CN86101730A - Separation method of liquid film of static electricity and device thereof - Google Patents
Separation method of liquid film of static electricity and device thereof Download PDFInfo
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- CN86101730A CN86101730A CN 86101730 CN86101730A CN86101730A CN 86101730 A CN86101730 A CN 86101730A CN 86101730 CN86101730 CN 86101730 CN 86101730 A CN86101730 A CN 86101730A CN 86101730 A CN86101730 A CN 86101730A
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Abstract
The invention belongs to chemical separation technology, the specific solute in this technology energy separation, purifying and the concentrated aqueous solution is applicable to and extracts metal ion in the hydrometallurgy process (comprising nuclear fuel cycle), also is applicable to aspects such as wastewater treatment.It is the process that a kind of continuous extraction-reextraction is carried out simultaneously.In mass transport process, realize disperseing mutually by electrostatic field, after separation finished, the power of relying on for support realized being separated.It is few, quick, efficient, energy-conservation that this method is separated progression, and technological process is simple, is easy to realize serialization and automation.
Description
The present invention relates to a kind of chemical separation technology, the specific solute in this technology energy separation, purifying and the concentrated aqueous solution.Be applicable to that (comprising nuclear fuel cycle) in the hydrometallurgy process from the aqueous solution extracts useful metal, and be applicable to aspect such as wastewater treatment.
Solvent extraction technology is a kind of separation method that this century, the forties grew up, and has become the representative art of hydrometallurgy at present.Solvent extraction is made up of the extraction and two processes of stripping, because the separation process of every grade of extraction and reextraction is subjected to the restriction of chemical balance, so required separation progression is more, the consumption of reagent is bigger.In addition, the reagent entrainment loss is also relatively more serious.
Liquid film separating method is a kind of new technology that middle nineteen sixties grows up, and it also is made up of the extraction and two processes of stripping.But the extraction in the liquid film separating method is carried out simultaneously with two processes of stripping, this just broken solvent extraction process intrinsic extraction equilibrium, this nonequilibrium behavior of liquid film makes required separation progression reduce, and saved the consumption of reagent.
Liquid film technology can be divided into emulsion liquid membrane and support two kinds of liquid films by configuration.Emulsion liquid membrane is by propositions such as United States Patent (USP)s 3779907,4014785, its principle is, the aqueous solution that will contain reextraction reagent is made water in oil emulsion with the organic solution that contains extractant and surfactant, again this emulsion is remained the aqueous solution of extracting metals ion and mixes with containing, form the compound emulsion of water-oil-water type.In this system, the metal ion of aqueous phase sees through oil film and concentrates in disperseing aqueous phase continuously.After stopping to stir, water-in-oil emulsion promptly with continuous water layering.The mass transfer specific area of this method is big, and mass transport process is fast.But this method uses surfactant to stablize liquid film, and this has just increased operations such as system breast, breakdown of emulsion, makes whole process more complicated, is difficult to realize continued operation.
Supporting liquid film (ISEC, Membrane Extraction Session 12, P.80,1980) liquid film material (oil solution that promptly contains extractant) dipping hydrophobicity porosu solid film to be made, the porosu solid film here is the supporting mass of liquid film.This liquid film placed contain when remaining between the aqueous solution of extracting metals ion and the stripping workshop, metal ion just is extracted in the film in a side of film, is diffused into opposite side and is stripped in another aqueous solution in film.
The process of supporting liquid film is simple, is easy to realize serialization, but owing to adopt the porosu solid film to make supporting mass, resistance to mass tranfer is bigger.Simultaneously, the liquid film material is difficult to securely in the hole attached to support membrane, and promptly the stability problem of film is difficult to solve.
The object of the invention is to provide a kind of new separation method and device, and it can develop the characteristics of liquid Membrane Separation Technique non-equilibrium extraction, can overcome or improve the above-mentioned shortcoming of liquid film technology again.Its main feature is to utilize the hole that is positioned on the middle electrode of reactive tank, the oil solution of these electrode both sides can be flowed freely by hole, and utilize static phase dispersing mode that active force is directly put on and disperseed water droplet and do not make the violent turbulence of oil-continuous phase, on electrode, install water fender, effectively the water droplet of these electrode both sides is separated, thereby guaranteed the coupling of extraction and reextraction process in reactive tank inside.Above-mentioned feature embodies by following process: will contain and remain the aqueous solution of extract solutes and contact with the organic solution of being opened by the electrode separation of crack with holes and water fender that contains extractant respectively with aqueous solution of back extraction, organic solution can flow freely by hole, contain and remain the aqueous solution and the aqueous solution of back extraction of extract solutes and separated by water fender, the aqueous solution that will be in the organic facies with the high-voltage electrostatic field is dispersed into droplet, in the extraction side, treat that the solute in the aqueous phase extracted droplet is extracted to continuous organic facies, the complex compound that is generated is under the promotion of its concentration gradient, spread to the back extraction side by the electrode hole, in the back extraction side, solute by back extraction in the aqueous solution of back extraction droplet, extractant in the organic facies obtains regeneration continuously, extractant spreads back the extraction side by the electrode hole under the ordering about of its concentration gradient, so circulation is laterally being carried out the extracting-back extraction process of getting continuously.Meanwhile, above-mentioned two kinds of water droplets of extraction side and reextraction side are sinking in the organic facies respectively under the gravity effect continuously, form the extraction and the reextraction process of adverse current, the water droplet sinks to the bottom, breaks away from electrostatic field, with the organic facies layering, obtain raffinate and concentrate respectively.Because this method both belonged to non-equilibrium system, exempted system breast, breakdown of emulsion operation again, therefore, not only have fast, efficient, energy-saving advantages, and have that flow process is simple, process is easy to realize advantages such as serialization and automation.
Said process is to finish in the specific device of the present invention a kind of being suitable for.This device is the improvement to liquid film extraction equipment.
Fig. 1 is separation process principle of the present invention and device schematic diagram.
Fig. 2 is the structural representation of the electrode of band water fender.
Device among Fig. 1 comprises a reactive tank [1], and its top is separated into abstraction pool [3] and reextraction pond [4] by electrode [2], and its bottom is separated into extraction depositing reservoir [12] and back extraction depositing reservoir [14] by water-stop sheet [13]. Abstraction pool [3] and extraction depositing reservoir [12] are full communicating, and reextraction pond [4] and reextraction depositing reservoir [14] also are communicated with fully. Water-stop sheet [13] is bonded on reactive tank [1] base plate, and bonding with the groove two side, and bonding portion will guarantee not leak, and prevents that the both sides water from going here and there mutually.
Hole [5] is arranged on the electrode [2], and water fender [6] is housed, the organic solution in abstraction pool [3] and reextraction pond [4] can flow freely by hole [5], and is dispersed in abstraction pool [3] and reextraction Water droplet in the organic phase in pond [4] is but separated by water fender [6]. Electrode [2] consists of two pairs of electric fields with the electrode [7] that is contained in reactive tank [1] both sides and [8], is applied to respectively on abstraction pool [3] and reextraction pond [4].
Raffinate in the extraction depositing reservoir [12] is drawn by conduit [11], and the concentrate in the reextraction depositing reservoir [14] is drawn by conduit [15], and an end of conduit [11] and [15] links to each other with the bottom of extraction depositing reservoir [12] and reextraction depositing reservoir [14] respectively.
In order to prevent interelectrode short circuit, have at least one to be insulating electrode in every pair of electrode, bare electrode (being on-insulated electrode) is if using resistant material in Korrosionsmedium makes, as corrosion resistant plate etc.In order to keep higher electrode efficiency, the porosity on the electrode should be less than 40%.In order to shorten the distance of complex compound and extractant horizontal proliferation, improve mass-transfer efficiency, interelectrode distance is the smaller the better, takes into account the feasibility on the charge door frame for movement, and general optional interelectrode distance is 5～20mm.
Reactive tank [1], water fender [6] and water-stop sheet [13] are all made with insulating materials.
During work, the organic solution that will contain extractant is filled with reactive tank [1], and on abstraction pool [3] and reextraction pond [4], apply the ac high-voltage electrostatic field simultaneously, contain and remain the feed liquid of extract solutes and add abstraction pool [3] along the indicated direction of arrow [9], strip liquor adds reextraction pond [4] along direction shown in the arrow [10].
According to principles of electrostatics, the water droplet in the dielectric solution is outside under the effect of electric field, will produce induced dipole and distorts, and the distortion degree increases with the increase of electric-field intensity.When electric-field intensity surpasses a certain critical value, water droplet just is dispersed into countless droplets.The present invention adds the feed liquid of abstraction pool [3] and the strip liquor of reextraction pond [4] and is being dispersed into countless droplets respectively in the organic facies continuously under the effect of suitable high-voltage electrostatic field.In abstraction pool [3], treat that the solute in the aqueous phase extracted droplet is extracted to continuous organic facies, the complex compound in the organic facies spreads to reextraction pond [4] by the hole [5] on the electrode [2] under the promotion of the concentration gradient of himself continuously.In reextraction pond [4], when the solute in the continuous organic facies by after back extraction is in the strip aqueous droplet, extractant in the organic facies just obtains regeneration continuously, and the concentration gradient of extractant itself is ordered about it again and spread back abstraction pool [3] by the hole [5] on the electrode [2], proceeds said process.Meanwhile, the above-mentioned two kinds of water droplets in abstraction pool [3] and reextraction pond [4] are sinking in the organic facies respectively under the gravity effect continuously, form counter-current extraction and countercurrent reextraction and get process.Two kinds of water droplets sink to reactive tank [1] bottom and just break away from electrostatic field and enter extraction depositing reservoir [12] and reextraction depositing reservoir [14] respectively, then with the organic facies layering, and then obtain raffinate and concentrate.
Mixed liquor in the abstraction pool [3] has an interface with the raffinate of extraction depositing reservoir [12], and the height at this interface can be controlled by the height of delivery port of adjusting conduit [11].Equally, between the concentrate of mixed liquor in reextraction pond [4] and reextraction depositing reservoir [14] interface is arranged also, its height is controlled by the height of the delivery port of regulating conduit [15].
In sum, technology proposed by the invention, it has kept, and liquid film technology separation progression is few, and advantages such as reagent consumption province have been avoided the system breast in the emulsion liquid membrane technology, breakdown of emulsion operation again, make the process simplification and are easy to realize serialization and automation.It is compared with the supporting liquid film, because of having saved the porosu solid film as the liquid film supporting mass, thereby resistance to mass tranfer is greatly reduced, and has avoided the stability of film, the contamination of film, the problems such as obstruction of micropore.In addition, because present technique adopts electrostatic field to make water be dispersed into droplet, this phase dispersing mode is not realize under the situation of violent turbulence in continuous phase, so can adopt the water of simple water fender in will extracting and strip to separate in this technology.Save mechanical driving part in the static phase process for dispersing, simplified equipment, and obtained the good effect that energy consumption is low, the reagent entrainment loss is few.This is particularly suitable for the operation of handling radioactive liquid.
The embodiment of the invention is as follows:
Reactive tank [1] is square, and its appearance and size is that 40(is long) * 100(is wide) * the 150(height) mm, make with lucite.The wide 75mm of electrode [2], high 100mm in the middle of the reactive tank [1], this electrode is made with stainless steel material, and electrode [2] is supported by water-stop sheet [13], and hole [5] and water fender [6] are arranged on the electrode [2], hole [5] is highly to be the rectangle of 2mm, vertically arranges two span 12mm.The water fender position is shown in Fig. 2 [A] or Fig. 2 [B].Electrode [2] can be made into double-plate, and as Fig. 2 [A] or one-board, as Fig. 2 [B], the double-plate structure is complicated, but water fender [6] does not influence electrode efficiency.Electrode [7], [8] they are insulating electrode, make with the common metal material, and the polyester film of external pasting 0.05 * 2mm, and be separately fixed at the two side of reactive tank [1], can be screwed.Distance is 10mm between electrode [2] and electrode [7], [8], and electrode is connected on the adjustable high-voltage ac power.Water-stop sheet [13] separates raffinate and concentrate, makes with lucite.
Utilize said apparatus from the aqueous solution, to extract cobalt (Co).Feed liquid is for containing 1000ppmCo
2+With 0.1M CH
3The aqueous solution of COONa, its initial pH value transfers to 5.0.Anti-stripping agent is 1.0M H
2SO
4The aqueous solution.Organic facies is for containing the 10%(volume) the hydrogenation kerosin of di-(2-ethylhexyl)phosphoric acid (extractant).Apply voltage 3kV in the experiment, recording electric current is 650 μ A.The feed liquid flow is 150ml/h, and the anti-stripping agent flow is 10ml/h, and recording the time of staying of water droplet in electric field in the experiment is 4s.At last, the concentration that obtains cobalt in the raffinate is 5ppm, and the concentration of cobalt is near 15000ppm in the concentrate, and the concentration of cobalt is lower than 200ppm in the organic facies, and total enrichment factor is near 3000.
Claims (7)
1, a kind of method of from the aqueous solution, removing specific solute, belong to chemical separation technology, this method has the extraction and two processes of stripping, it is characterized in that to contain and remain the aqueous solution and the aqueous solution of back extraction of extract solutes and have the organic solution that contains extractant with electrode separation respectively and contact by crack with holes and water fender, the aqueous solution that adopts the high-voltage electrostatic field will be in the organic facies is dispersed into droplet, in the extraction side, treat that the solute in the aqueous phase extracted droplet is extracted to continuous organic facies, complex compound is under the promotion of its concentration gradient, hole by electrode spreads to the back extraction side, in the back extraction side, solute by back extraction in the stripping aqueous solution droplet, extractant in the organic facies obtains regeneration continuously, extractant spreads back the extraction side by the electrode hole under the ordering about of its concentration gradient, so circulation, the extracting-back extraction process of getting is laterally being carried out continuously, meanwhile, above-mentioned two kinds of water droplets of extraction side and back extraction side are under the gravity effect, sinking in the organic facies continuously respectively, form the extraction and the reextraction process of adverse current, the water droplet sinks to the bottom, breaks away from electrostatic field, with the organic facies layering, obtain raffinate and concentrate respectively.
2, separation method as claimed in claim 1 is characterized in that continuous phase is that dielectric constant is lower than 10 organic solution, and decentralized photo is that dielectric constant is higher than 80 the aqueous solution.
3, a kind of device of separation method of liquid film of static electricity, constitute by reactive tank, it is characterized in that the composed as follows of this device: reactive tank [1] is separated into abstraction pool [3] and reextraction pond [4] by electrode [2], electrode [2] is supported by water-stop sheet [13], water-stop sheet [13] is divided into extraction depositing reservoir [12] and reextraction depositing reservoir [14] to reactive tank [1] lower part, hole [5] and water fender [6] are arranged on the electrode [2], electrode [2] is with the electrode [7] in abstraction pool [3] and reextraction pond [4] and [8] constitute two pairs of electric fields respectively, having one in every pair of electric field at least is insulating electrode, be connected with a conduit [11] of drawing raffinate in extraction depositing reservoir [12] bottom, be connected with a conduit [15] of drawing concentrate, reactive tank [1] in back extraction depositing reservoir [14] bottom, water fender [6] and water-stop sheet [13] are made with insulating materials.
4, separator as claimed in claim 3 is characterized in that the hole on the middle electrode [2] of reactive tank [1] is a rectangle, and porosity is less than 40%.
5, as claim 3,4 described separators, it is characterized in that electrode [2] is a bare electrode, make with corrosion resistant metal material, as corrosion resistant plate, electrode [7], [8] they are insulating electrode.
6, as claim 3,4 described separators, the spacing that it is characterized in that two electrodes is 5～20mm.
7, separator as claimed in claim 5, the spacing that it is characterized in that two electrodes is 5～20mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86101730A CN86101730B (en) | 1986-03-19 | 1986-03-19 | Separation method of liquid film of static electricity and its device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86101730A CN86101730B (en) | 1986-03-19 | 1986-03-19 | Separation method of liquid film of static electricity and its device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86101730A true CN86101730A (en) | 1987-09-16 |
| CN86101730B CN86101730B (en) | 1987-09-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN86101730A Expired CN86101730B (en) | 1986-03-19 | 1986-03-19 | Separation method of liquid film of static electricity and its device |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034716C (en) * | 1992-09-03 | 1997-04-30 | 中国原子能科学研究院 | Electrostatic quasi-liquid membrane efficient concentration method |
| WO1997018880A1 (en) * | 1995-11-17 | 1997-05-29 | British Nuclear Fuels Plc | Extraction method and apparatus |
| WO1997040902A1 (en) * | 1996-04-30 | 1997-11-06 | British Nuclear Fuels Plc | Extraction method and apparatus |
| CN110745900A (en) * | 2019-11-04 | 2020-02-04 | 西安建筑科技大学 | Method for separating heavy metals chromium (VI) and cadmium (II) |
| CN112007381A (en) * | 2020-09-08 | 2020-12-01 | 绍兴市九鑫环保有限公司 | Continuous extraction device and extraction method for phosphorus-containing waste acid |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125664C (en) * | 2000-04-07 | 2003-10-29 | 清华大学 | Dispersive film extractor |
| CN1125665C (en) * | 2000-06-16 | 2003-10-29 | 清华大学 | In-line membrane extractor used in conjuction with electrospray mass spectroscope |
-
1986
- 1986-03-19 CN CN86101730A patent/CN86101730B/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1034716C (en) * | 1992-09-03 | 1997-04-30 | 中国原子能科学研究院 | Electrostatic quasi-liquid membrane efficient concentration method |
| WO1997018880A1 (en) * | 1995-11-17 | 1997-05-29 | British Nuclear Fuels Plc | Extraction method and apparatus |
| WO1997040902A1 (en) * | 1996-04-30 | 1997-11-06 | British Nuclear Fuels Plc | Extraction method and apparatus |
| CN110745900A (en) * | 2019-11-04 | 2020-02-04 | 西安建筑科技大学 | Method for separating heavy metals chromium (VI) and cadmium (II) |
| CN110745900B (en) * | 2019-11-04 | 2022-05-10 | 西安建筑科技大学 | Method for separating heavy metal hexavalent chromium and divalent cadmium |
| CN112007381A (en) * | 2020-09-08 | 2020-12-01 | 绍兴市九鑫环保有限公司 | Continuous extraction device and extraction method for phosphorus-containing waste acid |
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| Publication number | Publication date |
|---|---|
| CN86101730B (en) | 1987-09-23 |
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