CN86101637A - The manufacture method of the accelerating agent of petroleum fuel oils - Google Patents
The manufacture method of the accelerating agent of petroleum fuel oils Download PDFInfo
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- CN86101637A CN86101637A CN86101637.8A CN86101637A CN86101637A CN 86101637 A CN86101637 A CN 86101637A CN 86101637 A CN86101637 A CN 86101637A CN 86101637 A CN86101637 A CN 86101637A
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- accelerating agent
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Abstract
The present invention relates to the manufacture method of petroleum fuel oils accelerating agent, it is characterized in that 32 oxygenated compounds of the organic germanium more than the 1mmg/l are dissolved in the water, after in this solution, adding mixed alcohols, in this mixing solutions, add petroleum-type and tensio-active agent formation even mixed solution.The accelerating agent that adds the present invention can improve condensation rate, vaporization rate and the diffustivity of oil fuel, thereby improves rate of combustion, because the pollution of combustion chamber reduces, the solid substance quantity in the exhaust reduces greatly.
Description
The invention belongs to and make the industrial field of selling the oil fuel accelerating agent, the objective of the invention is in oil fuel, to add a small amount of this accelerating agent and reduce the incomplete combustion part as much as possible, thereby promote this fuel combustion.
As everyone knows, in the past in order to improve the efficiency of combustion of oil fuel, generally be to improve combustion engine, improve nozzle, or add oxygenant or add spraying etc.The former can improve the admixture of fuel and forced air or the flame transmission in when burning, makes exhaust complete, and the latter can be used in incendiary oxygen and can reasonably provide.
Yet the improvement of the shape of combustion chamber, nozzle form or inflow, outflow route shape is though can improve efficiency of combustion, but under the situation of high engine speeds rotation, only from the form of fluidic viscosity aspect, engine, its improvement is restricted, and this is the shortcoming of preceding kind of method.When utilizing additive such as oxygen to improve burning, be not only the quick uniform mixing difficulty of oxygenant, and the amount of oxygenant has delicate influence to ignition timing in the combustion chamber and compression ratio, therefore be difficult to control, addition is not general.(allowed band of addition is too narrow, determine addition according to the character of oil and the structure of engine), this is the shortcoming of a kind of method in back.
The present invention adds alcohols to make it into uniform mixing liquid with petroleum-type and tensio-active agent in the solution that contains organic germanium 32 oxygenated compounds, thereby can overcome above-mentioned existing shortcoming in the past.
The present invention is dissolved in 32 oxygenated compounds of the organic germanium more than the 1mmg/l in the water, in this solution, add mixed alcohols (containing oxidable and the reductive material) after, in this mixed solution, add petroleum-type and tensio-active agent and make it form homogeneous mixture solotion.
The amount of said organogermanium 32 oxygenated compounds, even think that 1mmg/l just has suitable effect, it is big more to measure more the multiple-effect fruit, has not just seen the raising of effect but surpass 200mmg/l.But all be considered to roughly usage range up to 1000mmg/l, on effect and economically, consider, preferably 50mmg/l～500mmg/l.
Alcohols is pressed methyl alcohol 20%, and the ratio of ethanol 80%, usage quantity are 900mml/ and even 300mml/l.The amount of alcohols in its expression 1, also harmless according to the blending ratio increase and decrease of other composition.The consumption of petroleum-type is 50mml/l to 400mml/l, and dosage of surfactant is 50mml/l to 300mml/l.The above-mentioned water yield is enough to dissolve organic germanium 32 oxygenated compounds just, according to the consumption of organic germanium and different, but generally uses 5mml/l～20mml/l.Affinity when improving organic germanium solution and petroleum-type uniform mixing, alcohols will mix in advance.Do not have resistance when adding petroleum-type and be the accelerating agent for mixing the present invention toward oil fuel in, adding tensio-active agent is in order to improve the dispersiveness of accelerating agent, it to be mixed fast and equably with fuel.The usage quantity of the present invention's accelerating agent is different with oil fuel, thinks that the consumption of 100ppm-1000ppm just can be obtained enough effects, adds about 500ppm just can achieve the desired result in the gasoline that petrol engine is used.
Think that the organic germanium that uses among the present invention can promote the sub-granular of fuel pellet, therefore, the contact area of inferring fuel particle and oxygen increases, and owing in the organic germanium active oxygen is arranged, thereby the flare point of oil fuel reduces, and improves combustionvelocity.Think that also owing to add the above the present invention's of specified amount accelerating agent, the condensation rate of oil fuel, vaporization rate and diffustivity all have significant improvement.
According to the present invention, organic germanium 32 oxygenated compounds are solution, can evenly spread in the oil, needn't worry the phenomenon of segregation and so on.Therefore think that when the present invention's accelerating agent was sneaked into oil fuel, the energy rapid diffusion was evenly sneaked into, thereby obtain the oil fuel of even matter.
Embodiment
100mmg organic germanium 32 oxygenated compounds are dissolved in the water of 10mml, in this solution, add alcohols (methyl alcohol 20%, ethanol 80%) and the stirring of 770mml, make homogeneous solution.100mml oil and 100mml tensio-active agent are slowly added stirring on one side in the above-mentioned solution on one side then, promptly make the present invention's accelerating agent 1000mml.
If above-mentioned accelerating agent is added in the oil fuel with the ratio of 100ppm～1000ppm, then improve efficiency of combustion 5%～10%, in oil engine, can increase output rating about 10%.
According to the present invention, then can be with in oil, being difficult to mixed uniformly organic germanium 32 oxygenated compounds, with the arbitrary proportion uniform mixing, and and oil fuel when mixing, no matter addition what, it all have can rapid diffusion character.
Additional experimental example 1
Accelerating agent: add the foregoing description goods 500ppm
Oil fuel: No. 1 light oil of Esso (ESSO) oil
10800 cards, proportion 0.8326
Engine: Isuzu Motors industry 6BD-type
Free air delivery: 5785cc
Output rating: 85ps/2100rpm
Torque capacity: 31kgm/1500rpm
Test method: press JIS-D-1005
By above-mentioned test, obtain following result.
And do not add
1) torque capacity 31kgm/1500rpm 32.5kgm/15
2) output rating 84.8ps/2096rpm 93ps/2107rpm
3) continuous operation
50 hours
Fuel disappear
Consumption 12.68l/h 12.12l/h
Illustrate below and use accelerating agent of the present invention and do not use the present invention
" gasoline automobile exhaust system test example " during accelerating agent and
" gasoline automobile exhaust and specific fuel consumption test-results comparison sheet ".
Gasoline automobile exhaust system test example-1(10 type and idle running)
(adding the occasion of accelerating agent)
Date of test: 1985.10.26, weather: fine, test unit: (wealth) Japanese car transportation technology association
Each parameter of automobile:
Car name: SUBARU pattern: E-AB4
License number: AB4-034436, purposes: riding
Number of strokes may: 38006km
Gross vehicle load: 1185kg
Test car weight: 1020kg
Inertia weight: 1000kg of equal value
Primover pattern: EA81 peak power output 100/5600ps/rpm
Circulation: 4, cylinder: 4, gross exhaust gas: 1780cc
Variator (automatically) is semi-automatic, manually, advances 3 sections
Reduction ratio: 3.77
Use fuel: lead-free standard oil
The tire air is pressed (standard): 1.8kg/Cm
2
" (actual measurement): 2.8kg/Cm
2
Testing apparatus
Chassis ergograph BANZAI BCD-100E type
Analysis of exhaust gas meter: (idle running exhaust system test) HoribaMEXA-8320 type
(10 types ") " "
The CVS device HoribaCVS-31 type (amount of taking 6.18m
3/ mm)
The idle running exhaust system test:
Room temp: 26.0 ℃ of temperature of cooling water: 82 ℃
Normal atmosphere: 763.0mmHg lubricating oil temperature: 94 ℃
Gear engine pressure of inspiration(Pi) measured value (NDIR) concentration correction value
Position rotation speed-mmHg
Degree rpm CO HC CO
2CO HC
N 660 453 0.01 11.7 10.6% 0.02 16.0
ppm% ppm ppm% ppm
D 550 410 ″ 10.0 ″ ″ 13.7
ppm ppm
10 type exhaust system tests:
Dry-bulb temperature in the testing laboratory: 26.0 ℃～26.0 ℃
" wet-bulb temperature: 16.0 ℃～16.0 ℃
" relative temperature: 34%
" normal atmosphere: 763.0mmHg
10 types turn round the zero hour: 10: 20
Specific fuel consumption: 12.1km/l
The KH(NOx humidity correction factor): 0.893
Test car warming-up zero hour: 9: 50
Temperature of cooling water: 82 ℃～82 ℃
Lubricating oil temperature: 94 ℃～94 ℃
Be equivalent to the negative 461mmHg(20km/h of chassis ergograph)
The engine pressure of inspiration(Pi) 453mmHg(40km/h of lotus)
414mmHg（60km/h）
Vapor pipe peristome static pressure difference: mmAq(40km/h)
The real concentration of diluted ambient is discharged
Composition exhaust concentration concentration A-(B * weight
A B （1-1/DF）〕
CO（NDIR） 29.0ppm 0.3ppm 28.71ppm 0.67g/km
HC（FID） 7.49ppmc 2.33ppmc 5.26ppmc 0.06g/km
NOx（CID） 9.47ppm 0.02ppm 9.45ppm 0.32g/km
CO
2（NDIR） 0.57% 0.03% 0.54% 195g/km
Remarks: normal, zero load speed of rotation (N) 800 ± 50
13 ° ± 3 °/800 ± 50BTDC/rpm of rpm ignition timing
Gasoline automobile exhaust system test example-2(10 type and idle running)
(adding the occasion of short fuel agent)
Test period: 1985.11.29. weather: fine, test unit: (wealth) Japanese car transportation technology association
Each parameter of automobile:
Car name: SUBARU pattern: E-AB4
License number: AB4-034436, purposes: riding
Number of strokes may: 38639km
Gross vehicle load: 1185kg
Test car weight: 1020kg
Inertia weight: 1000kg of equal value
Primover pattern: EA81, peak power: 100/5600ps/rpm
Circulation: 4, cylinder: 4, gross exhaust gas: 1780cc
Variator: (automatically) is semi-automatic, manually, advances 3 sections
Reduction ratio: 3.77
Use fuel: lead-free standard oil
The tire air is pressed (standard): 1.8kg/Cm
2
" (actual measurement): 2.7kg/Cm
2
Testing apparatus
Chassis ergograph BANZAI BCD-100E type
Analysis of exhaust gas meter: (idle running exhaust system test) MEXA-8320 type
(10 types ") " "
CVS device: the Horiba CVS-31 type (amount of taking: 6.18m
3/ mm)
The idle running exhaust system test
Room temp: 27.0 ℃ of temperature of cooling water: 86 ℃
Normal atmosphere: 751.7mmHg lubricating oil temperature: 105 ℃
Gear engine pressure of inspiration(Pi) measured value (NDIR) concentration correction value
Position rotation speed-mmHg
Degree rpm CO HC CO
2CO HC
N 750 472 0.01 21.0 8.6% 0.01% 35.3
ppm% ppm ppm% ppm
D 580 405 0.01 11.0 9.2% 0.01 17.3
ppm% ppm ppm% ppm
10 type exhaust system tests:
Dry-bulb temperature in the testing laboratory: 27.0 ℃～27.0 ℃
" wet-bulb temperature: 15.0 ℃～15.0 ℃
" relative temperature: 24%
" normal atmosphere: 751.7mmHg
10 types turn round the zero hour: 12: 00
Specific fuel consumption: 12.3Km/l
The KH(NOx humidity correction factor): 0.858
Test car warming-up zero hour: 11: 30
Temperature of cooling water: 86 ℃～86 ℃
Lubricating oil temperature: 105 ℃～105 ℃
Be equivalent to the negative 486mmHg(20Km/h of chassis ergograph)
The engine pressure of inspiration(Pi) of lotus: 459mmHg(40Km/h)
397mmHg（40Km/h）
Steam discharge pipe peristome static pressure difference: mmAq(40Km/h)
The real concentration of diluted ambient is discharged
Composition exhaust concentration concentration A-(B * weight
A B （1-1/DF）〕
CO（NDIR）18.6ppm 1.3ppm 17.36ppm 0.40g/Km
HC（FID）8.35ppmc 2.47ppmc 5.99ppmc 0.07g/Km
NOx（CLD）15.10ppm 0.09ppm 15.01ppm 0.48g/Km
CO
2（NDIR）0.58% 0.04ppm 0.54% 192g/Km
Remarks: normal, zero load speed of rotation (N) 800 ± 50
Rpm. 13 ° ± 3 °/800 ± 50BTDC/rpm of ignition timing
Gasoline automobile exhaust system test example-3(10 type and idle running)
(not adding the occasion of accelerating agent)
1985,8,02, weather date of test:: fine, test unit: (wealth) Japan
Automobile Transportation Technical Association
Each parameter of automobile
Car name: SUBARU pattern E-A84
License number: AB4-03446, purposes: riding
Number of strokes may: 35428Km
Gross vehicle load: 1185kg
Test car weight: 1020kg
Inertia weight: 1000kg of equal value
Primover pattern: EA81, peak power output 100/5600PS/rpm
Circulation: 4, cylinder: 4, gross exhaust gas 1780CC
Variator: 3.77
Use fuel: lead-free standard oil
The tire air is pressed (standard): 1.8kg/cm
2
(actual measurement): 1.8kg/cm
2
Testing apparatus
Chassis ergograph BANZAI BCD100E type
Analysis of exhaust gas meter: (idle running exhaust system test) Horiba MEXA-8320 type
(10 type exhaust system test) " "
The CVS device Horiba CVS-31 type (amount of taking 6.16m
3/ mm)
10 type exhaust system tests:
Dry-bulb temperature in the testing laboratory: 23.0 ℃～23.0 ℃
Wet-bulb temperature in the testing laboratory: 18.0 ℃～18.0 ℃
Relative temperature in the testing laboratory: 62%
Normal atmosphere in the testing laboratory: 752.5mmHg
10 types turn round the zero hour: 14: 40
Specific fuel consumption: 9.9km/l
The KH(NOx humidity correction factor): 1.006
Test car warming-up zero hour: 14: 00
Temperature of cooling water: 81 ℃～81 ℃
Lubricating oil temperature: 100 ℃～100 ℃
Be equivalent to chassis ergograph load 430mmHg(20km/h)
Engine pressure of inspiration(Pi) 435mmHg(40km/h)
402mmHg（60km/h）
Vapor pipe peristome static pressure difference: mmAg(40km/h)
The real concentration of diluted exhaust concentration environmental concentration is discharged weight
Composition A B A-(B * (1-1/DE))
CO（NDIR）480.0ppm 1.0ppm 479.05ppm 10.9g/km
HC（FID） 71.8ppmc 2.68ppmc 69.26ppmc 0.78g/km
NO
x（CLD） 1.55ppm 0.01ppm 1.54ppm 0.06g/km
CO
2（NDIR） 0.66% 0.04% 0.62% 220g/km
Remarks: normal, zero load speed of rotation (N) 800 ± 50rpm
Ignition timing 13 ± 3 ℃/800 ± 50 BTDC/rpm
Gasoline automobile exhaust and specific fuel consumption test-results
Comparison sheet (10 type)
Test unit: (wealth) Japanese car transportation technology association
Car name: SUBARU pattern: E-AB4
Circulation: 4 cylinders: 4
Peak power output: 100/5600ps/rpm purposes: riding
Gross exhaust gas: 1780CC variator: automatically
1985 1985 1985 date of test
November 29 October 26 August 2
Accelerating agent adds or does not add and add
Stroke state number of strokes may 35,428 38,006 38639
(Km) add back stroke distances 2,578 3211
Carbon monoxide CO 10.90 0.67 0.40
The hydrocarbon HC 0.78 0.06 0.07 of exhaust weight
(g/km) gross weight 11.68 0.73 0.47
Specific fuel consumption km/l 9.9 12.1 12.3
Raising rate 100 122.22 124.24
Exhaust gross weight g/l 115.63 8.83 5.78
Gradient 100-92.36-95.00
By above experimental result, can confirm aspect torque capacity, output rating and fuel consumption side, to have excellent results, and think that the pollution of fuel chambers reduces that the amount of the solids in the exhaust significantly reduces.
Claims (5)
1, the manufacture method of the accelerating agent of petroleum fuel oils, it is characterized in that 32 oxygenated compounds of the organic germanium more than the 1mmg/l are dissolved in the water, after in this solution, adding mixed alcohols, in this mixing solutions, add petroleum-type and tensio-active agent, thereby generate even mixed solution.
2, the manufacture method of the accelerating agent of petroleum fuel oils according to claim 1, the consumption that it is characterized in that organic germanium 32 oxygenated compounds is 1mmg/l to 1000mmg/l.
3, the manufacture method of the accelerating agent of petroleum fuel oils according to claim 1 is characterized in that the consumption of alcohols, and the ratio in methyl alcohol 20%, ethanol 80% is 900mml/l300mml/l.
4, the manufacture method of the accelerating agent of petroleum fuel oil according to claim 1, the consumption that it is characterized in that petroleum-type is 50mml/l to 400mml/l.
5, the manufacture method of the accelerating agent of petroleum fuel oil according to claim 1, the consumption that it is characterized in that tensio-active agent is 50mml/l to 300mml/l.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86101637 CN1011594B (en) | 1986-03-07 | 1986-03-14 | Method for preparing combustion improver of petroleum fuel oil |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/837,180 US4666458A (en) | 1984-09-03 | 1986-03-07 | Method of manufacturing a burning accelerator for fuel oils such as petroleum |
| CN 86101637 CN1011594B (en) | 1986-03-07 | 1986-03-14 | Method for preparing combustion improver of petroleum fuel oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86101637A true CN86101637A (en) | 1987-09-23 |
| CN1011594B CN1011594B (en) | 1991-02-13 |
Family
ID=25742183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 86101637 Expired CN1011594B (en) | 1986-03-07 | 1986-03-14 | Method for preparing combustion improver of petroleum fuel oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1011594B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190356A (en) * | 2016-07-12 | 2016-12-07 | 黑龙江金源仑特种纤维有限公司 | A kind of cracking hydrocarbon oil gas saver |
-
1986
- 1986-03-14 CN CN 86101637 patent/CN1011594B/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106190356A (en) * | 2016-07-12 | 2016-12-07 | 黑龙江金源仑特种纤维有限公司 | A kind of cracking hydrocarbon oil gas saver |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1011594B (en) | 1991-02-13 |
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