CN86106469B - Industrial concentration method for sepiolite - Google Patents
Industrial concentration method for sepiolite Download PDFInfo
- Publication number
- CN86106469B CN86106469B CN86106469A CN86106469A CN86106469B CN 86106469 B CN86106469 B CN 86106469B CN 86106469 A CN86106469 A CN 86106469A CN 86106469 A CN86106469 A CN 86106469A CN 86106469 B CN86106469 B CN 86106469B
- Authority
- CN
- China
- Prior art keywords
- sepiolite
- waterglass
- time
- minutes
- sedimentation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The present invention relates to an industrial enriching method for sepiolite, which can be used for obtaining high-grade sepiolite from sepiolite raw ores. The sepiolite crude ores are swelled and crushed by adding water, water glass is added to the sepiolite raw ores to be dispersed at a high speed for one to two times in a dispersion machine. By means of gravity sedimentation, solid and liquid in upper suspension liquid are separated, the upper suspension liquid is dried, and sepiolite ore concentrates are obtained. The present invention can obtain high-grade sepiolite ore concentrates containing more than 90% of the sepiolite, and the recovery rate is more than 85%. From the enriching verification by using sepiolite soil in four different areas, the method is generally applied, and the method can be applied to the construction of sepiolite separating plants. The present invention has the advantages of stable quality of products, and low cost.
Description
The present invention relates to the beneficiation method in a kind of sepiolite clay ore deposit, particularly a kind ofly add dispersant obtains the sepiolite concentrate with the gravity separation principle beneficiation method.
Sepiolite is a kind of mineral resources of rareness.Because of it has special physical and chemical performance and processing performance has the wide industrial purposes.China successively in the Leping, Jiangxi, ground such as liuyang hunan, stone Tan, Yin Tiansi, Chen Jia gulf find to have the sepiolite industrial mineral deposit of industrial value, account for 1/4th of world saving, but, fail well to be utilized always because raw ore sepiolite content is low.
Present existing sepiolite beneficiation method, as the clear 55-47937 dental of Japanese Patent Laid communique sepiolite process for purification, be heated to 90 ℃ of dispersions with polyalcohols such as hydrogen peroxide or polyethylene glycol, sedimentation separation, low-grade sepiolite is low by the refining concentrate grade that draws of this method condition, still is not so good as the method for purification of general clay.1985 in addition " Hunan geology " sepiolite paper special edition supplementary issue first phases, delivered the isolation and purification of Yonghe County, Hunan sepiolite, this method a small amount of X diffraction test standard sepiolite that is used to purify, amount is few, time is long, and the cost height can't be realized commercial scale processing.
The purpose of this method is to provide a method simple, and cost is low, constant product quality, concentrate grade height, the sepiolite beneficiation method that the rate of recovery is high.
Sepiolite beneficiation method of the present invention is that with medicament combines with mechanical means, removes accompanying impurities talcum, quartz, calcite, montmorillonite etc. from sepiolite clay, makes sepiolite obtain enrichment.
The present invention adopts mechanical means that mineral such as the close fine sepiolite of character, quartz, talcum are scatter.This mechanical means mainly uses a kind of high speed dispersor.Disperse function that sample is smashed to pieces to mineral and disperse each other, but do not destroy the sepiolite structure.
The present invention utilizes medicament that the mineral that disperse are further disperseed, and medicament is waterglass (or mixture of waterglass and a small amount of calgon).Waterglass can produce inhibitory action to calcite, talcum, quartz etc. in wholesomeness ground, and sepiolite is disperseed, and when adding waterglass, slurry mud is thinning, talcum, and quartzy, the calcite subparticle power of can relying on for support is sunk and is separated with sepiolite suspension.
The present invention proposes three kinds of beneficiation methods:
First method: adopt two sections dispersions, secondary settlement obtains the sepiolite concentrate.The sepiolite raw ore is soaked slurrying, adding medicine dispersed with stirring in dispersion machine.First section disperse water glass (or mixture of waterglass and a small amount of calgon) consumption raw ore per ton is 10～36 kilograms, stirred 2～10 minutes, for the second time adding waterglass raw ore per ton before the sedimentation after disperseing is 4.5～11.5 kilograms, added the back mixing 2～3 minutes, and carried out the sedimentation first time and remove slag.The upper strata suspension that is obtained is carried out second section dispersion again in dispersion machine, sedimentation for the second time.Suspension in dispersion machine second section disperseed 2～25 minutes, adding waterglass raw ore per ton for the third time before the sedimentation after disperseing is 4.5～11.5 kilograms, mixing 2～3 minutes, placement is spent the night, carry out the sedimentation second time and remove slag, the upper strata suspension of Huo Deing is the sepiolite concentrate slurry once more, and this concentrate slurry is carried out Separation of Solid and Liquid, drying gets the sepiolite concentrate.
Second method: adopt one section to disperse secondary settlement.Raw ore is soaked slurrying, put into dispersion machine, in dispersion machine, add waterglass (or waterglass and a small amount of sodium hexametaphosphate mixture) then, raw ore per ton is 10～36 kilograms, jitter time is 5～20 minutes, and adding waterglass raw ore per ton for the second time before the sedimentation after disperseing is 4.5～11.5 kilograms, adds the back mixing 2～3 minutes, placement is spent the night, carry out the sedimentation first time and remove slag, it is 6～13 kilograms that the upper strata suspension that is obtained is added waterglass raw ore per ton more for the third time, mixing 2～3 minutes, placement is spent the night, carry out the sedimentation second time and remove slag, the upper strata suspension of Huo Deing is concentrate slurry once more, and this concentrate slurry is carried out Separation of Solid and Liquid, drying gets the sepiolite concentrate.
The third method: adopt one section to disperse a sedimentation.Can disperse a sedimentation can obtain high-grade sepiolite concentrate through one section to the former mining increase waterglass consumption of sepiolite.Raw ore is soaked slurrying, put into dispersion machine, in dispersion machine, add waterglass (or waterglass and a small amount of sodium hexametaphosphate mixture) then, raw ore per ton is 25～53 kilograms, dispersed with stirring 2～10 minutes, adding waterglass raw ore per ton for the second time before the sedimentation after disperseing is 6～15 kilograms, dispersed with stirring 2～3 minutes, placement is spent the night, sedimentation is removed slag, and the upper strata suspension that is obtained is concentrate slurry, and this concentrate slurry is made Separation of Solid and Liquid, drying gets the sepiolite concentrate.
The present invention to the sepiolite clay raw ore by soaking slurrying in 1: 9～1: 7.Native concentration is 10～15% in the dispersion slip in dispersion machine.During sedimentation in the slip native concentration be 10～15%, the sedimentation time is more than 10 hours.
The mine tailing redispersible recovery of the present invention after to the sepiolite clay ore dressing be sepiolite wherein.
Example one
Each 1 kilogram of flat, Chen Jiawan, stone Tan, temple, silver-colored field sepiolite original soil seek pleasure, carry out respectively by soaking slurrying in 1: 9～1: 7, add 70～180 milliliters of 14.3% waterglass, disperseed 2～10 minutes in the dispersion machine high speed, add for the second time 30～80 milliliters of waterglass, mixing 2～3 minutes, placement is spent the night, and upper strata suspension was disperseed 5～20 minutes in the dispersion machine high speed again, adds 30～80 milliliters of 14.3% waterglass for the third time, mixing 2～3 minutes, placement is spent the night, sedimentation remove slag upper strata suspension concentrate slurry, concentrate slurry is carried out Separation of Solid and Liquid, drying gets the sepiolite concentrate.Concentrate X diffraction phase analysis the results are shown in Table 1.
Table 1 sepiolite concentrate X diffraction phase analysis result
The former local product phase composition in place of production % sepiolite
The quartzy calcite rate of recovery of sepiolite % sepiolite talcum %
Leping 21.8 91 45＜1 87.7
Temple, silver field 38 94＜15＜1 93.4
Stone Tan 47 95＜14＜1 96.1
Chen Jia gulf 27.9 92 152 90
Example two
Get 1 kilogram of Chen Jia gulf weathering type sepiolite, add water and soaked slurrying in about 1: 9, add 70～180 milliliters of 14.3% waterglass, high speed dispersion 5～25 minutes adds 45～90 milliliters of waterglass, mixing 2～3 minutes for the second time.Placement is spent the night, and sedimentation is removed slag, and gets upper strata suspension concentrate slurry is carried out Separation of Solid and Liquid, and drying gets the sepiolite concentrate.Diffraction phase analysis the results are shown in Table 2.
Table 2 X diffraction phase analysis result
Genus phase component % sepiolite
The quartzy calcite rate of recovery of sepiolite talcum %
Original soil 27.9 16 15 41
Concentrate 88 551 96.2
Mine tailing 2 24 22 52 3.8
Example three
Get 21.5 kilograms of loam mould sepiolite original soils, original soil contains sepiolite 50%, soak slurrying, adding 100～150 milliliters of 28.6% waterglass by the per kilogram raw ore disperseed 2～10 minutes in the dispersion machine high speed, rare to about 200 kilograms, the per kilogram raw ore is added 25～60 milliliters of 28.6% waterglass, mixing 2 minutes, placement is spent the night, sedimentation is removed slag, and gets upper strata suspension concentrate slurry, concentrate slurry is carried out solid-liquid disperse, dry, promptly get sepiolite 95% concentrate, contain sepiolite 95% smart mineral facies component: sepiolite 95%, talcum＜1%, quartzy＜4%, Fig. 1 is seen in the contrast of the pure sepiolite X of this concentrate and Spain diffraction analysis.
Description of drawings:
The pure sepiolite X of figure concentrate product and Spain diffraction analysis contrast figure
(1) this test enriched products
(2) the pure sepiolite of Spain
Claims (8)
1, a kind of sepiolite beneficiation method, the invention is characterized in sepiolite is soaked slurrying, put into dispersion machine, in dispersion machine, add waterglass (or mixture of waterglass and a small amount of calgon) then and carry out first section dispersion, time is 2～10 minutes, add for the second time waterglass again, mixing carries out the sedimentation first time and removes slag after 2～3 minutes, with the upper strata suspension second section dispersion of beginning in dispersion machine again that is obtained, the time is 5～25 minutes, add waterglass more for the third time, mixing carried out second sedimentation in 2～3 minutes and removes slag, and the upper strata suspension of Huo Deing is the sepiolite concentrate slurry once more, and this concentrate slurry is made Separation of Solid and Liquid, drying gets the sepiolite concentrate.
2, a kind of sepiolite beneficiation method, the invention is characterized in sepiolite is soaked slurrying, put into dispersion machine, in dispersion machine, add waterglass (or mixture of waterglass and a small amount of calgon) then and carried out high speed dispersion 5～20 minutes, add for the second time waterglass again, mixing carries out the sedimentation first time and removes slag after 2～3 minutes, the upper strata suspension that is obtained is added waterglass more for the third time, mixing 2～3 minutes, carry out the sedimentation second time and remove slag, the upper strata suspension of Huo Deing is the sepiolite concentrate slurry once more, and this concentrate slurry is made Separation of Solid and Liquid, drying gets the sepiolite concentrate.
3, sepiolite beneficiation method according to claim 1 and 2 is characterized in that the sepiolite raw ore by soaking slurrying in 1: 9～1: 7.
4, sepiolite beneficiation method according to claim 1 and 2, it is characterized in that first section, to be dispersed in the waterglass that adds in the dispersion machine be 10～36 kilograms in raw ore per ton, adding waterglass raw ore per ton for the second time before the sedimentation is 4.5～11.5 kilograms.
5, sepiolite beneficiation method according to claim 1 and 2 is characterized in that sepiolite clay concentration is 10～15% in first section dispersion ore pulp.
6, sepiolite beneficiation method according to claim 1 is characterized in that placing after second section dispersion and adds waterglass for the third time before the sedimentation and make scattered inhibitor, and waterglass consumption raw ore per ton is 4.5～11.5 kilograms.
7, sepiolite beneficiation method according to claim 2 is characterized in that the sedimentation first time upper strata suspension that is obtained that removes slag is added waterglass more for the third time, carries out the sedimentation second time and removes slag, and the amount raw ore per ton that adds waterglass is 6～13 kilograms.
8, a kind of sepiolite beneficiation method, the present invention is characterised in that sepiolite clay is soaked slurrying, puts into high speed dispersor, add waterglass then in dispersion machine, raw ore waterglass consumption per ton is 25～53 kilograms, disperses 2～3 minutes, add for the second time waterglass, raw ore waterglass consumption per ton is 6～15 kilograms, mixing 2～10 minutes, and the slurry that sinks removes slag, the upper strata suspension that is obtained is sepiolite concentrate liquid, concentrate slurry is made Separation of Solid and Liquid, and drying gets the sepiolite concentrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86106469A CN86106469B (en) | 1986-09-26 | 1986-09-26 | Industrial concentration method for sepiolite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86106469A CN86106469B (en) | 1986-09-26 | 1986-09-26 | Industrial concentration method for sepiolite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86106469A CN86106469A (en) | 1987-04-29 |
| CN86106469B true CN86106469B (en) | 1988-10-05 |
Family
ID=4803227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN86106469A Expired CN86106469B (en) | 1986-09-26 | 1986-09-26 | Industrial concentration method for sepiolite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN86106469B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101288857B (en) * | 2007-04-20 | 2011-03-16 | 湖南鸿雁海泡石科技有限公司 | Sepiolite purification technique |
| CN101829479B (en) * | 2010-05-31 | 2012-11-14 | 赵溶 | Hollow glass desiccant and production method thereof |
| CN102371208A (en) * | 2011-10-31 | 2012-03-14 | 湖南九华碳素高科有限公司 | Process for purifying low-grade sepiolite |
| CN105597679B (en) * | 2016-02-15 | 2018-06-19 | 苏州中材非金属矿工业设计研究院有限公司 | A kind of method that high-performance sorbing material is prepared with low-quality staple fiber sepiolite |
| CN107814388A (en) * | 2016-09-12 | 2018-03-20 | 先声药业有限公司 | A kind of preparation method of montmorillonite |
| CN112871434B (en) * | 2020-12-25 | 2022-11-29 | 湖南省地质测试研究院(国土资源部长沙矿产资源监督检测中心) | Method for sorting nano sepiolite |
-
1986
- 1986-09-26 CN CN86106469A patent/CN86106469B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CN86106469A (en) | 1987-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Grant | Abrasion pH, an index of chemical weathering | |
| CN106902975B (en) | A kind of substep desiliconization method for upgrading of high alumina high-silicon type bauxite | |
| CN101234366A (en) | Reverse flotation iron increase and silicon removing method for refractory limonite | |
| CN105478232A (en) | Mineral processing method for enriching vanadium pentoxide from graphite vanadium ore | |
| CN86106469B (en) | Industrial concentration method for sepiolite | |
| WO2019218295A1 (en) | Efficient purification method for high-silicon, high-calcium, high-iron and low-grade brucite | |
| CN110237937B (en) | Test method for realizing magnesite single-step reverse flotation desilication and decalcification | |
| Bulatovic et al. | Process development for impurity removal from a tin gravity concentrate | |
| CN109336126B (en) | Method for purifying high-iron low-grade kaolin | |
| CN103056035A (en) | Carbonate inhibitor and preparation method and application thereof | |
| CN107309075A (en) | Collophane beneficiation method | |
| Zhang et al. | The ultimate mineral processing challenge: Recovery of rare earths, phosphorus and uranium from Florida phosphatic clay | |
| CN109665535A (en) | One kind being directed to the bentonitic method of purification of middle-low grade | |
| RU2296624C2 (en) | Heat-and-power station ash-and-slack waste processing method | |
| CN1035448A (en) | The ore-dressing technique of FLOTATION SEPARATION bastnaesite and monazite | |
| CN114671440A (en) | Superconducting high-gradient magnetic separation high-silicon solid waste low-carbon green preparation of high-purity SiO2Method (2) | |
| US3827984A (en) | Precipitating agent for water purification processes,and a method of preparing same | |
| Jian | A novel depressor useful for flotation separation of diaspore and kaolinite | |
| CN86107171A (en) | The application of sulfomethylated derivative of calcium lignosulfonate in phosphate rock floating | |
| CN112619883A (en) | Method for preparing super-white glass material by purifying fine quartz sandstone | |
| CN113731644B (en) | Impurity removal method of magnesite ore washing, friction screening and asynchronous reverse flotation | |
| CN111250243A (en) | Beneficiation method for comprehensively recycling various products from low-grade kyanite ore | |
| Yalcin | Sedimentation Characteristics of Cu--Ni Mill Tailings and Thickener Size Estimation | |
| CN110369164B (en) | Beneficiation method for pre-enrichment of rubidium | |
| SU954372A1 (en) | Method of deironing boxites |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |