CO5060425A1 - MIXED FUNGICIDES BASED ON TRIPELOXIMETER DERIVATIVES AND FUNGICIDES FOR RICE - Google Patents

MIXED FUNGICIDES BASED ON TRIPELOXIMETER DERIVATIVES AND FUNGICIDES FOR RICE

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CO5060425A1
CO5060425A1 CO99017822A CO99017822A CO5060425A1 CO 5060425 A1 CO5060425 A1 CO 5060425A1 CO 99017822 A CO99017822 A CO 99017822A CO 99017822 A CO99017822 A CO 99017822A CO 5060425 A1 CO5060425 A1 CO 5060425A1
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alkylamino
alkyl
alkylaminocarbonyl
aryl
cycloalkyl
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CO99017822A
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Spanish (es)
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Klaus Schelberger
Thomas Grote
Sauter Hubert
Eberhard Ammermann
Gisela Lorenz
Siegfred Strathmann
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Basf Ag
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06—Aerosols
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/56—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by doubly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D339/00—Heterocyclic compounds containing rings having two sulfur atoms as the only ring hetero atoms
    • C07D339/02—Five-membered rings
    • C07D339/06—Five-membered rings having the hetero atoms in positions 1 and 3, e.g. cyclic dithiocarbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/06—Peri-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D513/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C07D513/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00 in which the condensed system contains two hetero rings
    • C07D513/04—Ortho-condensed systems

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

Mezclas para la protección de plantas, que contienen comocomponentes activos a) derivados de ácido fenilacético de la fórmula I en la que los sustituyentes y el índice tienen los significados siguientes: X NOCH3 , CHOCH3 , CHCH3 Y O, NR R1 , R cada uno independiente del otro, hidrógeno y C1 -C4 -alquilo; R2 ciano, nitro, trifluorometilo, halógeno, C1 -C4 alquilo y C1 -C4 -alcoxi; m 0, 1 ó 2 pudiendo los radicales R2 ser diferentes cuando m es 2; R3 hidrógeno, ciano, C1 -C4 -alquilo, C1 -C4 - halógenoalquilo, C3 -C6 -cicloalquilo; R4 , R6 cada uno independientemente del otro, hidrógeno, C1 -C10 -alquilo C3 -C6 -cicloalquilo, C2 -C10 - alquenilo, C2 -C10 -alquinilo, C1 -C10 -alquicarbonilo, C2 -C10 -alquenilcarbonilo, C3 -C10 -alquenicarbonilo o C1 -C10 -alquilsulfonilo, cuyos radicales pueden estar parcial o completamente halogenados o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, aminotiocarbonilo, halógeno, C1 -C6 -alquilo, C1 -C6 -halogenoalquilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alcoxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di-C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di-C1 -C6 - alquilaminocarbonilo, C1 -C6 - alquilaminotiocarbonilo, di-C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 - alqueniloxi, C3 -C6 -cicloalquilo, C3 -C6 -cicloalqueniloxi, heterociclo, heterocicliloxi, bencilo, benciloxi, arilo, ariloxi, - 2 -ariltio, hetarilo, hetariloxi, y hetariltio, cuyos grupos cíclicos pueden por su parte estar parcial o completamente halogenados o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino carboxilo, aminocarbonilo, aminotiocarbonilo, halógeno, C1 -C6 -alquilo, C1 -C6 -halógenoalquilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C3 -C6 -cicloalquilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alquiloxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di-C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di-C1 -C6 - alquilaminocarbonilo, C1 -C6 - alquilaminotiocarbonilo, di-C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariltio, hetarilo, hetariloxi, hetariltio o C(=NOR7 )-An -R8 ; arilo, arilcarbonilo, arilsulfonilo, hetarilo, hetarilcarbonilo o hetarilsulfonilo, cuyos radicales pueden estar parcial o completamente halogenados o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, aminotiocarbonilo, halógeno, C1 -C6 -alquilo, C1 -C6 -halógenoalquilo, C1 -C6 -alquilcarbonilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C3 -C6 -cicloalquilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alquiloxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di-C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di-C1 -C6 - alquilaminocarbonilo, C1 -C6 - alquilaminotiocarbonilo, di-C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariloxi, hetarilo, hetariloxi o C(=NOR7 )-An -R8 ; R5 hidrógeno C1 -C6 -alquilo, C2 -C6 -alquenilo, C2 -C6 -alquinilo, pudiendo los radicales hidrocarburo de estos grupos estar parcial o completamente halogenados o llevar de uno a tres de los radicales siguientes: ciano, nitro, hidroxi, mercapto, amino carboxilo, aminocarbonilo, halógeno, C1 -C6 -alquilaminotiocarbonilo, di-C1 -C6 -alquilaminocarbonilo, C1 -C6 - alquilaminotiocarbonilo, di-C1 -C6 - alquilaminotiocarbonilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alcoxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di-C1 -C6 - alquilamino, C2 -C6 -alqueniloxi, C3 -C6 -cicloalquilo, C3 -C6 -cicloalquiloxi,heterocíclico, heterocicliloxi, arilo, ariloxi, aril-C1 -C4 -alcoxi, ariltio, aril-C1 -C4 -alquiltio, hetarilo, hetariloxi, hetaril-C1 -C4 -alcoxi, hetariltio, hetaril-C1 -C4 -alquiltio, cuyos radicales cíclicos pueden por su parte estar parcial o completamente halógenados y/o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino carboxilo, aminocarbonilo, aminotiocarbonilo, C1 -C6 -alquilo, C1 -C6 - halogenoalquilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C3 -C6 -cicloalquilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alcoxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquil-amino, di-C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di-C1 -C6 - alquilaminocarbonilo, C1 -C6 - alquilaminotiocarbonilo, di-C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariloxi, ariltio, hetarilo, hetariloxi, hetariltio y C(=NOR7 )-An -R8 ; C3 -C6 -cicloalquilo, C3 -C6 -cicloalquenilo, heterociclico, arilo, hetarilo, cuyos radicales cíclicos pueden estar parcial o completamente halogenados o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, aminotiocarbonilo halógeno, C1 -C6 -alquilo, C1 -C6 -halógenoalquilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C3 -C6 -cicloalquilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alcoxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di-C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di-C1 -C6 -alquilaminocarbonilo, C1 -C6 - alquilaminotiocarbonilo, di-C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariloxi, hetarilo y hetariloxi; Significado A oxígeno, azufre o nitrógeno y llevando el nitrógeno hidrógeno o C1 -C6 -alquilo; n 0 ó 1; R7 hidrógeno o C1 -C6 -alquilo y R8 hidrógeno o C1 -C6 -alquilo, así como sus sales, y b) por lo menos un compuesto de las fórmulas II hasta VII en una proporción en peso del compuesto I y el compuesto II hasta VII de 2500:1 a 1:500.Mixtures for the protection of plants, which contain as active components a) derivatives of phenylacetic acid of the formula I in which the substituents and the index have the following meanings: X NOCH3, CHOCH3, CHCH3 YO, NR R1, R each independent of other, hydrogen and C1-C4-alkyl; R2 cyano, nitro, trifluoromethyl, halogen, C1-C4 alkyl and C1-C4 -alkoxy; m 0, 1 or 2 the radicals R2 can be different when m is 2; R3 hydrogen, cyano, C1-C4-alkyl, C1-C4-halogenoalkyl, C3-C6 -cycloalkyl; R4, R6 each independently of the other, hydrogen, C1-C10 -C3 alkyl-C6 -cycloalkyl, C2-C10 -alkenyl, C2-C10 -alkynyl, C1-C10 -alkylcarbonyl, C2-C10 -alkenylcarbonyl, C3-C10 - alkenylcarbonyl or C1-C10-alkyl sulfonyl, whose radicals can be partially or completely halogenated or carry from one to three of the following groups: cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl, halogen, C1-C6-alkyl , C1-C6 -halogenoalkyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoxyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkoxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkylamino, di -C1 -C6 -alkylamino, C1-C6-alkylaminocarbonyl, di-C1-C6-alkylaminocarbonyl, C1-C6-alkylaminothiocarbonyl, di-C1-C6-alkylaminothiocarbonyl, C2-C6-alkenyl, C2-C6-alkenyloxy, C3-C6 -Cycloalkyl, C3-C6 -cycloalkenyloxy, heterocycle, heterocyclyloxy, benzyl, benzyloxy, aryl, aryloxy, - 2 -arylthio, hetaryl, heteroaryl xi, and hetarylthio, whose cyclic groups can be partially or completely halogenated or carry from one to three of the following groups: cyano, nitro, hydroxy, mercapto, amino carboxyl, aminocarbonyl, aminothiocarbonyl, halogen, C1-C6-alkyl , C1-C6 -haloalkyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoxyl, C3 -C6 -cycloalkyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkyloxycarbonyl, C1-C6 -alkylthio, C1 -C6 -alkylamino, di-C1-C6 -alkylamino, C1-C6 -alkylaminocarbonyl, di-C1-C6 - alkylaminocarbonyl, C1-C6 - alkylaminothiocarbonyl, di-C1-C6 - alkylaminothiocarbonyl, C2-C6-alkenyl, C2-C6 -alkenyloxy, benzyl, benzyloxy, aryl, arylthio, hetaryl, heteroyloxy, hetarylthio or C (= NOR7) -An -R8; aryl, arylcarbonyl, arylsulfonyl, heteroaryl, heteroarylcarbonyl or hetarylsulfonyl, the radicals of which may be partially or completely halogenated or carry from one to three of the following groups: cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl, halogen, C1 -C6 -alkyl, C1-C6 -haloalkyl, C1-C6 -alkylcarbonyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoxyl, C3-C6 -cycloalkyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkyloxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkylamino, di-C1-C6 -alkylamino, C1-C6 -alkylaminocarbonyl, di-C1-C6-alkylaminocarbonyl, C1-C6-alkylamino-thiocarbonyl, di-C1-C6-alkylamino-thiocarbonyl , C2-C6-alkenyl, C2-C6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl, heteroyloxy or C (= NOR7) -An-R8; R 5 hydrogen C1-C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, the hydrocarbon radicals of these groups being able to be partially or completely halogenated or carry from one to three of the following radicals: cyano, nitro, hydroxy, mercapto , amino carboxyl, aminocarbonyl, halogen, C1-C6-alkylaminothiocarbonyl, di-C1-C6-alkylaminocarbonyl, C1-C6-alkylamino-thiocarbonyl, di-C1-C6-alkylaminothiocarbonyl, C1-C6-alkylsulfonyl, C1-C6-alkyl-alkyl-C1-C 1-6 alkylsulfoxyl, C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkoxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkylamino, di-C1-C6-alkylamino, C2-C6 -alkenyloxy, C3-C6 -cycloalkyl, C3 - C6-cycloalkyloxy, heterocyclic, heterocyclyloxy, aryl, aryloxy, aryl-C1-C4 -alkoxy, arylthio, aryl-C1-C4-alkylthio, heteroaryl, heteroaryloxy, C1-C4 -alkoxy, heteroaryl, heterocyl-C1-C4 - alkylthio, whose cyclic radicals can be partially or completely halogenated and / or carry from one to three of the following groups it is: cyano, nitro, hydroxy, mercapto, amino carboxyl, aminocarbonyl, aminothiocarbonyl, C1-C6 -alkyl, C1-C6-halogenoalkyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoxyl, C3-C6 -cycloalkyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkoxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkyl-amino, di-C1-C6 -alkylamino, C1-C6 -alkylaminocarbonyl, di-C1-C6 -alkylaminocarbonyl , C1-C6-alkylamino-thiocarbonyl, di-C1-C6-alkylamino-thiocarbonyl, C2-C6-alkenyl, C2-C6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroyloxy, heteroaryl and C (= NOR7) -A -R8; C3-C6 -cycloalkyl, C3-C6 -cycloalkenyl, heterocyclic, aryl, heteroaryl, whose cyclic radicals can be partially or completely halogenated or carry from one to three of the following groups: cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl halogen, C1-C6 -alkyl, C1-C6 -haloalkyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoxyl, C3-C6 -cycloalkyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkoxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkylamino, di-C1-C6 -alkylamino, C1-C6 -alkylaminocarbonyl, di-C1-C6 -alkylaminocarbonyl, C1-C6-alkylamino-thiocarbonyl, di-C1-C6 -alkylamino-thiocarbonyl , C2-C6-alkenyl, C2-C6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, hetaryl and heteroyloxy; Meaning To oxygen, sulfur or nitrogen and carrying hydrogen nitrogen or C1-C6-alkyl; n 0 or 1; R 7 hydrogen or C 1 -C 6 -alkyl and R 8 hydrogen or C 1 -C 6 -alkyl, as well as their salts, and b) at least one compound of formulas II to VII in a weight ratio of compound I and compound II to VII from 2500: 1 to 1: 500.

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