CN85106542A - The injection moulding casting method of multi-layer bottomed parison - Google Patents

The injection moulding casting method of multi-layer bottomed parison Download PDF

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Publication number
CN85106542A
CN85106542A CN85106542.2A CN85106542A CN85106542A CN 85106542 A CN85106542 A CN 85106542A CN 85106542 A CN85106542 A CN 85106542A CN 85106542 A CN85106542 A CN 85106542A
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China
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molten resin
resin
layer
injection moulding
layers
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Expired - Lifetime
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CN85106542.2A
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Chinese (zh)
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CN1018899B (en
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中村喜则
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Nissei ASB Machine Co Ltd
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Nissei ASB Machine Co Ltd
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Priority to CN 85106542 priority Critical patent/CN1018899B/en
Publication of CN85106542A publication Critical patent/CN85106542A/en
Publication of CN1018899B publication Critical patent/CN1018899B/en
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Abstract

The invention provides a kind of injection moulding casting method of multi-layer bottomed parison.The method comprises: use the triple channel combining nozzle that has with concentric first melt canal that is communicated with of spray orifice, second melts body passage and the 3rd melts the body passage and communicates at the least significant end opening of the inboard first passage of spray orifice respectively, the innermost layer and the outermost layer of the die bed base that the resin that imports from first melt canal forms, the back cover parison of making can be four layers or five layers of section structure, and the resin that imports from second and third melt canal can form four layers of section structure back cover parison of an intermediate layer and a central core or five layers of section structure back cover parison of two intermediate layers and a central core.

Description

The injection moulding casting method of multi-layer bottomed parison
The invention relates to when blowing or orientation blow mollding manufacturing have four layers of synthetic resin container more than the wall, need be subjected to the injection moulding casting method of the multi-layer bottomed parison of injection moulding casting in advance.
Blowing or orientation blow mollding are made has certain thickness thin-walled synthetic resin container, and its wall part structure is made up of two-layer above thin-walled, and purpose is the defective for the synthetic resin that remedies the formation container, hear resistance for example, vapour lock etc.
In order to make the compound wall container, in general, preferably use a kind of resin as the intermediate layer, be injected between the another kind of resin, form a kind of three-decker material.Container promptly thus material make.This three layers of wall container constitute internal layer and skin by same resin, and constitute the intermediate layer by another kind of resin.This container can form with a kind of three layers of back cover parison blowing, and this parison then will be produced through the injection moulding casting with a kind of double-decker nozzle.
Yet both having made is in molten state, and when parison was subjected to the injection moulding casting, two kinds of different resins of use can be not bonded to each other yet, and externally can separate at an easy rate again under the pressure effect.
Therefore, in being full of the bottle of carbonated beverage or this class I liquid I, when infiltrating internal layer, carbonic acid gas, just weakened gas to outer field infiltration owing to inject the vapour lock that existence produced in the intermediate layer between the ectonexine., carbonic acid gas forms bubble so often being arrested between internal layer and the intermediate layer.
As a kind of way that prevents above-mentioned phenomenon: be to attempt to form two-layer adhesive layer to make five-layer structure on the both sides, intermediate layer.
The injection moulding of five layers of back cover parison is cast in the Japan Patent that application publication number is 56-501082 and introduces to some extent.The technology that this patent is introduced, be cast into the basis with three layers, comprising with three kinds of high polymers method of fusion input respectively, first kind of high polymer molten stream forms the interior surface layers of parison, second kind of high polymer forms outer surface layer, and the third high polymer then forms central core.If adopt five layers of casting, then use a kind of five-way road nozzle, the 4th kind of high polymer molten flow through nozzle introduce the 3rd with first kind of high polymer molten stream between, and the 5th kind of high polymer molten stream introduces the 3rd and between second kind of high polymer molten flow.
In above-mentioned conventional art, two kinds of different high polymer molten streams, be interior surface layers and the outer surface layer that first melt-flow of internal layer and outer field second melt-flow form parison, constitute other three layers the 3rd, the 4th, the 5th kind of high polymer molten stream imports between first and second melt-flow.Therefore, the multi-channel nozzle that this moment is used, its number of channels must equate with the melt-flow number of plies that the back cover parison requires.
Different with extruding casting nozzle is: no matter the melt-flow port number has what in the injection moulding casting nozzle, and finally all melt-flow all are incorporated in the same nozzle bore, and each the melt-flow passage that pushes in the casting nozzle all is in communication with the outside.Therefore, the number of melt-flow passage just is subjected to certain restriction in the injection moulding casting nozzle, because provide the melt-flow passage identical with the back cover parison number of plies very difficult in same nozzle, so also be difficult to cast five layers of back cover parison reliably with this nozzle.And, both allowed to obtain a kind of like this combining nozzle, even after the hollow container of five layers of uniform section has been made by blowing or orientation blow mollding, still needed special foundry engieering to come injection moulding casting back cover parison to prevent the minimizing of the thin-walled number of plies.
The present inventor is through research back discovery repeatedly, and above-mentioned technical problem can solve by using a kind of nozzle that has some melt-flow passage, and this nozzle can be used as the nozzle of injection moulding casting.
Therefore, first purpose of the present invention provides a kind of new method.This method uses three-channel nozzle injection moulding to cast the multi-layer bottomed parison with five layers or four layers section structure.
Another object of the present invention provides the method that multi-layer bottomed parison is cast in a kind of injection moulding, and the method not only can improve the vapour lock performance separately but also can improve hear resistance, or improves vapour lock and hear resistance simultaneously.
In order to reach above-mentioned target, feature of the present invention is to use three-channel nozzle, and nozzle has and concentric first melt canal that links to each other of spray orifice, and second and third passage is communicated with in the inboard of spray orifice, the end of first passage respectively.The resin of first passage forms the innermost layer and the outermost layer of back cover base, and the resin of second and third passage forms the central core of four layers of section back cover parison and central core and two intermediate layers of one deck central core or five layers of section back cover parison.
By the multi-layer bottomed parison of the present invention's casting, finally to make hollow container by blowing or orientation blow mollding.Therefore the resin of the present invention's use all is a thermoplastic resin.According to purposes by the container of back cover parison casting, the performance of resin and other, several resin-bonded that can generally be used for the container injection moulding are used, these resins have polyethylene terephthalate, vinyl chloride, polypropylene, Merlon, acrylonitrile, vinylidene chloride, polyamide, polyalkenyl alcohol, polystyrene, polyacetals etc.
According to injection moulding process of the present invention, it can also be five layers that the resin bed that forms the back cover parison can be four layers, and this depends on the injection moulding state of resin melt in the melt-flow passage of three-channel nozzle.
Melt-flow is injected from the bottom of back cover parison mold, and this situation with conventional back cover parison injection moulding casting is identical.Through three-channel nozzle, be subjected to the inlet of temperature controlled per share melt-flow at spray orifice through a cavity, under certain pressure, flow into core around.
According to the present invention, no matter in all case, at first import molten resin (being called " first molten resin " later on) and carry out injection moulding from first melt canal, the amount that remains to be charged into first molten resin of cavity changes with the resin kind of using.After first molten resin of scheduled volume had injected, the molten resin (being called " second molten resin " later on) that will import from second melt canal injected first molten resin again.Molten resin (being called " the 3rd molten resin " later on) with the 3rd melt canal injects second molten resin then.
By above-mentioned substep injection mode, the first fusion tool fat is divided into two strands by second molten resin in cavity, forms the innermost layer and the outermost layer of back cover parison.And the 3rd molten resin is divided into two intermediate layers with second molten resin, and last just to form with the 3rd molten resin be central core, and section is the back cover parison of five-layer structure.
And when second and third molten resin injected first molten resin simultaneously under certain pressure, the 3rd molten resin just can't be divided into two strands with second molten resin, but has formed the intermediate layer with second molten resin.The result makes the back cover parison of formation like this just have four layers of section structure.
In above-mentioned five layers of back cover parison, central core can be used as gas barrier layer or refractory layer.If four-layer structure, then two intermediate layers can be divided into a gas barrier layer and a refractory layer.The performance in these intermediate layers can decide according to the final use of the container that is blow molded into by the back cover parison.
Fig. 1 is the generalized section of nozzle of the present invention and injection-moulding device.
Fig. 2 to Fig. 5 is that nozzle is not held the part sectioned view of inlet and illustrating of five stratotype bases substep injection moulding process.
Fig. 6, five layers of back cover parison of injection molded product vertically partly cut open the forward sight enlarged drawing.
Fig. 7 and Fig. 8 are respectively terminal partial sectional view of inlet of nozzle and illustrating of four stratotype base injection moulding process.
Fig. 9, four layers of back cover parison of injection molded product vertically partly cut open the forward sight enlarged drawing.
In each figure, label 1 is the mould crust of casting back cover parison.Label 2 is a mold core.Between mould crust 1 and mold core 2, formed cavity 3.Inlet 4 is positioned at the bottom of cavity 3, and injector arrangement 5 links to each other with inlet.
Injector arrangement 5 is three-layer composite structures, and first melt canal 6 is communicated with nozzle bore, and second melt canal 7 and the 3rd melt canal 8 be the least significant end opening of first melt canal in nozzle bore respectively, and keeps concentric with spray orifice.Melt canal 6,7,8 directly is communicated with three injection device (not shown)s respectively, or with heat fusing runner 11,12,13 join.
Subsequent, this paper will introduce the injection moulding casting process of five layers of section structure back cover parison.The first molten resin 6a that at first forms parison injects cavity 3(Fig. 2 with a predetermined amount from first melt canal 6).
Then, the second molten resin 7a in formation intermediate layer injects from second melt canal 7 and imports in the first molten resin 6a under certain pressure.(Fig. 3).
After first molten resin injected, central core just formed from the 3rd melt canal 8 at the second molten resin 7a, and the 3rd molten resin 8a injects and imports in the second molten resin 7a (Fig. 4) under pressure.
When the 3rd molten resin imports die cavity under pressure, when continuing above-mentioned substep injection moulding process simultaneously, the second molten resin 7a is divided into secondary air with the first molten resin 6a, one presses close to mold shell 1, one presses close to core rod 2, and the 3rd molten resin is divided into two parts with the second molten resin 7a, and such the 3rd molten resin is located in the center.
The molten resin injection moulding process stop to be performed such, promptly at first stop to inject the second molten resin 7a and the 3rd molten resin 8a, stop to inject the first molten resin 6a at last.Therefore, the end of second and third molten resin 7a and 8a is closed in the inside as shown in Figure 5, finally forms five layers of back cover parison 9 and comprises the innermost layer A that is formed by the first molten resin 6a 1With outermost layer A 3, and the intermediate layer B that forms by second molten resin 1And B 2Reach layer B that be clipped in the middle that forms by the 3rd molten resin 1And B 2Between central core C(Fig. 5).
When four layers of section structure parison of injection moulding casting, at first inject first molten resin with step same as described above.Then, when above-mentioned injection moulding one end.Be about to the second molten resin 7a and the 3rd molten resin 8a and inject simultaneously, and under certain pressure, import among the first molten resin 6a, then, these the two kinds of resins and first molten resin are injected (Fig. 7) simultaneously.
These two gangs of molten resin 7a and 8a are divided into the first molten resin 6a by mould crust one side and pattern core two strands of molten streams on one side, the second molten resin 7a and the 3rd molten resin 8a and the first molten resin 6a charge into cavity 3 simultaneously, on one side and make the first molten resin 6a inject cavity 3 along mould crust one side and core rod respectively.
After cavity is full of, at first stop to inject second and third molten resin.Stop to inject the first molten resin 6a at last to seal the least significant end of second and third molten resin 7a and 8a.
The result has formed four layers of back cover parison 10 in cavity, wherein two intermediate layer B 1And B 2Form by the second molten resin 7a and the 3rd molten resin 8a.The intermediate layer is at the innermost layer A that is formed by the first molten resin 6a 1With outermost layer A 2Between have (Fig. 8) side by side.
When above-mentioned back cover parison 9 and 10 is used to blow the bottle of carbonated drink, the first molten resin 6a can use poly terephthalic acid second fat, the 3rd molten resin can be with the resin with gas barrier properties, such as polyalkenyl alcohol etc., the second molten resin 7a can be with the fusions or the polyamide of polyethylene terephthalate and vinyl alcohol.
The weight ratio of second and third molten resin 7a and 8a approximately is the 5-10% of whole parison.Must be noted that, the injecting condition temperature of molten resin for example in the said process, injection time, the temperature of mould and other are to change with the resin material that uses.And the distribution of each layer wall thickness also can be regulated by suitable selection and control injecting condition.

Claims (5)

1, a kind of injection moulding casting method that is used for multi-layer bottomed parison comprises: use the compound nozzle of triple channel that has with concentric first melt canal that is communicated with of nozzle bore, second melt canal and the 3rd melt canal communicate at the most not end opening of the first passage that is positioned at the spray orifice inboard respectively, form the innermost layer and the outermost layer of back cover base from the resin of first passage ejection.The resin that comes out from second and third melt canal forms an intermediate layer and central core or two intermediate layers and a central core, finally forms the back cover parison of four layers or five layers section structure.
2, carry out the substep injection moulding serially according to the injection moulding casting method that is used for multi-layer bottomed parison of claim 1, first molten resin of scheduled volume is injected die cavity from first melt canal.Second molten resin of scheduled volume is from the second channel importing and inject first molten resin under certain pressure, simultaneously this second molten resin is carried out injection moulding with first molten resin.Another kind of the 3rd molten resin injects from the 3rd melt canal and be injected into second molten resin under certain pressure, simultaneously this resin is carried out injection moulding with first and second molten resin.Be cast as back cover section bar at last with five layers of section structure.
3, according to the injection moulding of the also practicable another kind of substep of the injection moulding casting method that is used for multi-layer bottomed parison of claim (1).At first first molten resin with scheduled volume imports cavity from first melt canal, then almost at one time, inject mutually different second molten resin and the 3rd molten resin from second and third passage, and under certain pressure, two kinds of resins are together imported in first molten resin, three kinds of resin injection mouldings simultaneously form the back cover parison with four layers of section structure at last then.
4, according to the injection moulding casting method that is used for multi-layer bottomed parison of claim (1) and (2), wherein the resin in the formation intermediate layer that imports from second melt canal has certain adhesiveness.
5,,, include those gas barrier properties or hear resistance and be better than first resin that melts the formation layer structure that the body passage imports wherein from the 3rd resin that melts the formation central core that the body passage imports according to the injection moulding casting method that is used for multi-layer bottomed parison of claim 1,2 and 3.
CN 85106542 1985-08-30 1985-08-30 Injection moulding apparatus for multi-layer bottomed parisons Expired CN1018899B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 85106542 CN1018899B (en) 1985-08-30 1985-08-30 Injection moulding apparatus for multi-layer bottomed parisons

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Application Number Priority Date Filing Date Title
CN 85106542 CN1018899B (en) 1985-08-30 1985-08-30 Injection moulding apparatus for multi-layer bottomed parisons

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CN85106542A true CN85106542A (en) 1987-03-18
CN1018899B CN1018899B (en) 1992-11-04

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1067637C (en) * 1995-11-02 2001-06-27 本田技研工业株式会社 Process for producing dumper for vehicle
CN103069175A (en) * 2010-07-15 2013-04-24 富士通将军股份有限公司 Propeller fan and production method for same
CN114007843A (en) * 2019-06-28 2022-02-01 日精Asb机械株式会社 Resin molded article manufacturing device, resin molded article manufacturing method, and resin molded article

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1067637C (en) * 1995-11-02 2001-06-27 本田技研工业株式会社 Process for producing dumper for vehicle
CN103069175A (en) * 2010-07-15 2013-04-24 富士通将军股份有限公司 Propeller fan and production method for same
CN103069175B (en) * 2010-07-15 2015-11-25 富士通将军股份有限公司 Propeller type fan and manufacture method thereof
US9316233B2 (en) 2010-07-15 2016-04-19 Fujitsu General Limited Propeller fan and manufacturing method thereof
CN114007843A (en) * 2019-06-28 2022-02-01 日精Asb机械株式会社 Resin molded article manufacturing device, resin molded article manufacturing method, and resin molded article
CN114007843B (en) * 2019-06-28 2024-01-09 日精Asb机械株式会社 Apparatus for producing resin molded article, method for producing resin molded article, and resin molded article

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