CS240447B1 - Method of chlorinated polyolefin stabilization - Google Patents

Abstract

The present invention provides a process for stabilising a chlorinated polyolefin present in solution, wherein a stabiliser is applied to a carrier material provided with a hardenable adhesion agent or the stabiliser is applied, together with an adhesion agent, to the carrier material, the stabiliser being present in a layer thickness of at least 0.2 mm., the adhesion agent is hardened at ambient or elevated temperature and the stabiliser thereby bound and the carrier material coated with the stabiliser is introduced into the chlorinated polyolefin present in solution.

Description

-2- OÓJiaCTB ΠΡΗΜΟΗβΗΗΗ H3QgpeTeHHfl H3o6peTeHne KacaeTca cnocoóa CTafinjin3anHH xnopupoBaHHoronojinojie $ HHa, κοτορκΑ nony ^ eH ΧΛορκροΒβΗΗβΜ b pacTBope h emeHaxoflHTCH b pacTBope. CTadnnH3aiíHH ocymecTBoeTCH ot ssíctbbhh noBbiuieHHHX τβΜ -neparp, CBeia h Kucnoposa.

XapaKTeptiCTHKa H3BecTHux TexHimecKHX peuieHHfi Κ3ΒβοτΗθ xnopupOBaHo noooae $ wpa b pacTBope, b cycneH3on b nceBflooKtPKeHHOM cjioe. Πολ fleňcTBueu HarpeBa, CBeTa 0 khc-nopoaa npoHCxoawT peaKijHH pa1nP »eHHH, b pe3yBi> TaTe κοτοροΑBusenaeTCH xbophcthJi Boaopos. B coqeiaHH0 c οκηοβητθπβηημ npopeccoM 3το πρηβολητ k ok- 'paiUHBaHHK 0 yXyflllieHKIO ΜβΧΒΗΗΊβΟΚΗΧ CBOňOTB. ftifl npesoTBpameHHH stoíi peaKitHH pa3BoaceH0H bboshtch pas-ooue TiodaBKH, HanpHMep, H3BecTHne with CTadoH3aiíHH ΠΒΧ Me-TaocosepacaiHHe no He coflepacaiw ueTajm οοβΛΗΗθΗΗΗ. Hx bbo-λητ hbh catiHX no ceo, ho κβκ CTaÓHOSHpyiomyio cueci. 3th xo-p O lil O Πρ160 # ΗΕ16 flO ΟΤ800Ο38ΙξΜΗ ΠΒΧ CTaÓHO3aT0pH aaiOT flJIRXJIOpHpOBaHHUX, ΠΟΟΟΕβφΜΗΟΒ Ββ0Β8ΓΟΠρ0ΗΤΗΜβ pe3yjIBTaTH. ΛθΚβΠρΗ ΒΒβΑΘΗΗΚ ^ ÓOBBUIHX ΚΟΟ ^ βΟΤΒ ΟΗΗΚβΤΟΗβΟΗΗΚβ ββ5-CTBHe, ΟΗΟ ΟΗΟ 0100011ξβ OTCyTCTB isT (ΟΠΟ3ΗΗΗ6ΗΗΗ6 33ΗΒΚ0 ΦΡΓ1544993 η 1544604). Kpoue τογο, H3BecTHue MeTanncosepacaiHHeCTaóHosaTopbi ημθιοτ ηθλοοτητοκ, ητο οηη 3awaoiyio HecoBwe- 240447 -3- CTHMil C XJI0pMp0B8HHHMM nOJlHOJie $ HHaMH (naTem C1I1A 3347820, na-T6HT ΓΛΡ II4270). 3το πρηβολητ x yxyfliueHHio np03paHH0óTH h xa-qeCTBa ΠΟΒβρΧΗΟΟΤΗ H3r0TaBJIHBaetií> 1X H3 ^ eJlHÍÍ. Πο Η3ΒβΟΤΗΗΜ Λ0chx nop peuieHHHu CMeniHBaioT HeodxosHuoe KOjiHneciBO cTaConsaTO-pa c yace BbicyuieHHhiM noporaxou xjiopnpoBaHHoro nojiHOJie $ HHa. HepoTaxoMaHeHeHeHeHeHe3aHH3aTopcHeHeHeHeHeHHeHeHcHe3aTHeHnHeHnHeHeHeHe flocTaraeTCH. Κροωθ τογο b £ pe3yji Tate TepMHqecxHx HarpysoxHa- xaopupoBaHHbie nojiHQJie $ HHH bo BpeMH hx nojiyneHHH h nepepa-dOTKH Mory npOHBXHTBCH ΟΠΗΟΘΗΗΗΘ ΒΗΙΠΘ HBJISHHH pa3JI0XeHHff.Hiodu λοοτηίβ azimuth CTadHJiH3Hpyioinero seficTBHH, cjieayeT BBO-ΛΗΤΒ dOJlBIUHe ΚΟΗΗΗβΟΤΒβ cTadHJiH3aTopa, ίτο HedJiaronpnHTHO CXA-Ha 3UBaeTCH ctohmocth. jfcjiee, H3BecTH0, hto CTadHJiH3aTop momo paciBopaTB b Jier-xoBeiyyeu pacTBopureJie h sodaBJiHTB stot pacTBop x nopomxyΧΛΟρΗρΟΒΒΗΗΟΓΟ Π0ΛΜ3ΤΜΛ6Η3. ΠρΠ 3T0M HeodXOflHMO # 0CTHrHyT £ roMoreHHoro pacnpeflejieHHH ciadoH3aTopa b xjiopupoBaHHOu πολη-οηβφΗΗβ. 3τοτ cnocod ΗΜββτ o / maxo τοτ ηθλοοτητοκ, ητο xjiopHpo — BaHHEft nojinojie $ HH bo BpeMH npouecca nonyqeHHH He 3auiHmeH otTepMHHecKHX noBpescfleHHfó. ,ΡΟΜβ τογο, ysajiemíe pacTBopmeiiHco3saeT 3HaHHTejiBHbie TpysHOCTH. CTadHHH3anHH eme HaxomflmerocH b pacrBope xjiopiipoBaflHoronojiHone $ HHA λο CHX nop aa npaxTHxe eme He ocymecTBjífwiacB, no-cxojiBxy HaxoafliiíwecH b pacTBope ocTaTOHHtie KOJinnecTBa xnopn-ctor Boflopofla cymecTBeHHO CHHacaioT CTadHJiH3Hpyiomee meficTBue.Πρκ 3Tom ocTaeTcn tojibko cjiadaa οοτητοίηηη ctoííkoctb η πρκ · no-cneflyiomHX TepMHMecxHX Harpy3xax προκοχοΛΗΤ HeacejiaTejiBHue hb-JieHHH pa3J103KeHHH. Xο CHX nop H3BeCTeH TOJIBKO lHH cnocod (buiioxeHafaf 3anBxa ΦΡΓK 169 1694076), but COiopOMY CTadHJiH3HpyioT HaH-XOflHmHfiCH B paCTBOpe XJIOpHpOBHHiHiNHiNHi. Πο 3T0uy cnocotíy b pacTBop xjiopHpoBaHHo nojinojie $ HHa, KOTopuf; Μοκβτ cosepaaTB xjiophcthíí βολορΟλ λο waxcHMyM 1.0Bec. %, sodaBiHioT and JixHJi - hjih apHJi-ojiOBO-iy-coji £ b KOjinnecTBeot 0.01 λο 1.0 Bec.nacTefc.

Ha npaxTHxe osHaxo dbuio noxa3aHo, hto Taxoro xojiHqeciBaCTaduJiHsaropa ηθλοοτητοπηο, cjiemyeT modaBJíHTB cTaÓHJiH3aTop bxojiwqecTBe uHHHuyu 2.0 Bec.nacTH. ΛpyΓOβ ηθλοοτητοκ coctohtb tou, mto 9T0T CTadHJiH3aTop axTHBeH tojibko πρκ Tewneparypaxstrne IOO ° C. IloaTOMy b TeunepaTypHolí odjiacTW λο IOO ° C xjiopn-poBaHHhift nojiHOJieijHH He CTatíoH3HpoBaH η Μοκβτ noflBepraTBCH 240M7 -4 ~

TepMHWeCKMM nOBpe & fleHHHM.

IlemB H3O0peTeHHH

UejiBio H3oópeTeHHH ηβοθτοη yjiyqnieHHe KauecTBa paciBopoBXJlOpHpOBaHHUX ΠΟΠΗΟηβφΗΗΟΒ, B MaCTHOCTH, ΠΟΒΗ1116ΗΗ6 ΤθρΜΟ- HCBeTOCTOňKOCTH, and Tarase yflyqiueHHe nojie3Htix cboíictb. Kpoue το-γο, ΗβΟόΧΟΛΗΜΟ CHH3HTB CTOHMOCTB nOJiyMeHHH H paClllHpHTB B03 -MO3KHOCTH ΠρΗΜβΗβΗΗΗ.

Msnoatemae cviuhocth H3odpeTeHHa 3asaua z3odpeTeHHH coctoht b tom, nTotíti paepadOTaTB cno-cod CTadHJIM3aitHM ΧΠΟρΖρΟΒΘΗΗΟΓΟ ΠΟΟΟΠβφΗΗΘ, KOTOpuň HaXOJlMT-ch b pacTBope; npzqeM stot cnocod ποβΒΟοβτ ΒΒβΛβΗΗβ uamKOBHqecTB cTadH03aTopoB de3 Bpe / woro BO3aeftcTBHH Ha cTadHJiB-HOCTB npOTHB ^ eilCTBHH ΗΘΓρβΒΘ, ΟΒβΤΘH KHCJ10OOfla; 3T0T ΟΠΟ-cod odecneqMBaeT eme AOCTaTOOo BucoKyro CTadHjiBHocTB χπορπρο-Β3ΗΗ0Γ0 ΠΟΟΟΠβφΗΗβ B npHCyTCTBHH OCTaTO ^ HOrO ΚΟΟΗβΟΤΒΗ XJIO-ΡΜΟΤΟΓΟ. BOflOpOAa, ΠρΗ 3T0M CflOCOde He Β03ΗΗΚββΤ BpeaHBlX ΠΟΰΟΊ-HUX ΛβίίΟΤΒΗβ CTadHJIH3aT0pa Η ΠρΗΜβΗΗΜΗ pa3JIHqHfcie CTadHJlH3aTOpH.

CornacHO HeodpeTOHMio ea ^ anu peiuaTcn τβΜ, wto CTatii iH3a-τορ HaHOCHT Ha HOCHTeBB, cHadaceHHbifi OTBepoaeMUM; Αγθητ ποβμιπθηηη a ^ re3HH OTBepaaaeiCH πρπ κομηθτ-HOfi έπη noBtwieHHOfi TeMnepaType μ οβη3ηβ3θτ npa stou CTadno -3aTop. nighttime aioft CTaso npoaecca HOCHTenB what cjio-eu CTadnjJH3aTopa aodaBBHioT κ Haxom «meMycH b paoTBope xjioph -poBaHHOuy noooj ^ HHy. lloacHO Tarase CTadHHH3aTop nepeMeuiMBaTB c acHSKHu areHiounoBHiueHHH 8Λγθ3ηη c nonyMeHHeM TwcnepcHM ·, b KOTopyio norpyaca-I0T HOCMTenB. Ha noBepxHOCiB ηοοητθλη, CMOqeHHyio ocnepcHeft H3areHTa ποβηκιθημη asreSHH h cTadH03aTopa, ηθηοοητ eme monoa-ΗΗΤβΛΒΗΟ nopoulok CTadH3IH3aT0pa. HaoniUHII Ha nOBepXHOCTH HOUCH — TejiH nocne OTBepacseHHH areHTa noBbiiiieHMH asreswH ciadHJiH3aTopBHMHBaeiCJÍ ΟΠΗρΤΟΒΗΜ paCTBOpOM, ΠρβΛΠΟηΤΗΤΘΛΒΗΟ ΜβΤ3Η0ΛΒΗΜΜ. ^ Ka ^ ecTBe CTadnnn3aTopoB HcnonB3yioT TBepAue, npeanoM-ΤΗΤ6ΛΒΗ0. nopouiKOodpasHue, cosepacainHe He He cosepKamae ue-tsjiji CTaÓHJiHsaTopbi caMH no cede hjih b BHfle CTadH03HpyioiueSCMecn. B KanecTBe He cosepacamHX ueTao CTadH03aTopoB mosboHCnojiB303au> a3OTC0, nepscatHHe opraHHnecKue οοβΛΗΗβΗΗΗ, κβκ, 240447 Ί -5-

HanpHMep, Mejl8MHH, 2- $ eHHJIHHflOJI, CJlOJKHhiiS 3φΗρ aMHHOKpOTOHOBOftKHCJ1OTU, ΗΗΛφβΗΗΛ-ΗΟΗβΒΗΗΘ, HJIH 0praHHM6CHH6 ΟΟΟΟφΗΤΗ, ΜΗΟΓΟ -aTOMHhie cnupThi, ηητηοκοηληητη, y <ř-adcopdepu. B KanecTBe ue-TaocosepacainMX CTadHJiM3aTopoB HcnojiB3yioT coesnHeHHa CBMHija »MHJia, cofleprcamne KajiBunfi, uhhk, dapnn and KastoHft, ojiOBO-opraHH-qecKHe coe / hHeHHH and okhcjibj μθτθοοβ. HOCHTOB ΧΗΜΗΊβΟΚΗ ΗΗβρΤβΗ Π0 0TH01116HHK) K XJlOpHpOBaHHOMynojiHOJie $ KHy, CTadHJiH3aTopy h areHTy ποβμθηο aflre3HH. Πρηγολ-hijmh HOCHTeflHMH hbjijhotch, HanpHuep, qacTHUM $> ap $ opa, KepawH-kh, CTeoa h MeTaoa. B KayecTBe areHTa ποββμιθηηη Address HcnojiLayiOT anOKCHS-Hyio CMOJiy, nojiHypeTaHOByio CMOJiy hjih amoMOCHJiHK8T. B KayecTBe xjiopHpoBaHHbix ποβηοπθΦηηοβ HcnojiB3yioT xjiopnpo-ΒΗΗΗΒΙβ ΠΟΠΗΠρΟΠΟβΗΗ, XJlOpHpOBaHHbie nOJlHSTHJieHH, XJlOpHpOBaHHbieconooMepbi 3THJieHa-nponoeHa h XJlOpHpOBaHHbie conojiHuepu Święte-Ha-nponHJieHa-snow. 3th nonHMepH HtvieioT co / iepsaHHe xjiopa b byJiacTH 1-70 Bec.qacTefl.

HaoHZHMH HaHoHoHHEfi Ha HaXo £ HIHHMCH B paCTBOpe XJIOpupOBaHHHi} nojiHMep oqeHB xopomee CTadHJiH3Hpyiomee seficTBue. IIojiHMepu b · pe3ynBTaie He npeTepneBaioT ηηκηκηχ H3ueHeHH0 bo Βρεωπ nojiywe-HHH, nepepadOTKH Π ΠρΗΜθΗΘΗΗΗ.

Cnocod COrnaCHÓ H30dpeTeHHIO n03B0JIHeT 3ΗΗΜΜΤβΛΒΗ0 CHH3HTBpacxos cTadHJioaTopa. Πο cpaBHeHHio c H3BecTHuiíH cnocodaMHypOBHH Τ6ΧΗΗΚΗ »ΠΟ KOTOptJM CTadHJlH3aT0p BBOflHT B B XJIOpHpOBaHHhlňΠΟΛΗΟΛβφΗΗ BHS6 paCTBOpa HJIH IIOpOlIlKa, paCXOfl CTadHJIH3aT0paCHHKaeTCH flecHTH- λο TECHyeKpaTHO, πρκΗβΜ Hadjuosaeicn mnoBHineHHoe ciadHJiH3Hpyioinee seiicTBHe. Tara Mojkho ynoTpedjiaTBΤΗΚΗ6 CTadHJIH3aT0pU C HCn0JIB30BaHHeM KOTOpHX B H3BeCTHEX 0Π0 CODAX Ile-jiocTHraioT ΛοοτβτοΗΗόβ CTadHJiH3aaHH hjih HadjnoflaeiCHBpeflHoe nodOHHoe aeMCTBHe, κοτοροβ HCKJiioqaeT HcnojiB30BaHHe3Toro CTadHJiH3aTopa.

/ tyrne npeHMymecTBOM HBJiniiCH Tarae το, hto HOCHTejiB, co-sePaTiNg cTadHJiH3aTop, b HT HT HT HT HT HT HT HT HT HT HT HT HT HT HT. CTadoH3Hpyiomero seMCT-bkh bch TeMnepaTypHan odJiacTB xjiopHpoBaHHoro nojinojie ^ MHa oxBa-THBaeTCH CTasHHUH nojiyyeHHH, nepepadoTKH h πρΗΜβΗβΗΗΗ. HecMOT Ha-pa npucyTCTBHe b pscTBope xjiopHpoBaHHoro nojiHOJie $ HHA Octa-τοηηογο KOJioecTBa xjiopHcioro Boaopoaa well cnocody corjiacHO 240447 -6- Η3θβρβΤ6ΗΗΚ) Α00ΤΗΓ3βΤ0Η flOCTaTOWHO BbIGOKaH OCTaTOMHaH CTA -dOBHOCTB, T8K ΊΤΟ Πρκ ΠΟΟJieSyK) IHMX nepepadOTKe Μ ΠρΗΜΘΗβΗΗΗHe προκοχοΑκτ yxyAuieHMft. IIpw ηοπολβ3οβ3ημη MeTaJuicoflep »amnx CTadooaTopoB no ho-BObty cnocody ΗβΑΒ3 Η ObUIO yCTaHOBHTB HHK3KHX BpeSHHX nodOHHHXTteňcTBHfi.

Budop CTadooaTopa on CTadoH3Hpyioineii cmoch 3aBHCHTot npeaycMOTpeHHoii otijiTH πρΗΜβΗβΗΗΗ η3γοτ3βληβ8Θμηχ our -JlHfi.

npoepu βηποαηθηηη oodpeTeHHH H30dpeTeHHe ΠΟΗΟΗΗβΤΟΗ ΠΟΛρΟύΗββ ΗΗ5Κβ HeCKOJIBKHMH npnMe — paMH. Cnocod cornacHO n3oópeieHHio βμποηηητοη cnesyioníHu odpa-3ou:

Ha HocoeJiB;

Ha 3tot arem noBuuieHHH aareenH HaHOcm TBepsuíí, npesno ^ i-τητθλβηο nopouiKOsupplied by CTadHJiH3aT0p.

Mokho Tarae CMeiuoaTB TBepsKft CTadon3aTop on γομογθηηοcuemaHHyio CTadoH3Hpyioinyio CMecB nepeMeuiaTB c mak km aremoMnoBbnueHHH asresHH, c nonyqeHueM AHcnepcnH. Πρκ stom HcnoAB3yioTpaBHbie KonoecTBa ciadoH3aTopa κ arema noBHineHo 'asre3HH.

TaK nonynioT AHcnepczio H310r CTadHJiHsaiopa from 10r kha-Koro arema noBHiHHH andAre3HZ. B 3Ty AHcnepcH »norpyrcaioT xhmh-necKH HHepTHHn HoerneAB, nonati ixohhap o $ ap $ opa c βηθιβηθΑnOBepXHOCTBW 0K0JI0 115 MM ^. / ΠρβΑΠΟΜΤΗΤΘΛΒΗΟ MTOdbl HOCHTeJlB ΗΜβΛ BHCOKyiO BeJIOHHy Π0-BepxHOCTH. Ha noBepxHOCTB HOcmejiH »CMoyeHHyio AzcnepGHeíi, Ha-eme Höcht PA3 ηοροωοκ CTadoH3aTopa and ητο TOJimzHa CaO · H CRA dOH3aiopa cocTaBflaeT MHHHMyM 0.2 BCfl BHeiUHHH nOBepXHOCTB ΗΟΟΗΤβΑΗ ΠΟΚρΗΤβ Takhte odpasoMAocTaTOHHO tojicthíi cnoíí CTadoH3aTopa.

HocmeaiB c HaHecenHbíM cTadoH3aTopoM BucyuiHBaeíCH πρκTeMnepaiype 50 ° C b cyuioBHOw uiKa $ y o ποαηογο οτΒβρκΑβΗΗΗarema noBáiiiéHHH 3Are3HH, TaK mo oh CBfl3tJBaeT CTadOH3aTop.

HOTBBIUHHCbHUHWCfl HeCBH3aHHbIU Ha ΟΒΟΒΚΧΗΟΟΤΚΧΗΟΟΤΚCHCHCHCHadadadadadadadadadadadadadUMUMUMUMUMUMUMUMUMUMUMUMUMUMUMUMUMUMUMUMUMΜΜΜΜΜΜununununununununununununununununununununun. 240447 -7- 03 IlOJiytieHHOrO T3KHM 0tfpa30M H0CMT6JIH; CociaBH nojiHMepHux pacTBO-poB cjieaytoiUHe:

IIoJiHMepmjfi pacTBop A

XnopHpoBaHHuň b pacTBope nojM3ToeH nonyqaioT xjiopupoBaHHeMCM6CH n0JlH3THJieH0B H3 40% Π0ΛΗ3ΤΗΛ6Η3 BbIGOKOrO flaBfleHHfl cocpesHHu MOJieKyjiapHHM Bača 23000 h 60 $ noJMSTHJieHOBbix bockóbΒΗΟΟΚΟΓΟ flaBJíeHHH CO CpeflHHM MOJieKyjIflpHblM ΒΘΟΟΜ 4500-b Teipa xjiopMeiaHe and coaepscaHHH xjiopa 63.5 $. B pe3yji £ TaTe nocjieaywineí} flHCTHJiJiHUHH nojiywaioT pacTBop b Kcoone c coaepjKaHHew TBepaoroBemecTBa $ 32. nonuMepHHŽi pacTBop B;

XnopupoBaHHbifi b pacTBope nojiwsTHJieH nojiynaioT xjiopHpoBaHneii

COnpHHHMH COnPhHHM MOJYKyJIHpHhlM BeCOM 180000 b TeTpaxjiopMeTaHe and coaepKaHHH xjiopa 37%. B pe3yji £ Ta- τβ nocaeay®mefi ancTiuiJiflu; Hii noayyaioT pacTBop b KCiuojie c coaep- * xaHHeu TBepaoro BemecTBa 32%.

ΠΟΠΗΜβΡΗΗϋ paCTBOP C

XnopHpOBaHHHíí b pacTBope ποοπροπόθΗ nojiynaioT xjiopnpOBaHH-eu H30TaKToecKoro noannponHaeHOBoro bockh co cpeaHHM MOJieity-jihPHhu BecoM 35000 b TeTpaxjiopMeTaHe o coaepxaHHH xjiopa 62%. B pe3yji £ TaTe nocneayioinefi aflCTOJiaiao noaynaioT pacTBop b kcoo-jie c coaepxcaHHeM TBepaoro BemecTBa 32.

Ilpotíhl H0CHT6J1H C Η3ΗβΟ6ΗΗΗΜ Ha ΗβΓΟ CTaÓHJlH3aTOpOM BBOaH “jim b nojimíepHbie pacTBopu A.Bh C, npHqew Kassani? pa3 b 25 r no-jiHo pacTBopa BBoaow no aBe npoCu HOCHTeJiH c HaHeceHHHMCTaÓHJiKsaiopoM, Kpowe b a aiejiBHbix onbiTax nEnE3OBaJiHpa3Jin «HEe CTaOHJiH3aTo.pu h pasjin ^ Hae arema nOBUiueHHH aare3HH. / Uh onpeaeJieHHH aocTHraeMoro GiaÓHBHšHpyioinero aeficTBUH npoda e saKJiroueHHe noasepraJiH TepnoodpadoTKe b TepwocTaTe πρκTeMnepsType MacjiHHOfi daHH 130 ° C. 240447 -8-

flocmrHyTyio οτβπβΗΒ CTadHaH3auwH H3Mepaan caeflyroiUHMii Me-TOAaMHS

I. OnpefleaeHHe οτβπβΗΗ OKpauiHBaHUH ΟτβπβΗΒ OKpamHBaHMH nojiHuepHoro pacTBopa oaeHHBaan BH3y-ηλβηο Bbipa h / s KaflH daaaax no caeflywiiietl nutaae 1 - caatío xenTtift (Havana οκρθιιιηβθηηη) 2 - ^ 3 enTOBamň - KenTuíi 4 - WHT6HCMBH0 XeJlTblti 5 - ΗβηΤΟ-ΚΟρΗ ΗβΒΗί ^! 6 - ΤΛΟβΤΛΟ — ΗρΗ ^ ΗβΒΗίί 7 - K0pHMH6Btlft 8.- ΤβΜΗΟΚΟρΗ ^ ΗβΒΗβ9 - qepHwfi 2. OnpeseneHHe BbweaeHHH xaopHCToro Boaoposa

BusejieHHe xaopHCToro Bo ^ opo ^ and H3uepHflH no Η3ΜβΗβΗΗθβ Me-τοΛπκβ TG Z 28475/02 b MacanHofi daHe npw TeMnepaiype

Macao 100 ° C. 5 r nccaeflyeMoro noaHMepHoro pacTBopa noMemaioT bKoady SpaeHweiiep ομκοοτβιο 100 ua h pacTBopmeaB BunapuBaioTb cyuinaBHOM inKa $ y npa 60 ° C. Ilocae βτογο Koady Spaemietiepa codpaTHUM xoaosHaBHHKOM noMemaioT b Harpeiyio and IOO ° C MacanHy »lady h n3nepfltoT BpeMH 40 noMyTHeHHH pacTBopa HmpaTŮ cepedpa.ΠρΗΜΘΡ I

Ciadwan3HpyiomaH cmscb:

Arem noibiiiieHHH aare3ifn: noaHMepHEn pacTBop; IIposoaKHTsaBHOCTB τβρωκΊβοκοί} odpadOTKii (Nacu) OKpaiiiHBainie: CTadOBHOCTB no MefiKCHep ^ MHH: 2 npoep CTadHausnpyioinaH ομθοβ 50 Bec.nacTefí οοηοβηογοcyaL $ aTa οβηηιχθ50 Bec.qacTeti οοηοβηογο $ OC $ HTa CBHHIjanoanypeTaflOBafl CMoaa

A 0 3 6 12 24 72 I I I 2 2 2 3 60 60 60 40 80 Bec.nacTeii MeaaMHHa20 Bec.nacTeii okmck μθγηηη 240447 -9-

IlojiMMepHbi pacTsop: A

AreHT noBHiueHMH aflre3HHi BpeMH TepuooÓpadoTKH (wacu): nonnypeTaHOBaH cmoju l 48 72 0 3 6 12 24 OKpauiHBaHne: II II 2 2 3 CTaÓHBBHOCTB ΠΟ ΜβΜκΟΗβρ / 60 / J IIoBHMepHuí! pacTBop: BpeMH TepMoodpadoTKH / naCH /: KHCJIOTH nojiHypeTaHOBaH A 0 3 6 12 c my and 24 48 72 ΟκρθΙΑΗΒβΗΗβ: CTadoBHOCTB no MeliKCHepy / MHH /: I 4 6 60 9 60 60 49 ΠρΗΜΘΡ 4 CTa <5oH3Hpyiomaff cm6Cl:

Arem noBHineHHfl address: IIojiHuepHHij pacTBop:

BpeMH TepuoodpaóoTKH (naciá): OKpauiHBaHHe: CTatioBHocTB no MeKKepepy / mhh): ΠρΗΜβρ 5 CTaónjiH3HpyiomaH CMecB:

AreHT nOBHIilSHHH aSre3HHSIIoBHMepHui? pacTBop:

BpeMH TppMOodpadOTKH / wacu /: OitpauiMBaHne: CTaÓHJiBHOCTB no MeíiKCHepy / Ktm /: 50 Bec.nacTen οοηοβηογοcyjiB $ aTa CBHHita50 Bec.nacTeíο οοηοβηογοφΟΟφΗΤβ ΟΒΗΗΙξβaflioMocoMKaT Haipun (raflKoe cieKJio)

A 0 3 6 12 24 48 72 I I I 2 2 2 3 60 60 60 30 50 Bec.wacTeíi οοηοβηογο cyjiB- (Í) 3T3 ΗΙΕΗΙξβ 50 Bec.MacTef, οοηοβηογοφοο;:; τ &amp; chKHixaκοροΰοκοΕϋΗ cmojih

A 0 3 6 12 24 48 72 I II 2 2 2 3 60 60 60 42 240447 -10- Πρμμθρ 6 · CTadnJiH3Hpyioiiiafl ομθοβ:

AreHT n0BHiu6HHH asre3HH: IIojiHMepHuft paciBop:

BpeMH TepuoodpadoTKH / nacti /: OKpanitfBaHne: GTadoBHocis no MeflKCHepy / MHH /: HpHMep 7 CTadHilH3Hpyl0maH ΟΜβΟΒΖ

Arem noBUiueHHH aare3WH: nonHMepHuň pacTBop:

BpeMH TepuoodpadOTKH / Load /: OKpauiHBaHHe: CTadHJiBHocTi no MefttccHepy / MHH /: Ilpatiep 8 CTadnJiH3npyromaH cuect;

AreHT noBHiueHHH aare3Hn: nojiHuepHaith paCTBop:

BpeMH TepMOOÓpadoTKH (load): ΟκρβιπΗΒΗΗΗβ: CTadHJiBHocTB no MetiKOHepy / mbh /: IIpHMep 9 (cpaBHHTejiBHtift npHizep) IIonHMepEtiU pacTBop:

50 Bec.nacTeft οοηοβηογοΟ ^ ΛΒφθΤΒ CBHHHa50 Bec ο nacTet) οοηοβηογοφΟΟφΒΤβ CBHHUaanoKCHAHas cMOJAA 0 3 6 12 24 48 72 I I I 2 2 2 3 60 60 60 39

50 Bec.nacTen οοηοβηογοcyji &amp; $ aTa CBBHifa z50 Bec.nacTei) οοηοβηογοφΟΟφΜΤβ CBHHlianojiuypeTaHOBaH cm oji aB 0 3 6 12 24 72 1 2 3 3 3 3 3 60 60 60 60

50 Bec.nacTefi οοηοβηογο .cyjiB $ aTa cBiiHija50 Bec.nacTen οοηοβηογοφΟΟφΗΤβ CBHHIjanojiwypeTaHOBan CMOiiaC 0 3 6 12 24 48 72 2 4 7 9 60 60 60 60 A de3 CTadiiJinaaTopa 240447 -11-

Bpeiííi TepMootfotóH (nacw) 0 3 6 12 24 48 72 OKpauiHBaHMe: CTaÓHJIBHOCTB Π0 I 3 4 8 9 MeiíKCHepy (mhh): 40 21 7 5 ΠρΗΜβΡ 10 (CPaBHHTSflBHHI} ΠΡΗΜβο). 3 6 12 24 48 72 OKpauiHBaHHe: I 2 3 3 3 5 6 CTaÓHJIBHOCTB no MeíSKcnepy (mhh): ΠρΗΜβΡ II (, ΟΡβΒΗΗΤβΛΒΗΗδ ΠΡΗΜβρ) OKpauiHBaHHe 48 72 2 5 9 CTaÓHJIBHOCTB no MefiKCHepy (MHH): 60 60 60 60 12 ΠρΗΜβρ (cpaBHHTOJiBHbiB npHMep) 2 Bec.qaciH nopouiKOOópaaHOií CTaÓHJiH3Hpyioineň cmoch »using lenses TonmeJí H3 paBHHX loaded TpexocHOBHoro cyjiBýaia cBHHna SByx- ΟΟΗΟΒΗΟΓΟ $ h $ OC HTa CBHHIía , BMeillHBaiOT HenOCpeaCTBeHHO B nojiHMep- Hbifl pacTBop A, πρπηβω KOonecTBO 0TaÓHJiH3aT0pa paccnHiaHO Ha cosepsaHne TBepaoro BemecTBa b nojiHwepHOM pacTBope. IlocjieΒΒθίδΗΗΗ CTaÓHJlH3HpyiO14efi CíiieCH npOHCXO.W nOMyTH6HH6 nOHHMep-ηογο pacTBopa h nepe3 κοροτκοε βρόμη CTaóHJiH3aTopti BbinasaioT bocaaoK, flow hto He npowcxojiHT γομογοηηογο CMeuieHHH. Bhjih on-peaejieHH cjiesyraniHe 3HayeHHH BeJiHnHH: BpeMH TepuooópaÓoTKK (nacn): 0 3 6 12 24 48 72 1 II 3 3 3 4 5 CTaÓHJIBHOCTB no MefiKCHepy (mhh): 60 60 60 36 Πρί JWHU, C2adHJlH3HpOBaHHb! e COFJiaCHO Η3θύρ8Τ6ΗΗΚ) »b npOTHBOnOJlOK-HOCTB XnopupOBaHHblM nOJlHOJie ^ HHaM, CTaÓHJlH3Hp0BaHHHM ΠΟ H3B6CT-Houyu ypoBHio τθχηηκη HenocpescTBeHHbíM BBeA6HneM CTA <5miH3aTOpOB, oČnasasT yjiynujeHHOií τβρΜΟΟτοϋκοοτΒίο b οτηοϊιιθηηη bhs6ji6hhh xjio-pUCTOFO BOflOpOfla K CTOÍ3KOCTBK) K OKpaUHBaHHK) ΧΟΤΗ COrJiaOHO H30O-peTeHK-j pacxos CTaHHiH3aTopoB aaation CHoaeTCH. $ 240447 -12- OPMyna ΗΒΟΰρβΤβΗΗΗ first CnoeoC CTA <5OH3aiíHH XJIOpHpOBaHHOrO nOJIHOJie $ HHA, noKOTOpOUy XflOpUpOBaHHhlfí ΠΟΠΗΟηβφήΗ HCnOJIB3yiOT B paCTBOpe OT-jiMyaroiHHňCH those ητο CTatfoneaTop ηηηοοητ Ha ηοοητθλβ, cHaÓsceHhhí5 OTBepoaeMHM, npesnoyTHTeJiBHO mchakhm θγθητομ ποβηιπ6ηηη θαre3HH OH HaHOCHT CTaÓH3IH3aTOp COBMeCTHO C ΘΓΘΗΤΟΜ ΠΟΒΗΙϋβΗΗΗ3ΑΓβ3ΗΗ Ha HOCHTeJlB CJIOeM TOJI1HHHOM MHHHMyM 0.2 MM.areHT Nobuo-πιθηηη asre3HH πρΗ κθΜΗ3ΤΗθβ h η ποΒΗΐιίθΗΗοίί it TeMnepaType ΟΤΒθρ-JKAaiOT η πρκ 3Τ0Μ CTaÓHJlH3aT0p CBH3HBaiOT η 3aTeM HOCHTeJIB cHaHeceHHuw Ha Hero CTaÓHJiH3aTopoM AoóaBJíJWT κ HaxoAHineMycn bpadBope xnopnpoBaHHOuy noJiHOJie $ HHy. 2. Gnocoó no nyHKiyI, oTJioaioinHnCH τβΜ, ητο CTaóOH3aTopCMeiDHBaJOT c MAEHM araHTOM ποβηιπ6ηηη aAre3HH h nojiyqaioTcyc-neH3nio, b KOTopyio norpyacaioT HOCHTeJIB. 3. Cnocoó no nyHKTy 2, OTjinqaioiuHkCH θ μ Ha Ha noBepx -HOCTB HOCHTeJIH, CM0M6HHyK) ΑΗΰΠβρΟΗβϋ ΘΓβΗΤΘ ΠΟΒΜΙΠβΗΗΗ ΘΛΓββΗΗh CTa <5on3aTopa, hhhocht nopouiK0oópa3Hnň CTaÓHJiH3aT0p. 4. Cnocoó no nyHKTau 1-3; 5. Cnocoóne nyHKTy 4 ,. OTJinqaioiHHfiCH τθμ, μτο npoMHTHfi ho-cmejiB BHcyuiHBaioT πρκ κομηθτηομ TeMnepaType. Sixth Cnocoó well nyHKTau 1-5 OTJiHnaiomHĚCH τθμ, ητο b Kaqe-οτβθ CTaóM3iH3aTopoB HcnojiB3yioT TBepAhie, npejuioqTHTejiBHO ποροω-KOO (5pa3Ht e, He coflepacautfie hjih coAepacamHe ueiann CTaÓOH3aTopMcaun but he CEOE b βηαθ CMecn 7. Gnocoó well nyHKTy 6 OTJioaioímiíiCH τθμ, ητο b KanecTBeHecoAepx.amnx MeTaJiJi CTadon3aTopoB HcnojiB3yioT a30TC0Aep3KaimieopraHHwecKMe coeAHHeHHH, Hanpwuep, ueJiauHH 2- $ eHHJi-HHS0Ji, 240447 -13- OJIOKHUe 3φΗρω ΘΜΗΗΟΚρΟΤΟΗΟΒΟβ KHCJIOTH, aHipeHHJIMOWeBHHy ΗΛΗSnOKCHGOeSKHSHHH, 0ρΓ3ΗΗΜ60ΚΗβ φΟϋφΗΤΗ, ΜΗ0Γ03Τ0ΜΗΗβ ΟΠΗρΤΗ, aHTHOKCHTiaHTu η y <&amp; - adcopÓepú. g. Cnocod well nyHKTy 6 ouiijqaioiiiHííCH τβΜ, ητο b KanecTBe MeTaocosepacamnx cTadHflH3aTopoB wcnojiB3yioT006ΛΜΗ6ΗΗΗ CBHHUa, MblJia KaflBlJHfl, UHHKa <5apHH, KaSMHH, ojiobo - opraHHnecKwe coeflHHeHnn h okhcblj MeTannoB 9. Cnocod, well nyHKTaM 1-8 OTJinqaiomnfiCH τβΜ, ςτο HOCHTenBΧΗΜΗΗβΟΚΗ ΗΗΟρΤΘΗ Π ΗΗΚ ΟΤΗΟΙΙΙβΗΗΚ) K ΧΛΟρΗρΟΒΗΗΗΗΜ ΠΟΠΗΟΛβφΗΗΘΜ, CTadow3aTopy h aremy ποβηιιι6ηηη asre3iin h πρβ, πιποητΗτβηΒΗοcoctoht H3 φθρφορβ, KepaM0KH, cieKJia hjih MeTaJina. 10. Cnocod no nyHKTaM 1-9, OTJiHqaramHMCH τβΜ, ητο b Kane-ctb6 areHTa ποβμιπθηηη aaresó HcnojiB3yioT θποκοητιηηθ cmohh, nonwypeTaHOBbie cmwim hjih θπκμοοηληκητη. 11th Cnocod no nyHKTaM I-IO, oTjiHuaioiuMííCfl τβΜ, ητο b Ka-ΜβΟΤΒβ XJlOpHpOBaHHblX ΠΟΛΗΟηόφΚΗΟΒ HCnOJIB3yiOT XJIOpupOBaHHHenojiHnponnjieHbí, xjiopHpoBaHHhie ποοΒΤϊυιβΗΗ, xnopnpoBaHHbie Cono-AHMepu BTHJieHanponHJieHa, xnopHpoBaHHbie conoJiHMepu sTHJieHa-nponHneHa-flHeHa. 12. Cnocod no nyHKTy II, οτληηοϊοιηημοη τβΜ, hto coaepwa-ΗΗβ XJlOpa B XnopnpOBaHHOM ΠΟΛΗΟΠβφΗΗβ COCTaBJIfleT OT I Λ0 70Bec.nacTeň. 240447 -14-

AHHOTaiWH

Cnocoó CTaÓMJlH3aiW XJlOpupOBaHHUX NOJIHOJlOipMHOB M3oópeTeHHe KacaeTCH cnocoóa CTaÓHJiHsaiíWH xjiopMpoBaHHbixποοοΛθφΗΗΟΒ, κοτορυβ HaxoflHTCH b paciBope. COURSEHEETHEATCH <5HJIM3aiHH npOTHB B03fleiCTBHH ΤβΙΜΘ »CBeTa Z KMCJIOpO.ua.

UejiBio H3oópeTeHHH HBJífieTCfl yjiyquieHHe KawecTBa, b yacTHOCTH.no-BHinoHMO Tepwo - η CBOTOCTOfiKOCTH »μ yjiyMiueHHe nojie3Htix cboKctb. 3aZiaMa COCTOHT B TOM, CHH3HTB COFFEE — qecTBoHymeBoYoMoCoHoHiOnHa3aTop, AOCTHFHyTB cymecTBeHoCoBoCoOcOeOyHOiCiHJlBHOCTH H C ^ ejiaTB B03M0JKHHM ΠρΗΜΟΗβΗΗβpa3jiMMHux cTa <5HJiH3aiopoB. #jih peuieHHH 3T0ň 3asaqH upefljiaraeT-CH onocotí, Π0 KOTOpOMy n0p0UlK00Ópa3Hblil CTaÓHJIH3aT0p ΗβΗΟΟΗΤHa HocMTejit, CHaÓsteHHHíí areHTOM noBumeHHH asre3HH. HHacjioh HaHeceHHoro cTaOHJiH3aTopa sojistHa cocraBJiHTB MMHHMyM 0,2mm.Αγθητ noBbíiaeHHH asre3HH oTBepoaeTCH npH KOMHaTHoJj hjih ποβη-uieHHOfi TewnepaType h CBH3biBaeT npH 3T0m CTaÓzjiH3aTop. IlocjieΟΚΟΗΜΗΗΜΗ OTBepKfleHHH HOCHTeJlB C ΗΘΗβΟβΗΗΗΜ Ha Η6Γ0 CTaÓHJIIl-3aTopoM flotíaBjíHWT κ HaxoflHmeMycH b paciBope xjiopHpoBaHHOMynojiHOJie $ MHy. 240447 ..

Claims (12)

15 240447 of the invention A process for stabilizing a solution-chlorinated polyolefin, wherein the stabilizer is applied to a carrier provided with a curable, preferably adhesion-promoting liquid agent, or applied to a stabilizer together with a carrier-enhancing agent in a layer of at least 0.2 thickness. mm, the adhesion-increasing component cures at a normal or elevated temperature while binding the stabilizer, and the stabilizer carrier is added to the chlorinated polyolefin which is in solution. 2. Process according to claim 1, characterized in that the stabilizer is mixed with a liquid adhesion sensor and a carrier is introduced into the suspension. 3. A process as claimed in claim 2, wherein a powdered stabilizer is applied to the surface of the carrier of the wetted adhesion promoter and stabilizer. 4. The process of claim 1, wherein the stabilizer adhering to the surface of the carrier is eluted with an alcoholic solution, preferably a methanol solution, after curing of the adhesion promoter. 5. The process of claim 4 wherein the eluted carrier is dried at a normal temperature. 6. A process according to any one of claims 1 to 5, characterized in that the stabilizers used are solid, preferably powder-free, metal-free stabilizers and separate or in a mixture. 7. A process as claimed in claim 6, wherein the non-containing stabilizers are nitrogen-containing organic compounds such as melamine, 2-phenylindole, aminocrotonic esters, diphenylureas or epoxy compounds, organic phosphites, long chain alcohols of antioxidants and UF absorbers. 8. A method according to claim 6, wherein said metal-containing stabilizers are lead, calcium, zinc, barium and cadmium compounds. soaps, organic lead compounds and metal oxides. 9. A process as claimed in claim 1, wherein the carrier is chemically inert to the chlorinated polyolefin, stabilizer and adhesion promoter, and preferably consists of porcelain, ceramic, glass or metal. 10. A process as claimed in any one of claims 1 to 9 wherein the adhesion promoter is epoxy resin, polyurethane resin or alumosilicate. 11. Process according to claim 1, characterized in that chlorinated polypropylenes, chlorinated polyethylenes, chlorinated copolymers of ethylene and propylene or chlorinated copolymers ethylene, propylene, diene are used as chlorinated polyolefins. 12. The process of claim 11 wherein the chlorine content of the chlorinated polyolefin is 1 to 70% by weight. Recognized by the invention on the basis of the results of the expert review by the Patent Inventory Office, Berlin, DD.