CN85107434A - A kind of bituminous composition - Google Patents

A kind of bituminous composition Download PDF

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Publication number
CN85107434A
CN85107434A CN85107434.0A CN85107434A CN85107434A CN 85107434 A CN85107434 A CN 85107434A CN 85107434 A CN85107434 A CN 85107434A CN 85107434 A CN85107434 A CN 85107434A
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CN
China
Prior art keywords
organic solvent
bituminous composition
liquid phase
pitch
propylene oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN85107434.0A
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Chinese (zh)
Other versions
CN1006300B (en
Inventor
于学敏
张宝钧
李自明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG CHEMICAL INST
Original Assignee
SHANDONG CHEMICAL INST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANDONG CHEMICAL INST filed Critical SHANDONG CHEMICAL INST
Priority to CN88100013A priority Critical patent/CN1006300B/en
Publication of CN85107434A publication Critical patent/CN85107434A/en
Publication of CN1006300B publication Critical patent/CN1006300B/en
Expired legal-status Critical Current

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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention utilizes the resulting liquid phase by product of chlorohydrination production propylene oxide process to make bituminous composition for organic solvent, and it consists of (weight %):
10-50 pitch
0-20 properties-correcting agent
The 0-20 weighting agent
The equal amount organic solvent

Description

A kind of bituminous composition
The invention belongs to the bituminous composition field.
The solvent-borne type bituminous composition is by solvent evaporates and dry and hard film forming.Therefore, in bituminous composition, be very important to choice of Solvent.It is related to the formation of filming, and influences the quality and the cost of coating.The solvent of bituminous composition generally adopts aliphatic hydrocarbon (as gasoline, hexanaphthene, normal heptane etc.) or aromatic hydrocarbon (as benzene,toluene,xylene etc.).These materials all are important Organic Chemicals, and price is more expensive.
Task of the present invention is exactly to seek the bituminous composition solvent that a kind of solubility property is good, evaporation rate is moderate, cheap and easy to get.
The liquid phase by product that chlorohydrination production propylene oxide process is produced is a kind of mixture.Its main component is propylene dichloride and dichloroisopropyl ether, and total content is greater than 90 percent.Up to now, these by products do not obtain reasonable use as yet, make it become the burden that chlorohydrination is produced this technology of propylene oxide.The present invention utilizes propylene dichloride and dichloroisopropyl ether that pitch, rubber and resin are had good solubility energy and the moderate characteristics of evaporation rate, made with pitch be base-material, with rubber or resin be properties-correcting agent, be weighting agent with the mineral substance, with the mixture of propylene dichloride and dichloroisopropyl ether or propylene dichloride or dichloroisopropyl ether bituminous composition as organic solvent.This bituminous composition contains (weight %):
10-50 pitch
0-20 properties-correcting agent
The 0-20 weighting agent
The equal amount organic solvent
The organic solvent that is adopted in the above-mentioned prescription is mixture or propylene dichloride or the dichloroisopropyl ether that mainly contains propylene dichloride, dichloroisopropyl ether.The properties-correcting agent that is adopted in the prescription is rubber (as natural rubber, chloroprene rubber, styrene-butadiene rubber(SBR), isoprene-isobutylene rubber, regenerated rubber etc.), or resin (as polystyrene, resol etc.).In order to further specify problem, introduce the preparation method below:
Pitch, rubber (or resin) are crushed to the fragment of diameter below 15 millimeters, in stirring tank with the liquid phase by product (mixture or propylene dichloride or the dichloroisopropyl ether that mainly contain propylene dichloride, dichloroisopropyl ether) of chlorohydrination production propylene oxide process with rubber (or resin) stirring and dissolving 24 hours at normal temperatures, after treating the rubber dissolving, add pitch again, continue to stir at normal temperatures tinning sealing after 24 hours, the bituminous composition product.
Embodiment:
Example one:
The weight % name of an article
25 No. 10 petroleum pitch
5 chloroprene rubbers
The liquid phase mixture of 70 by-products (mainly contains two
Chloropropane and dichloroisopropyl ether).
Example two:
The weight % name of an article
20 No. 10 petroleum pitch
The liquid phase mixture of 80 by-products (mainly contains dichloro third
Alkane and dichloroisopropyl ether)
Example three:
The weight % name of an article
23 pitches
7.7 rubber
69.3 propylene dichloride
Example four:
The weight % name of an article
23 pitches
7.7 polystyrene
69.5 dichloroisopropyl ether
Example five:
The weight % name of an article
25 pitches
5 chloroprene rubbers
35 toluene
The liquid phase mixture of 35 by-products (mainly contains dichloro third
Alkane and dichloroisopropyl ether)
Example six:
The weight % name of an article
23 pitches
7.7 rubber
30 dimethylbenzene
39.3 the liquid phase mixture of by-product (mainly contains dichloro third
Alkane and dichloroisopropyl ether)
Example seven:
The weight % name of an article
22.5 No. 60 petroleum pitch
22.5 No. 10 petroleum pitch
1 natural rubber
9 talcum powder
The liquid phase mixture of 45 by-products (mainly contains dichloro third
Alkane and dichloroisopropyl ether)
The technical feature of the bituminous composition that example one is made according to the present invention is:
Viscosity (being coated with cup No. 4) 93 seconds
Freeze-thaw-test: after freezing four hours, at room temperature soak four under negative 20 ℃
Hour, repeat 25 times and do not split.
Cohesive force:>2.2 kilograms per centimeter 2
Thermotolerance: 80 ℃ did not trickle in eight hours, 110 ℃ three hours not
Trickling.
Water-permeable: 2 kilograms per centimeter 2Pressure is above waterproof following half an hour.
Splitting resistance: when 6 millimeters cracks appear in test specimen plate face, film and do not split.
Resistance to acids and bases: soaked in 22 days the back do not have peel off, foaming, layering, wrinkling
Phenomenon.
More than these performances all above state-set standard.
The present invention has opened up an approach of making asphalt paint take the liquid phase accessory substance of chlorohydrination production propylene oxide process as solvent. This liquid phase accessory substance is the solvent that a kind of solubility property is good, evaporation rate is moderate, cheap and easy to get. According to the solvent load difference, it can be used as asphalt adhesive, pitch joint seal ointment or water-repellent paint, does not add the product of modifier and filler, is the adhesive bitument primer that construction is used. The present invention compares with other organic solvent type asphalt paints, and not only production technology is simple, and asphalt paint quality height the more important thing is that the production cost that can make coating reduces about 40%, has significant economic benefit. In addition, also make the liquid phase accessory substance of chlorohydrination production propylene oxide process find the approach of reasonable utilization, the change refuse is useful paint solvent, has obvious social benefit.

Claims (4)

1, a kind of is that base-material, rubber or resin are that properties-correcting agent, mineral substance are the organic solvent type coating of weighting agent with pitch.It is characterized in that its organic solvent adopts the liquid phase mixture of chlorohydrination production propylene oxide process by-product.
2,, it is characterized in that its organic solvent adopts the propylene dichloride in the liquid phase mixture of chlorohydrination production propylene oxide process by-product according to the described organic solvent type bituminous composition of claim 1.
3,, it is characterized in that its organic solvent adopts the dichloroisopropyl ether in the liquid phase mixture of chlorohydrination production propylene oxide process by-product according to the described organic solvent type bituminous composition of claim 1.
4, according to the described organic solvent type bituminous composition of claim 1, it is characterized in that containing (weight %):
10-50 pitch
0-20 properties-correcting agent
The 0-20 weighting agent
The equal amount organic solvent
Wherein organic solvent is mixture or the propylene dichloride or the dichloroisopropyl ether of propylene dichloride and dichloroisopropyl ether.
CN88100013A 1985-09-27 1985-09-27 Coating asphalt Expired CN1006300B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN88100013A CN1006300B (en) 1985-09-27 1985-09-27 Coating asphalt

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN88100013A CN1006300B (en) 1985-09-27 1985-09-27 Coating asphalt

Publications (2)

Publication Number Publication Date
CN85107434A true CN85107434A (en) 1987-04-08
CN1006300B CN1006300B (en) 1990-01-03

Family

ID=4795627

Family Applications (1)

Application Number Title Priority Date Filing Date
CN88100013A Expired CN1006300B (en) 1985-09-27 1985-09-27 Coating asphalt

Country Status (1)

Country Link
CN (1) CN1006300B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103102808A (en) * 2012-11-13 2013-05-15 益阳祥瑞科技有限公司 Asphalt chloroprene rubber coating
CN103525305A (en) * 2013-09-27 2014-01-22 吴润秀 Low-temperature anti-cracking asphalt phenolic coating
CN103555205A (en) * 2013-11-14 2014-02-05 黄石市汇波防腐技术有限公司 Asphalt-based flexible isolated layer material as well as production method thereof
CN103937407A (en) * 2013-01-22 2014-07-23 张秀君 Non-curing rubber asphalt waterproof paint
CN104073118A (en) * 2014-06-26 2014-10-01 重庆桓通建筑工程材料有限公司 Priming paint for non-inflammable marked line of pavement
CN104087167A (en) * 2014-06-18 2014-10-08 安徽先锋门业科技有限公司 Preparation method for solvent-type chloroprene-rubber-modified asphalt waterproof coating

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103102808A (en) * 2012-11-13 2013-05-15 益阳祥瑞科技有限公司 Asphalt chloroprene rubber coating
CN103937407A (en) * 2013-01-22 2014-07-23 张秀君 Non-curing rubber asphalt waterproof paint
CN103937407B (en) * 2013-01-22 2016-06-15 张秀君 Uncured rubber asphalt waterproof coating
CN103525305A (en) * 2013-09-27 2014-01-22 吴润秀 Low-temperature anti-cracking asphalt phenolic coating
CN103555205A (en) * 2013-11-14 2014-02-05 黄石市汇波防腐技术有限公司 Asphalt-based flexible isolated layer material as well as production method thereof
CN104087167A (en) * 2014-06-18 2014-10-08 安徽先锋门业科技有限公司 Preparation method for solvent-type chloroprene-rubber-modified asphalt waterproof coating
CN104073118A (en) * 2014-06-26 2014-10-01 重庆桓通建筑工程材料有限公司 Priming paint for non-inflammable marked line of pavement

Also Published As

Publication number Publication date
CN1006300B (en) 1990-01-03

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