CO6491074A2 - RECOVERY OF HIGHER ALCOHOLS FROM DILUATED WATER SOLUTIONS - Google Patents

RECOVERY OF HIGHER ALCOHOLS FROM DILUATED WATER SOLUTIONS

Info

Publication number
CO6491074A2
CO6491074A2 CO12010206A CO12010206A CO6491074A2 CO 6491074 A2 CO6491074 A2 CO 6491074A2 CO 12010206 A CO12010206 A CO 12010206A CO 12010206 A CO12010206 A CO 12010206A CO 6491074 A2 CO6491074 A2 CO 6491074A2
Authority
CO
Colombia
Prior art keywords
recovery
fermentation
methods
diluated
alcohols
Prior art date
Application number
CO12010206A
Other languages
Spanish (es)
Inventor
William A Evanko
Mark Brothers
Ken Drobish
Aristos A Aristidou
Kent Evans
Andrew C Hawkins
Scott Lucas
Original Assignee
Gevo Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gevo Inc filed Critical Gevo Inc
Publication of CO6491074A2 publication Critical patent/CO6491074A2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/16—Butanols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D1/00—Evaporating
    • B01D1/30—Accessories for evaporators ; Constructional details thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/001—Processes specially adapted for distillation or rectification of fermented solutions
    • B01D3/002—Processes specially adapted for distillation or rectification of fermented solutions by continuous methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/06—Flash distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057—Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • B01D5/006—Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with evaporation or distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C07C29/84—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by extractive distillation
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M1/00—Apparatus for enzymology or microbiology
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Sustainable Development (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)

Abstract

Esta invención se refiere a los métodos para la recuperación de alcoholes C3-C6 a partir de soluciones acuosas diluidas, tales como caldos de fermentación. Tales métodos proveen productividad volumétrica mejorada para la fermentación y permiten la recuperación del alcohol. Tales métodos también posibilitan una reducción en el uso de energía en la producción y el secado del caldo de fermentación utilizado debido al incremento en la concentración efectiva del producto de alcohol mediante el proceso simultáneo de fermentación y recuperación que incrementa la cantidad de alcohol producido y recuperado por cantidad de caldo de fermentación secado. Por ende, la invención permite la producción y la recuperación de alcoholes C3-C6 a bajos costos de capital y menores costos de operación.This invention relates to methods for the recovery of C3-C6 alcohols from dilute aqueous solutions, such as fermentation broths. Such methods provide improved volumetric productivity for fermentation and allow alcohol recovery. Such methods also enable a reduction in the use of energy in the production and drying of the fermentation broth used due to the increase in the effective concentration of the alcohol product through the simultaneous fermentation and recovery process that increases the amount of alcohol produced and recovered. by quantity of dried fermentation broth. Therefore, the invention allows the production and recovery of C3-C6 alcohols at low capital costs and lower operating costs.

CO12010206A 2009-06-26 2012-01-24 RECOVERY OF HIGHER ALCOHOLS FROM DILUATED WATER SOLUTIONS CO6491074A2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US22096709P 2009-06-26 2009-06-26

Publications (1)

Publication Number Publication Date
CO6491074A2 true CO6491074A2 (en) 2012-07-31

Family

ID=43386923

Family Applications (1)

Application Number Title Priority Date Filing Date
CO12010206A CO6491074A2 (en) 2009-06-26 2012-01-24 RECOVERY OF HIGHER ALCOHOLS FROM DILUATED WATER SOLUTIONS

Country Status (12)

Country Link
US (3) US20110124068A1 (en)
EP (1) EP2446045A4 (en)
JP (1) JP2012531209A (en)
KR (1) KR20120104509A (en)
CN (1) CN102482689A (en)
AU (1) AU2010265880A1 (en)
BR (1) BR112012000659A2 (en)
CA (1) CA2766170A1 (en)
CO (1) CO6491074A2 (en)
MX (1) MX2012000251A (en)
RU (1) RU2012102626A (en)
WO (1) WO2010151832A1 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102712560A (en) * 2009-11-24 2012-10-03 巴斯夫欧洲公司 Method for isolating an alkanol from an aqueous biotransformation mixture
US8574406B2 (en) * 2010-02-09 2013-11-05 Butamax Advanced Biofuels Llc Process to remove product alcohol from a fermentation by vaporization under vacuum
MX2012014550A (en) 2010-06-17 2013-01-29 Butamax Tm Advanced Biofuels Yeast production culture for the production of butanol.
US8871488B2 (en) 2010-06-18 2014-10-28 Butamax Advanced Biofuels Llc Recombinant host cells comprising phosphoketolases
US8628643B2 (en) 2010-09-02 2014-01-14 Butamax Advanced Biofuels Llc Process to remove product alcohol from a fermentation by vaporization under vacuum
EP2583957A1 (en) 2011-10-18 2013-04-24 LANXESS Deutschland GmbH Linear butene from isobutanol
JP2015501643A (en) * 2011-12-09 2015-01-19 ビュータマックス・アドバンスド・バイオフューエルズ・エルエルシー Method for removing product alcohol from fermentation broth
WO2013088237A1 (en) * 2011-12-15 2013-06-20 Masdar Institute Of Science And Technology Vacuum membrane distillation (vmd) using aspirator to generate vacuum pressure
CA2870567A1 (en) 2012-05-04 2013-11-07 Butamax Advanced Biofuels Llc Processes and systems for alcohol production and recovery
US9828317B2 (en) 2012-06-29 2017-11-28 Gevo, Inc. Method for purification of alcohols
GB201215505D0 (en) 2012-08-31 2012-10-17 C5 Labs Aps Process for the production of ethanol
US9663759B2 (en) 2013-07-03 2017-05-30 Butamax Advanced Biofuels Llc Partial adaptation for butanol production
CN104154687B (en) * 2014-08-22 2016-08-24 珠海格力电器股份有限公司 Flash tank and air conditioner with same
KR102642284B1 (en) * 2017-03-20 2024-02-28 란자테크, 인크. Methods and systems for product recovery and cell recycling
US10865370B1 (en) * 2018-03-28 2020-12-15 Bioleap, Inc. Cook water preheat using evaporator vapor heat recovery
CN108452553B (en) * 2018-04-01 2023-12-15 重庆梁彬新材料技术有限公司 Alcohol water recovery unit for aerogel
US11091415B2 (en) 2019-02-08 2021-08-17 Lanzatech, Inc. Process for recovering close boiling products
CN112852597B (en) * 2021-01-08 2022-11-22 宁夏首朗吉元新能源科技有限公司 Recovery equipment and method for nutrient salt generated by fermentation of ferroalloy industrial tail gas

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US4359533A (en) * 1980-11-26 1982-11-16 The United States Of America As Represented By The Department Of Energy Fermentative alcohol production
US4460687A (en) * 1981-03-23 1984-07-17 Alfa Laval Ab Fermentation method
US4777135A (en) * 1985-02-04 1988-10-11 The University Of Vermont And State Agricultural College Method for producing butanol by fermentation
JPH02186971A (en) * 1989-01-11 1990-07-23 Jgc Corp Recovery of alcohol from culture solution
IL132883A0 (en) * 1997-05-14 2001-03-19 Univ Illinois A method of producing butanol using a mutant strain of clostridium beijerinckii
AU2003243366B2 (en) * 2002-05-30 2008-01-24 Natureworks Llc Methods and materials for the production of lactic acid in yeast
US20050089979A1 (en) * 2003-09-18 2005-04-28 Ezeji Thaddeus C. Process for continuous solvent production
US8945899B2 (en) * 2007-12-20 2015-02-03 Butamax Advanced Biofuels Llc Ketol-acid reductoisomerase using NADH
US20080132741A1 (en) * 2006-06-16 2008-06-05 D Amore Michael B Process for making butenes from dry isobutanol
US20080015397A1 (en) * 2006-06-16 2008-01-17 D Amore Michael B Process for making isooctenes from aqueous 1-butanol
US8975047B2 (en) * 2006-06-16 2015-03-10 E I Du Pont De Nemours And Company Process for making isooctenes from dry 1-butanol
US20080015395A1 (en) * 2006-06-16 2008-01-17 D Amore Michael B Process for making butenes from aqueous 1-butanol
US20080131948A1 (en) * 2006-12-01 2008-06-05 Leo Ernest Manzer Process for making isooctenes from dry 2-butanol
WO2008124490A1 (en) * 2007-04-03 2008-10-16 The Ohio State University Methods of producing butanol
AU2008235231B2 (en) * 2007-04-04 2012-08-30 Markus Lehmann Method for distilling a starting material and installation for carrying out said method
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EP2283141B1 (en) * 2008-06-04 2014-04-23 Butamax (TM) Advanced Biofuels LLC A method for producing butanol using extraction and gas stripping

Also Published As

Publication number Publication date
WO2010151832A1 (en) 2010-12-29
JP2012531209A (en) 2012-12-10
US20110124068A1 (en) 2011-05-26
US20140356920A1 (en) 2014-12-04
RU2012102626A (en) 2013-08-10
KR20120104509A (en) 2012-09-21
CA2766170A1 (en) 2010-12-29
AU2010265880A1 (en) 2012-01-19
US20130122561A1 (en) 2013-05-16
MX2012000251A (en) 2012-04-11
EP2446045A4 (en) 2017-04-19
BR112012000659A2 (en) 2019-09-24
EP2446045A1 (en) 2012-05-02
CN102482689A (en) 2012-05-30

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