CS181769B2 - Process for the cis-trans-isomerization of derivatives of vitamin a - Google Patents

Process for the cis-trans-isomerization of derivatives of vitamin a

Info

Publication number
CS181769B2
CS181769B2 CS7400005766A CS576674A CS181769B2 CS 181769 B2 CS181769 B2 CS 181769B2 CS 7400005766 A CS7400005766 A CS 7400005766A CS 576674 A CS576674 A CS 576674A CS 181769 B2 CS181769 B2 CS 181769B2
Authority
CS
Czechoslovakia
Prior art keywords
isomerization
cis
vitamin
trans
derivatives
Prior art date
Application number
CS7400005766A
Other languages
Czech (cs)
Inventor
Hansjoerg Stoller
Hans Peter Wagner
Original Assignee
Hoffmann La Roche
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoffmann La Roche filed Critical Hoffmann La Roche
Publication of CS181769B2 publication Critical patent/CS181769B2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/08—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/10—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by etherified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/06—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms
    • C07C403/12—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by singly-bound oxygen atoms by esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/14—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by doubly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
    • C07C403/20—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by carboxyl groups or halides, anhydrides, or (thio)esters thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CS7400005766A 1973-08-21 1974-08-19 Process for the cis-trans-isomerization of derivatives of vitamin a CS181769B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH1199473A CH590222A5 (en) 1973-08-21 1973-08-21

Publications (1)

Publication Number Publication Date
CS181769B2 true CS181769B2 (en) 1978-03-31

Family

ID=4378834

Family Applications (1)

Application Number Title Priority Date Filing Date
CS7400005766A CS181769B2 (en) 1973-08-21 1974-08-19 Process for the cis-trans-isomerization of derivatives of vitamin a

Country Status (13)

Country Link
JP (1) JPS5613712B2 (en)
AT (1) AT355231B (en)
BE (1) BE819012A (en)
CH (1) CH590222A5 (en)
CS (1) CS181769B2 (en)
DD (1) DD114803A5 (en)
DE (1) DE2439860C3 (en)
FR (1) FR2245626B1 (en)
GB (1) GB1452012A (en)
IL (1) IL45366A (en)
NL (1) NL176259C (en)
SU (1) SU731894A3 (en)
ZA (1) ZA744737B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5908957A (en) * 1997-02-14 1999-06-01 Roche Vitamins Inc. Isomerization process
CA2774168C (en) 2009-09-15 2021-02-23 Ronald Erwin Boch Pharmaceutical formulations comprising 9-cis-retinyl esters in a lipid vehicle
CN102939081A (en) 2010-04-19 2013-02-20 Qlt股份有限公司 Therapeutic regimen and method for treating or ameliorating visual disorders associated with an endogenous retinoid deficiency
ES2780357T3 (en) 2012-03-01 2020-08-25 Retinagenix Therapeutics Inc Retinal derivatives for use in improving visual function
CN111233726B (en) * 2020-03-26 2021-12-14 万华化学集团股份有限公司 Method for preparing all-trans vitamin A acetate
CN112358429B (en) * 2020-11-06 2023-05-02 万华化学集团股份有限公司 Heterogeneous catalyst and preparation method thereof, and preparation method of all-trans vitamin A acetate
CN113321604B (en) * 2021-06-23 2023-01-13 万华化学集团股份有限公司 Preparation method of beta-carotene
KR20240113569A (en) * 2021-12-03 2024-07-22 디에스엠 아이피 어셋츠 비.브이. novel composition

Also Published As

Publication number Publication date
GB1452012A (en) 1976-10-06
IL45366A (en) 1979-05-31
DE2439860B2 (en) 1979-05-23
NL176259C (en) 1985-03-18
ZA744737B (en) 1975-08-27
FR2245626A1 (en) 1975-04-25
NL176259B (en) 1984-10-16
JPS5613712B2 (en) 1981-03-30
ATA678474A (en) 1979-07-15
DD114803A5 (en) 1975-08-20
JPS5049256A (en) 1975-05-01
FR2245626B1 (en) 1978-11-10
SU731894A3 (en) 1980-04-30
DE2439860C3 (en) 1980-01-17
DE2439860A1 (en) 1975-03-06
IL45366A0 (en) 1974-10-22
BE819012A (en) 1975-02-20
NL7411171A (en) 1975-02-25
CH590222A5 (en) 1977-07-29
AT355231B (en) 1980-02-25

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