CS225040B1 - The visualization of the latent image of light sensitive negative working polymeric coating - Google Patents
The visualization of the latent image of light sensitive negative working polymeric coating Download PDFInfo
- Publication number
- CS225040B1 CS225040B1 CS356482A CS356482A CS225040B1 CS 225040 B1 CS225040 B1 CS 225040B1 CS 356482 A CS356482 A CS 356482A CS 356482 A CS356482 A CS 356482A CS 225040 B1 CS225040 B1 CS 225040B1
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- Czechoslovakia
- Prior art keywords
- latent image
- visualization
- polymer
- negative working
- solution
- Prior art date
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- 238000012800 visualization Methods 0.000 title description 3
- 239000011248 coating agent Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 229920000642 polymer Polymers 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims description 4
- 230000005855 radiation Effects 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims description 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007539 photo-oxidation reaction Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
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- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
Vynález sa týká spůsobu vizuálizácie latentného obrazu svetlocitlivej negativna pracujúcej polymérnej vrstvy.The invention relates to a method for visualizing a latent image of a photosensitive negative-acting polymer layer.
Súčasné svetlocitlivé polymérne vrstvy pre fotomechanickú reprodukciu sa můžu vizualizovať dvojako:Current light-sensitive polymer layers for photomechanical reproduction can be visualized in two ways:
a) zabudováním farebnej komponenty do polymérnej vrstvy (různé organické a anorganické farbivá a pigmenty),a) incorporating the color component into the polymer layer (various organic and inorganic dyes and pigments),
b) zabudováním bezfarebnej komponenty do polymérnej vrstvy, ktorá přejde na farebnú až po expozici! UV svetlom, t. j. pri kopírovaní obrazu (napr. leukozlúčeniny kationových farbív, azozlúčeniny, diazozlúčeniny a podobné).b) by incorporating a colorless component into the polymer layer, which only becomes color after exposure! UV light, t. j. in the copying of an image (e.g., cationic dye leuco compounds, azo compounds, diazo compounds and the like).
Podstata spůsobu vizualizácie latentného obrazu svetlocitlivej negativné pracujúcej polymérnej vrstvy podl’a vynálezu spoSíva v tom, že do svetlocitlivého roztoku sa přidá 1 až 15 % hmotnosti, vzhTadom na polymér, leukozlúčeniny trifenylmetánového farbiva vzorce IThe principle of the visualization of the latent image of the photosensitive negative working polymer layer according to the invention consists in adding to the photosensitive solution 1 to 15% by weight, based on the polymer, of the leuco compound of the triphenylmethane dye of the formula I
kde R je H, NOg, N(CH3)2, Cl, CH3, C2H5 v polohe 2 alebo 4; R* je H, CH-j a R je H, NOg, CHj, Cl, roztok sa naneste v 2 až 20 /una vrstva na požadovanú podložku, na ktorú pósobí ultrafialové žiarenie. Přitom sa latentný obraz polymérovej vrstvy mění na farebný. Tento sa áalej vyvolá vývojkou rozpuštěním nezosieťovaných miest, na ktoré žiarenie neúčinkovalo.wherein R is H, NOg, N (CH 3 ) 2 , Cl, CH 3 , C 2 H 5 at the 2 or 4 position; R * is H, CH-1, and R is H, NO 2, CH 3, Cl, apply the solution in a 2 to 20 µm layer on the desired ultraviolet light substrate. In this case, the latent image of the polymer layer becomes color. This is further induced by the developer by dissolving the non-crosslinked sites to which the radiation has not acted.
Do svetlocitlivého roztoku před nanesením na podložku sa přidá senzibilizátor s výhodou benzaldehyd, benzofenón a acetofenón, v koncentrácii 1 až 15 % hmotnosti vzhTadom na polymér alebo sa svetlocitlivý roztok prebubláva kyslíkom po dobu 5 až 30 minút.The sensitizer, preferably benzaldehyde, benzophenone and acetophenone, is added to the photosensitive solution prior to application to the substrate at a concentration of 1 to 15% by weight relative to the polymer, or the photosensitive solution is bubbled with oxygen for 5 to 30 minutes.
Přidáním senzibilizátorov alebo zvýšením obsahu volného kyslíka vo vrstvě sa zvýši rýchlosť farebnej změny leukofarbiva a súčasne sa zvyšuje aj rýchlosť sieťovacej reakcie svetlocitlivej vrstvy.By adding sensitizers or by increasing the free oxygen content in the layer, the rate of color change of the leuco dye is increased and at the same time the rate of crosslinking reaction of the photosensitive layer is increased.
Výhoda spósobu vizualizácie podTa vynálezu spočívá v tom, že súčasne s optickým záznamem informácie do polymérnej negativné praeujúcej vrstvy sa latentný obraz zviditelní v dósledku fotooxidačnej reakcie leukofarbiva. Proces je založený na fotooxidácii, a teda přítomnost vzdušného kyslíka nie je na závadu. Je možné púužiť také polymérne systémy, ktoré sú typické oxidačné a neznižuje sa přitom ich citlivosť.An advantage of the method of visualization according to the invention is that, along with the optical recording of the information into the polymeric negative working layer, the latent image becomes visible as a result of the photooxidation reaction of the leuco dye. The process is based on photooxidation and therefore the presence of air oxygen is not a problem. It is possible to use polymer systems which are typically oxidative and do not reduce their sensitivity.
Priprava svetlocitlivého polymérneho roztoku:Preparation of photosensitive polymer solution:
Základný polymérny roztok sa připravil rozpuštěním 1 až 5 g butadién-styrénového kopolyméru v 100 ml zmesného rozpúšťadlá (40 % chloroformu, 30 % toluénu, 15 % xylénu, 15 % octanu etylnatého) [AO ,72 837 (1976)].A master polymer solution was prepared by dissolving 1-5 g of butadiene-styrene copolymer in 100 ml of mixed solvent (40% chloroform, 30% toluene, 15% xylene, 15% ethyl acetate) [AO, 72 837 (1976)].
Do roztoku sa přidá antracén v množstve 2 % vzhTadom na polymér. Takto připravený roztok sa přefiltruje cez fritu 0,1.Anthracene is added to the solution in an amount of 2% relative to the polymer. The solution thus prepared is filtered through a sinter frit 0.1.
Příklad 1Example 1
Do 100 ml základného svetlocitlivého roztoku sa přidá 0,3 g 2-chlór-4z,4’-diaminotrifenylmeténu. Připravené světlocitlivé roztoky sa naniesli na podložku použitím odstředivky s 50 otáčkami za minutu. Polychromatickým UV žiarením (výbojka RVK, 125 W, Tesla) sa kopíroval obraz předlohy zo vzdialenosti 30 cm. Doba expozíoie 90 minút. Pri použiti silnejšieho zdroja žiarenia bola doba expozície 4 minúty. Po vyvolaní xylénom, toluénom alebo benzénom sa získá modrý vykopírovaný obraz.To 100 ml of the basic photosensitive solution is added 0.3 g of 2-chloro-4 ' , 4'-diaminotrifenylmethene. The prepared photosensitive solutions were applied to the support using a 50 rpm centrifuge. Polychromatic UV radiation (RVK lamp, 125 W, Tesla) copied the image of the original from a distance of 30 cm. Exposure time 90 minutes. The exposure time was 4 minutes when using a stronger radiation source. Upon developing with xylene, toluene or benzene, a blue copied image is obtained.
Přiklad 2Example 2
Do 100 ml základného svetlocitlivého roztoku sa přidá 0,6 g 4,4'-diamino-4' '-difen.ylamino-trifenylmetánu a po vyvolaní (postup ako v příklade 1) sa získá purpurovosfarbený vykopírovaný obraz.0.6 g of 4,4'-diamino-4''-diphenylamino-triphenylmethane was added to 100 ml of the basic photosensitive solution and developed as described in Example 1 to give a purple-colored copied image.
Příklad 3Example 3
Do základného svetlocitlivého roztoku sa přidá 0,8 g 4-nitro-4‘,4'-diaminotrifenylmetánu a po vyvolaní (postup ako v příklade 1) sa získá žitý vykopírovaný obraz.0.8 g of 4-nitro-4 ', 4 ' -diaminotrifenylmethane is added to the photosensitive solution and developed as described in Example 1 to give a rye copy.
Přiklad 4Example 4
Postup ako v příklade 1 s tým, že do základného svetlocitlivého roztoku sa přidá 0,3 g benzofenónu. Přidáním senzibilizátora sa dosahujú vyššie optické hustoty a podstatné sa zvýši rýchlosť vyfarbenia vrstvy. Doba expozície sa skráti na 4 minúty.A procedure as in Example 1, except that 0.3 g of benzophenone is added to the basic photosensitive solution. The addition of the sensitizer results in higher optical densities and a substantial increase in the coloring speed of the layer. The exposure time is reduced to 4 minutes.
Príklad5Example 5
Postup ako v příklade 1 s tým, že základný svetlocitlivý roztok sa 15 minút prebubláva kyslíkom. Zvýšenie koncentráeie kyslíka v systéme mé za následok takmer dvojnásobné zvýšenie optickej hustoty ako v systéme bez prebublávania kyslíkom, ako aj zvýšenie rýchlosti vyfarbenia. Doba expozicie uskutočnená bola 3 minúty.Procedure as in Example 1, except that the basic photosensitive solution was bubbled with oxygen for 15 minutes. An increase in the oxygen concentration in the system results in an almost two-fold increase in the optical density than in a system without oxygen bubbling, as well as an increase in the dyeing rate. The exposure time was 3 minutes.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS356482A CS225040B1 (en) | 1982-05-17 | 1982-05-17 | The visualization of the latent image of light sensitive negative working polymeric coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS356482A CS225040B1 (en) | 1982-05-17 | 1982-05-17 | The visualization of the latent image of light sensitive negative working polymeric coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS225040B1 true CS225040B1 (en) | 1984-02-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS356482A CS225040B1 (en) | 1982-05-17 | 1982-05-17 | The visualization of the latent image of light sensitive negative working polymeric coating |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS225040B1 (en) |
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1982
- 1982-05-17 CS CS356482A patent/CS225040B1/en unknown
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