CS246576B1 - Crystalic silicate with content of metal - Google Patents

Description

HasBaHHe Η3ο6ρετεΗΗΗ

MeTanJiocoflepJKainHň KpHCTajuiHHecKHň CHJiHKaT (IZ 40) OSjíaCTb ΠρΗΜβΗβΗΚΗ Η3θ6ρετεΗΗΗ Η3ο6ρετβΗΗε KacaeTca ηοβογο MeTaJinocoflepjKamero KpHCTajnmqecKoro CHjiHKaTac onpe ^ ejieHHoň CTpyKTypofi ρεηιετΚΗ η πορ, πρηγοαηογο b KauecTBe κομποηοητηKaTajiHaaTopa hjih ancopSeHTa.

XapaKTepHCTHKa n3BecTHbix ε BH BH BH BH BH BH BH BH BH BH BH BH BH BH BH BH BH BH ora ora ora ora ora ora ora ora ora ora ora ora ora ora ora ora ora. Hx ormmie coctoht b napaMerpax cHHTO3a h / hjih b hx φΗ3Ηκο-ΧΗΜΗΐεοκΗΧCBoňCTBax. flnH cnHTe3a aboahtob ceMenucTBa ZSM ρρερττΗΗΗ Han, HanpHMcp, πετΒερ-ΤΗΠΗωε cooahhchhh βμμοηηπ hjih φοσφορε '(US — PS 3702886); hjih hx. πρεππιεετΒεΗ-hhkh, τ3ΚΗε Kax περΒΗΗΗωε aMHHb (DE-OS 2442240) hjih cmoch οπηρτοβ NHj (DE-OS 2913552 ·).

KpHCTaJIJIHHBCKHB ΚρβΜΗΗεΒΜΘ KHCJIOTbl ΜΟβΗφΗΐχΗρΟΒβΗΗΗε ajHOMHHHBM, Tp86yi0ntH8ftTIH HX CHHT83a TCTpaaJIKHJlOpTOCHJIHKaT HJIH CHJlHKarBJIb, OnHCblBaBTCH, H3KO- Ηεμ b πβτεκτβχ DD-PS 144 397 144 398 h, OnHcaHHbia προΑΥκτω Ballad 6biTb otjiha HO HCnOJIb3OBaHbI KHK aflCOpSBHTbl HJIH ΚΟΜΠΟΗεΗΤΜ KaTaJIH3aTOPOB. fljiH οβεεπεπεΗΗΗ c8jibkthbhocth, Hrparaqen πρκ stom óco6ob 3ΗΗπεΗΗε, ctpbmht-CH riOJiyHHTb npOflyKTbl HCKJHOMHT8JIbHO HHCTOft φβ3Μ. #JIH nOJiyH8HHH npOAyKTOBHHCTOft φβ3Μ H XOpODIO KpHCTaJIJIH3OBaHHbIX o6bIHHO Tp86yBTCH flOJirO8 BpSMH KPHC-TaJiJiHsaixHH (Ηε ΜεΗεε nacoB 24 - 100 and 6οπεε nacoB) h / hr hjih cnenHajibHbiecjiojKHbre TBM ueHHbie Cambio, τεχΗΗπεοκΗ TpyflHo nocTynHbia ορΓΗΗΗΗεεκΗε cobah HBHHH-K Tomy Xe C ΤΟΗΚΗ 3pBHHH TBXHHKH 683OnaCHOCTH Η 3ΚΟΠΟΓΗΗ Bp8flHbI ~ onacHb h TpaSyioT nosTOMy προΒεΑθΗΗΗ. ójioiKHoň poKynopaipiH h / hjih cnocoSoBo683BpBJKHBaHHH. 246576

Uenb H3o6peTeHHfl

Uenbio H3o6peTeHHH hbjihctch hobhh MeTajinocoflepacamnH RpucTajinimecKHň cktih-k3t onpeflGjieftHoň CTpyKTypoň pemeTKU c h NOP TpeSyiomHň ajih nonyneHHH προ-pyKTOB hhctoh <J) a3bi h xoporno KpHCTanjingoBaHHbix NPOP; yKTOB oneHb κοροτκοεBpeMH KpHCTajiJiHáaííHH and Tax®e TexHnnecKH nerxo nocTynHbix n 6e3Bpep; HbiX χριπoKpyacaromeň CPEP BemecTB.

H3noaceHHe cyiUHoCTH H3o6peTeHHH nocTaBJíeHa 3apana CO3 n ATB MeTajuiocop EP »ainHň xpucTajunmecKuň CHJiHKaT, npn rOflHbEH Ha OCHOBaHHH OflHOPOfíHOň CTpyKTypbl pemeTKH Η nop H HHCTOTH φ33 flJIHHcnonb3OBaHHH KanecTBe apcopSeHTa η b / ηπη κομποηθητβ xaTajiH3aTopa bo mho" -rnx o6jiacrax npHMeHeHHH. flaHHaa 3aflaya peuiaeTcn c ποΜοιιχωο MeTajuiocoflepatamero KpHCTajuiHnecKoro chjih · "xaTa y κοτοροτο, cornacHo Η3ο6ρθτθηηκ> MonapHoe cooTHoineHHe SiO2: A1j, O3b MeTannocoflep-MEM xpucTannunecKoM cnjiUKaTe cocTaBJíneT ^ 30, and aojih SiO * b 6e3Bop; HOM npoflyxTe ^ 92 Mace"% H fluarpaMMa peHTreHoBCKoň flHýpannn ΗΜβετcne, Ayioi! IHE peýneKCbi: 3HaneHHH b w HHTeHCHBHOCTb HOPMHpOBaHHaH 1115 oneHb CHjibHaa 1030 OHeHb CHjIbHaH 1025 'CHJIbHafl 0.997 cna6aa 0.605 cnačan 0.575 cnaSan 0.562 cjiafíaa 0.427 cnaSan 0.388 oneHb CHjibHaa 0.384 CHJibHaa 0.377 cpeflHeň cmíbí 0.373 cpennen chjih 0.366 cjiaBaa 0.346 cnaSafl 0.336 cnaSan 0.306 cnaSan 0.300 cnaBan OP Πρίϊ KOTOPOM aflCOpSlpIOHHaH CnOCOČHOCTb 6β3ΒΟ, ηΗΟΓΟ MaTepnajia COCTaBHJia npH298 K p, south 6eH3ona> 7 Mace.Z, ajih H-reKcaHa ž9 Mace.Z η ajih. Bouh 48 Mace.npn flaBJíeHHH Napa HacbímeHHH copfiaTa h npn kotopom CHJiHKaT (night-xpucTaii nn3annn) coflepjKHT noBepxHocTHo-3κτηβηηθ semecTBa ηηηοηηογο h / hjih ηθηοηο-reHHoro early, oflHaKo CBoSoflHbie opraHHnecKHX οτηοηοβ rpm.

TococjepjantantantpppppppppppnecnecnecnecnecnecnecnecnecJJJJJJKK ^ ^ ^ ^ ^ ^ ^ ^ ^ ^T, ,TTTTTTTTTTTTTTTTpTpppppppppppppppppppp, OcoBeHHo SnaronpííHTHo, eenn pa3Mepw KpHCTaroiHTOB CHJiHKaTa cocTaB-πίηοτ 45 m.

MeTanjiocoflepjKannjň RpncTajuinnecKHň chjihkht, cornacno Η3θδρετεΗΗΐο? fíanee co ~ ροτκο o6o3HanaeMbiň LZ 40 otjihhho NOP xoflHT KanecTBe aflCopBeHTa η b / ηπη com- noHeHTa 246576 3 'KaTanHsaTopa, πρκηεΜ npoflyxTbi OTXofla xpHCTajiJiH3auHH not τρεβγιοτ' cnoKHott τβχΗοηοΓΗΗ peKynepaunH o6e3BpexHsaHHH h.

MeTajuiocoflepMaiuHň xpHCTajijiHnecxHň CHJiHxaT, corjiacHo Η3θ6ρετεΗΗΐο (LZ 40) oTJiHHaeTCH Bhicoxoň ηκοτοτοή φε3 h ormmioň kpacTasuimHocTbio and Tax- «e ot oTBHMaeTCH H38ecTHbix uecwiHTOB THna ZSM xapaxTepHoň peHTreHOBcxoň autarpaMMoň.

IkuiyHeHne Μοκετ GbiTb προΒεβεκο τηχημ o6pa3OM, HTO KpncTajtnn3aijnoHHaH CMecb, cocToamafl hs κε ΜεΗεε οαηογο CO8AHH8HHH MeTaJiJia, cnoco6Horo x oGpaaoBaHHronpocTpaHCTB8HHO-c8TMaToň CTpyKTypbi, HeopraHHnecKoro εοεΑΗΗεΗΗΗ xpeMHHH, Ηβ ΜεΗεε οαηογο HeopraHHnecxoro ocHOBaHHH and taxxi οαηογο noBepxHocTHO-aKTHBHoro BamacTBa aHHoHHoro h / hjih HeHOHoreHHoro THna, noABepraeTCH γηαρο-TepMajibHoň xpHCTajiAHsanHH what BpeMeHeM xpHCTaJiAH3anHH á20 nacoB.

IloCJie ΟΤΑ &amp; H Π8ΗΗΗ ΜβΤΟΗΗΟΓΟ paCTBOpa yflajIBHHH 3 «Γε3ΗΟΗΗΟΓΟ paCTBOpa LZ 40coflepatHT Hapan c ocHosaHHeM ηοοκηαηηηο cooTBeTCTByiomHe xojnmecTBa BepXHOCTHO-amino-aKTHBHbIX COaflHHCHHfí, flO6aBJ18HHbIX B CM8CB XpHCTaJIJIH3aAHH,

OnesHAHo, nofloSHan φ «3ΗΗεεκεΗ · affCopSííHH XAX ocnoBaHHň, Tax-η ΗεπρεΜεΗΗο nOBOpXHOCTHO aKTHBHbIX BeneCTB HBJíHeTCH p8UiaK> m8H ΠρεβΠΟΟΛΠΧΟή flJlH o6pa3OBa hhh IZ-LZ 40 40 B oTcyrcTByioT opraHHnecxHe κητηοημ, ooh ^ ηο EME EME hjih hxnpBsmecTBCHHHKH TpeGyioTCH ajih xpHCTajuiHaaAHH ero. B XaH8CTB8 HBOpraHHHBCKOrO ΚΟΜΠΟΗεΗΤΒ XpeMHHH npeHMymeCTBeHHo nORXOflHTρεΗΤΓεΗΟΗΜορφΗΗή ajnoMocnnHxaT hjih - rnflporajib c coothobibhhbm Sí04 / A140, OT 1 flo 1 000. HaJiee Ballad 6biTb HcnoJib3OBaHu: jKHflxoe CTexno, rHAPorenbχρεΜΗΗβΒΟΗ XHCJIOTbl HJIH XH38JIb3OJIb. B xaH8CTB8 nOBapXHOCTHO-aXTHBHbIX BOmeCTB aHHOHHOro THna HHBHb xoponio ΠΟΑ-XOABT OCHOBHbie 3JI8M6HTbl emeξΗΧ BemeCTB Kax, HanpHMep, Η-εΧΙΧεΗΟγΠΒφΟΗβΤΜhjih TaypHTbi. ΠρεΑΠΟΗΤΗΤεΠΒΗΟ ΜΟΓΥΤ TaKJKB GblTb HCnOJIb3OBaHbI ΘΜφορΤερΗΜε nOBOpXHOCTHO “aXTHBHMe B8I48CTBa (GeTHHHbl), XaK, HanpHMep ,. OHH HCnOJIh3yiOTCH B K0CM8TH-HBCKOň npOMbimnaHHOCTH, Tax XAX B mBJIOHHOň Cp8Ae KpHCTaJIJIH3aiIHH OHH flBH-CTByiOT XAX aHHOHHbie nOBOpXHOCTHO-aXTHBHbI8 BBIUCCTBa B xanecTBe noBepxHocTHo-ηκτηβηογο BemecTBa ηβηοηπογο THna c ycnexoMMoryT ĎMTb HcnoJibSOBaHbí, HanpHMep, TexcTHJibHbie BcnoMoraTejibHbie cpeflcŤsa, raxHe XAX aJixHjnJieHHJinoJiH3THJieH hjih noJiHBHHHJioBbiň οπκρτ . B xanecTBe meta-jiocoeAHHenHň, cnocoGHux x o6pa3OBaHHK> npocTpaHCTBeHHo-ceTnaToň cTpyxTypu, ficnoJibayeTCH npeHMymeCTBeHHo coeAHHeHHe ajnoMHHHH, χοτοροε HBJíHeTCH HHTpa- TOM aJHOMHHHB HJIH aJIBMHHaTOM ΗβΤρΗΗ.

Ammh3x h / hjih rHAPOoxHCb meJioHHoro MeTajuia h / hjih meJionHbix seMejib, h / hjihajnoMHHaT mejionn MoryT Gmtb HcnoJibsoBaHhi b xanecTBe HeopraHHnecxoro ochob3 — HHH. IIpeAnoHTHTiHHaH TeMnepaTypes xpHCTajuiH3aAHH cocTaBeHeT 400-480K, npennon-THTeJibHaH npoAOJDKHTeJibHocTb xpHCTaJUiH3anHH 5-15 nacoB. MeTaJiJioCoflepacatuHeCHJiHxaŤbi, noJiyneHHbie cornacno Η3θ6ρετεΗΗΐο, otjihhho xpHCTajuiHaoBaHbí h otjihh-ho ποαχοαητ απη HcnoJibsoBaHHH b xanecTBe xoMnoHeHToB xaTaJiHsaTopa hjih an-copčeHTOB. HHxcecjieAyioiqHe πρΗΜβρω οΘέ, ηοηηιοτ πρεΑΜβτ ο3ο6ρβτεκΗΗ ποΑΡοβΗεε: 246576 IIpHMepbi ocymecTBneHHH H3o6peTeHHH. ÍIpHMep 1 B aBTOKJiaBe BCTpaxHBaHHH nepeMeuiHBaioT JKHflHoro CTeKJia 880 r (350 rn ' "Si02,130 rn' NaOH) c r 1150 soflbi. The 3TOMy floSaBnaeTca pacTBop, coflepacamHň b-ka-necTBe noBepxHocTHo aKTHBHoro BeiuecTBa aHHoHHoro Tuna, H-aJiKHJicy. nbii) C h i c C h i c C i 8 C (E 30) b ConunecTBe 40 r, HMeIeHiOnB b b ueMeMeKe, BOfly b KojiHeCeBe 500 rMMuMaK (f = 0.910 Γη - *) 1 b xonunecTBe 240 r. flanee, Tax «e npnHBaHHH flo6aBnaeTca pacTBop, npuroToBJiHHBiNHyBeHpHnHhH 40 r AI (N0?) 3 · 9 H20 b 1000 r BOlb h 185 r 33οτηοη khcjioth (p = 131 rn '), aaKpbiTHH aBToxnaB noflorpeBaeTca b TeneHHe 4 nacoBfío 460 K h BbiflepaoiBaeTCH b TeqeHHe 10 nacoB npn TeMnepaType stack. NOC-oxjiaxfleHHH them aBTOKJiaBa npoflyKT KpHCTannH3aflHH (jiHJibTpyeTCH, npoMbiBaeTca hocTaTOK ΗπφΗΠΒτρβ cyniHTca NPH TeMnepaType 393 K. ÍIonynaeTCH 100% RpncTajuiH-necKHň npoflyKT, coflepatamnň He3HanHTenhHyio Flomo what KBapqa tt KpHCToSanHTa.BejiHHH Ha KpncTannHTa cocTaBJiaeT 1-2 jiim,

CornacHo sneMeHTapHOMy pineapples KpncTa; iJimecKm ηρορ, γκτ coflepamT 1.3 Macc% Ch 0.3 Macc.% H, cornacHo KOJinQecTBy ap, cop6npoBaHHoro noBepxHocTHo-aKTHBHoroBemecTBa.

Ilocne TepMHnecK6 o6pa6oTKH npoflyKT coflepjKHT (5 nacoB npH 873 K) cneflyw-ihhh XHMHnecKHn cocTaB:

Si02 - 95.8 Macc.

Al205 2.9 Macc.%

Na20 1.3 Macc.% NpoKajHHaa npho aflcopčHpoBana npn TeMnepaType 298 K 10.3 Macc,% H-rex-caHa, 8.8 Macc.% 6eH3ona n 6.3 Macc.% Soflbi. B TaBnuye 1 nomaHa nuarpaMMa peHTreHOBCKoň αηΦρβκαηη ρριπ HenpoKaneHHoronponyxTa. ΠρηΜερ 2300 r b pač.qeTe Ha 6e3B0flHbiH MaTepnan, ρεΗΤΓεΗοΗΜορφΗοτο anroMOCHnHKaTHoronaspořena c μοπβηημ cooTHoiueHneM Si02 / Al203 55 cycneHflupyioTCH npn cnnbHoMnepeMemHBaHHH b pacTBope, coneparameM 60 NaOH, 10 r pacTBopa amoMHHHTaHaTpna (290 RN1 AI205; rn1NaOH 273) and 20 Taoce r, HMeiomeroca b npoMbimneH-hom MacuiTaOe, oJamiMeTHJiTaypuTa (MeTaynoHa), b 2 mji βοαη. CMecb nepeBosHTca b ββτοκπββ h npn flanbHeňmeM HHTeHCHBHOM nepeMemHBaHHHSoóaBJíHioTCH 300 μπ pacTBopa aMMHaxa (250 rn 'NH3) aBTOKnaB cpa3y ACE aaKpbi ™ BaeTca h npn npoflon »awmeMcn nepeMemHBaHHH noflorpeBaeTCH b τθηθηηθ 4 nacoBflo TeMnepaTypbi 480 K h Bbiflep? KHBaeTCH npn flaHHoň TeMnepaType 5 xacoB.

Ilocne οτΦηηβτροβηβηηηη, προμβιβκη h cyiiiKH nposyKT HMeeT peHTreHOBCKyto flH-φρηκτοΓρβΜΜν cornacHo TaBnnpe 1, c Manoň εΜορφΗοή floneň (TaBnuija 2, cpaB-HeHHe). 246576 5 tpeflHHH -B & nmtHHa sepHa xpHCTannHHecKHX nacTHut cocTaBnana 0.5-2 μ. π Μ Tap K Tap H H b b b b b H H H H H H c. c. c. c. c. 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73 73

SiO, - 95.7 Macc.Z

Alt0, - 2.4 Macc.Z

Na.O -1,8 Mace.Z Πρκ τβΜπβρβτγρβ 298 K aflcopOHpyeTCJi: 9,5 Mace.Z H-rexcaHa10,5 Mace.Z CéHaona7,0 Mace.Z boam ΠρΗΜβρ 3.

KpHCTannHaauHH npoBOflHTCaHanorHHHO npHMepy eemecTBa HHOHoreHHoro early flo6aBn «eTCH okhcb βηκΗπφβΗΗΠΠοπΗοκ-CHBTwieHa (npsBoijenn ON) b KonHwecTBe 50 r, HMewmHn b bpnbpbΗΗΟΜMacm. npoflonxHTenbHocTb CHHTesa cocTasnaeT 10 nacoB npH TeMnepaType430 K. IIoJiyuaeTCH Ha 100Z KpHCTaJUiHHecKHn προηγκτ MHCToňn φββω what cpeflHHMpaďMepoM xpHCTaJirtHTa 1,5-3 jum. 3neMeHTapHMft and HanHs KpHCTannHuecKoro npo-flyxTa noKa3biBaeT 1.3 Macc.Z C h 0.2 Mace.Z H.

PeHTreHOBCKaa ΑΗφρβκτοΓρβΜΜβ HfleHTHHHa npHBefleHHQn b τββηκύβ 1. nocne TepMHHecKoft οβρββοτκΗ KpHCTannHHecKHn npoflyxT (5 nacoB npri 873 K) ΗΜββτ cneflywnpift XHMHuecKHn cOCTaB:

Si04 - 95.2 Mace.Z

Al40, - 2.6 Mace.Z

Nat0 - 2.2 MaceiZ η a «cop6HpyeT npH 298 K 10.9 Macc.Z Η-rexcaHa, 10.4 Mace.Z 6eH3ona h 6.8 Macc.Z BOffU. ΠρΗΜβρ 4 1000 r KH3ejib3OJiH (280 ra '* Si04) nocne floGaBneHun CMecH; 273 rn '* NaOH), and 50% KOH b 500 mji fight. nocne TiuaTenbHoro πβρβΜβΠΜΒβΗΗΗAOCaBJíaioT 1000 μπ βΜΜΗβΗΗΟΓΟ pacTBopa (120 rn'1 NH) · NPH ηβρβΜβιΠΗΒβΗΗΗη peaxipioHHaa cmccb noflorpeBaeTCH b c aBTOKJiaee MeiaanKoň πρκ npoflonxaiomeM CH ΠβρβΜβΙΠΗΒβΗΗΗ B "ΤβΗβΗΗβ ΠΡΗΜβρΗΟ 3 Hacoba FLO TeMnepaTypbl 480 K BMflep Η-b XHBaeTca ΗβΜ πρκ nannoň TeMnepaType b τβπβΗΗβ 15 Hacoba. ΠροΜΗτωή h swey-wéHHbiň npoflyxT BMcoxoKpHCTannHHeH, πρκ cpeflHeM pa3Mepe nacTHfl 3-5 | microns. EropeHTreHOBCKan ΑΗφρβκτοηρβΜΜβ cooTBeTCTByeT npHBefleHHoft b TaCnnije 1 oflHaxoHaCnioflaeTCH ΗβηΗΗΗβ αοπη λ Ksapija. nocne προκαπΗΒβΗΗπ πρκ 873 K. Ha eoafly XE-b TeneiiHe 5 nacoB npoflyxT ΗΜββτ cneflyioupifl XHMunecKHn cocTae: '

Si04 - 97.1 Macc.Z

Alt0,. - 1.7 Macc.Z

Na20 - 1.1 Macc.Z 246576 «Tape TeMnepaType 298 K aflcop6HpyeTca 9.3 Mace.Z H-reKcaHa, 7.5 Macč.Z 6εκ-3OJia h 5.3 Mace.Z H20. ΠρΗΜβρ 5.

H3 nPHMepa 1 noflBepraeTCH H3BecTHbiM o6pa3OM hoH-OHMeHH NH4 HOH3MH, MOeTCH H CyiUHTCH. ΠρΗ flOĎaBHeHHH 30 MaCC.Z rHflpoOKHCHajnoMHHHH THna SeMHTa and τειοκε 3 Macc.Z Ca CTeapa'Ta (b xanecTBe CBH3ywmeroBemecTBa hjih BemecTBa, npHflaromero CKOJib3KocTb) προβο ^ ητοη nocjieflyromaH npeccoBKa b iíHJWHflpHqecKHe 3KCTpynaTbi pa3MepoM 5x5 mm κοτορωε 3aTeM τε b-5 qeHHe nacoB npoKaJiHBaioTCH Ha BO3flyxe npH TeMnepaType 823 K. UHJiHHfflpHnec-3KCTpyflaTbi KaTanHTHnecKii HcnbiTbiBaioTCH πρκ cneflywiuHX ycnoBHHx b peaKiiHHnpeBpameHHH ΜετπηοΒΟΓο επΗρτε:

Cbipbe • MeTHHOBblH CnHpT, TeXHHHeCKHn conpoBOKfiKWiN ra3 • • BOflOPOfl HaBJiHHe 1.0 Mna Harpy3xa 2.0 r / r.nac cooTHoiueHHe ra3 / npoflyxT 500: 1 hh / h Πρκ TeMnepaType 648 K peaKHHOHHaa CMecb coctoht H3 70 06.% bohhoh h30 06 .% opraHHnecKoň φε3ω. Hojih apoMaTHnecKHx yrneBOflopoROB b opraHHnecKoňφθ3ε cocTaBJíaeT 56% 06th ΠρΗΜερ 6 ΠρΗ OflHHHKOBblX yCJIOBHHX K8K Η B npHMepe 5 KpHCTanjIHHeCKHH CHJIHKaT ΠρΗ H3 ~ 3 Mepa noflBepraeTca HoHooSMeHy, φορΜοεκε npoKaJiHBaHHio h. UHJiHHflpHnecKHe3KCTpy, on Tbi HcnbiTbiBaioTCH KaTanHTHnecKH πρκ cjienyioiuHX ycjioBHnx: cbiphe: rHflpoonHuieHHaH Φρ3κηηη flH3ejibHoro

ToruiHBa TeMnepaTypbi 453-633 K COnpOBOHCflaiOmHH ra3: BOHOpOfl

HaBJiHHe: 3.8 Mna

Harpy3Ka: 5 Ji / n q qac cooTHomeHHe ra3 / npoflyKT: 200: 1 hji / ji Πρκ TeMnepaType 653 K cjienyiomHM o6pa3OM oKa3biBanocb BJiHHHHe Ha Mopo3ocToň-KOCTb CbipbH:

CHHacaeTCH: TeMnepaTac aBTHHaHHH c 264 ho 235 K

TeMnepaTypa HanaJia KpHCTaJiJiH3anHH περβφΗΗΗ c 271 ho 249 K

Bbixofl jkhhkhx cocthbhji 94.3 Mace.Z, and b pe3yjibTaTe peaxHHH o6pa3OBajiocb5 Mace.2! C 1 -C 4 ynBonopoflOB. B H 2 BECTHORO UH 2 CHARACTERS (ZSM, cornacHoUS-PS 3702886) (ηηη cpaBHeHHH c KpHCTannHqecKHM cHJinkaToM LZ 40) εοοτΗετ-CTBywmHM θ3θ6ρετεΗΗΐο.

HIGH 1 d - 3HaneHHH B HM HHTeHCHBHOCTb, 15ρΜΗρΟΒΗΗΗΗΗ 1,115 oc 1,030 oc 246576 7 1,025. C 0,997 CJI 0,805 CJI 0,575 CJI 0,562 CJI 0,427 CJI 0,388 cc 0,384 c 0,377 cc 0,373 cc 0,366 CJI 0,346 CJI 0,336 CJI 0,306 cn 0,300 cn - oneHb cmhHaH - CHjibHaa - cjiaóaa - cpeflHen

TagjiHua 2 5 cornacHo US-PS 3702886 (cpaBHeHHe) d - 3HaneHue b hm1,1151,0010,7440,7080,6360,5990,5560,4990,4610,4260,3840,3720,3050,298

HHTeHCHBHOCTb, HOPMHpOBaHHaH.CC CJ1 cn Target

CJI

CJI cn

CJI

CJI cc c

CJI 'CJI 246576

®opMyna K3o6peTeHHH first MeTajuiocoftepjKamHň KpHCTaJuiHnecKHH cwiHKaT (LZ 40) c onpeflejieHHoft NPO-CTpancTBeHHoň cTpyKTypoň ceTKH h NOP npnroflHbiň fljia HcnoJiB3OBaHHH b Kane-CTBe aflcopSeHTa h / hjih KOMnoHeHTa xaTajinaaTopa, oTJiHnaioiuHňca τβΜ, ίτο MOjiapHoe cooTHonieHHe Si02: AL20, cocTaBJíneT b MeTajuiocoflepxameMKpHCTajiJiHqecKow CHJiHKaTe $ 30 h flojia SI02 b 6e3Bop; HOM προηγκτε> 92 Macc.5? H fluarpaMMa peHTreHOBCKo ηΗφρβκιρίΗ HMeeT cjienyronme ρεφπεκοΜί d - 3HaqeHHB B HM HHTeHCHBHOCTb, ΗθΡΜΗρθΒ3ΗΗ3Η

1,115. oc 1,030 c 1,025 c 0,997 CJI 0,605 CJI 0,575 CJI 0,562 CJI 0,427 CJI 0,388 C 0,384 c 0,377 cc 0,373 cc 0,366 CJI 0,346 CJI 0,336 CJI 0,306 CJI 0,300 CJI h, hhhHhHHHHHHHhhhhhhhhhhhhhhhhhhhhhhHyHNHhhhhhhhhhhhhhHyHyHh Macc.% hjih H reKcaHa $ 9 Macc./S η ajih BOflbíÍ8 Mace.Z npn flaBJíeHHH Napa nacbímeHHH COPD η, ητο οηπηκβτ conepxHTnoBepxHocTHo-aKTHBHbie semecTBa ηηηοηηογο h / hjih HeHOHoreHHoro early, oflHa-co CBo6o, AEH opraHHnecKHx κθτηοηοβ rpm. 2. MeTajmocoflepxainHn KpHCTaJuiHnecKHH CHJiHxaT no nyHKTy 1 f oTJiHnaiontHÉCíiT6M ^ HTO BejIHHHHa p KpHCTajUIOB COCTaBJIHeT £ 5 | UM, 246576

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HaoSpeTeime KacaeTCH MeTaJinocoflepacamero RpncTaJuinnecKoro cwiHKaTa (LZ 40) .UeJlbW Η3θ6ρβΤβΗΗΛ ΛΒΠΗβΤΟΗ HOBblft MeTaJIJIOCOflepjKaiHHň kpHCTaJIJIHMeCKHň CHJIHKaTc onpefleneHHoň CTpyxTypoň ρβπιβτκκ h NOP Tpe6yioiuHň ajih flocTHaceHHH HHCToňφβ3ω H xopomo KpHCTaJIJIH30BaHHbIX npOflyKTOB OHeHb Hé3HaHHTeJIbHOrO ΒρθΜΘΗΗKpucTaJinHsayHH h TexHnuecKH jierKo flocTynHbix h 0e3BpeflHbix ajih oKpyxaiojmeň cpeflbí BemecTB. 3aflaqa paapaOoTaTb τβκοή CHJIHKaT, noflxoflumHň Ha οοηοβηηΗη ero oflHopoflHoňCTpyxTypbi pemeTKH H NOP ero ηηοτοτω φβ3Η b xanecTBe aflCopOeHTa h / hjih com-noHeHTa KaTaJiHsaTopa flJin μηογηχ oOjiacTeň πρΗΜβΗβΗΗΗ, pemaeTCH τβΜ, ητοcornacHo Η3ο0ρβτβΗΗΐο MonapHoe cooTHomeHHe SiO ^ Me "Oy b MeTanjiocoflepjKameMKpHCTannHHecKOM cnnuKaTe> 30 h aojih Si02 b 6θ3βοαηομ npoflyxTe cocTaBJíaeT> 92 Macc.% h peHTreHOBCKafl ηΗφρεκηΗΗ ημθθτ cneflyramne ρεφηεκοω: d - 3HaneHHH B HM HHTeHCHBHOCTb, HOpMHpOBaHHaa

1,115 oc 1,030 c 1,025 c 0,997 CJI 0,605 cji 0,575 cn 0,562 CJI 0,427 CJI 0,388 C 0,384 c 0,377 cc 0,373 cc 0,366 CJI 0,346 CJI 0,336 CJI 0,306 CJI 0,300 CJI h, hto aflcop > 7 Macc,%, flJiH H-rexcaHa> 9 Macc,% h ajih bormi8 Macc. £ npn flaBJHHHhhhhhhhhhhhhhhHH cop6aTa. CHJIHKaT conepacHT noeepx-hoctho-aKTHBHbie BemecTea aHHOHHoro η / ηπη HenoHoreHoro early, onHaxo cbo-SofleH ot opraHunecKHx κβτΗΟΗΟΒ. Π 3Ο0ρβΗΗεΗΗβΜ ΠΟ pe3yjIbTaTaM 3KCnepTH3bI, OCymeCTBJiHHOn BeflOMCTBOMno flenaM Η306ρθτθηηη η πετβΗτοΒ TflP. 246576

Claims (2)

BACKGROUND OF THE INVENTION 1 # A crystalline metal-containing silicate having a defined lattice structure and pores suitable for use as an adsorbent and / or catalyst component, characterized in that the SiO 2: Al 2 O 3 molar ratio is 27 30 in the crystalline silicate and a proportion of SiO 2 in anhydrous 21 92% wt. and the X-ray diffraction diagram has the following reflexes: d (nm) normalized intensity 1,115 vs 1,030 vs 1,025 s 0,997 sl 0,605 sl 0,575 sl 0,562 sl 0,427 sl 0,388 sl 0,346 sl 0,356 sl 0,306 sl 0,300 sl 0,356 sl 0,306 sl 0,300 sl. and that the adsorption capacity of the anhydrous material at 298 K for benzenes is 7% by weight, for n-hexane * 2. 9 wt.% And 8 wt. % at pressure, saturated vapor sorbenta and that the silicate contains anionic and / or non-ionic surfactants, but without organic cations. 246 576 2. The crystalline silicate according to claim 1, wherein the crystal size thereof is 5 [mu].