CS245403B1

CS245403B1 - Chromatographic column for potentiostatical chromatography

Info

Publication number: CS245403B1
Application number: CS831432A
Authority: CS
Inventors: Jevgenij A Ostrovidov; Igor F Danilenko; Arkadij S Kanev; Alexandr M Voroncov
Original assignee: Jevgenij A Ostrovidov; Igor F Danilenko; Arkadij S Kanev; Alexandr M Voroncov
Priority date: 1983-03-01
Filing date: 1983-03-01
Publication date: 1986-10-16
Also published as: CS143283A1

Abstract

Chromatografická kolona pro potenciostatickou chromatografií, obsahující pouzdro, naplněná elektricky vodivým sorbentem a pomocnou elektrodu, spojenou se zdrojem polarizace a umístěnou na povrchu pouzdra kolony, obráceně k sorbentů a oddělené od něho membránou, provedenou z materiálu, majícího iontovou vodivost.Chromatographic column for potentiostatic chromatography containing a housing filled with an electrically conductive sorbent and an auxiliary electrode connected source of polarization and placed on the surface column housings, upside down to sorbents and separated from it by a membrane made a material having ionic conductivity.

Description

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Qaaaito ycrpožcTBa aah peaAB3anaa MeioAa ποτβΒκβο-craMaecKoít xpoMaTorpa$aa He Hpacnocotíneflu am Φβλβτ-paruua noABaxaaft $a3n c ÓOA&moit gropoctbd, hto yBeoaa-BaeT npoAO/nuaTexfcHocTb aHaaaea.Qaaaito ycrpožcTBa aah peaAB3anaa MeioAa ποτβΒκβο-craMaecKoit xpoMaTorpa $ aa He Hpacnocotíneflu am opβλβτ-paruua noABaxaaft $ a3n c ÓOA & moit gropoctbd, hto yBeoaa-BaeT npoAO / nuaTexfcHocTb and Haaaea.

Haaóoaee ÓM3aoa no TexHanecaoit cymaocTa a a30~ΰρβτβΗΒΒ HBJíBeTCfl xpoMaTorpa$anecKaa κοτιοηκθ, coAepm-qaa aopnyc c sneaTponpoBOAamaM copóeaTou a Bcnouora**τβλββμζ ssearpoA, coeAaaeHHHe c βοτοηηββομ nojwpa3a-naa 2] . fseacTHaa aoaoflaa coAepxaT aopnyc a ^paraty, MesmyaoTopuua 3aapenAeaa aoaoodMeaaaa MeMÓpaaa, noBepxaocTBκοτοροζ noapuTa οποβΜ coptíeaTa. C noMomw βοπομοιέιτθχβ-Horo saeKTpofla, ycTaHCBAeaaoro b aopnyce ycTpoňcTBa, aBHemHero ηοτοηηηηη noaapasanaa coptíeflT ycTpoScTBa mok-HO nOABepraTB 3ΑβΚΤρ0ΧΗΜΒ<Ιβ0Κ0δ nOJWpa3aUBB. Hepe3 cop-όβΗτ $BXhTpyeTCfl noToa ποαββχηο& $a3n, coAep«amaíl aaa-AB3apyeMyx) ομθοβ. Ha aaaAB3BpyeMtie MOAeayxu (hohh) AeS-GTByioT aACopdnaoHHue chtih, a3MeaHEmaeca b šaBacaMooraOT ΒβΑΒΊΗΗΗ ΘΑβΗΤρΟΧΗΜΒΊβΟΗΟί! Π0/Ζ£ρΒ38ΙΐΒΒ. ίΤ3ΜβΗΗΒ Βθ-HBHBHy noAjipa3anaa caoh coptíeaTa, mosho perynaposaTBBpeMH BHxona xpoMaTorpa$aqecxax naaoB.Haaóoaee ÓM3aoa no TexHanecaoit cymaocTa and a30 ~ ΰρβτβΗΒΒ HBJíBeTCfl xpoMaTorpa $ anecKaa κοτιοηκθ, coAepm-qaa aopnyc c sneaTponpoBOAamaM copóeaTou and Bcnouora ** τβλββμζ ssearpoA, coeAaaeHHHe c βοτοηηββομ nojwpa3a-naa 2]. fseacTHaa aoaoflaa coAepxaT aopnyc a ^ paraty, MesmyaoTopuua 3aapenAeaa aoaoodMeaaaa MeMopaaa, noBepxaocTBκοτοροζ noapuTa οποβΜ coptíeaTa. C noMomw βοπομοιέιτθχβ-Horo sa KT of of of of la of of, B a a a a a B B B c c c c c c c c c c c c c c c c c c Κ Κ Κ Κ Κ Κ Κ Κ Κ Κ Κ Κ Κ. Hepe3 cop-$ BXhTpyeTCfl noToa ποαββχηο & $ a3n, coAep «amaíl aaa-AB3apyeMyx] ομθοβ. Ha aaaAB3BpyeMtie MOAeayxu (hohh) AeS-GTByioT aACopdnaoHHue chtih, a3MeaHEmaeca b shaBacaMooraOT ΒβΑΒΊΗΗΗ ΘΑβΗΤρΟΧΗΜΒΊβΟΗΟί! Π0 / Ζ £ ρΒ38ΙΐΒΒ. ίΤ3ΜβΗΗΒ Βθ-HBHBHy noAjipa3anaa caoh copteaTa, mosho perynaposaTBBpeMH BHxona xpoMaTorpa $ aqecxax naaoB.

Oftaaao a3BeciHoe ycTpoňcTBo otíaaAaeT Manoň npoae-ΒΟΑΒΤβΛΒΗΟΟΤΒ». ΑηΘΑΒ3 AByXROMnOHeHTHCĚt CMeCB ΒΗΠΟΛΗΗ—eica b TeaeHae 30 μβη, ητο c3H3aHo c HB3aoň caopocTB»ýaaBTpanaa ποαββηηοΜ $a3H. ΗβΒβοτΗοβ ycTpoScTBo He ao-nycaaei ysexaneflaH raApaBAHaecaoro αββαθηβη jwj yBena-neaaa οκοροοτβ $azcBTpanaa ποαββκηοζ φβ3Η a3-3a orpaaa-ΗβΗΗΟίΤ ΠΡΟΊΗΟΟΤΒ BOHOO(ídeflHQ0 MeMtípaHH. ΚρΟΜΘ ΤΟΓΟ, ΠρΒΠΟΒΒΠΠβΗΗΟΜ ΓΗΑΡΗΒΑΒΗβΟΒΟΜ ΑΒΒΛβΗΒΒ HBCTB ΠΟΑΒΗΧΗΟβ φβ3Η 245403 c aHajuuMspyeMoft cMecuo $o&TpyeTCH qepes MeMčnaay, hoycneBax BsaaMoseílcTBOBaTB o coptíeHTOM.Oftaaao a3BeciHoe ycTkolikcTBo otíaaAaeT Manoň npoae-ΒΟΑΒΤβΛΒΗΟΟΤΒ ». ΑηΘΑΒ3 AByXROMnOHeHTHCĚt CMeCB ΒΗΠΟΛΗΗ — eica b TeaeHae 30 μβη, ητο c3H3aHo c HB3aoň caopocTB ýaaBTpanaa ποαββηηοΜ $ a3H. ΗβΒβοτΗοβ ycTpoScTBo He ao-nycaaei ysexaneflaH raApaBAHaecaoro αββαθηβη jwj yBena-NEAA οκοροοτβ $ azcBTpanaa ποαββκηοζ φβ3Η a3-3a orpaaa-ΗβΗΗΟίΤ ΠΡΟΊΗΟΟΤΒ Boho (ídeflHQ0 MeMtípaHH. ΚρΟΜΘ ΤΟΓΟ, ΠρΒΠΟΒΒΠΠβΗΗΟΜ ΓΗΑΡΗΒΑΒΗβΟΒΟΜ ΑΒΒΛβΗΒΒ HBCTB ΠΟΑΒΗΧΗΟβ φβ3Η 245,403 c aHajuuMspyeMoft cMecuo $ o & TpyeTCH qepes MeMčnaay, hoycneBax BsaaMoseílcTBOBaTB about coptieHTOM.

QeauD fl3otípereflBH ηβχηθτοη c^Kpameflae βρθμθηβaflaxasa nyreM yBexHHeHHH cxopocTH Φηλβτρθπηβ ποαββχ-HOŽ φθ3Η.QeauD fl3otipperb ηβχηθτοη c ^ Kpameflae βρθμθηβaflaxase nyreM yBexHHeHHH cxopocTH Φηλβτρθπηβ ποαββχ-HOŽ φθ3Η.

HocTaBxeflflax nexh Aocraraercx tom, ητο b xpoMaŤo-rpa$HBeOi©a KOXOHKB AflH ΠΟΤβΗΑΗΟβΤΘΤΗΉΘΟΧΟβ XpOMSTOrpa-Φ00, coAépxameft Kopnyc, 3βποπΗβΗΗΐ& axexTponpQBOAHUBMcopdeflTQM, a BcnoMoraTaxBHHft θχβχτροΑ, οοθαβηθηβηθ chctohhhxom nooapaaaiUM, βοπομογθτοχβηηΑ θχβκτροΑ pac-noxoxefl na ποΒθρχΗοοτχ Kopnyca xoaohxh, oópameaaofl xGOpdeHTy, 0 ΟΤΧβΧβΗ OT ΗβτO ΑΗΗφρΒΓΜΟδ, ΒΗΠΟΛΗβΗΗΟίΓ 03MaTepaaxa, oóxaAa»mero aosfloň προβοαημοοτββ.HocTaBxeflflax nexh Aocraraercx tom, ητο b xpoMaŤo-rpa $ HBeOi © and KOXOHKB AflH ΠΟΤβΗΑΗΟβΤΘΤΗΉΘΟΧΟβ XpOMSTOrpa-Φ00, coAépxameft Kopnyc, 3βποπΗβΗΗΐ & axexTponpQBOAHUBMcopdeflTQM and BcnoMoraTaxBHHft θχβχτροΑ, οοθαβηθηβηθ chctohhhxom nooapaaaiUM, βοπομογθτοχβηηΑ θχβκτροΑ pac-noxoxefl to ποΒθρχΗοοτχ Kopnyca xoaohxh, oópameaaofl xGOpdeHTy, 0 ΟΤΧβΧβΗ OT ΗβτO ΑΗΗφρΒΓΜΟδ, ΒΗΠΟΛΗβΗΗΟίΓ 03MaTepaaxa, oóxaAa »mero aosfloň προβοαημοοτββ.

Jtiia$parMa βηποαηθηβ 03 HoaoodMeflHoát čmouh.Jtiia $ parMa βηποαηθηβ 03 HoaoodMeflHoat Smear.

Ha φΒΓ. I B30Ópaseaa npeAaaraeMaa χροΜβτοΓρθφΗΉβ-cxax xoxoflxa; aa φχτ.2 - xpoMaTorpaganecKaft aaaiasaTop,coAopramafit npejyiaraeMys) xpoMaTorpa$nqecxyD xoxoHxy;Ha φΒΓ. I B30Ópaseaa npeAaaraeMaa χροΜβτοΓρθφΗΉβ-cxax xoxoflxa; aa φχτ.2 - xpoMaTorpaganecKaft aaaiasaTop, coAopramafit npejyiaraeMys) xpoMaTorpa $ nqecxyD xoxoHxy;

Ha φΧΓ.3 - XpOMaTOrpaMMH ΤΗΟΜΟΗβΒΗΗΗ, nOXyTOHHHe HaBSBecTHOM ycTpoftcTBe a npejmaraeMoft xoxoxxe.Ha φΧΓ.3 - XpOMaTOrpaMMH ΤΗΟΜΟΗβΒΗΗΗ, nOXyTOHHHe HaBSBecTHOM ycTpoftcTBe and npejmaraeMoft xoxoxxe.

XpoMaTorpagjBHecxa# xoxoxxa coctoht 03 xopnyca I,fla noBepxflociH xoroporo, otípameflHoH KdCopčeHry 2, yc-TaHCBxefl BcnoMoraTex&HHS δΑβχτροΑ 3. Mesjíy axexTpoAQM3 a copdeHTOM 2 ycTaHCBxefla Aaa$parMa 4. Φλβηηη Kopny-ca I repM6TH3Hpyx>TCH c noMomwo πρηχημηοΗ Βτγχκπ 5 cpe3HHQBHM XOXBHOM 6, ΟΠΟρΗΟΓΟ QHÁHHApa 7, flaKBAHCfiraftxx 8 0 onopHož BTyABH 9. Ha $xaHnax Tpyčxfl ycraHOB—xea sxexTpoxHsycmBít βχαβαηπι 10 03 φτοροπίΒΟΤΒ. Hphxhm-ΗΗβ BTyAKH 5, ΒΗΠ0ΧΗ6ΗΗΗ6 03 ΒβρΟΒβΒΐηβδ CTHAfl, ΒΗΠΟΑ—hhdt oAHcepeMeHHo φγΗΚϋ00 ToxonoABOAa x coptíeBTy. Ea-ΧΒΑΗΗΘ rafixa 8 BHnoaHeHH 03 yAaponpoHHoro noxacTapoxa.HOABOA AOABBXHOŽt φβ3Η B XOXOHKy npOHSBOAHTCH ΠΟ φϊΟρΟ-παβοτοβημ xanxAHHpaM II, hx repMeTH3aOHH npoHSBOjHTcec noMoqEu φτοροπχθοτοΒΗΧ xoHycoB 12, flaxerax Ha xanflx-xxpH, η φΗΐ^ρΗΗχ raex 13. Kopnyc koxohxh ΒκποχΗβΗ hs 245403 - 5 THTaHa, a b KaaecTBe coptíeflTa acnoM30BaH οκτηβαροβθη—Hsft yro/ií. c pa3Mepou sepaa 50-63 mkm. C wbd Bocnpe-ΠΗΤΟΤΒΟΒΗΤΒ BHHOCy COptíeHTa H3 ΚΟΠΟΗΚΗ B apBXBMHHXb Ty Max 5 ycTaflOBxeHH $anjE»TpyDntae saeMeHTH 14 B3 nopa-CToro $ToponaacTa.XpoMaTorpagjBHecxa # xoxoxxa coctoht 03 xopnyca I, fla noBepxflociH xoroporo, otípameflHoH KdCopčeHry 2 YC-TaHCBxefl BcnoMoraTex & HHS δΑβχτροΑ third Mesjíy axexTpoAQM3 and copdeHTOM 2 ycTaHCBxefla Aaa $ Parma fourth Φλβηηη kicks-ca I repM6TH3Hpyx> TCH c noMomwo πρηχημηοΗ Βτγχκπ 5 cpe3HHQBHM XOXBHOM 6, ΟΠΟρΗΟΓΟ QHÁHHApa 7, flaKBAHCfiraftxx 8 0 onopHožt BTyABH 9. Ha $ xaHnax Tpycxfl ycraHOB — xea sxexTpoxHsycmBit βχαβαηπι 10 03 φτοροπίΒΟΤΒ. Hphxhm-ΗΗβ BTyAKH 5, ΧΗΠ0ΧΗ6ΗΗΗ6 03 ΒβρΟΒβΒΐηβδ CTHAfl, ΒΗΠΟΑ — hhdt oAHcepeMeHHo φγΗΚϋ00 ToxonoABOAa x coptieBTy. EA-ΧΒΑΗΗΘ rafixa 8 BHnoaHeHH 03 yAaponpoHHoro noxacTapoxa.HOABOA AOABBXHOŽt φβ3Η B XOXOHKy npOHSBOAHTCH ΠΟ φϊΟρΟ-παβοτοβημ xanxAHHpaM II hx repMeTH3aOHH npoHSBOjHTcec noMoqEu φτοροπχθοτοΒΗΧ xoHycoB 12 flaxerax Ha-xanflx xxpH, η φΗΐ ^ ρΗΗχ Raex 13th Kopnyc koxohxh ΒκποχΗβΗ hs 245 403 - 5 THTaHa, ab KaaecTBe coptíeflTa acnoM30BaH οκτηβαροβθη — Hsft yro / ií. c pa3Mapou sepaa 50-63 mkm. C wbd Bocnpe-ΗΤΟΤΒΟΒΗΤΒΗΤΟΤΒΟΒΗΤΒ BHHOCy COptíeHTa H3 ΚΟΠΟΗΚΗ B apBXBMHHXb You Max 5 ycTaflOBxeHH $ anjE »TpyDntae saeMeHTH 14 B3 nopa-CToro $ ToponaacTa.

XpoMaToipa$aaecaa0 aHana3aiop, co^epsamaS npejua-raeMy» KonoflKy, patíOTaer cnenyioniHM odpa3OM ($ar.2). IIoflBB«Hy® $a3y B3 θΜκοοτΒ I c πομοπιβο flacoca 16 nepes meoTBXOAOBHfi KpaaJE* π omet b xpoMaTorpa$aaecKyE.KOJiOHKy IB. Smoai 03 xpoMaTorpa$0HecKo0 κοποηο nociy-naeT b Λβτβκτορ 19 ( 254 bm). Aflana3apyestyB npočjy bbo-flflT B ΠΟΤΟΚ nOffB0XflOa $Θ3Η C ΠΟΜΟΠΙΗΟ AO3apyBIHe0 ΠβΤΛΗ20, coeABHeHBoit c mecTaxoflOBHM KpaaoM Γ7, mnpaueM 21a euKOCTW 22. Κογμ aepH apaHa flaxoABTca b noaanaa I,nosBBKBaa $a3a no aaHajty E-3 nocTynaeí b xpowaTorpa-ýaaecKyB aonoflay, Many a A03apyBinyB πβτΠΒ. Ecna aepfiapaaa nepeBOjwT b πο3βιχββ Π, to nojcBflaaaa $a3a βητθο-aaer aaaa03apyeMuft pacTBop 03 AO3apyBme0 nerafl. £πηynaxeHBa pacTBopeHHoro B03,nyxa θμκοοτβ c ποαβαχηο0 $a-300 I noAorpeBasT no κβπθηβη aa sneKTpaaecKOM aarpeBa-Tene 23. UCTOHHBKOM nOftapB3aQBB ΚΟΠΟΗΚΗ CJJyaflT nOTeHUBO-οτβτ 24, flanpaseflae nonapasamaa KOHTponapyBT ηβφροΒΗΜΒΟΛΒΤΜβΤρΟΜ 25. ΟΒΓΗΘΛ ΑβΤβΚΤΟρθ-ΘΒΘΠΒββΤΟρβ ρβΓΒΟΤρΑ-pyDT caMonanymHM ποτβΑΠΗΟΜβτροω 26.XpoMaToipa $ aaecaa0 and Hana3aiop, what ^ epsamaS npejua-raeMy »KonoflKy, patiOTaer cnenyioniHM odpa3OM ($ ar.2). IIoflBB «Hy® $ a3y B3 Β ο Β c c c c c c c nep nep nep nep nep nep nep nep nep nep nep B B B B.......... IB. Smoai 03 xpoMaTorpa $ 0HecKo0 κοποηο nightsy-naeT b Λβτβκτορ 19 (254m). Aflana3apyestyB npočjy BBO-flflT B ΠΟΤΟΚ nOffB0XflOa Θ3Η C $ ΠΟΜΟΠΙΗΟ AO3apyBIHe0 ΠβΤΛΗ20, coeABHeHBoit c mecTaxoflOBHM KpaaoM Γ7, mnpaueM 21a euKOCTW 22nd Κογμ aepH Apah flaxoABTca b noaanaa I nosBBKBaa $ A3a no aaHajty E-3-nocTynaeí b xpowaTorpa ýaaecKyB aonoflay, Many and A03apyBinyB πβτΠΒ. Ecna aepfiapaaa nepeBOjwT b πο3βιχββ Π, to nojcBflaaaa $ a3a βητθο-aaer aaaa03apyeMuft pacTBop 03 AO3apyBme0 nerafl. £ πηynaxeHBa pacTBopeHHoro B03 nyxa θμκοοτβ ποαβαχηο0 $ c and I-300 noAorpeBasT well κβπθηβη aa sneKTpaaecKOM aarpeBa-Tene 23rd UCTOHHBKOM nOftapB3aQBB ΚΟΠΟΗΚΗ CJJyaflT nOTeHUBO-οτβτ 24 flanpaseflae nonapasamaa KOHTponapyBT ηβφροΒΗΜΒΟΛΒΤΜβΤρΟΜ 25th ΟΒΓΗΘΛ ΑβΤβΚΤΟρθ-ΘΒΘΠΒββΤΟρβ ρβΓΒΟΤρΑ-pyDT caMonanymHM ποτβΑΠΗΟΜβτροω 26th

Texflaqecaaa βφφβκτβΒΗοοτΒ H3otípeTeflaa saaaBHaeTcaβ caaaeHaa Bpewefla aaaxjB3a BeiqecTBa, πτο nocTaraeTcanpe;maraeMHM pacnonoaeaaeM BcnoMoraTenBHoro anearponaHa παΒβρχΗοοτιι Kopnyca, otípameHfloft a copdeHTy, a pa3-Αθπθηηθμ coptíeflTa a sneKTpona Aaa$parMo0, βηποηηθηηο0H3 MaTepaaxa, odnanaffimero βοηβο0 προβοαημοοτββ.Texflaqecaaa βφφβκτβΒΗοοτΒ H3otípeTeflaa saaaBHaeTcaβ caaaeHaa Bpewefla aaaxjB3a BeiqecTBa, πτο nocTaraeTcanpe; maraeMHM pacnonoaeaaeM BcnoMoraTenBHoro anearponaHa παΒβρχΗοοτιι Kopnyca, otípameHfloft and copdeHTy, and PO3-Αθπθηηθμ coptíeflTa and sneKTpona Aaa $ parMo0, βηποηηθηηο0H3 MaTepaaxa, odnanaffimero βοηβο0 προβοαημοοτββ.

Ba3BaflHoe pacnonoaeHae 3πβκτροΜ a Aaa$paiWH no-3Βομθτ yBeMHaBaTB raApasjuanecRoe jjaBxeflae a, cneno-BaTexBBo, ca op octl $an&Tpanaa HOHaaxaoft $a3u npa oah- 245403 - 6 - aaKOBOít npoHHocM aofloodMeflfloro MaTepBajia b asBecTflQMb npejyiaraeMOM ycTpo&ciBe, npa stom αββκθηβ6 ποαβηβηο®$asH βαοϊβ noBepxsocTB Aaa$parMH οΰβοπβΊΒΒββτ aocts-Tonfloe BpeMH pfls B3aBM0Ae&cTBHH ee c copdeatom. y&eaaHeflae cKopocra $aR£Tpanaa ποαββχηοΗ $a3HcopdeHTOM, sa KOTopnit c noMomuo BcnoMoraTejiBfloro θπβκ-Tpofla ποα&θτοη θπβκτροχΗΜΒΗβοΗβΗ no^Apasarmn, cHasaetBpeMH Buxoía xpoMaTorpa$anecRax jihrob, bto, b cbo® .onepeAB, coRpamae? BpeMH aaaAB3a BenjecTBa. ΠρΒΜβρ. UMeETCH XpOMaTOrpaMMH ΤΗΟΜΟΒβΒΗΗΗ, nojiy-ΗβΗΗΗθ Ha B3B6CTHQM yCTpoBCTBe B ΠρβΑΠΗΓββΜΟβ R0H0HR8(φΗΓ.3). yCAOBHH ΧρΟΜΘΤΟΓρβφΗρΟΒβΗΗΗ: ΠΟΑΒΒΙΗΗΗ φβ38 -0,01 Μ TeTpaóopaT aaipan (pífc9,2); copčefli - aaTBBapo-BaHHužt yro/ts, $paRH0H 50-63 mr, MHRpoflacoc; AereRiop(254 RM) f s 5 MM; HCTOHHHR ΠΟΗΗΡΒ380ΗΗ - ΠΟΤβΗΠΗΟ-CT8T, ϋΗφρΟΒΟίί ΒΟΖΤΒΤΜβΤρ, ΠΟΤβΗΒΗΟΜβΤρ (10 MB) { CRO-pocTB Φβλβτρηπηη - 0,5 ομ3/μβη; aanpHseflae no/mpasa-uaa - 0,8 B; oCfeeM A03apy®meŽ nesuta - 0,03 cm3. HaKbraho a3 npflBeseHHoS Ha φζτ.3 xpoMaTorpaMMH, BpeMHηροχο«ΑβΗΒΗ xpoMaTorpa$anecKoro naaa τηομοίβββηη nepeaasBecTHoe ycTpoScTBo a npejutaraeMy® Ronoflay οοοτθβληθτΟΟΟΤΒΘΦΟΦΒβΗΗΟ 12 B 4 MHH.Ba3BaflHoe pacnonoaeHae 3πβκτροΜ and AAA $ paiWH no-3Βομθτ yBeMHaBaTB raApasjuanecRoe jjaBxeflae and, cneno-BaTexBBo, CA op found himself $ n & Tpanaa HOHaaxaoft $ a3u NPA oah- 245403-6 - aaKOBOít npoHHocM aofloodMeflfloro MaTepBajia b asBecTflQMb npejyiaraeMOM ycTpo & Chiba NPA one hundred meters αββκθηβ6 ποαβηβηο® $ asH βαοϊβ noBepxsocTB Aaa $ parMH οΰβοπβΊΒΒββτ aocts-Tonfloe BpeMH pfls B3aBM0Ae & cTBHH ee c copdeatom. y & eaaHeflae cKopocra $ R $ £ Tpanaa ποαββχηοΗ a3HcopdeHTOM was KOTopnit c prefectures BcnoMoraTejiBfloro θπβκ-Tpofla ποα & θτοη θπβκτροχΗΜΒΗβοΗβΗ NOx Apasarmn, cHasaetBpeMH Buxoía xpoMaTorpa $ anecRax jihrob, BTO, b cbo® .onepeAB, coRpamae? BpeMH and aaAB3a BenjecTBa. ΠρΒΜβρ. UMeETCH XpOMaTOrpaMMH ΒΗΗΗβΒΗΗΗ, nojiy-ΗβΗΗΗθ Ha B3B6CTHQM yCTpoBCTBe B ΠρβΑΠΗΓββΜΟβ R0H0HR8 (φΗΓ.3). yCAOBHH ΧρΟΜΘΤΟΓρβφΗρΟΒβΗΗΗ: ΠΟΑΒΒΙΗΗΗ φβ38 -0,01 Μ TeTpaóopaT aaipan (pfc9,2); copčefli - aaTBBapo-BaHHuzh yro / ts, $ paRHHH 50-63 mr, MHRpoflacoc; AereRiop (254 RM) f with 5 MM; HCTOHHHR ΟΗΗΡΒΟΗΗΡΒΗΗΗΗΗΗ CTΟΤ CT CT CTΗ888 CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT CT 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 aanpHseflae no / mpasa-uaa - 0.8 B; oCfeeM A03apy®week - 0.03 cm3. HaKbraho a3 npflBeseHHoS Ha φζτ.

TaRBM 0dpa30M, ΠρΒΜβΗβΗΒβ ΠρβΑΠβΓθβΜΟΛ XPOMSTO-rpa$BHeCROft ROHOHRB Π03Β0ΑΗΘΤ CHB3BTB BpeMH aaamtsa Bτρπ pa3a. Kpowe τογο, coxpaaaeTCH bo3Mokhoctí> B03Aeít-CTBBH Ha CeH6RTHBH0CT£ ΘΑβΒΤρΟΧΗΜΒΗβΟΒΟίΙ nOAHPB3aHBBcopdeHTa. 245403TaRBM 0dpa30M, ΠρΒΜβΗβΗΒβ ΠρβΑΠβΓθβΜΟΛ XPOMSTO-rpa $ BHeCROft ROHOHRB Π03Β0ΑΗΘΤ CHB3BTB BpeMH aaamtsa Bτρπ pa3a. Kpowe τογο, coxpaaaeTCH bo3Mokhoctí> B03Aeit-CTBBH Ha CeH6RTHBH0CT £ ΘΑβΒΤρΟΧΗΜΒΗβΟΒΟίΙ nOAHPB3aHBBcopdeHTa. 245403

I ΦΦΜΖΗΑ HSOEPETEHHfl ί. XpoiiaTorpa$anecaaa aoAoaaa am noTewaaocTaTn-Ηθοκοβ χροΜβτοτρθφΗΑ, coAepsanpa Kopnyc, 3anoaHeaanit8ΙΘΚΤΡΟΠΡΟΒΟΑΗΙΚΒΜ copdeflTOM, B BcnoMoraTentHítít aneKT-poA, coeAHHeflHHe c ηοτοββακομ noAspn3aQBB, o τ π a -nacuasc a τβΜ, ar o, c uejaa caicpameaaa BpeweHaaaaaasa nyTew yBeaaHeaaa ckopoctb $aabTpanaa noABasaoít$asu, BcnoMoraTes&H&ft ΒχβκτροΑ pacnonosea aa noBepxao-cti Kopnyca koaohkb, odpameaaožt κ copdeaTy, a οτΑβπβΗoř aero Aaa$parMoft, Bunoaaeaaoa a3 MaTepaaaa, otíaasa-DIUeiO HOHHQŽ npOBOABMOCTBB. 2. Koaohks ποπ.Ι, o τ a a aammaaca tom,hto Aaa$parMa Bunoxaeaa a3 BoaooCtaeaaoft cmoah. MCTOHHHKH ΒΒφορΜΟΟΖΒ, ΠρβΒΗΤΗβ BO BHBM8HB6 ΠρβBKcnepTaae: 1. Eapeu B.A. a Apyrae. PeryjiapoBaHae οβπβκτΒΒΗο-ctb xpoMaTorpa$0HecKo& κοαοηκβ c πομοαββ 9Α6ΚΤρΗΗβ0Κ0-ro ποαη. "Jcnexa ra30B0ft xpoMaToipa$aa", 1978, Jt 5, c.77-82. 2. ABTOpCKOe ΟΒΒΑβΤβΛΒΟΤΒΟ CCGP ΠΟ 3ΘΗΒΚΘ Ά 2871510/23-25, ka. GOIN 31/06, 1979 (npoToran). 245403 - 8 - A Η Η Ο Τ A II Η aI HSΑ HSOEPETEHHl ί. XpoiiaTorpa $ anecaaa aoAoaaa am noTewaaocTaTn-Ηθοκοβ χροΜβτοτρθφΗΑ, coAepsanpa Kopnyc, 3anoaHeaanit8ΙΘΚΤΡΟΠΡΟΒΟΑΗΙΚΒΜ copdeflTOM, B-BcnoMoraTentHítít aneKT POA coeAHHeflHHe c ηοτοββακομ noAspn3aQBB about τ π and -nacuasc and τβΜ ar o, c uejaa caicpameaaa BpeweHaaaaaasa nyTew yBeaaHeaaa ckopoctb $ aabTpanaa $ noABasaoít asu, BcnoMoraTes & H βχβκτροΑ pacnonosea aa noBepxao-cti Kopnyca koaohkb, odpameaaožt κ copdeaTy, and οτΑβπβΗΗ aero Aaa $ parMoft, Bunoaaeaaoa a3 MaTepaaaa, otíaasa-DIUeiO HOHHQŽ npOBOABMOCTBB. 2. Koaohks ποπ.Ι, o τ and aammaaca tom, hto Aaa $ parMa Bunoxaeaa a3 BoaooCtaeaaoft cmoah. MCTOHHHKH ΒΒφορΜΟΟΖΒ, ΠρβΒΗΤΗβ BO BHBM8HB6 ΠρβBKcnepTaae: 1. Eapeu B.A. and Apyrae. PeryjiapoBaHae οβπβκτΒΒΗο-ctb xpoMaTorpa $ 0HecKo & κοαοηκβ c πομοαββ 9Α6ΚΤρΗΗβ0Κ0-ro ποαη. "Jcnexa ra30B0ft xpoMaToipa $ aa", 1978, Jt 5, c.77-82. 2. ABTOpCKOe CCGP ΟΑβΤβΛΒΟΤΒΟ ΠΟ 3ΘΗΒΚΘ Ά 2871510 / 23-25, ka. GOIN 31/06, 1979 (npoToran). 245403 - 8 - A Η Ο Τ A II Η a

XpoMaTorpa$aaecaaa aosoHaa αμ noveaoBocTaTB^e-caofl xpoMaTorpa$aa, coAepaaqaa aopnyc, aanoaaeaaHífsjíeKTponpoBOAWM copóeHTOM a BcnoMoraTexbBHfl θιθκγ-poA, coeftaHeflHHit c ηοτοηηβκομ noAspasama a pacnoxo-sceHAHžt aa noBepxaocTa aopnyca Konoaaa, oópaqeaaaft acoptíeflTy, a OTAeneflfluŽ oř aero Aaa$panioft, βηπολβθβ-aoft a3 MaTepaaaa, odzcaj^nniero aoaaoit npoBojQBMOcTUD. 245403XpoMaTorpa $ aaecaaa aosoHaa αμ noveaoBocTaTB ^ e-caofl xpoMaTorpa $ aa coAepaaqaa aopnyc, aanoaaeaaHífsjíeKTponpoBOAWM copóeHTOM and BcnoMoraTexbBHfl θιθκγ-POA coeftaHeflHHit c ηοτοηηβκομ noAspasama and pacnoxo-sceHAHžt aa noBepxaocTa aopnyca Konoaaa, oópaqeaaaft acoptíeflTy and OTAeneflfluŽ steed of aero Aaa $ panioft, βηπολβθβ -aoft a3 MaTepaaaa, odzcaj ^ nniero aoaaoit npoBojQBMOcTUD. 245403

Claims

Object of the Invention

A chromatographic column for potentiostatic chromatography, comprising a housing filled with an electrically conductive adsorbent and an auxiliary electrode connected to a source of polarization, characterized in that the auxiliary electrode is disposed on the surface of the column of the column facing the sorbent and separated therefrom by a membrane made of material having an ionic conductivity. Z. A column according to claim 1, wherein the membrane is an ion exchange resin. Recognized by the invention on the basis of the results of the expertises made by the USSR State Inventions and Discoveries Committee, Moscow SU 3 drawings