CS256916B1 - Method of adhesives production - Google Patents

Method of adhesives production Download PDF

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Publication number
CS256916B1
CS256916B1 CS839884A CS988483A CS256916B1 CS 256916 B1 CS256916 B1 CS 256916B1 CS 839884 A CS839884 A CS 839884A CS 988483 A CS988483 A CS 988483A CS 256916 B1 CS256916 B1 CS 256916B1
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CS
Czechoslovakia
Prior art keywords
methacrylate
forming
radical
trioxa
diepoxide
Prior art date
Application number
CS839884A
Other languages
Czech (cs)
Inventor
Rolf Maertin
Hans-Heinrich Hoerhold
Elisabeth Klemm
Horst Wolf
Ludwig Haase
Evelyne Riesenberg
Ute Rudolph
Original Assignee
Rolf Maertin
Hoerhold Hans Heinrich
Elisabeth Klemm
Horst Wolf
Ludwig Haase
Evelyne Riesenberg
Ute Rudolph
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Publication date
Application filed by Rolf Maertin, Hoerhold Hans Heinrich, Elisabeth Klemm, Horst Wolf, Ludwig Haase, Evelyne Riesenberg, Ute Rudolph filed Critical Rolf Maertin
Publication of CS256916B1 publication Critical patent/CS256916B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
    • C08F299/028—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight photopolymerisable compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/04—Joining glass to metal by means of an interlayer
    • C03C27/048—Joining glass to metal by means of an interlayer consisting of an adhesive specially adapted for that purpose
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06—Joining glass to glass by processes other than fusing
    • C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Description

11

Ha3naHne n3o6peTeHnfl:Cnnco6 nojiyqeHHH Kneee OSnacTb npHMeHeHHH H3o6peTeHHH: H3o6peTeHne othochtch k cnocoBy nojiyqeHHH KJieeB Ha οοηοββημη MeTaKpHJiaT—ah—atlOKCHflHOň nOJIHMepH3aUHOHHOÍi CHCTeMbl. KjieH COrnaCHO Η3θ6ρεΤβΗΗΙ0 OCOfíeHHOπρΗΓΟ,π,Ηω απη GKnenBaHHH onTHMecKHX fleTaneň b κομ6ηη8ηηη οτβκηο/οτεκπο hjihCTeKJio/MeTa.nji flpyr c npyroM απη. o6pa3OBaHHH οπτημθοκηχ cucTeM coSmoflaH bh-COKH6 TpeČOBaHHH Ha TOHHOCTb. ri03T0My OHH HaXOAHT ΠρΗΜβΗβΗΗβ npeHMymeCTBeHHO B OSnaCTH ΟΠΤΗΚΟ-MeXaHHHeC-Koň npOMbDUJieHHOCTH.Ha3naHne n3o6peTeHnfl: Cnnco6 nojiyqeHHH Kneee OSnacTb npHMeHeHHH H3o6peTeHHH: H3o6peTeHne othochtch k cnocoBy nojiyqeHHH KJieeB Ha οοηοββημη MeTaKpHJiaT — ah — atlOKCHflHnnnHMepH3aUHOHHOi CHCTeMbl. KjieH COrnaCHO Η3θ6ρεΤβΗΗΙ0 OCOfíeHHOπρΗΓΟ, π, αω απη GKnenBaHHH onTHMecKHX fleTaneň b κομ6ηη8ηηη οτβκηο / οτεκπο hjihCTeKJio / MeTa.nji flpyr c npyroM απη. o6pa3OBaHHH οπτημθοκηχ cucTeM coSmoflaH bh-COKH6 pe a H H H H H H H H H ri03T0My OHH HaXOAHT ΠρΗΜβΗβΗΗβ npeHMymeCTBeHHO B OSnaCTH ΟΠΤΗΚΟ-MeXaHHHeC-Horse npOMbDUJieHHOCTH.

XapaKTspucTHKa H3BecTHbix TexHHHecKHX peiueHHň: 1Í3 JlHTepaTypbl ywe H3BeCTHbI CMeCH H3 A^yHKAHOHanbHbtX anOKCHAHbIX CMOJI η Μβτ-aKpHJiOBOMerajioBoro 3(})Hpa απη πριίΜβΗβΗΗΗ b xaqecTBe HeTOKCHqecxoro xjieH(M.C. HmyMpaTOBa, JI.B. CepreeB, JI.A. TepacyHOBa, Οπτηκο-μθχ. ΠροΜωπιπ, 39(1972), 30). OTBepHweHne 3flecb ocymecTBJíHeTCH AH6eH3OHnnepoxcHAOM B.npHcyTctbhh AHMeTHJiaHHJiHHa ιιπη <$eHnn6yTauQHa npH KOMHaTHoň TeMnepaType 6ea fleňcT-BHfl CBeTa. HeflOCTaTOMHblM ΑΠΗ ΠρΗΜβΗ6ΗΗΗ npH 3TOM ΗΒΑΗβΤΟΗ κοροτκοβ ΒρβΜΗ 06pa6oTKii β 45-55 MHHyT nocne ποαγοτοβκη CMeceň KJieeB. ΠροδπβΜβτΗΗΗΟ flajibuieTO, MTO npH Η33Β3ΗΗ0Μ ΚΠΘβ HCnOJIb3yiOT TOAbKO HHHUHaTOpbl, Ofíp33ylOmH6 paflHKan,h nosTOMy AHftyHKUHOHajibHaH anoKCHflHaH CMona He yqacTByeT β ποηημθρη38αηη,a co6cTBeHiio cnywHT HanojiHHTejieM απη nojiHMeTaxpHJiaTa (H.Jahn., Epoxídharze,VEB Deutscher Verlag fur Grundstoffindustrie). PeaKAHH βποκοηαημχ rpynn c3φΗρΗΗΜΗ rpynnaMH ΠΟίΙΗΜβΤΚΠΜΘ Τ3ΚρΗίΙ3Τ3 ΠΡΗ O6pa3OBaHHH CJIOWHbK. 3φκρθΒ npOHCxoaht TOjibKO b He3HaqHTenbHOň Mepe (JI.H. KoMapoea, J. Polymer Sci. 16 (I)Ϊ643) .TáKHe Kjien opu npeepameHHH «ηηκογο κηβπ b OTBepwfleHHoe Kneeeoe coeAHHe-HHe HMeroT 3HaHHTejibHyio oSbeMHyw ycaflxy Me»Ay 18-202 (E.G. Hausler, E. KlemmK. Fricke, J. Benne: Plaste und Kautschuk 27 (1980) 678). Ππη πρΗΜβΗβΗΗΗ bKauecTBe oriTHHecKoro κηεπ c uexibio οκηθηβ3ηηη c ManbíM HanpH*eHHeM οπτΗΜβοκκχAerajieň c Bbicoxoň TOMHOcTbw ohh nosTOMy HenpHroAHbi. flajibtne μ3βθοτηη (boToqyBCTBHTenbHbie βποκοηαη b xaqecTBe ochobhoto MaTepnana 256916 ~-2--XapaKTspucTHKa H3BecTHbix TexHHHecKHX peiueHHň: 1Í3 JlHTepaTypbl YWE H3BeCTHbI CMeCH H3 N yHKAHOHanbHbtX anOKCHAHbIX CMOJI η Μβτ aKpHJiOBOMerajioBoro-3 (}) Hpa απη πριίΜβΗβΗΗΗ b xaqecTBe HeTOKCHqecxoro xjieH (MC HmyMpaTOBa, JI.B. CepreeB, JI.A. TepacyHOBa, Οπτηκο-μθχ (39) (1972), 30). OTBepHweHne 3flecb ocymecTBJiHeTCH AH6eH3OHnnepoxcHAOM B.npHcyTctbhh AHMeTHJiaHHJiHHa ιιπη <$ eHnn6yTauQHa npH KOMHaTHoň TeMnepaType 6ea fleTT-BHfl CBeTa. HeflOCTaTOMHblM ΑΠΗ ΠρΗΜβΗ6ΗΗΗ npH 3TOM ΗΒΑΗβΤΟΗ κοροτκοβ ΒρβΜΗ 06pa6oTKii β 45-55 MHHyT nocne ποαγοτοβκη CMeceň KJieeB. ΠροδπβΜβτΗΗΗΟ flajibuieTO MTO NPH Η33Β3ΗΗ0Μ ΚΠΘβ HCnOJIb3yiOT TOAbKO HHHUHaTOpbl, Ofíp33ylOmH6 paflHKan h nosTOMy AHftyHKUHOHajibHaH anoKCHflHaH Cmon He yqacTByeT β ποηημθρη38αηη and co6cTBeHiio cnywHT HanojiHHTejieM απη nojiHMeTaxpHJiaTa (H.Jahn., Epoxidharze, VEB Deutscher Verlag fur Grundstoffindustrie). PeaKAHH βποκοηαημχ rpynn c3φΗρΗΗΜΗ rpynnaMH ΠΟίΙΗΜβΤΚΠΜΘ Τ3ΚρΗίΙ3Τ3 ΠΡΗ O6pa3OBaHHH CJIOWHbK. ΦHKOKO OHKOKO bepKOKO b bKOKOKO b333333333333epepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepepep Hausler, E. Klemm, Fricke, J. Benne: Plaste und Kautschuk 27 (1980) 678). Ππη πρΗΜβΗβΗΗΗ bKauecTBe oriTHHecKoro κηεπ c uexibio οκηθηβ3ηηη c ManbiM HanpH * eHHeM οπτΗΜβοκκχAerajieň c Bbicoxoň TOMHOcTbw ohh nosTOMy HenpHroAHbi. flajibtne μ3βθοτηη (boToqyBCTBHTenbHbie βποκοηαη b xaqecTBe ochobhoto MaTepnana 256916 ~ -2--

Pfm πλθηοκ, OTBepamawtuHxcH nop bjihjthhsm cb6T3 (W.R. Watt, ACS Symposium Sé-rie 114, Epoxy Resin Chemistry, Editor: Ronald S. Bauer, Washington DC1979, 1-46). npHrOflHblMH φΟΤΟΗΗΗρΗβΤΟρβΜΗ, flaJOlUHMH BO3MOJKHOCTb ΠρΗΜΘΗβΗΗ» BOKOHOMHMecKOM OTHOmeHHH, OKasanHCb apHJiňOflOHHeBbte cojih. Πο G.H. Smith η M. Saint Paul, DE-OS 2 639 396, npn 3 tom cxopocTb φοτοοτΒβρ-JKfleHHH MO5KHO nOBblCHTb CeHCH6HJIH3aTOpaMH flJIH KpaCHTejIH.Pfm πλθηοκ, OTBepamawtuHxcH nop bjihjthhsm cb6T3 (W.R. Watt, ACS Symposium Serene 114, Epoxy Resin Chemistry, Editor: Ronald S. Bauer, Washington DC1979, 1-46). npHrOflHblMH φΟΤΟΗΗΗρΗβΤΟρβΜΗ, flaJOlUHMH BO3MOJKHOCTb ΠρΗΜΘΗβΗΗ »BOKOHOMHMecKOM OTHOmeHHH, OKasanHCb apHJinOflOHHeBbte cojih. Πο G.H. Smith M. M. Saint Paul, DE-OS 2 639 396, npn 3 tom cxopocTb οοτοοτΒβρ-JKfleHHH MO5KHO nOBblCHTb CeHCH6HJIH3aTOpaMH flJIH KpaCHTiIH.

Corjiacno naTeHTy US 4 026 705 h nareHTy GB 2 065 124 κ 3ποκοηρ,ηημ CMOjiaM po-easjunoT h areHTbi, Mo;m<t)Hij;npyioinne BaaxocTb, ksk ΜΟΗοφγΗκρηοΗβηΒΗΗβ anoKCHflbí,rjiHUHflHnMeTaKpHJiaT η τ.π. KpOMe toto b xaqecTBe κοΜποΗβΗτοΒ moxho npHČaBjíHTbopraHHHecKHe ΒΗΗΗΠΜΟΗΟΜβρω, κοτορωβ MoryT 6biTb nojiHMepHaoBaHbí κβτηοηηημ o6~pa30M Η πρη 3TOM ΠρΗΒΟρΗΤ K TepMOnJiaCTHMHblM nOJIHMepaM.Corjiacno naTeHTy US 4 026 705 h nareHTy GB 2 065 124 κ 3ποκοηρ, ηημ CMOjiaM-are bi bi bi bi m bi ij py py py py py. KpOMe this b xaqecTBe κοΜποΗβΗτοΒ moxho npHČaBjíHTbopraHHHecKHe ΒΗΗΗΠΜΟΗΟΜβρω, κοτορωβ MoryT 6biTb nojiHMepHaoBaHbí κβτηοηηημ o6 ~ pa30M Η πρη 3TOM ΠρΗΒΟρΗΤ K TepMOnJiaCTHMHblM nOJIHMepaM.

Ha3biBaioTCH: cmpen, BHHHnaueTaMHfl, ot-MeTnncTHpeHbí, H3o6yTKnBHHHjioBbiň 3φπρ,n-OKTHBHHHJIOBblřl 3φηρ, 3ΚρΟΠβΗΗ, 1,1-ρΗφβΗΗΠ3ΤψΙβΗΜ, BHHHJiapeHbl, BHHHJIUiHKJIO—ηηηΦβτμ, fluenbi η τ.ρ. Ceepx toto πρηββΒΠΗίοτ ppyrne uHKJiHMecKHe 3φ«ρω B xa-MecTBe nanbHeňjBHx MonoMepoB. ΠρηΟρβηθμηθμ apHJiňopoHneBwx cojieň h ceHCH0HJiH-3aTOpoB pna KpacHTejia nccne BpeMeH oCjiyqeHHa b 15 cex po >120 cex nojiynaiOTOTBep»«eHHbie nonuMepHbie πηθηκη. B xanecTBe KpacHTeneft ocoCeHHo npHropHbí ax-pHUHHOBbiň opaHxeBbiň, aKpHflHHOBbift MejiTbiň, ΓβΜβτοπορφκρΗΗ, κβτΟΗ Mnxjiepa H6βΗ3θφΠ3ΒΗΗ. B nenoM npn 3tom cnocoOe npeepameHne «mucoň CMecH MonoMepoB b TBepflyro nojiH-MepHyw nneHKy npoHcxoflHT b Φοτοηηηαηηροβ3ηηο8 GTaflHH peaKUHM. 3th ofliiocTy-.πβΗΜβτο OTnepxpaeMbie CHCTeMbi flaror cmHTbie nonHMepHbie cjioh. CoeflHHeHHbie hmhlonTHMecKne fleTajm b cnynae omn6oqHbix CKjieHBaHHň He flaiOT bosmómhocth τθρμη- iqecKoro pasteMa 6ea TpyflHocTeťi. Ecjih flocTHraeTCH pa3T>eM, Torfla οπτΗΗβοκηβpeTajiH TOJibKO c TpypoM mojkho no/iHocTb» ocBofioflHTb ot npHJiHnaromeň HepacTBOpn-Moň nneHKH nojiHMepHoro Kjiea. TeM cwibHO yxyflmaeTCH skohomhh cnocoSa. H3 naTeHTa DE 3 107 353 A 1 H3BecTHbi nojiHMepH3yeMbie CMecH, πρη κοτορωχ nojiH-Mepn3aiíHfl npeHMymecTBeHHO npoHcxoflHT b flByx cTyneHax, cHananá Φοτοχημηηθοκημh 3aTeM repMHMecKHM nyTeM hjih Η3θ0οροτ.Ha3biBaioTCH: cmpen, BHHHnaueTaMHfl, ot-MeTnncTHpeHbI, H3o6yTKnBHHHjioBbin 3φπρ, n-OKTHBHHHJIOBbll 3φηρ, 3ΚρΟΠβΗΗ, 1,1-ρΗφβΗΗΠ3ΤψΙβΗΜ, BHHHJiapeHbl, BHHHJIUiHKJIO — ηηηΦβτμ, fluenbi η τ.ρ. Ceepx this πρηββΒΠΗίοτ ppyrne uHKJiHMecKHe 3φ «ρω B xa-MecTBe nanbHeňjBHx MonoMepoB. 15 B B B B B B B 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 B xanecTBe KpacHTeneft ocoCeHHo npHropHbí ax-pHUHHOBbony opaHxeBbiň, aKpHflHHOBbift MejiTbien, ΓβΜβτοπορφκρΗΗ, κβτΟΗ Mnxjiepa H6βΗ3θφΠ3ΒΗΗ. B nenoM npn 3tom cnocoOe npeepameHne «muco CMecH MonoMepoB b TBepflyro nojiH-MepHyw nneHKy npoHcxoflHT b Φοτοηηηαηηροβ3ηηο8 GTaflHH peaKUHM. 3th ofliiocTy-.πβΗΜβτο OTnepxpaeMbie CHCTeMbi flaror cmHTbie nonHMepHbie cjioh. CoeflHHeHHbie hmhlonTHMecKne fleTajm b cnynae omn6oqHbix CKjieHBaHHn He flaiOT bosmómhocth τθρμη- iqecKoro pasteMa 6ea TpyflHocTeťi. Ecjih flocTHraeTCH pa3T> eM, Torfla οπτΗΗβοκηβpeTajiH TOJibKO c TpypoM mykho no / iHocTb »ocBofioflHTb ot npHJiHnaromeň HepacTBOpn-Can nneHKH nojiHMepHoro Kjiea. TeM cwibHO yxyflmaeTCH skhomhh cnocoSa. H3 naTeHTa DE 3 107 353 A 1 H3BecTHbi nojiHMepH3yeMbie CMecH, πρη κοτορωχ nojiH-Mepn3aiíHfl npeHMymecTBeHHO npoHcxoflHT b flByx cTyneHax, cHanana

HcnOJIb3OBaiIHbie πρη 3TOM ΤβΧΗΗΗβΟΚΟΜ peraeHHH ΜΟΗΟΜβρω npeflCTaBJlfllOT CO6oftanoKCHflbí, b cooTBeTCTByrcmeM cnynae b CMecH b 3THjieH0B0 HeHaebímeHHbíMH coeflH-ΗβΗΗΗΜΗ, KOTOpbie nOJlHMepH3yeMbI ΠΟ KaTHOHHOMy MeX3HH3My. B xanecTBe HHHu,H3Topa πρΗΜβΗΗΐοτ TpoňHyro κομ6ηη3αηιο, cocToumyro H3 apHJi-ftOflOHHeBOft COJIH, φθΤΟΗΗΗΐχΗ3Τθρ3 H3 pHfla apOMaTHHeCKHX KapOHHJIbHbIX COeflH“HeHH&amp; h TepMHuecKoro paflHKajioo6pa3OBaTejia. SnoKCHflbí mojkho Hcnohb3OBaTb h b .CMeCH C STHJieHOBO HeHaebímeHHbíMH COeflHHeHHHMH, nOJIHMepH3yeMbIMH paflHKajIbHblMnyTeM. 3 τη CMecn, flByxcTyneHnaTo OTBepsyjaeMbie 6e3 ycTaHOBJíeHHoň nocneflOBa-TejibHocTH no BpeMeHH φοτοχΗΜΗηβεκΗΜ h TepMHMecKHM nyTeM, ΗΜβΜΤ OCO0eHHOe3HaneHHe pna nojiynemiH npenperoB.HcnOJIb3OBaiIHbie πρη 3TOM ΤβΧΗΗΗβΟΚΟΜ peraeHHH ΜΟΗΟΜβρω npeflCTaBJlfllOT CO6oftanoKCHflbí, b cooTBeTCTByrcmeM cnynae b CMecH b 3THjieH0B0 HeHaebímeHHbíMH coeflH-ΗβΗΗΗΜΗ, KOTOpbie nOJlHMepH3yeMbI ΠΟ KaTHOHHOMy MeX3HH3My. B xanecTBe HHHu, H3Topa πρΗΜβΗΗΐοτ At leastHyro κομ6ηη3αηιο, cocToumyro H3 apHJi-ftOflOHHeBOft COJIH, ΤΟΗΗΗΐθΤΟΗΗΗΐχΗ3Τθρ3 H3 pHfla apOMaTHHeCKHX KapOHHJIbHbIX COeflH “HeHH &amp; h TepMHuecKoro paflHKajioo6pa3OBaTejia. SnoKCHflbí mojkho Hcnohb3OBaTb h b .CMeCH C STHJieHOBO HeHaebimHHbíMH COeflHHeHHHMH, nOJIHMepH3yeMbIMH paflHKajIbHblMnyTeM. 3 τη CMecn, flByxcTyneHnaTo OTBepsyjaeMbie 6e3 ycTaHOBJíeHHoň nocneflOBa-TejibHocTH no BpeMeHH φοτοχΗΜΗηβεκΗΜ h TepMHMecKHM nyTeM, ΜΤβΜΤ OCO0eHHOe3HaneHHe pna nojiynemiH npenperoB.

Bo3MoxHoe πρΗΜβΗβΗΗβ 3thx CMeceň b KanecTBe οπτημθοκογο Knea aph bmcokotoh—Hbix peTaneň HMeeT peraarotUHň Ηβροοτβτοκ, ητο πρκ TepMHnecKoň nojiHMepH3anHH byKa3aHHoň ofínacra TeMnepaTyp ot 100 po 160^0 bo BpeMH nojiHMepH3auiHH h cne-pyrouiero nponecca oxJianíneHHH po KOMHaTHoň TeMnepaTypbi BO3HHxai0T HanpaaceHHH bποηΗΜερΗΟΜ cnoe. Ceepx toto BCJieflCTBHe nojiHMepnaaifliH βτηπθηοβοη αβοΑηοη cbh-3H Βθ3ΗΗΚ3ΐοτ oSbeMHbie ycaflKH, KOTOpbie TaKxe cofleítcTByioT b yBejmaeHHH Hanpa-aceHHft b KJieeBOM cnoe.Bo3MoxHoe πρΗΜβΗβΗΗβ 3thx CMeceň b KanecTBe οπτημθοκογο Knea bmcokotoh APH-Hbix peTaneň HMeeT peraarotUHň Ηβροοτβτοκ, ητο πρκ TepMHnecKoň nojiHMepH3anHH byKa3aHHoň ofínacra TeMnepaTyp 100 rpm at 160 ^ 0 bo BpeMH nojiHMepH3auiHH h CNE-pyrouiero nponecca oxJianíneHHH after KOMHaTHoň TeMnepaTypbi BO3HHxai0T HanpaaceHHH bποηΗΜερΗΟΜ cnoe. Ceepx this BCJieflCTBHe nojiHMepnaaifliH βτηπθηοβοη αβοΑηοη cbh-3H Βθ3ΗΗΚ3ΐοτ oSbeMHbie ycaflKH, KOTOpbie TaKxe cofleítcTByioT b yBejmaeHHH Hanpa-aceHHft b KJieeBOM cnoe.

BbiJio ywe npenjipaceHO 3HanHTejibHO orpaHHHHTb sth ηθαοοτθτκη AByxcTyneHnaTOň jφοτοχΗΜΗΜθϋκοή nojiHMepH3auHeň (2-flHMeTHnflHOKcojiaH-4-HJi)MeTHnMeTaKpHJiaTa. ΠρΗ3tom oSbeMHyio ycapKy, BOSHUKatomyio b nepBott CTyneHH BCJiepcTBHé paflHKajibHoftnOJIHMepH3aiíHH 3THJieHOBOň flBOňHOň CBM3H, BO BTOpOň CTyneHH MOMHO ΚΟΜΠβΗΟΗρΟ-BaTb npn KaTHOHHoň nojiHMepH3auHH c pacKpbiTHeM uHKjia nyTeM čonojiHMepH3anHH coΟΠΗρΟΟρΤΟΟφΗρΟΜ. Hajlbme H3BeCTH0, ΗΤΟ SnOKCHflHbie CMOJIbl HMeiOT OTJIHHHyro anre-3hio oTHocHTenbHO cTeicna, oflHaKO hx He3HanHTejibHaH nróKocTb h BbicoKaa xpyn- 256916BbiJio ywe npenjipaceHO 3HanHTejibHO orpaHHHHTb sth ηθαοοτθτκη AByxcTyneHnaTOn φοτοχΗΜΗΜθοϋ nojiHMepH3auHen (2-flMeTHnflHOKcojiaH-4-HJi) MeTHnMeTaKpHJiaTa. ΠρΗ3tom oSbeMHyio ycapKy, BOSHUKatomyio b nepBott CTyneHH BCJiepcTBHé paflHKajibHoftnOJIHMepH3aiíHH 3THJieHOBOň flBOňHOň CBM3H, BO BTOpOň CTyneHH MOMHO ΚΟΜΠβΗΟΗρΟ-BaTb NPN KaTHOHHoň nojiHMepH3auHH c pacKpbiTHeM uHKjia rivet čonojiHMepH3anHH coΟΠΗρΟΟρΤΟΟφΗρΟΜ. Hajlbme H3BeCTH0, OK SnOKCHflHbie CMOJIbl HMeiOT OTJIHHHyro anre-3hio oTHocHTenbHO cTeicna, oflHaKO hx He3HanHTejibHaH nróKocTb h BbicoKaa xpyn- 256916

KOCTb BM3blBaiOT HeSHaHHTejlbHyW npOMHOCTb Ha pa3pblB ΠΟΠΗΜβρβ H He3HaHHTejlbHyiOyCTOňMHBOCTb ΚηβθΒΟΓΟ COeAHHeHHB K OOJIbUIHM Η3ΜβΗβΗΗΛΜ ΤβΜΠβρβΤΥΡΜ.KOCTb BM3blBaiOT HeSHaHHTejlbHyW npOMHOCTb Ha pa3pblB ΠΟΠΗΜβρβ H He3HaHHTejlbHyiOyCTOnMHBOCTb ΚηβθΒΟΓΟ COeAHHeHHB K OOJIbUIHM Η3ΜβΗβΗΗΛΜ ΤβΜΠβρβΤΥΡΜ.

Bbino ywe npeanoweHo ycTpaHHTb stot ΗβΑοοτβτοκ ixeneycTpeMJieHHoň BCTaBKoň cer-ΜβΗΤΟΒ H3 GnOXHhlX ΠΟΠΗ3φΗρΟΒ nyTeM COnOJlHMepH33nHH CO εΠΗρθθρΤΟ3φΗρθΜ.KaTHOHHaa ποπημθρη33Πηη c pacKpwTHeM uHKna 3«ecb προηοχοαητ TepMHnecKH c ok-COHHeBMMH COJIHMH B KanecTBe HHHAHaTOpa Η ΠρΗΒΟΑΗΤ K npO3panHb!M 3nOKCHflHbIMCMOJiaM C ynpyrHMH CBOftcTBaMH.Bbino YWE npeanoweHo ycTpaHHTb one hundred tons ΗβΑοοτβτοκ ixeneycTpeMJieHHoň BCTaBKoň cerium ΜβΗΤΟΒ H3 GnOXHhlX ΠΟΠΗ3φΗρΟΒ rivet COnOJlHMepH33nHH CO εΠΗρθθρΤΟ3φΗρθΜ.KaTHOHHaa ποπημθρη33Πηη c pacKpwTHeM uHKna 3 «ECB προηοχοαητ TepMHnecKH C OK-COHHeBMMH COJIHMH B KanecTBe HHHAHaTOpa Η ΠρΗΒΟΑΗΤ npO3panHb K! M 3nOKCHflHbIMCMOJiaM ynpyrHMH CBOftcTBaMH C.

Hcnojib3OBaHHeM σπΗροορτοΒφΗρβ KpoMe toto ynaeTca orpaHHHHTb o6beMHyw ycaflxy,COCTOjnuyWCH B npouecce ΟΤΒβΡ«ΑβΗΗΗ, MHHHMyMOM B 2 - 4%, B 3aBHCHMOCTH OTMaCCOBOTO COOTHOUieHHH HCnOJTb3OBaHHbK MOHOMepOB. Ha OCHOBaHHH 3THX CBOflCTBΤ3ΚΗβ nOJTHMepb! OTHOCHTeJIbHO xopomo BbinOJlHHIOT ΤρββΟΒβΗΗΗ, npeíTbHBJíeHHbie ΟΠΤΗ-necKOMy Kneio. ..Hcnojib3OBaHHeM σπΗροορτοΒφΗρβ KpoMe this ynaeTca orpaHHHTHT o6beMHyw ycaflxy, COCTOjnuyWCH B npouecce ΟΤΒβΡ «ΑβΗΗΗ, MHHHMyMOM B 2 - 4%, B 3aBHCHMOCTH OTMaCCOBOTO COOTHOUieHHH HCnOJTb3OBaHHbK MOHOMepOB. Ha OCHOBaHHH 3THX CBOflCTBΤ3ΚΗβ nOJTHMepb! OTHOCHTeJIbHO xopomo BbinOJlHHIOT ΤρββΟΒβΗΗΗ, npeíTbHBJíeHHbie ΟΠΤΗ-necKOMy Kneio. ..

Uejib n3o6peTeHHH:Uejib n3o6peTeHHH:

UeJIbH) Η3θ6ρβΤβΗΗΗ HBJIHeTCH nOJiyqeHHe ΚΑββΒ, flaromHX BO3MO)KHOCTb ΑΟΠΓΟΒβΗΗΜΧ,norOflOyCTOňHHBbK, BblCOKOTOHHbtX CKJieHBaHHň C MajlblM ΗΒΠρΗΜβΗΗβΜ H C 6OJ7bUIHMBblXOflOM ΓΟβΗΟΗ npoAyKHHH. H3jio»eHHe cymHocTH tooCpeTeHHg; B ocHOBy Η3θϋρθτβΗΗΗ nonoxeHa 3aAana, coxpaHHH H3eecTHue npeAnonTHTenbHbieCBoflcTBa anoKCHflHbix cmoji, co3flaTb cnocoS nonyqeHHH onTHuecKoro xjiea Ha ocho-B3HHH ' MeTaKpHJiaT—flH3nOKCHjHHOň nOJlHMepHaailHOHHOň CHCTeMbl, KOTOpblň ΠΟ3ΒΟΠΗβΤTexHOjiornnecKoe bjihhhhb Ha npopecc OTBep«AeHHH thkhm oGpasoM, mto6m Cbinn yn-paBJíHeMbi h 6wcTpoe nacTHMHoe oTBepncneHHe c uenbio φπκοβΗΗΗ ποηοΜβΗΗΗ mcTHpo-BaHHbix onTHHecKHX neTaneň c βο3μοκηοοτηο κορρβκιΐΗΗ h nocneaywmee MenneHHoeH nojiHoe oTBepwfleHHe.UeJIbH) θ3θ6ρβΤβΗΗΗ HBJIHeTCH nOJiyqeHHe ΚΑββΒ, flaromHX BO3MO) KHOCTb ΑΟΠΓΟΒβΗΗΜΧ, norOflOyCTOnHHBbK, BblCOKOTOHHbtX CKJieHBaHHn C MajlblM ΗΒΠρΗΜβΗΗβΜ H C 6OJ7bUIHMBblXOflOM ΓΟβΗΟΗ npoAyKHHH. H3jio »eHHe cymHocTH tooCpeTeHHg; B ocHOBy Η3θϋρθτβΗΗΗ nonoxeHa 3aAana, coxpaHHH H3eecTHue npeAnonTHTenbHbieCBoflcTBa anoKCHflHbix cmoji, co3flaTb cnocoS nonyqeHHH onTHuecKoro xjiea Ha ocho-B3HHH 'MeTaKpHJiaT-flH3nOKCHjHHOň nOJlHMepHaailHOHHOň CHCTeMbl, KOTOpblň ΠΟ3ΒΟΠΗβΤTexHOjiornnecKoe bjihhhhb Ha npopecc OTBep «AeHHH thkhm oGpasoM, mto6m Cbinn yn-paBJíHeMbi h 6wcTpoe nacTHMHoe oTBepncneHHe c uenbio φπκοβΗΗΗ ποηοΜβΗΗΗ mcTHpo-BaHHbix onTHHecKHX neTaneň c βο3μοκηοοτηο κορρβκιΐΗΗ h nocneaywmee MenneHHoeH nojiHoe oTBepwfleHHe.

KpoMe toto AonwHa 6biTb oGecneneHa xopoiuaa coBMecTHMOCTb Bcex κομποηθητοβΚΠβΗ H C BÓ3MO3KHMMH AO6aBK8MH ΑΠΗ ΜΟΑΗφΗΑΗρΟΒβΗΗΗ CBOňCTB KJieH, Β HaCTHOCTHManoro HanpHxeHHH ynpyrocTH h BpeMeHH OTBepwfleHHH,KpoMe this AonwHa 6biTb oGecneneHa xopoiuaa coBMecTHMOCTb Bcex κομποηθητοβΚΠβΗ H C BO3MO3KHMMH AO6aBK8MH ΑΠΗ ΜΟΑΗφΗΑΗρΟΒβΗΗΗ CBOňCTB KJieH, Β HaCTHOCTHManoro

Baflana npw cnoco6e απη nonyneHHH xneeB Ha OCHOBaHHH Μβτβκρκπβτ-AHsnoxcHAHOňnojiHMepH3aAHOHHoň CHCTeMbl cornacHO H3o6peTeHHio peuiaeTca τβΜ,πτο b peaxuHOHHOMpacTBOpe κ XHAKOMy KOMnoHeHTy MeTaxpHJiaTa, xax npeHMymecTBeHHO κ ΜβτβκρΗποΒΟΜβτΗ-noBOMy aýupyHnHK (2,2-AHMeTHJi-l, 3-AHOKCOJiaH-4-Hn)MeTHJiMeTaKpHJiaTy,c BecoBoňHaCTbK) 10-50% ΑΠΗ βΜΟΤροβ φοΤΟΧΗΜΗΗΘόΚΟϋ φΗΚΟβίχΗΗ paAHKanbHOň nOJlHMepHSaUHeftAoSaBHHioT φοτοΗΗΗΗΗβτορ, o6pa3yK>mHň paAHKaji,B BecoBoň qacTH 0,5-5% Η κ a«“snoKCHAHOMy KOMnoHeHTy, K3K npeHMymecŤBeHHO κ AHaHAurjiHUHAHnóBOMy 3φκργ, bBecoBoň qacTH 90-50% ahh nocneAyiotuero 3a φΗΚΟβΑΗβή Φοτοηηηαηηροβ8Ηηογο ot-Ββρ?ΚΗβΗΗΗ KJiea κθτηοηηοη nonHMepH3auHeň c pacKpwTHeM ijHKJia AoGaBnaioT φοτο-HHHUHaTOp, o6pa3yromHft xaTHOHbí, b BecoBoň nacra 0,5“5Z. ΠρβΑΠΟΗΤΗτεπΒΗο, ecjiH b xawecTBe φοτοΗΗΗρΗβτορβ, očpasyiomero panHxan, πρημθ-HHHJT npeHMymecŤBeHHO 6eH3OHH ΗΠΗ 6eH3OHHOBbie 3φΗρΜ, K3K Hanp. 6eH3OHHMeTHJ10-Bblň 3φΗρ, 6eH30HHH3Onp0nnn0Bblň 3φκρ ΗΠΗ 6eH3HJIAHMeTHJIKeTanb, H B KaneCTBeφοTOHHHHHaTOpa, oGpaayreinero xaTHOHbí, npHMeHHtoT npeHMymecŤBeHHO AHapunňOAo-HHeBbie ηπη TpHapuncyj^oHHeBbie cojih, xoTopbie B jcanécTBe προτηβοηοηοβ coAep-waT KOMnneKCHhie ηηηοηη xax Hanp. BF4‘, Α,βΈ4, »hah SbF~.Baflana NPW cnoco6e απη nonyneHHH xneeB Ha OCHOBaHHH Μβτβκρκπβτ-AHsnoxcHAHOňnojiHMepH3aAHOHHoň CHCTeMbl cornacHO H3o6peTeHHio peuiaeTca τβΜ, πτο b peaxuHOHHOMpacTBOpe XHAKOMy KOMnoHeHTy MeTaxpHJiaTa κ, κ ΜβτβκρΗποΒΟΜβτΗ npeHMymecTBeHHO XAX-noBOMy aýupyHnHK (2,2-AHMeTHJi-l, 3-AHOKCOJiaH-4-HN) MeTHJiMeTaKpHJiaTy c BecoBoňHaCTbK) 10-50% ΑΠΗ βΜΟΤροβ φοΤΟΧΗΜΗΗΘόΚΟϋ φΗΚΟβίχΗΗ paAHKanbHOň nOJlHMepHSaUHeftAoSaBHHioT φοτοΗΗΗΗΗβτορ, o6pa3yK> MHN paAHKaji B BecoBoň qacTH 0.5-5% Η κ and «" snoKCHAHOMy KOMnoHeHTy, K3K npeHMymecŤBeHHO κ AHaHAurjiHUHAHnóBOMy 3φκργ, bBecoBoň qacTH 90-50% ahh nocneAyiotuero 3a J τ τ τ J τ τ τ J J J J J J J J J J J J J J J J o o o o o o a a ““ ““ ““ “ ΠρβΑΠΟΗΤΗτεπΒΗο, ecjiH b xawecTBe φοτοΗΗΗρΗβτορβ, pp an an pan an an an e e e e e e e e e e e e e e e e e e 6eH3OHHMeTHJ10-BBLn 3φΗρ, 6eH30HHH3Onp0nnn0Bblň 3φκρ ΗΠΗ 6eH3HJIAHMeTHJIKeTanb H B KaneCTBeφοTOHHHHHaTOpa, oGpaayreinero xaTHOHbí, npHMeHHtoT npeHMymecŤBeHHO AHapunňOAo-HHeBbie ηπη TpHapuncyj ^ oHHeBbie cojih, xoTopbie B jcanécTBe προτηβοηοηοβ coAep-WAT KOMnneKCHhie ηηηοηη XAX hANP. BF4 ‘, Α, βΈ4,» hah SbF ~.

JlpeAnonTHTejibHbíM Aanbiue HBJIHeTCH to, ecnw b MeTaxpHJiaTAHanoKCHAHOň nojiHMepH—3anH0HHoft cHCTeMe απη ποβμιιιθηηη ynpyrocTH κπβΗ h yMeHbtneHHH oGbeMHOÉ ycaAKHcoAepwHTca cnnpoopTOaAHpHbiň κομποηθητ, khk npeHMymecŤBeHHO 2,2-6hc(1,4,6-TpHOKCa-CnHpO-Γ4,4]-ΗΟΗ3Η-2-ΜβΤΗΠΟΚΟΗφεΗΗΠ)-ΠρθΠ3Η, 2-φβΗΗΠ-ΟΚΟΗΜβTHJI“1,4,6-TpHOKca-cnHpo-[4,4]-HonaH ηπη 2-H3o6yTHnoKCHMeTHn- 1,4,6-TpHOKca-cnHpo-[4,4]-ηοηηη,β BecoBoň nacTH no 50%. npennOMTHTenbHO KpoMe ΤΟΓΟ TO, ecjiH K MeTaKpHJiaT-AHSnOKCHAHOft nOAHMepH3a— 256916 - 4 - UHOHHOň CHCTeMe ΠρκββΒΠΗΜΤ OJIHrOMepHbie ΜΗΟΓθφγΗΚ«ΗΟΗβπ&amp;ΗΗβ ΜβΤβΚρΗΠβΤΜ, KSKnpeHMymecTBeHHO προπγκτ npHCoenHHeHHH αη3Ηαηγιιηαηαη3ιοβογο οφκρβ c Μβτβκρκ-jiOBOň KHcnoTOň, b BecoBoíí qacTH ρ,ο 5X, OTHOcumeňcH κ KOjiHMecTBy MeTaxpHJia-Ta, c penbio ycKopeHHH paAHKajibHoň nojiHMepns aipin κοΜποΗβκτβ ΜβτβκρκπβτΒ.IIpejanoMTHTejibHMe cBoňcTaa h ycnoBHH ο6ρβ6οτκΗ KJiea cornacHo naoepeTeHHW bm-TeKaroT H3 bhah ero cocTaea. HeoxHAaHHO 6μπο HaňfleHO, mto Kneň, nojiyqeHHbiňno cnocoCy cornacHo Η3ο6ρβτβΗΗΐο, npeflCTaBnaeT coGoň roMoreHHbiň pacTBop, npo-ijecc OTBepjnqeHHn κοτοροτο fííin oGpaaoBanHH onTHqecKH npO3pauHoro cjioh KJiennocpencTBOM Φοτοβηηηηηροβηηηη Μοχβτ ynpaBJíHTbca b AByx nocneAOBaTejibHbix noBpeMeHH h b 3HanHTenbHoň Mepe HesaBHCHMbi-x CTyneHsx. TlepBÓft CTyneHbio oTBepx-ΑβΗΗΗ npexfle Bcero ocynecTBJíHeTCH tojisko Gbicrpan φοτοχΗΜΗΗβοκβπ φΗκεβΑΗΗKjien. flocTHrnyTan φοτΟπΗΗΑΗΗρΟΒβΗΗΟΰ paAHKajibHoň nojttiMepHsauHeň KOMnoHeHTa Μβτβκ-panaTa Φηκοβαηη yxe nosBOJineT TpaHcnopTHpoBKy"· cxneMBaMHbtx flpyr c npyroM ne-Taneň, 6e3 HapyraeHHH hx iocthpobkh. ΚροΜβ τογο b cthahh φκκεβιχΗΗ eme b Teqe-HHe HecKonbKHX AHeň BOSMoxen HenpoGjieMaTHqHbiň pasbeM oiuhSomhmx CKneHBaHHňnyreM TepMHqecKOň oGpaGoTKH BKJBoqan nojiHoe ynaneHne οότβτκοβ xnea οτ noBepx-HocTeň npH noMoinH opraHHqecKHX pacTBOpHTeJieň. TOJlbKO CO BTOpOň CTyneHblO ΟΤΒβρΧζΑβΗΗΗ. (φΟΤΟΧΗΜΗΗεεΚΗ HHHUHHpOBaHHOň) b noji-Hoft Mepe HannHaeTCH npouecc OTBepjRAeHHH. B 3τοή CTyneHH KaTHOHHan nojiHMepH-3aynH c pacKpbiTHeM uHKJia αηβποκοηαηογο κοΜΠΟΗβΗτβ' πρηβοαητ κ cnmBaHwo nojiH-MepOB Η 'Τ6Μ CaMblM Κ HOJlHOMy ΟΤΒβρ»ΑβΗΗΙΟ KJieH.JlpeAnonTHTejibHbíM Aanbiue HBJIHeTCH it ecnw b MeTaxpHJiaTAHanoKCHAHOň nojiHMepH-3anH0HHoft CHCl απη ποβμιιιθηηη ynpyrocTH κπβΗ h yMeHbtneHHH oGbeMHOÉ ycaAKHcoAepwHTca cnnpoopTOaAHpHbiň κομποηθητ, KHK npeHMymecŤBeHHO 2,2-6hc (1,4,6-TpHOKCa-CHHP-Γ4,4] -ΗΟΗ3Η 2- ,6βΤΗΠΟΚΟΗφεΗΗΠ) -ΠρθΠ3Η, 2-φβΗΗΠ-THβTHJI “1,4,6-TpHOKca-cnHpo- [4,4] -HonaH ηπη 2-H3o6yTHnoKCHMeTHn- 1,4,6-TpHOKca-cnHpo- [4,4] -ηοηηη , β BecoBoň nacTH no 50%. npennOMTHTenbHO KpoMe ΤΟΓΟ TOs ecjiH K MeTaKpHJiaT-AHSnOKCHAHOft nOAHMepH3a- 256916-4 - UHOHHOň CHCl ΠρκββΒΠΗΜΤ OJIHrOMepHbie ΜΗΟΓθφγΗΚ «ΗΟΗβπ &amp; ΗΗβ ΜβΤβΚρΗΠβΤΜ, KSKnpeHMymecTBeHHO προπγκτ npHCoenHHeHHH αη3Ηαηγιιηαηαη3ιοβογο οφκρβ c Μβτβκρκ-jiOBOň KHcnoTOň b BecoBoíí qacTH ρ, ο 5X OTHOcumeňcH κ KOjiHMecTBy MeTaxpHJia -Ta, c penbio ycKopeHHH paAHKajibHoon nojiHMepns aipin κοΜποΗβκτβ ΜβτβκρκπβτΒ. HeoxHAaHHO 6μπο HaňfleHO MTO Kneň, nojiyqeHHbiňno cnocoCy cornacHo Η3ο6ρβτβΗΗΐο, npeflCTaBnaeT Cogon roMoreHHbiň pacTBop, NPO-ijecc OTBepjnqeHHn κοτοροτο understood as meaning oGpaaoBanHH onTHqecKH npO3pauHoro cjioh KJiennocpencTBOM Φοτοβηηηηηροβηηηη Μοχβτ ynpaBJíHTbca AByx nocneAOBaTejibHbix noBpeMeHH b h b 3HanHTenbHoň Mepe HesaBHCHMbi-x CTyneHsx. TlepBÓft CTyneHbio oTBepx-ΑβΗΗΗ npexfle Bcero ocynecTBJíHeTCH tojisko Gbicrpan φοτοχΗΜΗΗβοκβπ φΗκεβΑΗΗKjien. flocTHrnyTan φοτΟπΗΗΑΗΗρΟΒβΗΗΟΰ paAHKajibHoň nojttiMepHsauHeň KOMnoHeHTa Μβτβκ-Panat Φηκοβαηη YXE nosBOJineT TpaHcnopTHpoBKy "· cxneMBaMHbtx flpyr c npyroM not Tanen, 6E3 HapyraeHHH hx iocthpobkh. ΚροΜβ τογο b cthahh φκκεβιχΗΗ eme b Teqe-HHE HecKonbKHX Ahen BOSMoxen HenpoGjieMaTHqHbiň pasbeM oiuhSomhmx CKneHBaHHňnyreM TepMHqecKOň oGpaGoTKH BKJBoqan nojiHoe ynaneHne οότβτκοβ xnea οτ noBepx-HocTeň NPH noMoinH opraHHqecKHX pacTBOpHTeJieň. TOJlbKO CO BTOpOň CTyneHblO ΟΤΒβρΧζΑβΗΗΗ. (φΟΤΟΧΗΜΗΗεεΚΗ HHHUHHpOBaHHOň) b noji-Hoft Mepe HannHaeTCH npouecc OTBepjRAeHHH. b 3τοή CTyneHH KaTHOHHan nojiHMepH-3aynH c pacKpbiTHeM uHKJia αηβποκοηαηογο κοΜΠΟΗβΗτβ 'πρηβοαητ κ cnmBaHwo nojiH-MepOB Η' M6Μ CaMblM OJ HOJlHOMy ΟΤΒβρ »ΑβΗΗΙΟ KJieH.

CnocoOoM cornacHo Η3ο6ρετβΗΗ» nojiyqaeTCH KJieň, κοτορωή β AByxcTyneHnaTOMnpoijecce oTBepaneHHH nosBOjiaeT rocrapoBKy η Koppexumo CKneHBaeMwx fleTaneň hBce TaKH Αβετ BosMOFHocTb noroAOycToftqHBoro CKneHBaHHH cmHBaHHeM nojiHMepoB hκοτορωΗ Ha ocHOBaHHH HasBaHHbK cboííctb ocoCeHHO πρΗΓΟΑβΗ b xaneCTBe οπτη-qecKoro xnea απη CKneHBaHHH onTHMecKHX AeTajieň coGjiioAaH βειοοκηθ πβρβΜβτρωKanecTBa.CnocoOoM cornacHo Η3ο6ρετβΗΗ »nojiyqaeTCH KJieň, κοτορωή β AByxcTyneHnaTOMnpoijecce oTBepaneHHH nosBOjiaeT rocrapoBKy η Koppexumo CKneHBaeMwx fleTaneň hBce Takhte Αβετ BosMOFHocTb noroAOycToftqHBoro CKneHBaHHH cmHBaHHeM nojiHMepoB hκοτορωΗ Ha ocHOBaHHH HasBaHHbK cboííctb ocoCeHHO πρΗΓΟΑβΗ b xaneCTBe οπτη-qecKoro xnea απη CKneHBaHHH onTHMecKHX AeTajieň coGjiioAaH βειοοκηθ πβρβΜβτρωKanecTBa.

Bapnaimeň KOjnwecTBa HHHnnaTopa, ηητθηοηβηοοτη ceeTa h BpeMeHH oGjiyqeHHHBO3MOWHO ΒΑΗΗΗΗβ H3 CKOpOCTb peaKAHH paAHKaJIbHOÍÍ nOJIHMepH3aAHH B aaBHCHMOC“τη οτ TexHonorHqecKHX TpeGoBaHHň. IIpHMepbl ΚΟΗΚρεΤΗΟΓΟ ΒΜΠΟΑΗβΗΗ»: HHxecneAyroiUHe npHMepbi cnyacaT απη noHCHeHHH nojiyqeHHH η πρημθηθηηη KJieH cor-nacHo Η3ο6ρετβΗΗΚ), ΟΑΗβκο, hhkohm o6pa3OM He orpaHHHHBaioT oG-beMa HsoGpeTe-HHH . ΠρΗΜβρ 1 B 2 r ΜβτβκρΗηοΒΟΜβτΗΠΟΒΟΓΟ 3φΗρβ (MMA) pacTBOpflioT 20 μγ 6eH3HJiAHMeTnnKeTa«“jih, 0,3 r ΑΗφβΗκηήοΑΟΗΗή-ΓβκοβφτοροφοςφΑΤβ,ε Taxate 5 r αη3ηαηγώηιχηαηποβογο3φΗρβ (DDGE) H 5'T 2,2 6hc(1,4,6-TpHOKCa-CnHpO-[4, A] -ΗΟΗ3Η-2“ΜβΤΗΠΟΚΟΗφθ-HHJi)-nponaHa b cooTBeTCTBywmeM cnyqae npH KpaTKOBpeMeHHOM, okojio 10-MHHyTHOMnepeMeuiHBaHHH h HarpeeaHHH Αθ 80 eC.Bapnaimeň KOJNWECTBa HHHnnaTopa, ηητθηοηβηοοτη ceeTa h BpeMeHH oGjiyqeHHHBO3MOWHO ΒΑΗΗΗΗβ H3 CKOpOCTb peaKAHH paAHKaJIbHOÍÍ nOJIHMepH3aAHH B aaBHCHMOC “τη οτ TexHonorHqecKHX TpeGoBaHHn. IIpHMepbl pρεΤΗΟΓΟ ΒΜΠΟΑΗβΗΗ »: HHxecneAyroiUHe npHMepbi cnyacaT hHeHHH nojiyqeHHH η πρημθηθηηη KJieH cor-nacHo Η3ο6ρετβΗΗΚ), ΗΑΗβκο, hhkohm o6pa3OM He orpaHHHHBaioT oG-beMa HsoGpeTe-HHH. ΠρΗΜβρ 1 B 2 R ΜβτβκρΗηοΒΟΜβτΗΠΟΒΟΓΟ 3φΗρβ (MMA) 20 pacTBOpflioT μγ 6eH3HJiAHMeTnnKeTa "" south, 0,3-ΓβκοβφτοροφοςφΑΤβ ΑΗφβΗκηήοΑΟΗΗή r, ε r 5 αη3ηαηγώηιχηαηποβογο3φΗρβ tax (DDGE) H 2.2 6HC 5'-T (1,4,6-TpHOKCa -CnHpO- [4, A] -ΗΟΗ3Η-2 “ΜβΤΗΠΟΚΟΗφθ-HJJi) -nponaHa b cooTBeTCTBywmeM cnyqae npH KpaTKOBpeMeHHOM, okojio 10-MHHyTHOMnepeMeuiHBaHHH h HarpeeaHHH Αθ 80 eC.

CnocoSHbiň κ npHMeHeHHio pacTBop xnea renepb noAaioT Me»Ay cxjieHBaeMbiMH οπτη~qecKHHH ueTajiHMH. 'nócne tohhoíí onranecKOň jocthpobkh AeTajieií Apyr κ APyry ηθΦηπβτροββηημμ cBe-ltom pTyTnoft jiaMnbi BbicOKOro AaBJíeHHH Ha paccToHiiHH 20-30 cm ocymecTBjíaeTCHoGnyqeHneM cjioh κηβπ qepee cTexjio onTkqecKHX AeTajieft b TeqeHHe 60 cex. TeMOnTHqeC-KHe ηθΤΟΠΗ 3βφΗΚΟΗρθΒ3ΗΜ B nOJIOJKeHHH H MOryT 6hlTb TpHHCnOpTHpOBaHbl6e3 HapymeHHH hx iocthpobkh.CnocoSHbi κ npHMeHeHHio pacTBop xnea renepb noAaioT Me »Ay cxjieHBaeMbiMH οπτη ~ qecKHHH ueTajiHMH. 'Nocturnal tohhoíí onranecKOň jocthpobkh AeTajieií κ pyr pyr ηθΦηπβτροββηημμ CBE-ltom pTyTnoft jiaMnbi BbicOKOro AaBJíeHHH Ha paccToHiiHH 20-30 cm ocymecTBjíaeTCHoGnyqeHneM cjioh κηβπ qepee cTexjio onTkqecKHX AeTajieft b TeqeHHe 60 CEX. TeMOnTHqeC-KHe ηθΤΟΠΗ 3βφΗΚΟΗρθΒ3ΗΜ B NOJIOJKeHHH H MOryT 6hlTb TpHHCnOpTHpOBaHbl6e3 HapymeHHH hx iocthpobkh.

OmnGoqno cKneemihie A®Tajm οπητβ pasbeMHbí τερΜΗπεοκοϋ οθρβθοτκοίί b TeqeHHe 120 cei< b cyraHJibHOM nn^y npH 80* Ch cnoň κηβπ mo»ho yAajiHTb οτ ποβθρχηοοτη neTajieň opraHHqecKHM pacTBOpHTéjieM, κβκ nanp. βιχβτοΗΟΜ, MeTHJieHXJiopHAOM nnH- 256916OmnGoqno cKneemihie A®This οπητβ pasbeMHb τερΜΗπεοκοϋ οθρβθοτκοίί b TeqeHHe 120 cei <b cyraHJibHOM nn ^ y npH 80 * Ch cnn κηβπ mo y hoAajHHTb οτ ποβθρχηοοτη neTajieň opraHHqecKHM pacTBOpHTéjieM, κβκ nanp. βιχβτοΗΟΜ, MeTHJieHXJiopHAOM nnH-256916

TpHXJiopaTHJienoM. ΠοΒτορΗΟβ Hcnanfe3OBaHHe onHTb nonyneHHbix onTHMecKHX fleTa·4·neň řípu ποΒτορβΗΗΗ npouecca wcthpobkh h (gunccamiH bo3moxho.TpHXJiopaTHJienoM. HT Β ο HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT p p p p p p p gun gun gun gun gun gun (gunccamiH bo3moxho.

Ecjih c caMoro Hanana moxho OTKaaaTbcn οτ ποπηοΛ paeTBopHMoeTH 3a4>nKCHpo-BanHoro cjioa κπβΗ, κ pacTBopy κπβπ moxho noCaBHTb nononHHTenbHo 0,1 rDDGE-6hc-MMA nnn toto, mtoBm nocrurHyTb fionee BwcTpoň Φηκοηιιηη.rioBTOpHbíM oBnyneHHeM nocne <j?nKcaijHn b TeneHHe 120 ceK moxho sanycxaTb cTy~neHb oTBepxfleHHB κπβΗ, κοτορβΗ saKOHnena οκοπο nocne 24-nacoBoro xpaHeHHHnp« KOMHaTHoň TeMnepaType. KneeBbie coeflHHeHHH, nonyneHHbie thkhm oBpasoM,OTHHHaWTCH BblCOKOň TOMHOCTbW, ΜβΠΜΜ ΗβΠρΗΧβΗΗβΜ H norOnOyCTOftHHBOCTbW. , npHMepbi 2-5Ecjih c Chamorro Hanan Moxhe OTKaaaTbcn οτ ποπηοΛ paeTBopHMoeTH 3A4> nKCHpo-BanHoro cjioa κπβΗ, κ pacTBopy κπβπ Moxhe noCaBHTb nononHHTenbHo 0.1 rDDGE 6HC-MMA-nnn this, mtoBm nocrurHyTb fionee BwcTpoň Φηκοηιιηη.rioBTOpHbíM oBnyneHHeM nocne <j? B nKcaijHn TeneHHe 120 ceK moxho sanycxaTb cTy ~ neHb oTBepxfleHHB κπβΗ, κοτορβΗ saKOHnena οκοπο nocne 24-nacoBoro xpaHeHHHnp «KOMHaTHoň TeMnepaType. KneeBbie coeflHHeHHH, nonyneHHbie thkhm oBpasoM, OTHHHaWTCH BblCOKOň TOMHOCTbW, ΜβΠΜΜ ΗβΠρΗΧβΗΗβΜ H norOnOyCTOftHHBOCTbW. , npHMepbi 2-5

OcHOBHoft cocraB απη cKneHBanHH onTHnecKHx neTaneň nonynaeTCH h oBpaBaTWBaeT-ch H3 ,cnenyrauHX BeinecTB aHanoriwHO npHMepy 1: 2,0 Γ ΜβΤβΚρΗΠΟΒΟΜΘΤΗΠΟΒΟΓΟ 3φΗρβ 5,0 Γ ΒΗβΗΠΗΓΠΗίηίΠΗΠΟΒΟΓΟ 3φΗρβ 5,0 Γ 2,2-6hC-(1 ,4,6-TpHOKCa-cnHpO-[4,4] -Η0Η3Η-2-ΜβΤΗη0Κ0ΗφβΗΗη)-Πρ0Π3Η30,3 Γ ΑΗφβΗΗπήοΠΟΗΗβΒΟΗ COHH (τβΒ. 1) 0,02 Γ ββΗΒΗΠΠΗΜβΤΗΠΚΘΤβΠΗ.OcHOBHoft cocraB απη cKneHBanHH onTHnecKHx neTaneň nonynaeTCH h oBpaBaTWBaeT-ch H3, cnenyrauHX BeinecTB and HanoriwHO npHMepy 1: 2,0 Γ ΜβΜβΚρΚ 3φΗρβ 5,0 Γ ΒΗβΒΗΠΗΓΠΗίηίΠΗΠΟΒΟΓΟ 5,0 Γ 2,2-6hC- cnHpO- [4,4] -Η0Η3Η-2-ΜβΤΗη0Κ0ΗφβΗΗη) -Πρ0Π3Η30,3 Γ ΑΗφβΗΗπήοΠΟΗΗβΒΟΗ COHH (τβΒ. 1) 0,02 Γ ββΗΒΗΠΠΗΜβΤΗΠΚΘΤβΠΗ.

BpeMH OfínyneHHH ΠΟ nOCTHWeHHH COCTOHHHH φΗΚΟβίΧΗΗ COCTaBHHeT 60 cex.flriH ΠΟΠΗΟΓΟ ΟΤΒβρΧΠβΗΗΗ CHOH ΚΠβΗ ΗβΟβΧΟΑΗΜΟ BpeMH oBnyMeHHH 90-150 ceK.BpeMH nOnHMepH3atlHH RO CHOCOBhOCTH ΠρΗΜβΗβΗΗΗ CKneeHHblX ΟΠΤΗΗβΟΚΗΧ ΛβτβπβήBHflHO H3 Ta6nHHH 1.BpeMH OfínyneHHH ΠΟ nOCTHWeHHH COCTOHHHH φΗΚΟβίΧΗΗ COCTaBHHeT 60 cex.flriH ΠΟΠΗΟΓΟ ΟΤΒβρΧΠβΗΗΗ CHOH ΚΠβΗ ΗβΟβΧΟΑΗΜΟ BpeMH oBnyMeHHH 90-150 ceK.BpeMH nOnHMepH3atlHH RO CHOCOBhOCTH ΠρΗΜβΗβΗΗΗ CKneeHHblX ΟΠΤΗΗβΟΚΗΧ ΛβτβπβήBHflHO H3 Ta6nHHH first

Ta6nHua 1: BpeMH nonHMepHaanHH (ctyneHb OTBepxneHHH κηβπ) [μ.] ππη ρ33πηηημχnpOTHBOHOHOB X” ΠρΗ ΠΗφβΗΗΠϋΟΠΟΗΗβΒΗΙΧ ΗΠΗ ΠΗ~ (4~ΤρβΤ. -ByTHn-BeH“ , 3eH)-ťtoflOHHeBbix connx ΠρΗΜβρ X" BpeMH ΠΟΠΗΜθρΗ33ΠΗΗ (μ.) 2 BF4 48 3 AsFfc 20 4 SbFg 12 5 PFg 24 O6inaa oBbeMHan ycanKa cnon Knen b npHMepax 2-5 nocne ποπηογο οτΒβρχπβΗΗΗcocTaBnueT 3,8%. IIpHMep 6Ta6nHua 1: BpeMH nonHMepHaanHH (ctyneHb OTBepxneHHH κηβπ) [μ.] Ππη ρ33πηηημχnpOTHBOHOHOB X "ΠρΗ ΠΗφβΗΗΠϋΟΠΟΗΗβΒΗΙΧ ΗΠΗ ΠΗ ~ (4 ~ ΤρβΤ. -ByTHn-run", 3E) -ťtoflOHHeBbix connx ΠρΗΜβρ X "BpeMH ΠΟΠΗΜθρΗ33ΠΗΗ (μ.) 2 BF 4 48 3 AsFfc 20 4 SbFg 12 5 PFg 24 O6inaa oBbeMHan ycanKa cnon Knen b npHMepax 2-5 nocne ποπηογο οτΒβρχπβΗΗΗcocTaBnueT 3.8% IIpHMep 6

Echu c caMoro Haqana moxho OTK33aTbCH οτ nonHoň pacTBopHMOcra 33Φηκοηροβ3η-ηογο cnoH κπβπ, κ pacTBopy Knen moxho noBaBHTb nononHHTenbHO 0,1 r DDGE-Bhc-UMA λπη toto, htoBw flOCTHrHyTb 6onee BbicTpoň φΗκοβπΗΗ, K ocHOBHOMy cocTaBy npHMepOB 2-5 npHBaBnnwT 0,4 r DDGE-Bhc-MMA. OBpaBoTKaonHTb ocyinecTBnHeTCH aHanorHHHO npiwepy 1, πρΗΗβΜ BpeMH φΗΚοβίξΗΗ cocTaBHHeT15 ceK h BpeMeHa ππη CTyneHH οτΒβρχπβΗΗΗ cooTBeTCTByroT. 3Η3ηθηηημ TaBnHiibi 1. IIpHMep 7 ' 1 r MeT3KpnnoBOMeTnnoBoro οφκρβ !C echo Chamorro Haqani Moxhe OTK33aTbCH οτ nonHoň pacTBopHMOcra 33Φηκοηροβ3η-ηογο cnoH κπβπ, κ pacTBopy Knen Moxhe noBaBHTb nononHHTenbHO DDGE 0.1 r-BHC-UMA λπη this, htoBw flOCTHrHyTb 6onee BbicTpoň φΗκοβπΗΗ K ocHOBHOMy cocTaBy npHMepOB 2-5 npHBaBnnwT 0.4 r DDGE-Bhc-MMA. OBpaBoTKaonHTb ocyinecTBnHeTCH and HanorHHHO npiwepy 1, πρΗΗβΜ BpeMH φΗΚοβίξΗΗ cocTaBHHeT15 ceK h BpeMeHa ππη CTyneHH οτΒβρχπβΗΗΗ cooTBeTCTByroT. 3Η3ηθηηημ TaBnHiibi 1. IIpHMep 7 '1 r MeT3KpnnoBOMeTnnoBoro οφκρβ!

0,02 r 6eH3nnflHMeTHnKeTanH 5 Γ ΠΗβΗΠΗΓΠΗΠΗΠΗΠΟΒΟΓΟ οφΗρβ 0,2 r ηΗφβΗΗΠϊίοηοΗΗβΒΟϋ conH (τβΒ, 1) OBpaBoTKy γομογθηη3ηροβ3Ηηογο pacreopa Knen cnenyeT npoBonuTb aHanornnHonpHMepaM 1-5. <k>pMyna Η3θ6ρβτβΗΗΗ: 1. Cnoco6 nonyneHHH KneeB Ha ochob3hhh ΜβτβκρΗπβτ—πη3ποκοηπηοΙι nonHMepH3a-UHOHHOň CHCTeMbl, OTHHHaiOmHňcH ΤΘΜ, MTO B peaKUHOHHOM paCTBOpe K XHflKOMy KOM“ 256916 - 6 - ποΗβΗτγ MeTaxpHJiaTa, xax npeHMymecTBeHHo κ MeTaxpiuiOBOMeTHjiOBOMy 3φπργ hjihΚ (2,2-/ΧΗΜβΤΗΠ-1,3~ΛΗΟΚΟΟΠβΗ-4-ΚΠ-)ΜβΤΗΠΜβΤ8ΚρΗΠβΤγ, C BeCOBOft HACTblO 10“ 50% «πη 6wcTpoň φοτοχΗΜΗΜβοκοή φΗκεβΜΗΗ paflHxaíibHOň nojiHMepHaauHeň flo6aBJiH-ιοτ φοτοΗΗΗΗΗβτορ, ofipaayiomHft pawncaji, β BecoBoň qacra 0,5-5% η κ αηβποχοηα-HOMy ΚΟΜΠΟΗβΗΤγ, Kax ΠρβΗΜγΠΙβΟΤΒβΗΗΟ Κ AHaHAHrJIHAHAHAOBOMy 3$Hpy, Β BecoBoftI qacTH 90-50% απη nocnenyromero aa φΗκοβηκεβ φοτοΗΗΗΐχΗΗρΟΒβΗΗΟΓΟ οτβερΧΑβΗΗΗιKJieH ΚβΤΗΟΗΗΟϋ nOAHMepH3aUHeň C paCXpHTHeM ΑΗΧΑβ ΑΟ63ΒΑΗΚ>Τ φΟΤΟΗΗΗΑΗβΤΟρ,o6pa3ywwHň κατηοημ, b BecoBoň wacTH 0,5-5%. 2. Cnoco6 ΠΟ Π. 1, OTJIHMaiomHftcH ΤβΜ, MTO B KaqeCTBe φΟΤΟΗΗΗΠΗβΤΟρβ, o6pa-3ywmero panHxaji, πρΗΜβΗΗΐοτ npeHMymecTBeHHo 6eH3OnH hjih CeH3OHH0Bbie 3φκρΜ, K3K Hanp. 6βΗ3ΟΗΗΜβΤΗΠΟΒΜβ 3φΗρ, 6βΗ3ΟΗΗΗ3ΟΠρΟΠΚΠΟΒΜή 3φΗΡ ΗΠΗ 6βΗ3ΗΠΑΗΜβ-THJiKeTanb, η β xanecTBe φοτοΗΗΗΑΗβτορβ, oOpasyiomero κατΗοκω, πρΗΜβΗΗΐοτnpeHMymecTBeHHo AHapHJiňoAOHHesbie ηπη τpHapHAcyπbφoHHeBbIe cojih, KOTopwe bxauecTBe προτηβοηοηοβ conepacaT xoMiuiexcHbie 3ηηοημ xax Hanp. BF+, AsFfe, PFfthjih SbFf . 3. Cnoco6 no π. 1, OTAHMawiuHňcH tgm, mto β MeTaxpHJiaTAHsnoxoHAHOň nojiHMe-pHaanHOHHOň CHCTeMe nna noBbnueHHH ynpyrocTH xjien h yMeHbmeHHH oCbeMHOň ycan-kh coflepwHTca οπΗροορτοΒφκρΗΜή κομποηθητ, xax npeHMymecTBeHHo 2,2-6hc(1,4,6-TpHOKca-CnHpO- |4,4] - ΙΙΟΗ3Η-2-ΜβΤΗΠΟΚΟΗφβΗΗΠ.)-ΠρΟΠ3Η, 2-φεΗΗΠ-ΟΚΟΗΜβ-τηπ-1,4,6-TpHOKca-cnHpo-[4,4] —ηοηβη hjih 2-η3Ο6υτηποχοημ6τηιι-1,4,6-TpHoxča-·cnwpo-[4,4] -HOHaH, B BeCOBOft M3CTH ao 50%. 4. Cnoco6 ΠΟ Π. 2, OTJIHHaMmHfiCH ΤβΜ, MTO κ ΜβΤβΧρΗΑβΤ-AHSnOKCHAHOň nOJIHMepH-3aiíHOHHOň CHCTeMe ΠρΗββΒΑΗΙΟΤ OAHrOMepHbie MHOΓOφyHK^HOHaJIbHbIe ΜβΤβΧρΗΠβΤΜ,xax npeHMymecTBeHHo npoAyxT npncoeAHHeHHH αηβηαηγιιηαηαηιιοβογο 3φπρ3 c Μβτβκ-pHJioBoň KHCJioToň b BecoBoň nacTH ao 5% c nejibio ycxopeHHH paAHKanbHoft nojiHMe-PH33AHH ΚΟΜΠΟΗβΗΤβ MeTaxpwiaTa. ÁHHOTaAHH: H3o6peTeHHe othochtch k cnoco6y nojiyMeHHM xjieeB, KOTopwe, b nacTHOcTH, npH-γοαηη απη CKneHBaHHH onTHMecKHX AeTaneň β χομ6ηη3αηη CTexno/cTexno hjih CTex-jio/MeTanJi.0.02 r 6eH3nnflHMeTHnKeTanH 5 Γ ΠΗβΗΠΗΓΠΗΠΗΠΗΠΟΒΟΓΟ οφΗρβ 0.2 r ηΗφβΗΗΠϊίοηοΗΗβΒΟϋ conH (τβΒ, 1) OBpaBoTKy γομογθηη3ηροβ3Ηηογο pacreopa Knen cnenyeT npoBonuTb and HanornnHonpHMepaM 1-5. <K> pMyna Η3θ6ρβτβΗΗΗ 1. Cnoco6 nonyneHHH KneeB Ha ochob3hhh ΜβτβκρΗπβτ-πη3ποκοηπηοΙι nonHMepH3a-UHOHHOň CHCTeMbl, OTHHHaiOmHňcH ΤΘΜ MTO B peaKUHOHHOM paCTBOpe K XHflKOMy COM "256916-6 - ποΗβΗτγ MeTaxpHJiaTa, XAX npeHMymecTBeHHo κ MeTaxpiuiOBOMeTHjiOBOMy 3φπργ hjihΚ (2,2- / ΧΗΜβΤΗΠ-1,3-4-ΛΗΟΚΟΟΠβΗ ΚΠ-) ΜβΤΗΠΜβΤ8ΚρΗΠβΤγ C BeCOBOft HACTblO 10 "50%" πη 6wcTpoň φοτοχΗΜΗΜβοκοή φΗκεβΜΗΗ paflHxaíibHOň nojiHMepHaauHeň flo6aBJiH-ιοτ φοτοΗΗΗΗΗβτορ, ofipaayiomHft pawncaji, β BecoBoň qacra 0.5-5% η κ αηβποχοηα Homo ΚΟΜΠΟΗβΗΤγ, Kax ΠρβΗΜγΠΙβΟΤΒβΗΗΟ Κ AHaHAHrJIHAHAHAOBOMy 3 $ Hpy, Β BecoBoftI qacTH 90-50% απη nocnenyromero aa φΗκοβηκεβ φοτοΗΗΗΐχΗΗρΟΒβΗΗΟΓΟ οτβερΧΑβΗΗΗιKJieH ΚβΤΗΟΗΗΟϋ nOAHMepH3aUHeň C paCXpHTHeM ΑΗΧΑβ ΑΟ63ΒΑΗΚ> Τ φΟΤΟΗΗΗΑΗβΤΟρ, o6pa3ywwH κατηοημ b BecoBoň wacth 0.5-5%. 2. Cnoco6 ΠΟ Π. 1, OTJIHMaiomHftcH ΤβΜ, MTO B KaqeCTBe φΟΤΟΗΗΗΠΗβΤΟρβ, o6pa-3ywmero panHxaji, πρΗΜβΗΗΐοτ npeHMymecTBeHHo 6eH3OnH hjih CeH3OHH0Bbie 3φκρΜ, K3K Hanp. 6βΗ3ΟΗΗΜβΤΗΠΟΒΜβ 3φΗρ, 6βΗ3ΟΗΗΗ3ΟΠρΟΠΚΠΟΒΜή 3φΗΡ ΗΠΗ 6βΗ3ΗΠΑΗΜβ-THJiKeTanb, η β xanecTBe φοτοΗΗΗΑΗβτορβ, oOpasyiomero κατΗοκω, πρΗΜβΗΗΐοτnpeHMymecTBeHHo AHapHJiňoAOHHesbie ηπη τpHapHAcyπbφoHHeBbIe cojih, KOTopwe bxauecTBe προτηβοηοηοβ conepacaT xoMiuiexcHbie 3ηηοημ XAX hANP. BF +, AsFfe, PFfthjih SbFf. 3. Cnoco6 no π. 1 OTAHMawiuHňcH TGM MTO MeTaxpHJiaTAHsnoxoHAHOň nojiHMe β-NNA pHaanHOHHOň CHCl noBbnueHHH ynpyrocTH xjien h yMeHbmeHHH oCbeMHOň ycan-kh coflepwHTca οπΗροορτοΒφκρΗΜή κομποηθητ, XAX npeHMymecTBeHHo 2,2-6hc (1,4,6-TpHOKca-CnHpO- | 4,4] - Η3Η-2-ΜβΤΗΠΟΚΟΗφβΗΗΠ.) - ΠρΟΠ3Η, 2-α-π-ΟΚΟΗΜβ-τηπ-1,4,6-TpHOKca-cnHpo- [4,4] —ηοηβη hjih 2-η3Ο6υτηποχοημ6τηιι-1,4,6-TpHoxca- · cnwpo - [4.4] -OHOH, B BeCOBOft M3CTH and 50%. 4. Cnoco6 ΠΟ Π. 2 OTJIHHaMmHfiCH ΤβΜ MTO-κ ΜβΤβΧρΗΑβΤ AHSnOKCHAHOň nOJIHMepH 3aiíHOHHOň-CHCl ^ ΠρΗββΒΑΗΙΟΤ OAHrOMepHbie MHOΓOφyHK HOHaJIbHbIe ΜβΤβΧρΗΠβΤΜ, XAX npeHMymecTBeHHo npoAyxT npncoeAHHeHHH αηβηαηγιιηαηαηιιοβογο 3φπρ3 Μβτβκ c-b pHJioBoň KHCJioToň BecoBoň nacTH and 5% c nejibio ycxopeHHH paAHKanbHoft nojiHMe-PH33AHH ΚΟΜΠΟΗβΗΤβ MeTaxpwiaTa. AHHOTaAHH: H3o6peTeHHe othochtch k cnoco6y nojiyMeHHM xjieeB, KOTopwe, b nacTHOcTH, npH-γοαηη απη CKneHBaHHH onTHMecKHX AeTane β χομ6ηη3αηη CTexno / cTexno hjih CTex-jio / MeTanJi.

UeJibio H3o6peTeHHH ηβπηθτοη - co3AaTb cxJieHBaHHH, κοτορωε AonroBeMHbl, πογοαο-yCTOňHHBbl H BblCOXOTOHHbl C MajIblM ΗβΠρΗΧβΗΗβΜ. 3aAana Η3θ6ρβτβΗΗΗ - BAHHTb Ha npoitecc OTBepxAeHHH npn xneax t3Khm o6pa3OM,mto6w 6μπη ynpaBjíaeMbi h 6bifcTpa« φΗκοβΑΗΗ é BOaMOXHOCTbio xoppexAHH h MeAJieH—Hoe nojiHoe OTBepwneHHe. OHa cornacHO Η3θ6ρετβΗΗΜ πρκ cnocoSe Ha οοηοβηηηηnonHMepH3auHOHHoň chct6mm pemaeTCH τβΜ, mto b peaxijHOHHOM pacTBope x whako-My xoMnoHeHTy MeTaxpHJiaTa b BecoBoň MacTH_10-50% ποββΒΠΗίοτ φοτοΗΗΗΑΗβτορ,o6pa3yromHň paAHxan, c BecoBoň MacTbio 0,5-5% hk AHanoxcHAHOMy xoMnoHeHTy cBecoBoň qacTbio 90-50% ΑοββΒΑΗΐοτ φοτοκΗΗΑΗβτορ, oSpaayranHň xaTHOHbí, b Beco-Boň Hacra 0,5-5%. npH3Hano Η3ο6ρετβΗΗβΜ no pesyjibTaTaM sxcnepTHSbi, ocymecTBJíeHHoň Βθαομοτβομno ΑθπβΜ Η3θ6ρβτβΗΗή η πβτβΗΤΟΒ TflP. , · . 256916 ‘UeJibio H3o6peTeHHH ηβπηθτοη - co3AaTb cxJieHBaHHH, κοτορωε AonroBeMHbl, πογοαο-yCTOnHHBbl H BblCOXOTOHHbl C MajIblM ΗβΠρΗΧβΗΗβΜ. 3aAana Η3θ6ρβτβΗΗΗ - BAHHTb Ha npoitecc OTBepxAeHHH npn xneax t3Khm o6pa3OM, mto6w 6μπη ynpaBjíaeMbi h 6bifcTpa «φΗκοβΑΗΗ BO BOaMOXHOCTbio xoppexAHH h MeAJieH — Hoe nojiHoe OTBepwneHHe. OH and cornacHO Η3θ6ρετβΗΗΜ πρκ cnocoSe Ha οοηοβηηηηnonHMepH3auHOHHoň chct6mm pemaeTCH τβΜ MTO b peaxijHOHHOM pacTBope x whako-My xoMnoHeHTy MeTaxpHJiaTa b BecoBoň MacTH_10-50% ποββΒΠΗίοτ φοτοΗΗΗΑΗβτορ, o6pa3yromHň paAHxan c BecoBoň MacTbio 0.5-5% hk AHanoxcHAHOMy xoMnoHeHTy cBecoBoň qacTbio 90-50 % ΑοββΒΑΗΐοτ φοτοκΗΗΑΗβτορ, oSpaayranHn xaTHOHb, b Beco-Boň Hacra 0.5-5%. npH3Hano Η3ο6ρετβΗΗβΜ no pesyjibTaM sxcnepTHSbi, ocymecTBJíeHHòň Βθαομοτβομno ΑθπβΜ Η3θ6ρβτβΗΗή η πβτβΗΤΟΒ TflP. , ·. 256916 ‘

Claims (4)

- 7 - PKEDdST. VYNÁLEZU- 7 - PKEDdST. THE INVENTION 1. Způsob výroby lepidel na bázi metakrylát - diepoxidovépolyraerační soustavy, vyznačující se tím, že k reakčnímuroztáku tekuté metakrylátové složky, především metylmetakry-látu nebo k /2,2 diinetyl-l,3-dioxolan-4yl/metylmetakrylátuhmotnostní koncentrace 10 až 50 é pro rychlou fixaci foto-chemickou fixaci radikální polymerace přidává fotoiniciátor,vytvářející radikál v hmotnostním množství 0,5 až 5 ,í a kdiepoxidové složce především jako k diandiglycidyl eteruve hmotnostním množství 90 až 50 pro fotoiniciovanévytvrzení lepidla kationbvóu polymerací s přerušením cyklunásledující po fixaci přidává fotoiniciátor, vytvářejícíkationy, o hmotnostním množství 0,5 až 5 >á.A process for the production of methacrylate-diepoxide-based polyacrylate adhesives, characterized in that a liquid methacrylate component, in particular methyl methacrylate or k / 2,2 diinetyl-1,3-dioxolane-4yl / methyl methacrylate, is present in the reaction vessel at a concentration of 10 to 50%. the rapid fixation of the photo-chemical fixation of radical polymerization adds a radical-forming photoinitiator of from 0.5 to 5% by weight and, in particular, from 90 to 50 for the photoinitiated cationic cure adhesive by polymerization with cyclic breakdown after fixation, adds photoinitiator, forming a photoinitiator. , of from 0.5 to 5% by weight. 2. Způsob podle bodu 1, vyznačující se tím, že jakc.foto-iniciátor, vytvářející radikál, se používá především bén-zoin nebo benzoinetery, jako například benzoiňmetyleter,benzoinisoprppyle.ter. nebo benzyldimetylketal a jako foto-iniciátor, vytvářející kationy, se především používá dia-nyljodoniová nebo triarylsulfoniove soli, které jako proti-iony obsahují komplexní aniony, jako například BP^, PPg nebo 3bP^.2. A process according to claim 1, wherein the radical-forming photo-initiator is used primarily by benzoin or benzoiners such as benzoethylether, benzoin isoprppyle. or benzyldimethyl ketal, and the cation-forming photo-initiator is, in particular, the diiodoiodonium or triarylsulfonium salts which contain complex anions as counter-ions, such as BP, PPg or 3bP. 3. Způsob podle bodu 1, vyznačující 3e tím, že v metakrylát-diepoxidová polymerizační soustava ke zvýšení pružnosti le-pidla a ke snížení objemového smrštování obsahuje 3piroo.r-toesterovou vložku, jako především 2,2-bis/l,4,6-trioxa-spiro-/4,4/-nonan-2-metvloxyfenyl/-propan, 2-fenyl~oxime-tyl-1,4,6-trioxa-spiro-/4,4/-nonan nebo 2-izobutyloxime-tyl-1,4,6-trioxa-spiro-/4,4/nonan, ve hmotnostním množstvído 50 ;4. 256916 - 8 -3. A process according to claim 1, wherein the methacrylate diepoxide polymerization system comprises a 3piro-toester liner, such as, in particular, 2,2-bis / l, 4.6 in order to increase the flexibility of the adhesive and to reduce the volume shrinkage. -trioxa-spiro- [4,4] -nonane-2-methoxyphenyl] propane, 2-phenyl-oxime-1,4,6-trioxa-spiro- (4,4) -nonane or 2-isobutyloxime- 1,4,6-trioxa-spiro [4.4] nonane, in an amount of up to 50% by weight. 256916 - 8 - 4. Způsob podle bodu 2, vyznačující se tím, že k raetakrylát-diepoxidové polymerizační soustavě se přidávají oligomernívícefunkění metakryláty, jako především produkt adicediandiglyoidyleteru s metakrylovou kyselinou ve hmotnost-ním množství do 5 $ za účelem urychlení radikálové polyme-race metakrylátové složky. 2569164. A process as claimed in claim 2, wherein oligomeric methacrylates are added to the methacrylate diepoxide polymerization system, and in particular to the methacrylic acid methacrylic acid adi-diamine glycidylidene product in an amount of up to $ 5 to accelerate the methacrylate component radical polymerization. 256916
CS839884A 1983-01-31 1983-12-23 Method of adhesives production CS256916B1 (en)

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EP0279224B1 (en) * 1987-02-12 1990-08-01 Siemens Aktiengesellschaft Method for photopolymerizing uv-curable materials
BR9606832A (en) 1995-01-13 1997-12-30 Minnesota Mining & Mfg Process of bonding a component to a glass and pressure sensitive adhesive sheet material
DE19727237C2 (en) * 1996-07-05 1998-09-17 Gsaenger Optoelektronik Gmbh Crystal arrangement and its use
DE10037626B4 (en) * 2000-08-02 2005-07-07 Weiss Chemie + Technik Gmbh & Co. Kg integrated system
US20050256219A1 (en) * 2002-03-11 2005-11-17 Hideaki Takase Photocurable resin composition and optical component

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