CN86102129A - Novel high stability paraffin wax emulsions - Google Patents
Novel high stability paraffin wax emulsions Download PDFInfo
- Publication number
- CN86102129A CN86102129A CN 86102129 CN86102129A CN86102129A CN 86102129 A CN86102129 A CN 86102129A CN 86102129 CN86102129 CN 86102129 CN 86102129 A CN86102129 A CN 86102129A CN 86102129 A CN86102129 A CN 86102129A
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- CN
- China
- Prior art keywords
- emulsion
- paraffin wax
- emulsifying agent
- employed
- soxylat
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The present invention is a kind of paraffin wax emulsions that extensive use is arranged.It is main raw material with paraffin.Be equipped with a certain amount of poiser, new emulsifying agent and water are made emulsion with changing emulsion process mutually, can obtain the paraffin wax emulsions of particle below 1 μ m.This emulsion is difficult for layering, preserves easily, and film-forming at a lower temperature when handling fabric with its, thereby can give fabric water-fast and durability.
Description
The invention relates to the textile finishing paraffin emulsion.
The paraffin emulsion that is used for fiber, wood-based plate, paper and leather surface processing at present mainly makes with saponification method.For example: it is main raw material that the R072286 patent has been introduced with the paraffin wax, is equipped with poiser lipid acid, emulsifying agent soap-like matter, is emulsified into the method for liquid at a certain temperature.This emulsion particle is thick, and layering easily is difficult to prolonged preservation.P0185,566 patents are improved saponification method, and the tensio-active agent that has proposed the use Compositional type is done the method for emulsifying agent.But the raw material sources deficiency, used tetramethylolmethane monostearate Brij, the lauryl alcohol polyoxyethylene ether sulfate, internal cause does not have scale operation in China, is difficult to obtain.The emulsion that makes is in this way compared with actual needs, and is still stable inadequately.Cause does not have cation type emulsion, and can not be suitable for the needs that various printed fabrics is handled.
The invention provides a kind of paraffin emulsion of novel high stability.Tensio-active agent not of the same race is carried out composite, the screening, make cationic complexed surfactant and anionic complexed surfactant at last, this complexed surfactant is made the emulsifying agent of paraffin wax emulsion, emulsifying property is good, and raw material is easy to get, the stability of emulsion height.
The present invention is main raw material (molten some 52-60 ℃) with the paraffin wax, join a certain amount of poiser, emulsifying agent, at room temperature add reactor together, heating dissolves to 80-90 ℃, stirs with high speed agitator simultaneously, add hot water then, kept about 1.5 hours, and then at a lower temperature and catalyst mix, promptly made the paraffin emulsion of novel high stability.Wherein, paraffin wax accounts for the 10%-20% of emulsion total amount, and poiser accounts for the 1%-5% of emulsion total amount, and mixed emulsifier accounts for the 5%-12% of emulsion total amount, and water accounts for the 50%-75% of emulsion total amount.
Poiser of the present invention is a lipid acid, and emulsifying agent divides two kinds of cationic emulsifier and anionic emulsifier.
Cationic emulsifier is: by the lipophilicity nonionogenic tenside, hydrophilic non-ionic surfactant and cats product are formed.
Anionic emulsifier is: by the lipophilicity nonionogenic tenside, hydrophilic non-ionic surfactant and anion surfactant are formed.
The lipophilicity nonionogenic tenside that the present invention selects for use has: stearin, sorbitan oleate, sorbitol anhydride stearate etc.
The hydrophilic non-ionic surfactant that the present invention selects for use has: nonylphenol Soxylat A 25-7, Span-20 Soxylat A 25-7, sorbitan monostearate Soxylat A 25-7, sorbitan monooleate Soxylat A 25-7.
The anion surfactant that the present invention selects for use is the alkylsurfuric acid of 8-18, alkylsulphonic acid, alkyl benzene sulphonate (ABS) and their sodium salt thereof, sylvite, ammonium salt.
The cats product that the present invention selects for use is a quaternary amine, and general formula is (RnN(CH
3)
3) X (Rn(Rm) N(CH
3)
3) X, (RnN(CH
3)
2CH
2 ) X, (Rn-
) X(n=12-18m=3-12, n, m can be identical also can be inequality, R is aliphatic hydrocarbon, X is a chlorine or bromine).
It should be noted: the various compositions in the above cited emulsifying agent, when the preparation emulsion, can choose any one kind of them, make the high stability paraffin wax emulsion of indication of the present invention with paraffin wax, poiser, catalyzer.
The paraffin emulsion that the present invention is prepared, outward appearance are blue streak white, emulsion particle below 1 μ m, with 3000 rev/mins of whizzers separate 1 hour not stratified.Because its particle is little,, handle the fabric good film-forming property so dispersing property is good, give baking, baking temperature is low, both can save the energy, can give fabric water-fast and durability again, since it can make cationic can make again cationic, so can be fit to the processing of each type dye fabric.
Be embodiments of the invention below.
Embodiment 1: get paraffin wax 17 grams, stearic acid 2 grams, glyceryl stearate 2 grams (lipophilicity), Soxylat A 25-7 5 grams (wetting ability), dodecyl dimethyl benzyl ammonia chloride 1 gram (positively charged ion), at room temperature put into the acid proof enamel reactor that has agitator together, heating and melting, in the time of 80 ℃-90 ℃, slowly add 40 gram water, stir simultaneously, adding along with external phase water, about about 1.5 hours, emulsion changed the O/W type into by w/o type gradually, after transformation is finished mutually, adding 30-35 gram water with fast speed, promptly is the cationic emulsion of indication of the present invention.
Embodiment 2: get paraffin wax 17 grams, stearic acid 2 grams, stearate Soxylat A 25-7 5 grams (wetting ability), sorbitan oleate 2 grams (lipophilicity), dodecyl benzyl dimethyl ammonium chloride 1 gram (positively charged ion) makes the cationic emulsion of O/W type by embodiment 1 method.
Embodiment 3: get paraffin wax 17 grams, stearic acid 2 grams, stearin 2 grams, (lipophilicity), sorbitan monooleate Soxylat A 25-7 5 grams (wetting ability), Sodium dodecylbenzene sulfonate 1 gram (negatively charged ion) makes O/W type anionic emulsion with embodiment 1 method.
Embodiment 4: get paraffin wax 17 grams, stearic acid 2 grams, 2 grams (lipophilicity), Soxylat A 25-7 5 grams (wetting ability), sodium laurylsulfonate 1 gram (negatively charged ion) make O/W anionic emulsion with same step.
Claims (2)
1, a kind of processing fabric that is applicable to, paper and leather, and be used for the paraffin emulsion of lubrication sdemoulding, by paraffin wax, poiser, emulsifying agent and water are formed, the invention is characterized in that employed lipophilicity nonionogenic tenside is stearin or sorbitol anhydride olein or sorbitol anhydride stearate etc. in the emulsifying agent, employed hydrophilic non-ionic surfactant has: the nonylphenol Soxylat A 25-7, Span-20 oxygen Vinyl Ether, the sorbitan monostearate Soxylat A 25-7, sorbitan monooleate Soxylat A 25-7 etc., employed anion surfactant is the alkylsurfuric acid of 8-18, alkylsulphonic acid, alkyl benzene sulphonate (ABS) and their sodium salt, sylvite, ammonium salt.Employed cats product is that quaternary amine, general formula are [RnN (CH
3)
3] X[Rn Rm N (CH
3)
3] X, [RnN (CH
3)
2CH
2 
] X, [Rn-N
] X (and X is chlorine or bromine, and R is an aliphatic hydrocarbon, n=12-8, m=8～18, n and m can be identical also can be inequality.
2, paraffin wax emulsion as claimed in claim 1 is characterized in that used compound emulsifying agent accounts for 5%～12% of emulsion total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86102129 CN86102129A (en) | 1986-04-01 | 1986-04-01 | Novel high stability paraffin wax emulsions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86102129 CN86102129A (en) | 1986-04-01 | 1986-04-01 | Novel high stability paraffin wax emulsions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN86102129A true CN86102129A (en) | 1987-02-11 |
Family
ID=4801622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 86102129 Pending CN86102129A (en) | 1986-04-01 | 1986-04-01 | Novel high stability paraffin wax emulsions |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN86102129A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064073C (en) * | 1996-02-29 | 2001-04-04 | 刘雁群 | Multipurpose emulsifying wax and its prepn. method |
| CN1306012C (en) * | 2002-02-01 | 2007-03-21 | 泰山学院 | High stability emulsified wax producing method |
| CN1668382B (en) * | 2002-07-31 | 2010-12-15 | 曼泰克株式会社 | Liquid spray unit, method for spraying liquid using it, and chemical preparation |
| CN102926287A (en) * | 2012-11-23 | 2013-02-13 | 张建新 | Preparation method for chitosan fruit moistureproof freshness protection package |
| CN103071425A (en) * | 2012-12-14 | 2013-05-01 | 江苏省海安石油化工厂 | Emulsifier |
| CN103341894A (en) * | 2013-07-22 | 2013-10-09 | 北京林业大学 | Paraffin-silane composite waterproofing agent and preparation method thereof |
| CN105121526A (en) * | 2013-04-19 | 2015-12-02 | 赢创德固赛有限公司 | Polyurethane foam with coarsening microcellular structure |
| CN106957533A (en) * | 2017-05-03 | 2017-07-18 | 吴子良 | A kind of paraffin wax emulsions and preparation method thereof |
| CN109487560A (en) * | 2018-11-22 | 2019-03-19 | 上海雅运新材料有限公司 | Complex wax microemulsion composition and its preparation method and application |
| CN111187642A (en) * | 2020-01-13 | 2020-05-22 | 嘉兴瑞勒新材料科技有限公司 | Production process of paraffin emulsion with high solid content |
| CN112064345A (en) * | 2020-09-14 | 2020-12-11 | 东华大学 | Processing method of special fabric for digital printing of textile coating |
-
1986
- 1986-04-01 CN CN 86102129 patent/CN86102129A/en active Pending
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1064073C (en) * | 1996-02-29 | 2001-04-04 | 刘雁群 | Multipurpose emulsifying wax and its prepn. method |
| CN1306012C (en) * | 2002-02-01 | 2007-03-21 | 泰山学院 | High stability emulsified wax producing method |
| CN1668382B (en) * | 2002-07-31 | 2010-12-15 | 曼泰克株式会社 | Liquid spray unit, method for spraying liquid using it, and chemical preparation |
| CN102926287A (en) * | 2012-11-23 | 2013-02-13 | 张建新 | Preparation method for chitosan fruit moistureproof freshness protection package |
| CN103071425A (en) * | 2012-12-14 | 2013-05-01 | 江苏省海安石油化工厂 | Emulsifier |
| CN105121526A (en) * | 2013-04-19 | 2015-12-02 | 赢创德固赛有限公司 | Polyurethane foam with coarsening microcellular structure |
| CN105121526B (en) * | 2013-04-19 | 2021-08-17 | 赢创运营有限公司 | Polyurethane foam with coarsened microcellular structure |
| CN103341894A (en) * | 2013-07-22 | 2013-10-09 | 北京林业大学 | Paraffin-silane composite waterproofing agent and preparation method thereof |
| CN103341894B (en) * | 2013-07-22 | 2016-01-20 | 北京林业大学 | A kind of paraffin-silane composite water-proof agent and preparation method thereof |
| CN106957533A (en) * | 2017-05-03 | 2017-07-18 | 吴子良 | A kind of paraffin wax emulsions and preparation method thereof |
| CN109487560A (en) * | 2018-11-22 | 2019-03-19 | 上海雅运新材料有限公司 | Complex wax microemulsion composition and its preparation method and application |
| CN109487560B (en) * | 2018-11-22 | 2021-06-08 | 太仓宝霓实业有限公司 | Composite wax microemulsion composition and preparation method and application thereof |
| CN111187642A (en) * | 2020-01-13 | 2020-05-22 | 嘉兴瑞勒新材料科技有限公司 | Production process of paraffin emulsion with high solid content |
| CN112064345A (en) * | 2020-09-14 | 2020-12-11 | 东华大学 | Processing method of special fabric for digital printing of textile coating |
| CN112064345B (en) * | 2020-09-14 | 2021-11-26 | 东华大学 | Processing method of special fabric for digital printing of textile coating |
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| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |