CS205186B1 - New polymers containing 1,2-dicarbonyl structures - Google Patents
New polymers containing 1,2-dicarbonyl structures Download PDFInfo
- Publication number
- CS205186B1 CS205186B1 CS423679A CS423679A CS205186B1 CS 205186 B1 CS205186 B1 CS 205186B1 CS 423679 A CS423679 A CS 423679A CS 423679 A CS423679 A CS 423679A CS 205186 B1 CS205186 B1 CS 205186B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- phenyl
- polymers containing
- new polymers
- structures
- vinyl
- Prior art date
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- 229920000642 polymer Polymers 0.000 title claims description 7
- -1 2-methacryloyloxyethoxy Chemical group 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
Vynález aa týká nových polymérov, ktoré obeahujú 1,2-dikarbonylové átruktúry, ktoré aa zíekajú kopolymerizáciou l-fenyl-2-^4-/2-metakryloyloxy-etoxy/fenylJ>etándiónu-l52 vzorcaThe invention aa relates to novel polymers which contain 1,2-dicarbonyl structures which aa obtain by copolymerization of 1-phenyl-2- [4- (2-methacryloyloxyethoxy) phenyl] ethanedione- 15 2 of the formula
O — CHg — CHg — 0 — OC — C — CH^ CH,O-CHg-CHg-O-OC-C-CH-CH,
CD a vinylovýml monomérmi.CD and vinyl monomers.
Doteraz neboli připravené kopolymáry, ktoré by obsahovali 1,2-dikarbenylová átruktúry. Námi připravený atonomér (1) umožňuje přípravu předmětných kopolymérov.To date, copolymers containing 1,2-dicarbenyl structures have not been prepared. The atonomer (1) prepared by us enables the preparation of the subject copolymers.
ft*edmetom tohto vynálezu eú nové polyméry, ktoré obeahujú 1,2-dikarbonylové átruktúry pripravitelná tak, Se (1) l-fenyl-2-(4-/2-metakryloyloxy-etoxy/-£snyl)etándi©a“l,2,iBa te- , polymerizuje o vinylovýml monomérmi. Vihylový monomár mdle byť styrén, kyselina akrylová a metftkrylová a ich eatery, akrylonitril, etylán, vinylchlorid, vinylacetát a vinylpyrolidón v množstve 0,1 - 99 mól % v inertnej atmosféro s radikálovým iniciátorem.The present invention relates to novel polymers which contain 1,2-dicarbonyl structures obtainable by Se (1) 1-phenyl-2- (4- (2-methacryloyloxy-ethoxy) -snyl) ethanediamine, 2, iBa te, polymerizes with vinyl monomers. The vinyl monomer may be styrene, acrylic and methacrylic acid, and their ethers, acrylonitrile, ethylene, vinyl chloride, vinyl acetate and vinylpyrrolidone in an amount of 0.1-99 mol% in an inert atmosphere with a radical initiator.
Uvedená polyméry ea mdžu využiť ako fosforeeenčná značkovače, optické zjasňovače alebo na polymér - analogická reakcie·These polymers can be used as phosphor-labelers, optical brighteners or polymer-analogous reactions.
Příklad 1 g l-fenyl-2-r4-/2-metakryloyloxy-etoxy/fenylJetándionu-1,2 a 18,12 g styrénuExample 1 g of 1-phenyl-2- [4- (2-methacryloyloxyethoxy) phenyl] ethanedione-1,2 and 18,12 g of styrene
205 186205 186
205188 a 0,01812 g azobisizobutyronitrilu aa polymeriaovalo v zatvorenej ampulka pod dueíkom pri 60 °C 12 hodin. Výťažok 3-krát prezrážaného polyméru,z benzénu do metanolu bol 5,6 g (29 «).205188 and 0.01812 g of azobisisobutyronitrile aa were polymerized in a sealed ampoule under an oven at 60 ° C for 12 hours. The yield of the 3-precipitated polymer from benzene to methanol was 5.6 g (29%).
Podobné aa polymerizovala reakčná zmea, ktorá obsahovala 0,1 a tiež 99 mol. % monomérov 1»A similar polymerized reaction mixture containing 0.1 and 99 moles was also polymerized. % of monomers 1 »
Příklad 2 ' g 1-fenyl-2-^4-/2-metakryloyloxy-etoxy/fenylJ-etándion-l,2 a 18,72 g metylmetakrylátu a 0,01872 g ^,οί'-azobisizobutyronitrilu aa polymerizevalo v zatvorenej ampulko pod dueíkom 2 hodiny pri 60 °C. Výťažok 3-krát prezráSaného polyméru z dlchlormetánu do metanolu bol 9;O3 g (45,8 %). Podobné aa zíakali kopolyméry diketónu (1) a kyselinou akrylovou a metakrylovou, ich aatarmi, akrylonitrilom, etylénom, vinylchloridoa, vinylaeetátom, akrylonitrilom, vinylpyrolidonom.EXAMPLE 2 1 g of 1-phenyl-2- [4- (2-methacryloyloxyethoxy) phenyl] ethanedione-1,2 and 18,72 g of methyl methacrylate and 0.01872 g of β-azobisisobutyronitrile and polymerized in a closed ampoule under due to 2 hours at 60 ° C. The yield of 3-rinsed polymer from dichloromethane to methanol was 9.0 g (45.8%). Similar and and deterred copolymers of diketone (1) and acrylic and methacrylic acid, their cathars, acrylonitrile, ethylene, vinyl chloride, vinyl acetate, acrylonitrile, vinylpyrrolidone.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS423679A CS205186B1 (en) | 1979-06-20 | 1979-06-20 | New polymers containing 1,2-dicarbonyl structures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS423679A CS205186B1 (en) | 1979-06-20 | 1979-06-20 | New polymers containing 1,2-dicarbonyl structures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS205186B1 true CS205186B1 (en) | 1981-05-29 |
Family
ID=5384627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS423679A CS205186B1 (en) | 1979-06-20 | 1979-06-20 | New polymers containing 1,2-dicarbonyl structures |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS205186B1 (en) |
-
1979
- 1979-06-20 CS CS423679A patent/CS205186B1/en unknown
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