CN86103668Y - Meltblown and conformal materials used as seedbeds - Google Patents

Meltblown and conformal materials used as seedbeds

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CN86103668Y
CN86103668Y CN86103668 CN86103668Y CN 86103668 Y CN86103668 Y CN 86103668Y CN 86103668 CN86103668 CN 86103668 CN 86103668 Y CN86103668 Y CN 86103668Y
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meltblown
seeds
stream
polymer
article
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蒂莫西·莫里斯·麦克法兰
詹姆斯·约瑟夫·奥康纳
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金伯利-克拉克公司
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Abstract

本发明一般完成了提供一种熔喷材料的苗床,种子掺合在材料之中。最好除了掺合种子以外,还掺合有吸收剂材料,例如纤维素纤维和超级吸收剂材料(如水凝胶)。The present invention generally accomplishes the provision of a seedbed of meltblown material in which seeds are incorporated. Preferably, in addition to the seeds, absorbent materials such as cellulosic fibers and superabsorbent materials (eg, hydrogels) are also blended.

Description

[0001] 本发明涉及到以非织造物做为苗床的措施和应用。特别是涉及到提供熔喷物材料,这种材料已将种子和为萌发种子用的供养基质,例如肥料和超级吸收剂等掺合在一起。[0001] The present invention relates to measures and applications of nonwovens as seedbeds. In particular, it relates to the provision of meltblown materials that have blended seeds with a nutrient substrate for germinating the seeds, such as fertilizers and superabsorbents, and the like.

[0002] 黄麻纤维织造的和合成的结网用于侵蚀控制已有好几年了。平网难以使土壤充分固定,也难掌握,並在搁放时易被撕裂。闭式网太贵,並且是不可降解的,易被网下生长的草抬起,可被风把网从地上吹起,最终必须把它拿掉致使侵蚀控制失效。[0002] Jute fiber woven and synthetic netting has been used for erosion control for several years. Flat nets are difficult to adequately fix the soil, difficult to grasp, and prone to tearing when set aside. Closed nets are too expensive and are non-degradable, easily lifted by grass growing under the net, can be lifted from the ground by the wind, and must eventually be removed rendering erosion control ineffective.

[0003] 现有的网已被使用或已被建议应用于诸如公路的建造和维护、环境美化和露天采矿分离上。除了可能有某些环境美化类的应用以外,所有这些用途都要求一旦被网复盖的面积被设置以后不需要很多维护的系统。如果一种产品,它既会被充分降解,使植物充分发育,还可提供恒定的侵蚀控制,这将是最理想的。[0003] Existing nets have been used or have been proposed for applications such as construction and maintenance of roads, landscaping and separation of open pit mining. All of these uses, with the possible exception of certain landscaping-type applications, require a system that does not require much maintenance once the area covered by the net is set up. It would be ideal if a product would both be sufficiently degraded to allow full plant development and provide constant erosion control.

[0004] 美国专利3,315,408(Fisher)是一个早期用人工织造物供土壤侵蚀控制用的例子。尽管此专利建议使用不同类型的纱线,包括可生物降解的纱线,和含有待释放的药剂或物质(例如肥料、农药和除草剂等)的管形的或多孔芯的纱线,但此专利所讲的织造物材料具有织造物材料不足的缺点,需要有一定的柔软性,並且需是可编制的线。此外,所讲的此织造物並不具有足够的多方面适应性以提供一个完整的农业-园艺系统。[0004] U.S. Patent 3,315,408 (Fisher) is an early example of artificial woven fabrics for soil erosion control. Although this patent suggests the use of different types of yarns, including biodegradable yarns, and yarns with tubular or porous cores containing agents or substances to be released (eg, fertilizers, pesticides, herbicides, etc.) The woven material mentioned in the patent has the disadvantage of insufficient woven material, needs to have a certain flexibility, and needs to be a woven thread. Furthermore, the described fabric is not sufficiently versatile to provide a complete agro-horticultural system.

[0005] 与网型相反,其它类型的,使用材料薄板的覆盖料或地被物都已Contrary to the net type, other types of covering materials or ground coverings using material sheets have been

[0006] 公开,例如,美国专利3,205,619(Henry),美国专利3,303,323(Popa),美国专利3,467,142(Boyle),美国专利3,511,694(Lippoldt等人),美国专利3,427,194(Lippoldt等人),以及美国专利3,516,196(Lippoldt等人)。Henry,Popa,和Boyle等人的专利讲了利用这样一些薄板做灌溉或液体分流用。还有的建议把种子、杀真菌剂、肥料、杀虫剂、除莠剂和生长激素等都装到地被板上,用来促进草或其它植物的种植和生长。可参看美国专利3,557,491(Franklin等人),美国专利3,160,986(Watson等人)。然而在以前不可能提供这样的组分和适合要求的具有网眼结构的地面覆盖物,特别是具有足够的适应性和其它基本特征的地面覆盖物,为农业-园艺提供一完整系统。Disclosure, for example, U.S. Patent 3,205,619 (Henry), U.S. Patent 3,303,323 (Popa), U.S. Patent 3,467,142 (Boyle), U.S. Patent 3,511,694 (Lippoldt et al. al), U.S. Patent 3,427,194 (Lippoldt et al.), and U.S. Patent 3,516,196 (Lippoldt et al.). The Henry, Popa, and Boyle et al. patents teach the use of such sheets for irrigation or liquid diversion. Others suggest placing seeds, fungicides, fertilizers, pesticides, herbicides and growth hormones on the floor covering to promote the planting and growth of grasses or other plants. See U.S. Patent 3,557,491 (Franklin et al.), U.S. Patent 3,160,986 (Watson et al.). However, it has not been previously possible to provide such a composition and a floor covering with a mesh structure suitable for the requirements, especially a floor covering with sufficient adaptability and other essential characteristics, to provide a complete system for agro-horticulture.

[0007] 美国专利3,848,359(Seitn等人)公开了用于侵蚀控制环境美化和其它农业用途的编织覆盖物。公开了在这种织造物中可含有一个可降解的种子袋。此产品的缺点是,成形很复杂,再有,种子袋不易保留水份,必须被固定到织造物上,和容易移位。[0007] U.S. Patent 3,848,359 (Seitn et al.) discloses woven mulch for erosion control landscaping and other agricultural uses. It is disclosed that a degradable seed bag may be included in the fabric. The disadvantage of this product is that it is complicated to form, and furthermore, the seed bag does not retain moisture easily, must be fastened to the fabric, and is easily displaced.

[0008] 美国专利4,429,001(Kolpan)和英国专利申请GB2,113,731(Minto等人)公开了在熔喷基质中使用强吸收剂物质做成一吸附层。在英国专利申请中公开了吸收剂材料可以是粘土,海绵或超级吸收剂。U.S. Patent No. 4,429,001 (Kolpan) and British Patent Application GB2,113,731 (Minto et al.) disclose the use of strong absorbent materials in meltblown substrates to make an adsorbent layer. It is disclosed in the UK patent application that the absorbent material may be clay, sponge or superabsorbent.

[0009] 美国专利4,100,324(Anderson等人)公开了用聚合物纤维和纤维素纤维的熔喷混合体制成一种非织造物。[0009] U.S. Patent No. 4,100,324 (Anderson et al.) discloses a nonwoven made from a meltblown blend of polymeric fibers and cellulosic fibers.

[0010] 仍然需要一种农业上用的织造物,它在播种期将是稳定的,在一There remains a need for an agriculturally useful woven fabric that will be stable during sowing

[0011] 合理的时间范围内被降解,並进一步在萌发和抽芽期将给种子提供保护和营养。[0011] Degraded within a reasonable time frame, and further will provide protection and nutrition to the seeds during germination and germination.

[0012] 本发明的一个目的是克服以前的人工材料、工艺过程和设备的缺点。One object of the present invention is to overcome the shortcomings of previous artificial materials, processes and equipment.

[0013] 本发明的另一个目的是提供一种人工苗床或覆盖物,它比以前的苗床更少需要浇水。Another object of the present invention is to provide an artificial seedbed or mulch that requires less watering than previous seedbeds.

[0014] 本发明的再一个目的是为制做人工苗床提供一种低成本的工艺过程和设备。Another object of the present invention is to provide a kind of low-cost technological process and equipment for making artificial seedbed.

[0015] 本发明的这些目的和其它目的都可以由提供一种已有种子掺合在其中的熔喷物材料来实现。除了掺合种子之外,最好还掺有吸收剂材料,例如纤维素纤维和超级吸收剂材料(如水凝胶)等。此外,最好熔喷聚合物能受太阳光和/或土壤中水的作用而降解。These and other objects of the present invention can be achieved by providing a meltblown material in which existing seeds are blended. In addition to the blended seeds, absorbent materials such as cellulosic fibers and superabsorbent materials (eg, hydrogels) and the like are preferably blended. Additionally, it is preferred that the meltblown polymer be degraded by sunlight and/or water in the soil.

[0016] 本发明的特别优先的形式在于制品是用一种设备和工艺过程做出的,在其中产生空气成形的聚烯烃纤维和纤维素纤维的结构,並在成形过程中将种子和超级吸收剂颗粒掺在其中。这种形式下生产的制品含有嵌入到非织造熔喷材料的膨松结构中的种子,种子在那里可自由地抽芽,且不易被摇松或被鸟啄去。A particularly preferred form of the present invention is that the article is made with an apparatus and process in which a structure of air-formed polyolefin fibers and cellulosic fibers is created and in which seeds and superabsorbents are formed granules are incorporated into it. Articles produced in this form contain seeds embedded in the lofty structure of the nonwoven meltblown material, where the seeds are free to germinate and not easily shake loose or be pecked by birds.

[0017] 附图简要说明Brief description of drawings

[0018] 图1是本发明的一种制品的横截面片断。1 is a cross-sectional fragment of an article of the present invention.

[0019] 图2是本发明的一种制品在抽芽之后的横截面片断。Figure 2 is a cross-sectional fragment of a product of the present invention after germination.

[0020] 图3是为本发明制品的成形设备的图解说明。[0020] FIG. 3 is a diagrammatic illustration of an apparatus for forming an article of the present invention.

[0021] 图4是按照本发明为制做一种多层制品的成形设备的图解说明。4 is a schematic illustration of a forming apparatus for making a multilayer article in accordance with the present invention.

[0022] 图5、6和7都是按照本发明的多层制品的横截面片断。[0022] Figures 5, 6 and 7 are cross-sectional fragments of a multilayer article according to the present invention.

[0023] 图8是按照本发明的另一种成形设备的图解说明。[0023] FIG. 8 is a diagrammatic illustration of another forming apparatus in accordance with the present invention.

[0024] 图9和10都是按照本发明的多层制品的横截面片断,这些也可以在图8的设备上制做。[0024] FIGS. 9 and 10 are cross-sectional fragments of multilayer articles according to the present invention, which can also be made on the apparatus of FIG. 8 .

[0025] 实现本发明的模式MODE FOR IMPLEMENTING THE INVENTION

[0026] 本发明的设备、工艺过程和制品都具有许多优点,远远超过已有的那些方法、设备和制品。用本发明制成的人工苗床可以保证使种子分散均匀。因为种子是嵌入材料中的,所以将不会从苗床上被冲走。本发明的制品在播种后並不需要任何覆盖物以预防干涸。此外,由于不需要稻草或其它材料,所以就减少了使用这些材料时被吹得到处皆是,弄得很难看的问题。本发明另一个优点是当种子处于萌发时期为防鸟提供了条件。本发明的材料将进一步被迅速降解,这种降解作用可由所用聚合物的结构来控制。本发明减少了给苗床浇水的次数,並允许在陡坡地播种。此外,与使用草皮相比,大大改善了在背阴处的坡地上播种,因为草场上的草在阴面生长不好。本材料的重量很轻,放下去播种比用草皮要容易得多。本发明的制品还可以含有添加物,如杀虫剂或除莠剂以抑制杂草生长,甚至可以染色在草生长之前使之呈现草的外观。用超级吸收剂与草种配合,则长草季节可超越正常的秋季和春季的种植时间。本发明的这些优点和其它优点在以下的详述中将显得更加明显。[0026] The apparatus, process, and articles of manufacture of the present invention have many advantages over those of existing methods, apparatus, and articles of manufacture. The artificial seedbed made by the invention can ensure that the seeds are dispersed evenly. Because the seeds are embedded in the material, they will not be washed away from the seedbed. The product of the present invention does not require any covering to prevent drying out after sowing. In addition, since straw or other materials are not required, the problem of being blown all over the place and making them unsightly when using these materials is reduced. Another advantage of the present invention is that it provides conditions for bird protection when the seeds are in the germination stage. The materials of the present invention will further degrade rapidly, and this degradation can be controlled by the structure of the polymer used. The present invention reduces the number of times the seedbed is watered and allows sowing on steep slopes. In addition, sowing on slopes in the shade is greatly improved compared to using turf, where grass does not grow well on the shady side. The material is light in weight, and it is much easier to lay down and sow than to use sod. The articles of the present invention may also contain additives, such as pesticides or herbicides, to inhibit weed growth, and may even be dyed to give the grass the appearance of grass before it grows. Combined with grass seeds with superabsorbents, the long grass season can go beyond the normal fall and spring planting times. These and other advantages of the present invention will become more apparent from the detailed description that follows.

[0027] 图1是按照本发明的一个制品的横截面片断。图1的制品10是由空气成形的聚合物纤维12和木纤维14组成的网状物。制品10还含有种子16和超级吸收剂18。干的超级吸收剂18和种子16都被牢固地夹在纤维12和14的网内。用挤压后在空气成形时立即进行混合的方法使纤维12和14机械地结合在一起。热塑性聚合物和木浆纤维的混合物的熔喷方法是已知的,如在美国4,100,324[0027] FIG. 1 is a cross-sectional fragment of an article in accordance with the present invention. The article 10 of FIG. 1 is a web composed of air-formed polymer fibers 12 and wood fibers 14 . Article 10 also contains seeds 16 and superabsorbent 18. Both the dry superabsorbent 18 and the seed 16 are firmly trapped within the web of fibers 12 and 14 . Fibers 12 and 14 are mechanically bound together by mixing immediately after extrusion during air forming. Melt blowing of mixtures of thermoplastic polymers and wood pulp fibers is known, as in U.S. 4,100,324

[0028] (Anderson等人)所公开的那样,可参考。纤维素纤维和熔喷聚合物的空气一成形的结合体通称为共型。把超级吸收剂引入到熔喷混合材料中的一个系统是在美国1984,4月23日,申请的申请号为602,993号的专利中公开的,(发明者Mcfarland等人),这个是与本发明共同设计的,因此可参考。[0028] As disclosed in (Anderson et al.), cf. Air-formed combinations of cellulosic fibers and meltblown polymers are commonly referred to as coforms. A system for incorporating superabsorbents into meltblown blends is disclosed in U.S. Patent Application No. 602,993, filed on April 23, 1984, (Inventor Mcfarland et al.), which is related to The present invention was co-designed and is therefore hereby referenced.

[0029] 图2说明一种按照本发明的苗床20。种子24已经长出芽26和根28。根28穿入土壤30中。混合了的聚合物纤维32和木纤维34还没有降解到一个明显的程度。超级吸收剂18已吸收了水並膨胀了起来。2 illustrates a seedbed 20 according to the present invention. The seed 24 has grown a bud 26 and a root 28. The roots 28 penetrate into the soil 30 . The combined polymer fibers 32 and wood fibers 34 have not degraded to a significant degree. The superabsorbent 18 has absorbed the water and swelled.

[0030] 图3说明本发明的设备和工艺过程,它是由熔喷物挤压设备40组成,将熔喷物纤维44沉降到移动着的有小孔的传动带42上。挤压设备40包括一个聚合物加料斗46,聚合物被送入挤压装置48中。聚合物从中心喷管50中被挤压成一组细液流。这些细液流须经过由喷管口52和54来的高速空气流,这就使连续的液流断开並形成熔喷材料。紧接在喷管56之下,从喷管62将种子60投入到空气流中。通过鼓风机66把种子从贮存器64中吹出来。在种子装置下边有加入从喷管70中来的高级吸收剂68。超级吸收剂68是经鼓风机74从装料斗72引入的。紧接挤压喷管56下面加入由成纤器78来的脱落木纤维。虽然用图来说明时,种子、木纤维和超级吸收剂的各管口之间要有明显的距离,但是最好的装置是三个管口的位置安放得非常相近,紧接在熔喷挤压喷管56之下。由滚轮80把浆料引入成纤器78中,在这里把浆液打散並使之与由通道82来的空气流相会合,将纤维84吹到成形的材料流中,其中含有熔喷物81,超级吸收剂68和种子60。含有超级吸收剂68和种子60的熔喷Fig. 3 illustrates equipment and technological process of the present invention, and it is made up of melt-blown material extrusion equipment 40, and melt-blown material fiber 44 is settled on the moving belt 42 with small holes. The extrusion apparatus 40 includes a polymer feed hopper 46 into which the polymer is fed into an extrusion device 48 . The polymer is extruded from the central nozzle 50 into a series of thin streams. These thin streams must pass through the high velocity air flow from nozzle ports 52 and 54, which breaks the continuous stream and forms the meltblown material. Immediately below nozzle 56, seed 60 is injected from nozzle 62 into the air flow. Seeds are blown out of reservoir 64 by blower 66 . Underneath the seed unit is a high-grade absorbent 68 fed from a nozzle 70. Superabsorbent 68 is introduced from hopper 72 via blower 74 . Immediately below extrusion nozzle 56, the shed wood fibers from fiberizer 78 are added. Although there should be a clear distance between the nozzles of the seeds, wood fibers and superabsorbents, the best device is to place the three nozzles very close together, immediately after the meltblown extrusion. below the pressure nozzle 56 . The slurry is introduced by rollers 80 into fiberizer 78 where it is broken up and joined with the air stream from passage 82, blowing fibers 84 into the formed stream of material containing meltblown material 81 , Super Absorber 68 and Seed 60. Meltblown with Super Absorber 68 and Seed 60

[0031] 物被沉降到有小孔的传送带42上,用一排风扇装置44画出。由主动辊47和49移动的有小孔的传送带42将网板5输送到装置53上,在那里被卷成卷以备储存。为了供各种不同用途使用可将卷55再切割成一定大小。[0031] The material is settled onto a perforated conveyor belt 42, depicted with a row of fan units 44. A perforated conveyor belt 42 moved by drive rollers 47 and 49 transports the web 5 to a device 53 where it is wound into rolls for storage. The roll 55 may be recut to size for use in a variety of different applications.

[0032] 图4中所示的设备可用来说明,用本发明有可能对工艺过程、设备和产品做某些变化和修改。图4系统有三个熔喷挤压罐110,112,和114。如图所示,每一个罐装有一进料斗,为的是按照本发明加入特殊的材料。在图4的多功能系统中,利用罐110,112和114中任何的一到三个罐都可通过这些加料斗116,118,和120制成一种单层,双层或三层的产品。此外,每一个罐中可以装一样的料或通过进料斗116,118,和120供应不同的添加料。值得注意的是在每一种情况下,成纤器122,124和126都是用来把脱落的纤维素纤维分别送到熔喷流128,130和132中。例如,挤压器110可以挤压熔喷的聚丙烯,脱落的木纤维将在134处加到其中。送料斗116将会供应超级吸收剂136,以使铺制成一种含有超级吸收剂140的单层熔喷物。然后单层的基质140将经过熔喷物挤压器112的下方,在把纤维素纤维144吹入熔喷物流130之前,紧接着在那里种子142将会被吹入熔喷流130中,熔喷物流130将被铺制成一层含有熔喷物146的种子层,在含有熔喷物140的超级吸收剂层之上。然后140和146的双层混合物会移至熔喷物加料斗114之下,在这里将会加入另一种聚丙烯132的熔喷流,紧接在加入脱落木纤维150之前把细粒的肥料148从这里加入。此熔喷物流132将被铺在前面的层146之上成为层152。这种三层的混合物含有用以[0032] The apparatus shown in FIG. 4 can be used to illustrate that certain changes and modifications to the process, equipment and products are possible with the present invention. The system of FIG. 4 has three meltblown extrusion tanks 110 , 112 , and 114 . As shown, each tank is equipped with a feed hopper for feeding specific materials in accordance with the present invention. In the multifunctional system of FIG. 4, any one to three of tanks 110, 112, and 114 can be used to make a single-layer, double-layer, or three-layer product through the hoppers 116, 118, and 120. . In addition, each tank can be filled with the same material or supplied with different additives through feed hoppers 116, 118, and 120. Notably, in each case, fiberizers 122, 124, and 126 are used to deliver shed cellulosic fibers to meltblown streams 128, 130, and 132, respectively. For example, extruder 110 may extrude meltblown polypropylene to which shed wood fibers will be added at 134 . The hopper 116 will supply the superabsorbent 136 so that the layup is a single layer meltblown containing the superabsorbent 140 . The single layer of matrix 140 will then pass under the meltblown extruder 112, before blowing the cellulosic fibers 144 into the meltblown stream 130, where the seeds 142 will be blown into the meltblown stream 130, where the The spray stream 130 will be spread as a seed layer containing the meltblown 146 on top of the superabsorbent layer containing the meltblown 140 . The two-layer mixture of 140 and 146 will then move under the meltblown hopper 114 where another meltblown stream of polypropylene 132 will be added, and the fine-grained fertilizer will be added immediately prior to the addition of the shed wood fibers 150. 148 join from here. This meltblown stream 132 will be spread over the preceding layer 146 as layer 152 . This three-layer mixture contains

[0033] 保持湿度的超级吸收剂、种子、和为种子萌发用的肥料。然后可把由层140、层146和层152所形成的混合层156卷起或在脱离成形设备以后切割成适用的形状。並不是把种子、肥料、和超级吸收剂等配料非得在所示之处引入不可,以任何次序引入它们都是可以的。此外,在某些例子中,在每层都混合有种子、超级吸收剂和肥料,这可能会更好。开动熔喷物加料器110,仅制成共型或熔喷聚合物而不加入其它的特殊物质也是可能的。如果颗粒较小並且颗粒容易被风扇装置160吸下则这样做可能是有利的。颗粒似乎不大可能被下一个风扇162和164吸去,因为颗粒被收集在第一个形成层140中。Moisture-maintaining superabsorbent, seeds, and fertilizers for seed germination. The hybrid layer 156 formed from layers 140, 146, and 152 may then be rolled or cut to a suitable shape after being released from the forming equipment. It is not necessary to introduce ingredients such as seeds, fertilizers, and superabsorbents where indicated, they may be introduced in any order. Also, in some cases it may be better to have seeds, superabsorbent and fertilizer mixed in each layer. It is also possible to activate the meltblown material feeder 110 and only make the co-type or meltblown polymer without adding other special substances. This may be advantageous if the particles are small and easily sucked down by the fan arrangement 160 . It seems unlikely that the particles will be picked up by the next fans 162 and 164 because the particles are collected in the first cambium 140 .

[0034] 图5是由层140,层146和层152组成的本发明的一种板156的横截面。颗粒136是在最低层里的超级吸收剂。颗粒142是在中层146里的种子,而颗粒148是在最上层152里的肥料。[0034] FIG. 5 is a cross-section of a panel 156 of the present invention composed of layer 140, layer 146, and layer 152. Particles 136 are superabsorbent in the lowest layer. Particles 142 are seeds in the middle layer 146 and particles 148 are fertilizer in the uppermost layer 152 .

[0035] 图6的结构是按照本发明所制成的另一种双层的结构。图6的双层结构是用一个起始层170制成的,该层由脱落木纤维和熔喷材料组成。种子174和肥料176以及超级吸收剂178都从上层172加入。值得注意的是有些颗粒,例如种子175已迁移到低层,这是由于在成形时通过结构的空气将种子排出。图6的结构可以用两罐的成形系统来制做,也可以用象图4那样的系统,其中有一个罐不使用。[0035] The structure of FIG. 6 is another double-layer structure made according to the present invention. The two-layer structure of Figure 6 is made with a starting layer 170 consisting of exfoliated wood fibers and meltblown material. Seed 174 and fertilizer 176 and superabsorbent 178 are all added from upper layer 172 . It is worth noting that some particles, such as seeds 175, have migrated to the lower layers due to the air expelling the seeds through the structure while forming. The structure of Figure 6 can be made with a two-can forming system, or a system like that of Figure 4, in which one can is not used.

[0036] 图7是另一种替代的结构。在图7的结构中,上层180配有肥料184。中层182配有超级吸收剂186,而紧挨着地铺放的层188含有草籽190。由于上面的超级吸收剂使种子持续地保持湿润,所以这种结构是相当理想的。当种子萌发时供给种子的肥料是可溶型的。这种方式的另一个变化是上层的聚合物纤维192,可以做[0036] FIG. 7 is another alternative structure. In the structure of FIG. 7 , the upper layer 180 is provided with fertilizer 184 . The middle layer 182 is provided with superabsorbent 186 , while the next layer 188 contains grass seeds 190 . This structure is ideal since the superabsorbent above keeps the seeds constantly moist. The fertilizers supplied to the seeds when they germinate are of the soluble type. Another variation of this approach is the polymer fiber 192 of the upper layer, which can do

[0037] 成绿色聚合物被挤压出或者在使用前把浆染成绿色以提供一个在抽芽之前为一较令人喜爱的人工苗床。本发明的其它变化包括可以改变挤压罐的数目,颗粒投料管的数目、和添加料的变化。[0037] The greening polymer is extruded or the pulp is dyed green before use to provide an artificial seedbed that is more desirable prior to germination. Other variations of the present invention include variations in the number of squeeze tanks, the number of pellet feed tubes, and the addition of materials.

[0038] 按照本发明的另一种可替换的方式是图8的199设备。除了有两个颗粒送料器208和210之外,图8的设备相当于图4的。此外还装备有一个可渗透的基质材料194的原料槽192。送料器208和210适用于将颗粒200和202从颗粒储存装置204和206中输送到层140和146上面。这个系统特别适合于沉降那些太易损坏而不能投入到熔喷流中的种子。用于热敏材料的这些颗粒撒布器还可用来撒布活的热敏物质:如真菌孢子,酵母、幼虫、益虫卵或细菌等,为的是在苗床上做非化学性的有机病虫害控制。颗粒撒布器还适合于间歇地撒布着色剂或其它标记物,以便指示在所撒布材料的特性上的改变。图8的这种设备允许在添加料上形成很大的变化,无论是在三个熔喷物层中的每一层上,还是在两个熔喷物层之间。可以使用可渗透性的基质194做成容易处理並在成形时能减少添加料损失的基层。优良的可渗透性材料是一种纺粘型聚丙烯纤维基质。设备199可以在不使用某些添加料撒布器或者不用再外加基底层194的情况下工作。[0038] Another alternative in accordance with the present invention is the 199 device of FIG. 8 . The apparatus of FIG. 8 is equivalent to that of FIG. 4, except that there are two particle feeders 208 and 210. Furthermore, a feed tank 192 is provided with a permeable matrix material 194 . Feeders 208 and 210 are adapted to deliver particles 200 and 202 from particle storage devices 204 and 206 onto layers 140 and 146 . This system is particularly suitable for settling seeds that are too fragile to be thrown into the meltblown stream. These granular spreaders for heat-sensitive materials can also be used to spread live heat-sensitive substances such as fungal spores, yeast, larvae, eggs of beneficial insects or bacteria, etc., for non-chemical organic pest control in seedbeds. The particle spreader is also suitable for intermittently spreading a colorant or other marker to indicate changes in the properties of the material being spread. The apparatus of Figure 8 allows for a large variation in the additive, either in each of the three meltblown layers, or between two meltblown layers. The permeable substrate 194 can be used to provide a base layer that is easy to handle and reduces additive loss during forming. A good permeable material is a spunbond polypropylene fiber matrix. Apparatus 199 can operate without the use of certain additive dispensers or without additional base layer 194.

[0039] 图9和10是按照本发明所做出的制品的横截面。这些制品相似于图5和7的制品,但在两层之间具有由颗粒加料器208和210所加入的细粒材料。在图9中分层结构220有一个无添加料的共型222的基层,已把缓慢溶解的肥料大颗粒226施加到层222的表面224上。中层228是含有加入的超级吸收剂230的共型。已把种子234放置在层228表面上232处。顶层236是含有9 and 10 are cross-sections of articles made in accordance with the present invention. These articles are similar to the articles of Figures 5 and 7, but have fine particulate material added by particulate feeders 208 and 210 between the two layers. In FIG. 9 the layered structure 220 has a base layer of an additive-free conformal 222 to which the surface 224 of layer 222 has been applied with slowly dissolving fertilizer macroparticles 226. The middle layer 228 is a conformal type with superabsorbent 230 added. Seeds 234 have been placed 232 on the surface of layer 228. The top layer 236 is containing

[0040] 外加入的超级吸收剂238的典型。Typical of externally added superabsorbent 238.

[0041] 图10说明的是另一种三层结构240,它在一可渗透性的聚丙烯纺粘型材料241(例如用做菱形花纹衬板的材料)上做成的。底层242是一层熔喷聚丙烯纤维244。将缓慢生长的草种248从进料器208投放到层242和层246之间的界面245上,层246包含熔喷聚丙烯和木纤维之共型,超级吸收剂水凝胶250加入其中。经装料器210将快速生长的草种(例如一年生的黑麦草)投放到中层246与顶层254之间的界面252上,然后用层254覆盖这些种子,此层是由相同于层246的共型加上超级吸收剂256的颗粒所构成。混合层240是特别理想的,因为当慢速生长的草(例如兰草)缓慢生长时,快速生长的黑麦草将充做地被物。图8的设备可以用不同的方法操作,从而在结构上做出很大变化,在各层内,和在两层之间使用不同的添加料,以及用不同类型的浆料做为基底层。10 illustrates another three-layer structure 240, which is made on a permeable polypropylene spunbond material 241 (such as the material used for diamond backing). Bottom layer 242 is a layer of meltblown polypropylene fibers 244 . Slow growing grass seed 248 is dropped from feeder 208 onto interface 245 between layer 242 and layer 246 comprising a co-type of meltblown polypropylene and wood fibers to which superabsorbent hydrogel 250 is added. Fast-growing grass seeds (eg, annual ryegrass) are dropped onto the interface 252 between the middle layer 246 and the top layer 254 via the loader 210, and the seeds are then covered with the layer 254, which is composed of the same common layer as the layer 246. Type plus superabsorbent 256 particles. The mixed layer 240 is particularly desirable because the fast-growing ryegrass will act as ground cover when slow-growing grasses (eg, bluegrass) are slow-growing. The apparatus of Figure 8 can be operated in different ways, thereby making great changes in structure, using different additives within each layer, and between layers, and using different types of slurries as base layers.

[0042] 本发明中制做熔喷材料的聚合物原料可以是任何一种适宜的聚合物。最好是聚乙烯和聚丙烯,因为可以把它们制成可降解的形式。按已知的方式,可以用增加或减少紫外光抑制剂的方法来控制聚乙烯和聚丙烯的降解。此外,人们已经知道,象美国专利3,795,654所公开的那样做成一种含有可水溶的稳定剂的聚烯烃,此稳定剂将被水从聚烯烃中浸出,没有暴露在阳光下的线型聚烯烃则可以被水降解。可在本发明中使用的其它聚合物还有如聚酯类如尼龙类,在这里聚合物可以是非常缓慢降解的或不降解的。某些容易发生泄流的坡地上使用稳定性聚合物可能是有益的。The polymer raw material that makes meltblown material in the present invention can be any suitable polymer. Polyethylene and polypropylene are preferred as they can be made in a degradable form. Degradation of polyethylene and polypropylene can be controlled by increasing or decreasing UV inhibitors in a known manner. In addition, it is known to make a polyolefin as disclosed in U.S. Patent 3,795,654 containing a water-soluble stabilizer which will be leached from the polyolefin by water without exposure to sunlight. Linear polyolefins can be degraded by water. Other polymers that can be used in the present invention are also polyesters such as nylons, where the polymer may be very slowly degrading or not degrading. The use of stabilizing polymers may be beneficial on some slopes prone to leaks.

[0043] 任何适宜的添加料都可与非织选的熔喷聚合物和草种配料制成本发明的混合物。这些添加料有:颜料、农药(例如:二嗪农)、除莠[0043] Any suitable additives can be combined with the nonwoven meltblown polymer and grass seed furnish to make the mixtures of the present invention. These additives are: pigments, pesticides (eg diazinon), herbicides

[0044] 剂、杀真菌剂(例如环烷酸的铜盐)和灭鼠剂等。为使动物(例如狗或猫)远离新生长的植物还可添加气味防护剂。优先选用的添加料是超级吸收剂,尤其是水凝胶,因为它能给种子和肥料提供一个湿润的苗床以保证营养。[0044] agents, fungicides (such as copper salts of naphthenic acid) and rodenticides and the like. Odor repellants can also be added to keep animals (such as dogs or cats) away from new growth. The preferred additives are superabsorbents, especially hydrogels, because they provide a moist seedbed for seeds and fertilizers for nutrients.

[0045] 加到基质中的种子可以是任何所希望的类型。适合于用在地被物上的典型种子有费菜、车轴草、常春藤、野豌豆、和花类(例如天兰绣球属)的种子。最好的材料是草种,因为它广泛的生长,籽粒小,可用一般的颗粒供应系统处理。[0045] The seeds added to the substrate can be of any desired type. Typical seeds suitable for use on ground cover are fenugreek, clover, ivy, vetch, and flowers (eg, hydrangeas). The best material is grass seed because it grows widely and has a small kernel that can be handled by a typical pellet supply system.

[0046] 本发明的板产品在收集以后可以进一步处理,方法是通过热和压力进行压制来控制板的厚度。此外,板可被模压加工以增加其强度和耐磨性。[0046] After collection, the board product of the present invention can be further processed by pressing with heat and pressure to control the thickness of the board. In addition, the panels can be molded to increase their strength and wear resistance.

[0047] 吹送的纤维最好是微纤维,其直径平均小于约10微米,因为这样的纤维在纤维的每单位体积中可提供较多个点与颗粒接触。平均直径小于5甚至1微米的非常细的纤维也可以使用,特别是同很细小的种子或水凝胶颗粒一起使用。[0047] The blown fibers are preferably microfibers having an average diameter of less than about 10 microns because such fibers provide more points of contact with the particles per unit volume of the fiber. Very fine fibers with an average diameter of less than 5 or even 1 micron can also be used, especially with very fine seeds or hydrogel particles.

[0048] 超级吸收剂或水凝胶颗粒最好是能在压力下迅速吸收並保留大量的液体。较好的颗粒应包括:改良的淀粉、在美国专利3,981,100内叙述了这种样品、和含有亲水基的高分子量的丙烯酸聚合物。各种各样水可溶性的超级吸收剂颗粒都是在市场上很容易买到的,並且可吸收超过其本身重量20倍以上的水,而最好的可吸收超过其本身重量100倍的水。吸收剂的颗粒大小可以很不相同,但一般在约90微米到约425微米之间的较好,为的是能很好的保留在苗床上,并且在成形时容易掌握,不致于在环境中产生粉尘。[0048] The superabsorbent or hydrogel particles are preferably capable of rapidly absorbing and retaining large amounts of liquid under pressure. Preferred granules would include modified starch, such a sample as described in U.S. Patent 3,981,100, and high molecular weight acrylic polymers containing hydrophilic groups. A wide variety of water-soluble superabsorbent particles are readily available on the market and can absorb more than 20 times their weight in water, and the best can absorb more than 100 times their weight in water. The particle size of the absorbent can vary widely, but generally between about 90 microns and about 425 microns is preferred for good retention in the seedbed and easy handling during shaping so that it does not become sluggish in the environment. Generate dust.

[0049] 种子、超级吸收剂和其它材料的颗粒可以在任何合适之处被送入Particles of seeds, superabsorbents and other materials can be fed into any suitable place

[0050] 微纤维的熔喷流中。可以在熔喷纤维已稍固化的地方引入种子,这样可使种子不会受到高温破坏。然而既使熔喷流是有点熔化状,但是在熔喷时非常高的冷却速率将防止给种子实质性的破坏,因为冷却将在热能传递到並损伤到种子以前进行,种子一般用于的隔离外皮保护着。用机械力量足以把种子和其它的颗粒捕获,这种聚合物的结合料一般不需要把颗粒固定在应有的位置上。此外,象在图8中所说明的,吹送到空气流中的过碎的添加料可能会被沉降到两层之间。in a meltblown stream of microfibers. Seeds can be introduced where the meltblown fibers have been slightly solidified so that the seeds are not damaged by high temperatures. However, even though the meltblown stream is somewhat molten, very high cooling rates during meltblown will prevent substantial damage to the seed, since cooling will take place before the heat energy is transferred to and damaged the seed, which is typically used for isolation of The skin protects. Mechanically sufficient to capture seeds and other particles, such polymeric binders generally do not need to hold the particles in place. Furthermore, as illustrated in Figure 8, too finely divided additive blown into the air stream may settle between the two layers.

[0051] 如果需要本发明的人工铺料与其它产品相结合。可以做成带有纺粘布的混合铺料。事实上,这会是较理想的,因为在熔喷物成形过程中有时使用纺粘布做为载板。此外,也可以在组织基质或其它可渗透膜上做成。在组织或纺粘物基质上成形会减少超级吸收剂或草种通过成形空气系统时被排出到有小孔的传送带底下的可能。[0051] The artificial covering of the present invention is combined with other products if required. Can be made into a mix of spunbond fabrics. In fact, this would be desirable since spunbond is sometimes used as a carrier during meltblown formation. In addition, it can also be made on tissue matrices or other permeable membranes. Forming on a tissue or spunbond substrate reduces the likelihood of superabsorbent or grass seed being expelled under a perforated conveyor belt as it passes through the forming air system.

[0052] 可以各种不同的方式使用本发明的人工床。典型的是,将混合板固定在地上並浇水,直到草或其它种子抽了芽並生了根。熔喷材料和纤维素纤维将随之降解並散开。此外,也可将整捆的人工苗床浸湿並保持在特定温度下,直到已经开始萌发。然后可将其展开並铺放到地上以便更快地装备成地被物。这样一种工艺过程对在场地上播种会有好处,例如棒球场或者儿童游戏场,在这些地方使草快速生根长起来是特别合乎需要的。[0052] The artificial bed of the present invention can be used in various ways. Typically, the mixing board is held in the ground and watered until the grass or other seed sprouts and takes root. The meltblown material and cellulosic fibers will then degrade and disperse. Alternatively, whole bundles of artificial seedbeds can be soaked and kept at a specific temperature until germination has begun. It can then be unfolded and laid on the ground for quicker equipping into a cover. Such a process would be beneficial for sowing fields, such as baseball fields or children's playgrounds, where rapid rooting and growth of grass is particularly desirable.

[0053] 另外,可以使用此基质物作为装饰方法,例如用它复盖各种形像的物体並使草萌芽以造成一个有生命的雕塑品。[0053] In addition, this substrate can be used as a decorative method, such as covering various figurative objects and sprouting grass to create a living sculpture.

[0054] 本发明已经总地描述了将脱落木纤维从浆料中添加到熔喷料中,但另一方面也可以利用其它来源的纤维素纤维。典型的其它来源有落花生种子、泥炭藓、和白报纸等。这些以及其它的纤维素材料对于[0054] The present invention has generally described the addition of shed wood fibers from pulp to meltblown materials, but on the other hand cellulosic fibers from other sources may also be utilized. Typical other sources are groundnut seeds, peat moss, and white newspapers. These and other cellulosic materials are

[0055] 本发明都会是适合的,因为用它们的目的是提供一种吸收剂结构以及给基质一定的强度。[0055] The present invention would all be suitable because the purpose of their use is to provide an absorbent structure as well as to give the matrix some strength.

[0056] 由以上叙述可明显地看出,本发明的设备、工艺过程和制品在本发明的精神范围以内都可以有许多变化,本发明的范围仅以权利要求的范围为限。Can obviously find out from above description, equipment of the present invention, technological process and product all can have many changes within the spirit scope of the present invention, and the scope of the present invention is only limited by the scope of claims.

文件名称    页    行    补正前    补正后File Name Page Line Before Correction After Correction

说明书    2    2    3,303,323    3,302,323Instructions 2 2 3, 303, 323 3, 302, 323

14    Seitn    Seith14 Seitn Seith

6    2    网板5    网板516 2 stencils 5 stencils 51

9    7    草种    草种2559 7 Grass Seeds Grass Seeds 255

Claims (34)

1、由一种熔喷聚合物和多数种子组成的一种制品。1. A product consisting of a meltblown polymer and a plurality of seeds. 2、权利要求1的制品,还包含纤维素纤维。2. The article of claim 1, further comprising cellulosic fibers. 3、权利要求1的制品,还包含超级吸收剂。3. The article of claim 1, further comprising a superabsorbent. 4、权利要求1的制品,制品中含有许多层。4. The article of claim 1 comprising a plurality of layers. 5、权利要求1的制品,在制品的多层中每层内含有添加物。5. The article of claim 1 comprising an additive in each of the multiple layers of the article. 6、权利要求1的制品,该制品中还包含纤维素纤维和超级吸收剂。6. The article of claim 1 further comprising cellulosic fibers and a superabsorbent. 7、权利要求1的制品,所述制品中含有一种纺粘型聚合物材料的底板。7. The article of claim 1 comprising a base plate of a spunbond polymeric material. 8、权利要求1的制品,其中所述的熔喷聚合物是一种线型聚烯烃,并容易受日光或水的作用而降解。8. The article of claim 1 wherein said meltblown polymer is a linear polyolefin and is susceptible to degradation by sunlight or water. 9、权利要求1的制品,至少还含有一种从下列配料中选定的一种配料,这些配料包括:肥料、超级吸收剂、着色剂、除莠剂、杀真菌剂、灭鼠剂、防动物、细菌和孢子的气味防护剂。9. The article of claim 1 further comprising at least one ingredient selected from the group consisting of fertilizers, superabsorbents, colorants, herbicides, fungicides, rodenticides, Odor protectant for animals, bacteria and spores. 10、制做人工生长床的工艺过程,特征在于它包括至少熔喷一种聚合物材料流並将种子沉降到该熔喷材料中。10. A process for making an artificial growth bed, characterized in that it comprises at least meltblowing a stream of a polymer material and depositing seeds into the meltblown material. 11、权利要求10的工艺过程,还包括把种子和超级吸收剂引入到所述形成的流中。11. The process of claim 10, further comprising introducing seeds and superabsorbent into said formed stream. 12、权利要求10的工艺过程,还包括把种子和天然吸收剂纤维引入到至少一种所述的聚合物材料流中。12. The process of claim 10, further comprising introducing seeds and natural absorbent fibers into at least one of said streams of polymeric material. 13、权利要求10的工艺过程,还包括至少两个制做熔喷多聚物的挤压罐和一条移动的有小孔的传送带,在传送带上收集熔喷物纤维。13. The process of claim 10, further comprising at least two extrusion tanks for making the meltblown polymer and a moving orifice conveyor on which the meltblown fibers are collected. 14、权利要求10的工艺过程,其中还有一种移动並有小孔的构件,用来收集熔喷材料。14. The process of claim 10 wherein there is also a moving and orifice member for collecting the meltblown material. 15、权利要求13的工艺过程,其中把不同的添加料引入到每一种聚合物流中。15. The process of claim 13 wherein different additives are introduced into each polymer stream. 16、权利要求10的工艺过程,其中所述过程包括:第一个罐用来制做含有纤维素纤维的熔喷材料,至少其它罐中的一个用来制做含有颗粒的熔喷材料,颗粒是在成形时引入到材料流中的,所述的颗粒在这里包括:种子、肥料、超级吸收剂、除莠剂、杀真菌剂、着色剂、和它们的混合物。16. The process of claim 10, wherein the process comprises: a first tank is used to make a meltblown material containing cellulosic fibers, at least one of the other tanks is used to make a meltblown material containing particles, the particles Introduced into the material stream at the time of forming, the particles here include: seeds, fertilizers, superabsorbents, herbicides, fungicides, colorants, and mixtures thereof. 17、权利要求10的工艺过程,其中所述的聚合物材料是一种线型聚烯烃,并容易受阳光而降解。17. The process of claim 10 wherein said polymeric material is a linear polyolefin and is susceptible to degradation by sunlight. 18、权利要求14的工艺过程,其中将可渗透的腹板在收集所述的熔喷材料以前,安置在有小孔的构件上。18. The process of claim 14 wherein a permeable web is placed on the apertured member prior to collecting said meltblown material. 19、制做混合制品的工艺过程,它包括提供第一条有脱落木纤维引入到其中的熔喷物的材料流。收集所述的第一条材料流来制做一种腹板,提供至少二分之一的熔喷聚合物的材料流,内含引入到其中的脱落木纤维,将所述熔喷物材料流的至少二分之一收集到该腹板上,並把种子加到至少一个收集腹板上及熔喷物流中。19. A process for making a hybrid product comprising providing a first stream of material having a meltblown into which shed wood fibers are introduced. Collecting the first stream of material to make a web, providing at least one-half of the stream of meltblown polymer containing the exfoliated wood fibers introduced therein, and converting the stream of meltblown material At least one-half of the seed is collected on the web, and the seed is added to at least one collection web and to the meltblown stream. 20、权利要求19的工艺过程,其中将所述的种子沉降到所述腹板的表面上,並用熔喷物材料覆盖,此材料是从至少二分之一的所述材料流中得到。20. The process of claim 19 wherein said seeds are deposited onto the surface of said web and covered with a meltblown material derived from at least one-half of said material stream. 21、权利要求19的工艺过程,包括将超级吸收剂加到至少一个所述收集腹板上和所述熔喷物流中。21. The process of claim 19 including adding a superabsorbent to at least one of said collection webs and to said meltblown stream. 22、权利要求19的工艺过程,包括将所述腹板收集到一个可渗透的纺粘型材料上。22. The process of claim 19 including collecting said webs on a permeable spunbond material. 23、为制做混合型熔喷物制品的设备,包括一个挤压装置,至少能形成一条熔喷材料流;一种投料装置,将纤维素纤维投入到至少一个所述熔喷物的材料流中;为把种子投入到至少一个所述熔喷材料所成形的流中的投料装置;以及收集熔喷聚合物材料、种子、和纤维素纤维的混合物的装置。23. Equipment for making mixed melt-blown products, including an extrusion device capable of forming at least one melt-blown material flow; a feeding device for feeding cellulose fibers into at least one material flow of the melt-blown product in; a feeding device for injecting seeds into at least one of the streams formed by said meltblown material; and a device for collecting the mixture of meltblown polymer material, seeds, and cellulosic fibers. 24、权利要求23的设备,包括多个为熔喷材料用的挤压装置,随后将熔喷材料沉降到相同移动的收集装置中。24. The apparatus of claim 23, comprising a plurality of extrusion devices for the meltblown material, followed by deposition of the meltblown material into the same moving collection device. 25、权利要求23的设备,包括投料装置,至少投入是下列配料中的一种,主要包括:超级吸收剂、肥料、和着色剂。25. The apparatus of claim 23, including a feeding device, at least one of the following ingredients, including superabsorbents, fertilizers, and colorants. 26、权利要求23的设备,其中所述的为投入种子和纤维素纤维的装置包括输送所述种子和超级吸收剂到一空气流中的装置。26. The apparatus of claim 23 wherein said means for introducing seeds and cellulosic fibers comprises means for delivering said seeds and superabsorbent into a stream of air. 27、权利要求23的设备,其中所述的收集装置是一条移动的有小孔的传送带。27. The apparatus of claim 23 wherein said collection means is a moving perforated conveyor belt. 28、为制做混合材料的设备,包括制做熔喷聚合物材料的装置和把种子加到所述熔喷物材料上的装置。28. Apparatus for making mixed materials, comprising means for making meltblown polymer materials and means for applying seeds to said meltblown material. 29、权利要求28的设备,其中所述的投放种子的装置包括一个撒布器,位于所述熔喷物材料的收集器之上。29. The apparatus of claim 28 wherein said means for distributing seed comprises a spreader positioned above said collector of meltblown material. 30、为萌发种子的一个工艺过程,包括提供一种苗床,其中含有熔喷聚合物,许多种子,把所述苗床放在一合适的基底上並湿润该苗床。30. A process for germinating seeds comprising providing a seedbed comprising a meltblown polymer, a plurality of seeds, placing said seedbed on a suitable substrate and moistening the seedbed. 31、权利要求30的工艺过程,其中所述的苗床还包含有超级吸收剂。31. The process of claim 30 wherein said seedbed further comprises a superabsorbent. 32、权利要求30的工艺过程,其中所述的苗床还至少含有一种选自以下的材料:超级吸收剂、着色剂、除莠剂、杀孢子-真菌剂、灭鼠剂、为防动物和细菌用的气味防护剂。32. The process of claim 30, wherein said seedbed further comprises at least one material selected from the group consisting of superabsorbents, colorants, herbicides, sporicidal-fungicides, rodenticides, anti-animal and Odor protectant for bacteria. 33、权利要求30的方法,其中所述的聚合物是紫外光可降解的聚丙烯。33. The method of claim 30 wherein said polymer is ultraviolet light degradable polypropylene. 34、权利要求30的方法,其中所述的苗床还含有脱落的木纤维。34. The method of claim 30 wherein said seedbed further contains exfoliated wood fibers.
CN86103668 1986-05-05 Meltblown and conformal materials used as seedbeds Expired CN86103668Y (en)

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CN86103668Y true CN86103668Y (en) 1986-11-05

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