CS198056B1 - Fire-coated layer on steel based on aluminium,zinc,titan - Google Patents

Fire-coated layer on steel based on aluminium,zinc,titan Download PDF

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Publication number
CS198056B1
CS198056B1 CS787778A CS787778A CS198056B1 CS 198056 B1 CS198056 B1 CS 198056B1 CS 787778 A CS787778 A CS 787778A CS 787778 A CS787778 A CS 787778A CS 198056 B1 CS198056 B1 CS 198056B1
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CS
Czechoslovakia
Prior art keywords
coating
zinc
titan
aluminium
fire
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CS787778A
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Czech (cs)
Slovak (sk)
Inventor
Jaroslav Kocich
Ladislav Servatka
Zoltan Jasovsky
Tatiana Grigerova
Original Assignee
Jaroslav Kocich
Ladislav Servatka
Zoltan Jasovsky
Tatiana Grigerova
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Application filed by Jaroslav Kocich, Ladislav Servatka, Zoltan Jasovsky, Tatiana Grigerova filed Critical Jaroslav Kocich
Priority to CS787778A priority Critical patent/CS198056B1/en
Publication of CS198056B1 publication Critical patent/CS198056B1/en

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  • Coating With Molten Metal (AREA)

Description

(54) Žlarovo nanesený povlek na oceli na báze hliník, zlnok, titan(54) Glaze coating on steel based on aluminum, grain, titanium

Vynález ea týká žiarových z Hat lnových povlakov xxa báze Al-Zn-Ti nanesenýoh na οοοί’οvom materiál!. Tieto povlaky eú vysoko korozně a tepelne odolná, májá dobrá tvárniteEnosť a přilnavost’ a eú vhodná ako náhrada žiarove pozinkovaných a pohliníkovanýoh pleohov.The present invention relates to heat-resistant hat liner xx and Al-Zn-Ti based coatings coated on a material. These coatings are highly corrosion-resistant and heat-resistant, have good formability and adhesion, and are suitable as a substitute for hot-dip galvanized and aluminized baldness.

V sáčasnosti ea vo svete už vyrábajú ooelové pleohy so žiarovýml zliatlnovými povlakmi Al-Zn-Si v SendzimiroveJ kontinuálněj linke. Křemík v tomto zllatinovom povlaku má inhibičný účlnok tj. zabraňuje, resp. spomaluje nařastaniu medzivrstvy vo formě intermetaliokýoh zláčenln medzi základným ooel’ovým materiálem a vlastným povlakem Al-Zn. Nevýhodou tohto žiarováho povlaku na báze Al-Zn-Sl je jeho náohylnoeť ku koráznemu odlupovaniu, tj. postupnému odlupovaniu povlaku od medzivrstvy v sline aeresívnyoh atmosférických koróznyoh prostrediaoh. Ďalžou nevýhodou tohto povlaku pri určitých aplikáclaoh je kopírovanie vytvořeného kvetu na povrohu povlaku, podobné ako zinkového kvetu pri žiarovom zinkovom povlaku, pri nanážaní nátěrových hmdt alebo fólií z plastických hmdt v kontinuálnyoh linkáoh.At the present time, and in the world, they already produce ooel puddles with Al-Zn-Si refractory alloys in Sendzimir's continuous line. The silicon in this filamentous coating has an inhibitory effect, i.e. it prevents or prevents the formation of silicon. it slows the build-up of the interlayer in the form of intermetallic paints between the base material and the actual Al-Zn coating. A disadvantage of this Al-Zn-S1-based hot-dip coating is its susceptibility to corrosive peeling, i.e., gradual peeling of the coating from the interlayer in the sinter of an aggressive atmospheric corrosive environment. A further disadvantage of this coating in certain applications is the copying of the formed flower on the surface of the coating, similar to that of a hot-dip galvanized coating, by applying coating compositions or plastic films in a continuous line.

Uvedená nevýhody rieSi žlarovo nanesený zliatlnový povlak nanesený na ooel*ovom materiál! na báze Al-Zn-Ti, ktorý pozostáva z 15-90 % hliníka, 0,01 až 1,5 # titánu a zbytok tvoří zlnok. Povlak mdže obsahovat’ ečte áalšiu legujúeu přísadu křemík v množstva 0,5 až 11The aforementioned drawbacks are solved by a glazed cast aluminum coating applied to the oel * material! based on Al-Zn-Ti, consisting of 15-90% aluminum, 0.01 to 1.5 # titanium and the remainder being zinc. The coating may contain an additional alloying additive of silicon in an amount of 0.5 to 11

Titán přítomný v zliatlne pri nanážaní žiarováho povlaku plní dvojaká funkoiu, ako Inhibitor rastu medzivrstvy, skládájáoej sa z intermetaliokýoh zláčenln, a ako očkovadlo,The titanium present in the galvanically applied coating has a dual function as an interlayer growth inhibitor, consisting of intermetallic compounds, and as an inoculant,

198 0?6198 0? 6

198 956 čím sa podstatné zjemňuje výsledná átruktára povlaku pri gaohovaní veTmi tenkej a rovnoměrně j medzlvrstvy medzl základným materiálom a povlakom. Prl laboratómyoh skúSkaoh nanáSanla povlaku na báze Al-Zn-Ti prl rýohloetlaoh oohladzovania 5 až 6 °C sek**1 sa vytvořil povlak s praktioky bezkvetou Struktúrou. Květy sa mobil pozorovat* len pod optiokým mikroskopem. To znamená, Se v případe apllkáole tohto povlaku prl výrobě lakovanýoh pleohov, nie je potřebná pleohy před lakováním prevaloovať za účelom odstránenia kvetov.198 956, thereby substantially refining the resulting coating structure when enriching with a very thin and uniform interlayer between the base material and the coating. Prl laboratómyoh skúSkaoh nanáSanla coating based on Al-Zn-Ti PRL rýohloetlaoh oohladzovania 5-6 ° C sec-1 ** to form a coating with praktioky bezkvetou structure. Flowers can only be observed under an optical microscope. That is, in the case of the application of this coating for the manufacture of lacquered bald, it is not necessary to roll the bald before painting to remove the flowers.

Mimo titánu je možná súčasne ako legujúou přísadu přidat’ křemík v množstve 0,5 až $>t čím sa eSte zesilní inhibičný účlnok titánu a vzniknutá medzivrstva je eSte tenSla a rovnoměrnějSia. SúSasná pridávanie legúr Ti a Si je výhodná najmtt pri nanáSaní zliatinováho povlaku oez tavidlo u maeívnyoh ooel’ovýoh konStrukoií, kde je najváčSle nebezpečenstvo vzniku hruběj medzlvrstvy a hrubozmnej Štruktúry povlaku.Besides titanium it is possible to simultaneously add an additive such legujúou is silicon in an amount of 0.5 to $> t thereby even zesilní inhibitory účlnok titanium and the resulting intermediate layer is even more uniformly and tenSla. The simultaneous addition of Ti and Si alloys is particularly advantageous in the application of an alloy coating as a flux in a massive steel construction, where there is the greatest danger of forming a coarser interlayer and a coarse-grained coating structure.

Prl urýohlenej oykllokej korozněj skúSke za přítomnosti SO^ sa zletilí u povlakov na báze Al-Zn-Ti, naneeenýoh na ooel'ovom plechu, že v koráznej odolnosti sú minimálně na tej ietej úrovni ako žiarová povlaky Al-Zn, legovaná Sl. Počae ekúSok nebolo u povlakov Al-Zn-Ti, reep. Al-Zn-Ti-Si pozorovaná korózne odlupovanie, pričom korózne splodiny holi rovnoměrnějSle rozložená pa povrohu.According to an advanced circular corrosion test in the presence of SO2, the filaments of Al-Zn-Ti-based coatings, coated on a corrugated sheet, are of at least the same level of corrosion resistance as Al-Zn hot-dip coatings alloyed with S1. Early noise was not found in Al-Zn-Ti coatings, reep. Al-Zn-Ti-Si observed corrosion peeling, wherein the corrosion products of the sticks were more evenly distributed over the surface.

Příklady prevedeniaExamples of design

Příklad 1.Example 1.

Žiarový povlak zloženia AI 52 Ti 0,14 ¢, zbytok ZN, nanesený na ooel'ový pleoh a obeahom uhlíku do 0,65 % hmotnoetnáho ea použil prl koróznyoh ekúSkaoh v agresivněj klíme v peoi kontinuálněJ pekárenekej linky v zaparovaoej časti. Povlak po 60 dňooh skúSky ostal praktioky nepoSkodený, zletilá sa iba slabá strata lesku.The Al 52 Ti hot-dip coating of 0.14 ¢, the remainder of the ZN, deposited on the oak skin and with a carbon content of up to 0.65% by weight and used a corrosive ecu in an aggressive climate in a continuous bakery line in the steamed portion. After 60 days of testing, the coating remained practically undamaged, with only a slight loss of luster aged.

Příklad 2.Example 2.

Žiarový povlak zloženia AI 35 Ti 0,28 ý>, Si 1,4 ý>, zbytok Zn nanesený na rovnaký οοβί’οvý pleoh, pri urýohlenýoh koróznyoh oykllokýoh ekúSkaoh za přítomnosti S02 v kondenzačněj komoře v porovnaní koróznej odolnosti bol minimálně na úrovni žiarovýoh povlakov legova nýoh len Si ( AI 34,3 ?í, Si 1,57 zbytok Zn ), pričom korozně splodiny boli JemnejSle a rovnoměrnějSie rozložená po povrohu.Dip coating composition of Al 35 Ti 0.28 y> Si 1.4 y>, Zn residue deposited on the same οοβί'οvý pleoh at urýohlenýoh koróznyoh oykllokýoh ekúSkaoh the presence of S0 2 in the coupling chamber in the corrosion resistance was compared to a minimum level žiarovýoh Si alloys (Al 34.3%, Si 1.57 Zn residue), the corrosion products were finer and more evenly distributed over the surface.

Claims (2)

PREDMET VYNÁLEZUOBJECT OF THE INVENTION 1. Žiarovo nanesený povlak na ooeli na báze hliník, zinok, titán, vyznačujúoi ea tým, že obsahuje 15 až 90 % hmotanoetnýoh hliníka, 0,01 až 1,5 % hmotnoetnáho titánu a ábytok tvoří zinok.1. A heat-deposited aluminum, zinc, titanium-based ooeli coating comprising 15 to 90% by weight of aluminum, 0.01 to 1.5% by weight of titanium and the furniture being zinc. 2. Žiarovo nanesený povlak podl’a hodu 1, vyznačujúoi sa tým, že obsahuje legujúou přísadu kremíka v množstve 0,5 až 11 % hmotnostnýoh.2. The hot-dip coating according to claim 1, characterized in that it contains an alloying additive of silicon in an amount of 0.5 to 11% by weight.
CS787778A 1978-11-30 1978-11-30 Fire-coated layer on steel based on aluminium,zinc,titan CS198056B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0816009A1 (en) * 1996-06-28 1998-01-07 Showa Aluminum Kabushiki Kaisha Aluminum brazing alloy for cold brazing and method for brazing low-melting alumininum material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0816009A1 (en) * 1996-06-28 1998-01-07 Showa Aluminum Kabushiki Kaisha Aluminum brazing alloy for cold brazing and method for brazing low-melting alumininum material

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