b b b b 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3φφβκτΗΒΗ3Η o6maa ηκτηβηοοτβ oGecnenHBaeT Ha Bbixofle o ^ HHHajwaToro annapaTa3Η3Η6ΗΗ6 DE paBHoe 79 - 99%. IIponycKHaa cnoco0HocTb Kacxafla cocTaBnneT 15 MS / nac. 3ΚΟΗΟΜΗΗ 3H3HM3 0ΠΗ3Κβ K 80%. flanbHeitmaa nepepaĎoTKa προβγκτβ ποπηογο rH, nponH3a Μοκβτ npoH3BOflHTbca H9-BeCTHbÍM O0pa3OM.

AHHOTayHH

Gnocoč nonyweHHH 0-h γπιοκο3Η npoflyKTOB rHflponH3a KpaxMana Η3θ6ρβτβΗΗβ Kaca-RCH cnoco6a nonyneHHH 0-γπκ> κο3μ h npoflyKTOB rHflponHsa KpaxMana H3 OHHineHHOrO npOHyKTa HaCTHHHOrO ΓΗΗΡΟΠΗ33 B XOfle ΚΟΤΟΡΟΓΟ προπγκτHaCTHHHOrO rHflpOHH3a 0ΤβρΗΠΗ3γ »Τ, flOBOflHT Flo 3Η8ΗβΗΗΗ pH 4.0 - 6 , 0, flO3HpO-BaHnew floSaBnaiOT CBoGonHbiň shsh H3 rpynnu shshmob, aacmennHWiUHX KpaxManη / ηπη οπΗΓΟΜβρΜ KpaxMana, HanpHMep, απβΦη aMunasu, 6eTa-aMRna3bi, Ramm-3MH-na3bi, KOTopbie Ballad 6μτβ gononHeHbí nnnasaMH, Seta-rnwKaHasaMH ηπη neHTOSaHa-33MH, KaTanH3HpOBaHHblft 3H3HMOM Cy6cTp3T ΠβρβΒΟΗΗΤ b OflHH ΗΠΗ 6θΠββ peaKHHOH "Hbix cocyflOB b KOTopbix HMeeTCH κοΜππβκο HocHTenb / b 3hshm φορΜβ Ηβ πρβππτετ-Bywmeň« Ηφφγ3ΗΗ, noflBeprawT KOM0HHHpoBaHHoň nwpojiHTHHecKoň ο6ρβ6οτκβ CBO-GoflHblM 3Η3ΗΜΟΜ Η φΗΚΟΗρΟΒΒΗΗΜΜ Ha ΗΟΟΗΤβΠβ 3H3HM0M, rHflpOnHTHHe CKyW oGpaGoT "κγ προβοαητ NPN TeMnepaType 326-338 K ηρβπηοΗΤΗΤβΠΒΗΟ 331 to 335 K, and τβκ-XE NPN HananbHOM sHaneHHH DE paBHOM 35-80% nepHOHHnecKan ηπη HenpepuBHano6pa6oTKa ΒβΛβτ b τβπβΗΗβ oflHoň ηπη 6onee CTyneHeň κ Kohyo rňnpónHsa, CNE-ΗηΦηηηομυ flna npoflyKTa, 3βτβΜ πγτβΜ TeMnepaTypHoň οβρββοτκπ fle33KTHBHpywT3Η3ΗΜ b cy6cTpaTe, OBHinawT h nepepaCaTbieaioT b KpaxManbHuň cnpon, KpaxManb-Hbiň caxap ηπη BHHorpaflHuň caxap.

OopMyna H3o6peTgHHg 1. Cnoco6 nonyneHHH D-rnwKosu h npoflyKTOB rHHponHsa KpaxMana πγτβΜ γηπροπη- 3a Κ3Τ3ΠΗ3ΗρθΒ3ΗΗΟΓΟ KHCnOTOŮ η / ηΠΗ 3H3HM0M OTnHHaWIUHnCfl ΤβΜ, ΗΤΟ Κ ΟΗΗΠΙβΗ “

Hony npoflyxTy nacTHHHoro rHflponHsa, nonyneHHOMy HaeecTHUM oCpaaQM h HMerane- 259045 8

My 3Ηθηθηηθ DE pasHoe 15 - 35% ripunaiOT θκτηβηοθτβ αο3ηροβκο &amp; οβο0ο, π (ηογο, pacTBopHMoro, pacinennjwinero KpaxMan hjih onHrocaxapHflbí 3H3HM3, KaTajiH3HpoBaH "Hblň 3H3MMOM cyCcTpaT ΠθρθΒΟβΗΤ B OflHH HJIH 6ojiee peaKIJHOHHhDÍ COCyflOB (PEAK ~ τορ c MeiaajtKoň, peaKTOp c βηχρθβμμ θλοθμ) b κοτορωχ ΗΜβετω κοΜηπεκο hoch-TeJIb / 3H3HM B φθρΜΘ Ηβ nperiHTCTByiOIUeň ΠΗφφν3ΗΗ, npOBOflHTCH KOMSHHHpOBaHHaarHflpojiHTHBecKaa o6pa6oTKa Rip TeMnepaType 326-338 K πρβχζποητΗτεηΒΗΟ 328 ~ 331 K cHanajia ro 3Η3ηθηηη DE 35-80% H πρκ HeoSxoflHMocTH, one hundred tons npon; eccnpoflojTDKaioT b ojíhom hjih fíojree peaKTopax ro βηθμθηηη DE ρββηογο 95 to 99%. ' KOMiureKc HocHTeJir> / 3H3HM yflepjKHsaioT hjih pereHepHpyraT, aare .nesaKTHBHpyraT "cBoSoAHbiň" 3H3HM riyTeM τερΜΗΒβοκοϋ o6pa6oTKK, rHflponH3aT otoíusiot h nepepa-CarbiBaioT ηθβθοτημμ oSpaaoM. Cnoco6 second well nyHKTy 1 OTnHHarantHňcH τβΜ, ητο b xanecTBe pacmermínomero kpax-msjs hjih oj iHrocaxapHlb 3H3HMa HcnojibayioT am ^ aMHJia3bi, 6eTa-aMHJia3bi, raMwa-! 3. HNHOPHMH 1 H 2, OTHIHHIIOHHEcH tgm, hto pacmenJiHiOJTi; Haxaxapmrbi 3H3HM flonojiHH10T 6eTa-TJH0KaHa3aMH, neHTasaHaaaMH, jinnaseMH hjihHenJiiona3aMH. 4. Cnocoó no nyHKTaM 1,2 h 3, oTnHnOrHncH- τθμ, ητο γη, π; ροιιη3 προρ, γκτβ nacran-ΗΟΓΟ rHflP0JlH3a ΠΡΟΒΟΛΗΤ B XOft HenpepbIBHOrO HJIH KBa3HHenpepbIBHOrO OflHO ΗΠΗMHorocTyneHnaToro riponecca. 5. CnocoS no nyHKTy 1, OTjiHnawiUHIicH τèμ, hto npn ocyinecTBjieiiHH nojiHoro ruR-pojiHaa npoflyKTa nacranHoro rHflpojiHaa uejrecoo0pa3Ho H3nojn> 3onaTb 6ojiee 6 pe-sepByapoB c yenbio BefleHHH HenpepbiBHoro npoyecca. 6. Cnocofi no nyHCTy 1, OTjiHnaraqHňcH τèμ, wo MexamrnecKoe pasflejienne TBep-floft h «HflKoň φβ3 npoflyKTa nacrannoro rHfípoji h3a προη3βορ; ητ b xo; 7th CnocoB well nyHKTaM 1, 2, 3, 4, 5 h, 6 oTJiHnaraiuHňcH τθμ, ητο προΗ3ΒθβΗτεηonpefleneHHoe ποβμηιθηηθ θκτηβηοθτη nocpe ^ CTBOM ββοηη npnpofíiioro 3H3HMa, well ™ -jiynaeMoro b ochobhom H3 ο6θ, π; ηθηημχ οθτθτκοβ KOjinnecTBa 3H3hmh neoGxoflHMóroftJIH HMMO0HJIH3aUHH . 8. GnocoC no nyHKTaM 1, 2, 3 o 7, oTnHnaramHncH tn, miiorocTy ™ neiwaToro npoyecca na Kaac, npHroflHoň rrk CTyneriH CaMOTO paSJIHBHOrO COCTasa. 9. CnocoC no nyHKTaM 1, 2 H 3, oTJiHHarauHncH, ητο πητοηημθ ρεακτορπ cTeMnepaTypaMH peaKijHH 318 - 338 K HcnojiB3yroTcn b κομ6ηιΙ3ιχηη, c npeflBKjiranen-HbiMH peaKTopaMH c MemanKaMH. ΠρΗ3ΗΒΗΟ Η3θ6ρθΤΘΗΗΘΜ ΠΟ pesyjIBTaTaM 3KcnepTH3bI, OCymeCTBJíeHHOň BeflOMCTBOMIJO flenaM Η3θ6ρβΤΘΗΗίί Η ΠΘΤΘΗΤΟΒ ΓΧ1Ρ. 259045

Claims (9)

OBJECT OF THE INVENTION CLAIMS 1. A process for the preparation of D-glucose and starch hydrolysis products by starch hydrolysis with an acid and / or enzyme catalysed method, wherein the purified partial hydrolysis product obtained in a known manner having a pH of 15 to 35% is dosed with a specific activity of the free soluble enzyme cleaving. starch or oligosaccharides, the enzyme-catalyzed sub-substrate is introduced into one or more reaction vessels in which the diffusion-free carrier-enzyme complex is carried out, the combined hydrolysis treatment is carried out at a temperature of 326 to 338 K, preferably 328 to 331 K, initially to DE values of 35-80% and, if necessary, a process in one or more reactors up to a value of 95-99%. complex, carrier-enzyme is left or regenerated, and the free enzyme is deactivated by heat treatment. The hydrolyzate is purified and processed in a known manner. 2. A process according to claim 1 wherein the enzymatic digestion starch or oligosaccharides are free-amylase, -amylase, -amylase or amyloglucosidase, or as an enzyme-fixed enzyme. 3. The process of claim 1, wherein the enzymatic starch or oligosaccharides are supplemented with gluconase, pentazanase, lipase, or cellulase. 4. The process of clauses 1, 2 and 3, wherein the hydrolysis product of the partial hydrolysis is carried out continuously or semi-continuously by one or more step processes. 259045 ΙΟ 5. A process as claimed in claim 1, wherein more than 6 reactors are used in continuous operation during the complete hydrolysis of the partial hydrolysis product. 6. A process according to claim 1 wherein the mechanical separation of the solid and liquid phases of the partial hydrolysis product of the step process is carried out at a DE of 35 to 80%. 7. A process according to any one of claims 1 to 6, wherein the definitive addition of activity is effected by converting the natural enzyme obtained from separate enzyme residues required for pro-mobilization. 8. A process according to any one of claims 1 to 7, wherein, in a multi-stage process, the hydrolysis products of the respective composition are taken from different stages. 9. A process as claimed in any one of claims 1 to 3, wherein the flow reactors with a reaction temperature of 318 to 338 K are used in combination with pre-stirred reactors. 259045