CN2873482Y - Fire-proof type high strength heat insulation multilayer honeycomb corrugate board - Google Patents
Fire-proof type high strength heat insulation multilayer honeycomb corrugate board Download PDFInfo
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- CN2873482Y CN2873482Y CN 200620080220 CN200620080220U CN2873482Y CN 2873482 Y CN2873482 Y CN 2873482Y CN 200620080220 CN200620080220 CN 200620080220 CN 200620080220 U CN200620080220 U CN 200620080220U CN 2873482 Y CN2873482 Y CN 2873482Y
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- China
- Prior art keywords
- corrugated board
- honeycomb
- fire
- layer
- single face
- Prior art date
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- 238000009413 insulation Methods 0.000 title abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003063 flame retardant Substances 0.000 claims abstract description 32
- 239000000853 adhesive Substances 0.000 claims abstract description 27
- 230000001070 adhesive effect Effects 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 238000007598 dipping method Methods 0.000 claims abstract description 14
- 238000005507 spraying Methods 0.000 claims abstract description 13
- 239000003112 inhibitor Substances 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 13
- 239000002131 composite material Substances 0.000 claims description 11
- 239000006260 foam Substances 0.000 claims description 8
- 230000001413 cellular effect Effects 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000006243 Fine Thermal Substances 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000011162 core material Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 description 18
- 235000019795 sodium metasilicate Nutrition 0.000 description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 18
- 229910052911 sodium silicate Inorganic materials 0.000 description 18
- 238000000034 method Methods 0.000 description 14
- 239000000123 paper Substances 0.000 description 13
- 239000002585 base Substances 0.000 description 11
- 239000010410 layer Substances 0.000 description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- 150000003863 ammonium salts Chemical class 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 229910021538 borax Inorganic materials 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000004328 sodium tetraborate Substances 0.000 description 6
- 235000010339 sodium tetraborate Nutrition 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 5
- 235000011130 ammonium sulphate Nutrition 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 229920000881 Modified starch Polymers 0.000 description 4
- 238000004026 adhesive bonding Methods 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 4
- 239000011609 ammonium molybdate Substances 0.000 description 4
- 235000018660 ammonium molybdate Nutrition 0.000 description 4
- 229940010552 ammonium molybdate Drugs 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 4
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 235000019426 modified starch Nutrition 0.000 description 4
- 239000004254 Ammonium phosphate Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 3
- 235000019289 ammonium phosphates Nutrition 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000003618 dip coating Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- 230000010412 perfusion Effects 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000005030 aluminium foil Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000004330 calcium propionate Substances 0.000 description 2
- 235000010331 calcium propionate Nutrition 0.000 description 2
- 239000011111 cardboard Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- -1 melmac Substances 0.000 description 2
- 239000011325 microbead Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 description 1
- SFHYNDMGZXWXBU-LIMNOBDPSA-N 6-amino-2-[[(e)-(3-formylphenyl)methylideneamino]carbamoylamino]-1,3-dioxobenzo[de]isoquinoline-5,8-disulfonic acid Chemical compound O=C1C(C2=3)=CC(S(O)(=O)=O)=CC=3C(N)=C(S(O)(=O)=O)C=C2C(=O)N1NC(=O)N\N=C\C1=CC=CC(C=O)=C1 SFHYNDMGZXWXBU-LIMNOBDPSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000274582 Pycnanthus angolensis Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- JGDWZAJSBNDIKN-UHFFFAOYSA-N [Ba].B(O)(O)B(O)O Chemical compound [Ba].B(O)(O)B(O)O JGDWZAJSBNDIKN-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- IOPOLWHQYJSKCT-UHFFFAOYSA-L barium(2+);dihydrogen phosphate Chemical compound [Ba+2].OP(O)([O-])=O.OP(O)([O-])=O IOPOLWHQYJSKCT-UHFFFAOYSA-L 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
Landscapes
- Building Environments (AREA)
Abstract
Fireproof multilayer beehive corrugated paper with high intensity and thermal insulation is characterized in that pieces of single face corrugated paper are compounded by bond to form core materials, the very outer layer of which compounds with faceplate. The single face corrugated paper is disposed as dipped or sprayed with water based fire retardant, and after desiccation encased with a layer of fireproof adhesive by dipping or spraying. The corrugated paper beehive compounded materials have advantages such as high intensity, excellent fireproof capability, fine thermal insulation and eminent integral technical performance. The compounding between layers is extreme intense and hardly influenced by surroundings, thus the separation between layers can be avoided. In the field of fireproof, sound insulation and thermal insulation, mine wool and alumina silicate products which are harmful for labor can be replaced. Thereby, the paper belongs to eminent environmental protection materials without public hazard.
Description
Technical field
The utility model belongs to a kind of multilayer composite of corrugated board, particularly a kind of fire-proof high strength heat insulating multi-wall corrugated board.
Background technology
The cellular material of papery reaches the advantage of material-saving light weight, environmental protection because its good mechanical architectural characteristic is arranged, and the sandwich that is widely used in the packing plank frame is filled, and also obtains excellent popularization and use in fields such as building materials, furniture, car and boat.
No matter be hexagonal honeycomb or corrugation cross section honeycomb, their adiabatic sound insulation property mainly is to depend on coating panel to produce.In the middle of the comb core is penetrating, is air dielectric.The papery cellular material can reach flame retardant effect by immersion, spray coated flame retardant agent, perhaps uses pretreated fire retardant papers to form the papery cellular material with anti-flaming function.The fire retardant papers honeycomb that fire retardant adhesive is made is B1 level nonflammable material according to GB8624 fireproof building material rank division method.But do not reach the A level composite material standard of not firing.Because general the use soaked spray slaine, ammonium salt based flame retardant, in use along with the continuous of environment humidity, temperature replaces, changes, fire-retardant slaine, ammonium salt are escaped from the paper fiber, are reduced, thereby anti-flammability can successively decrease along with time lengthening, and is more outstanding in the relatively poor high humidity environment of closure.The common paperys of impregnation process such as single process fire-retardant fireproof material such as amino resins, phenolic resins, melmac, sodium metasilicate are difficult to be impregnated into internal fiber, generally be coated on the outside, when meeting fire burns, certain anti-flammability is arranged, but internal fiber can set off a large amount of carbon monoxide and ejection flame etc., and environment is caused very big harm.
The high-strength corrugated board that conventional packing is used (multilayer) is perpendicular to the needs that all can not satisfy engineering material on the mechanical strength on corrugated board surface and the moisture resistance.
Summary of the invention
Technical problem to be solved in the utility model provides and a kind ofly can satisfy the required mechanical strength of common engineering material, and fire prevention, adiabatic multi-wall corrugated board.
The utility model fire-proof high strength heat insulating multi-layer honeycomb corrugated board, it is characterized in that it being to be compounded to form core successively by adhesive by single face corrugated board, core outermost layer composite panel, the following processing of described single face corrugated board process: dipping or spraying water-based flame-stabilizing, pass through dipping or spray coating one deck refractory adhesive again after the drying.
The single face corrugated board compound tense both can be compound successively according to the identical mode of cellular direction, also can be the mode compound layer by layer (intersection that comprises erratic behavior) that cellular direction is intersected.
Corrugated board of the present utility model is through after-treatment, and corrugated board is isolated by one deck refractory adhesive, not only can improve mechanical strength, and fire-retardant, fire protecting performance is good.
Its manufacturing process below is described:
(1) single face corrugated board dipping or spraying water-based flame-stabilizing, drying;
(2) and then by the dipping or the spray coating refractory adhesive;
(3) corrugated board through above-mentioned processing is combined into multi-layer honeycomb shape corrugated board successively.
Single face corrugated board in the above-mentioned steps (2) behind the coating refractory adhesive can carry out drying earlier, and multilayer is compound by adhesive again, also can be directly compound successively under wet state.The utility model preferably coats the single face corrugated board elder generation drying application of adhesive composite methods again behind the refractory adhesive.Owing to coat the influence that direct compound meeting behind the refractory adhesive is subjected to uneven drying, gel shrinkage stress inequality is destroyed combined strength bination between each single-face corrugation and craze and transfiguration thereby preferably take once more the compound production technology of gluing.
Employed water-based flame-stabilizing, the water-based flame-stabilizing of People's Republic of China's industry standards of public safety " aqua type flame retardant treating agent general technical specifications " (GA 159-1997) regulation is to be decentralized medium with water, adopt spraying or impregnating mode to make timber, fabric or cardboard etc. obtain the fire retardant of the combustibility of regulation, in the known technology by some such fire retardants.Be made up of ammonium salt, boric acid, borax and water as common water-based flame-stabilizing, ammonium salt can be ammonium phosphate, ammonium sulfate, ammonium chloride, diammonium hydrogen phosphate, APP etc.The utility model water-based flame-stabilizing preferably adopts water base fire-retardant mould inhibitor.
Water base fire-retardant mould inhibitor is the compound prescription of water-soluble metal salt, can be boric acid and salt thereof such as Firebrake ZB, Boratex, ammonium borate, hypoboric acid barium etc., also can select in phosphate, sulfate, hydrochloride, ammonium salt or the molybdenum salt two or more, as ammonium phosphate, phosphoguanidine, barium dihydrogen phosphate, APP, ammonium sulfate, ammonium chloride, two cyanogen ammoniums etc.The concrete component of selecting can be that crosslinked composition takes place sodium metasilicate or the prodan with following refractory adhesive.
Below enumerate the composition of several water base fire-retardant mould inhibitors, but be not limited to these.
(1) comprises the water of Firebrake ZB 3-8%, sodium tetraborate 5-8%, sodium hydrogen phosphate 3-5% and surplus according to the percetage by weight meter.
(2) comprise the water of ammonium sulfate 5-8%, sodium tetraborate 5-6%, ammonium molybdate 4-5% and surplus according to the percetage by weight meter.
(3) comprise the water of ammonium chloride 3-6%, ammonium molybdate 4-5%, APP 4-8%, calcium propionate 2-3% and surplus according to the percetage by weight meter.
Employed refractory adhesive is mainly the mixed glue solution of sodium metasilicate or sodium metasilicate and prodan or starch derivatives.
Below enumerate severally, but be not limited to these:
(1) be that 35-60 ℃ sodium metasilicate 80-90%, prodan 5-15%, polyvinyl alcohol 2-5% and odium stearate 1-1.5% forms according to the percetage by weight meter by Baume degrees.
(2) be that 35-60 ℃ sodium metasilicate 80-90%, starch derivatives 5-15%, odium stearate 1-1.5% and ethylene glycol 3-5% forms according to the percetage by weight meter by Baume degrees.
(3) form by sodium metasilicate 85-98%, glycerine 1-14% and odium stearate 1-1.5% according to the percetage by weight meter.
Boric acid and its esters not only have excellent flame-retardant performance to also have good mildew-resistant to suppress action of microorganisms, or the good crosslinking agent of sodium metasilicate and amylan, coat impregnation (refractory adhesive) for secondary, raising intensity, mildew-resistant humidity resistance there is good action, ammonium salt also is the crosslinking agent of sodium metasilicate and amylan except that good flame retardancy is arranged, lowered the pH value of sodium metasilicate simultaneously, reduced the effect of alkali silica.The cheap fire line of refractory adhesive cost economic of double-steeping is good, nuisanceless, the intensity height, and simultaneously because the rewetting reproducibility, goods can keep 100% recycling, are the optimal materials of both economical environmental protection and energy saving.
Double-steeping fire prevention treatment process of the present utility model can produce good comprehensive effectiveness.After for the first time fire-retardant mould inhibitor processing, electricity has good penetration in water base fire-retardant mould inhibitor, the dipping that can all fill is penetrated into corrugated paper inside and outside all, thereby remedied that fire protection flame retarding viscosity is big, poor permeability, the not tractable shortcoming of cardboard internal fiber.The sodium metasilicate of the slaine of fire-retardant mould inhibitor or oxide, ammonium salt and secondary coating dipping or prodan, starch derivatives have good curing cross-linked effect.To the protection against the tide that coats sizing material, early strong and increase gel strength significant effect is arranged.The gel layer that coats is in the interface portion of fire-retardant mould inhibitor and interpenetrate the effect that part has obtained being significantly higher than uncrosslinked single sodium metasilicate, early help to improve the operation work efficiency simultaneously by force, since the coating gel rear enclosed of secondary fire-retardant mould inhibitor, fire-retardant mould inhibitor is not influenced by the environment humidity can escape and reduce fire-retardant fungicidal properties.The utility model goods improve a fire-protection rating than traditional its fire protecting performance of fire-retardant paper product (single water-based flame-stabilizing is handled or single sodium metasilicate coats processing), reach compound A2 level incombustible material standard according to GB8624 fireproof building material rank division method.Record oxygen index (OI) 〉=70, SDR smoke density grade≤2, the residue length 〉=460mm that on average burns, average flue gas peak value≤125 ℃, mean calorie≤42MJ/kg, the hot burst size≤16.8MJ/m of unit are
2, density is generally 20-200kg/m
3, carbonization length≤15mm, flue gas toxity LCO 〉=25mg/L.The magnesia cladding boards of 80mm, fire endurance 〉=1.2h (GB/T9978-99), concora crush intensity be with material with the weight corrugated sheet more than four times up to 5mpa, temperature tolerance 〉=150 ℃, thermal conductivity factor≤0.05w/MK, sound insulation Rw 〉=35dB, (GBJ75-84), so the multilayer corrugated structure has good thermal resistance and acoustic resistance.
Because the sodium metasilicate in the refractory adhesive belongs to the strong basicity component, and contactant and adherend are had very strong corrosion contamination and rewetting reproducibility.Therefore the panel layer of the multi-wall corrugated board that obtains of the utility model is preferably the composite bed of paper or paper aluminium foil or the waterproof paper of handling through waterproof material.Mould paper as pouring, plastic film-coating paper, aluminium-foil paper, waxed paper or the like with effective moistureproof and waterproof, makes its thermal insulation, thermal conductivity factor and intensity be in stable state.
Because corrugated board has formed many honeycomb holes after compound, honeycomb hole has formed fluid space, so that reduce the heat-insulating property of complex, it is inner and cause intensity and adiabatic combination property to reduce also to cause wet gas and water to enter the complex honeycomb.The utility model adopts the edge honeycomb face to the multi-layer honeycomb corrugated board to spray the measure that organic foam class material seals honeycomb hole, and coating thickness is generally 5～20mm.Organic foam class material has the effect of lightweight, low heat conductivity, material-saving.For example spray phenolic resin foam or closed-cell foam materials such as melamine, polyurethane on the honeycomb face, these materials all have good thermal insulation and extremely low water imbibition.
Require higher application in order to satisfy some sound insulation heat-insulating properties and fire protecting performance, the utility model adopts the inorganic heat-insulating and sound-proof material of perfusion in its honeycomb, and edge honeycomb face sprays the method that organic foam class material seals again.Concrete production process can be: wherein relative down another side honeycomb hole is up behind the face closure of honeycomb, inorganic heat-insulating and sound-proof material pours into, when pouring into thing when reaching 5～20mm honeycomb edge suitable for reading, spray organic foam material again with fixing airtight fill material, if intersect the corrugation complex then in horizontal and vertical two faces perfusion and sealing.
The inorganic heat-insulating material that pours in complex can be microbead glass, expanded perlite, silicon vermiculite power, calcium silicate powder, precipitated calcium carbonate, lightweight coal powder etc., and they belong to granular, pulverulent material, its moisture content≤3, granularity≤3mm.
The multi-wall corrugated board that the utility model obtains has the intensity height, and fire protecting performance is good, the heat-insulating property height, and the characteristics that comprehensive technical performance is good, interlayer combined strength bination height, it is little influenced by environmental change, thereby can not produce the interlayer segregation phenomenon.In the application that generally requires fire prevention, sound insulation, thermal insulation, can substitute bigger rock mineral wool and the aluminium silicate products of work harm, belong to a kind of nuisanceless green environment-friendly materials of function admirable.With multi-wall corrugated board place relative humidity greater than 90%, the environment of 25 ℃ of temperature, the total number of bacteria after 30 days in every gram material is no more than 2, anti-mold effect is good.
Description of drawings
Fig. 1 is one of cross section structure schematic diagram of the present utility model;
Fig. 2 is the A-A view among Fig. 1.
Among the figure: 1 single face corrugated board, 2 panels, 3 inorganic heat-insulating and sound-proof material 4 honeycomb hole closed materials
The specific embodiment
Below in conjunction with embodiment the utility model is described:
As Fig. 1, single face corrugated board 1 is compounded to form core successively by adhesive, and core outermost layer composite panel 2 is filled with inorganic heat-insulating and sound-proof material 3 in the honeycomb of core, and edge honeycomb face seals honeycomb hole with honeycomb hole closed material 4 (organic foam class materials).The following processing of single face corrugated board process: dipping or spraying water-based flame-stabilizing or water base fire-retardant mould inhibitor, pass through dipping or spray coating one deck refractory adhesive again after the drying.
Embodiment 1: making flow process is:
Single face corrugated board → fire-retardant mould inhibitor single-steeping → drying box oven dry → secondary refractory adhesive coats perfusion inorganic material → phenolic resin foam sealing of hole → finished product in dipping → drying box → gluing → scale severing → complex drying → complex honeycomb
Water base fire-retardant mould inhibitor is made up of the water of Firebrake ZB 3-8%, sodium tetraborate 5-8%, sodium hydrogen phosphate 3-5% and surplus according to the percetage by weight meter.
Refractory adhesive is that 35-60 ℃ sodium metasilicate 80-90%, prodan 5-15%, polyvinyl alcohol 2-5% and odium stearate 1-1.5% forms according to the percetage by weight meter by Baume degrees.
It is 6cm that the interior filling of complex honeycomb has microbead glass, complex thickness, and flush coat is that the combined wall board performance test of magnesium oxide plate is as follows:
1, meets A level incombustible material GB8624
2, fire endurance 〉=1.2h (GB/T9978)
3, air-borne sound weighted transmission loss R
w〉=48dB (GBJ75-84)
4, thermal resistance: 0.812m
2K/w is equivalent to the thermal resistance of 650mm brick wall.
Be perfused with the expanded perlite material in the complex, its core (complex) thickness is that the fire-proof wooden door index that obtains of 6cm is as follows:
Fire endurance 〉=60mm air-borne sound weighted transmission loss R
w〉=39dB
Thermal conductivity factor 0.05w/m
2K/w density :≤160kg/m
3
Embodiment 2:
Water base fire-retardant mould inhibitor is made up of the water of ammonium sulfate 5-8%, sodium tetraborate 5-6%, ammonium molybdate 4-5% and surplus according to the percetage by weight meter.
Refractory adhesive is that 35-60 ℃ sodium metasilicate 80-90%, starch derivatives 5-15%, odium stearate 1-1.5% and ethylene glycol 3-5% forms according to the percetage by weight meter by Baume degrees.
Production process: use 1650 type single-face corrugation production equipments, corrugation mould 3.0mm, the A type corrugation of stupefied high 5.0mm.Use the plane base stock to be fabric width 1600mm, the C level boxboard of grammes per square metre 175 grams, the common corrugated paper of 150g are done and are pressed stupefied layer, use polyvinyl alcohol to make adhesive, make single face corrugated board.Be cut into length * wide=4000 * 1600 (mm).After using water base fire-retardant mould inhibitor spraying or dip-coating single face corrugated board, drying is to moisture content＜20% o'clock, and dipping coats refractory adhesive again, also can adopt the method for two sides spraying, and coating weight is situation and deciding as required, generally at 100-500 gram/m
2Between.Drying is to moisture content≤8% o'clock again, and compound successively behind stupefied gluing of glue spreader, pressurization is dry.Composite thickness is decided as required.Composite adhesive glue adopts common known products.Make the utility model goods, its thickness 100mm, density is 200kg/m
3Test plane compression strength 3.1mpa, thermal conductivity factor:
0.055W/MK, sound insulation R
w〉=36dB meets A level (sandwich) incombustible material GB8624 standard.
Embodiment 3:
Making single face corrugated board → dip-coating, the water base fire-retardant mould inhibitor of immersion trough → drying oven dehydration → secondary by the single face pressing machine and coat the corrugation gluing of dip-coating or sprayed fire proofing gel sodium metasilicate → redrying baking oven dehydration → once more, severing → collection is compound → and roll-in rolls off the production line → dry slaking goods.
Water base fire-retardant mould inhibitor is made up of the water of ammonium chloride 3-6%, ammonium molybdate 4-5%, APP 4-8%, calcium propionate 2-3% and surplus according to the percetage by weight meter.
Refractory adhesive is made up of sodium metasilicate 85-98%, glycerine 1-14% and odium stearate 1-1.5% according to the percetage by weight meter.
The wooden fireproof door that utilizes the utility model goods to make records its thickness and is 50mm the key technical indexes: fire endurance 〉=1.2h, and composite is A2 level (compound sandwich material GB8624-97), concora crush intensity 〉=2.5mpa, thermal conductivity factor: 0.068W/MK.
Embodiment 4:
According to the method for embodiment 1, the inner partition plate that utilizes the utility model sandwich complex to make, flush coat are the magnesium oxide plate of thickness 10mm, and it is as follows that gross thickness is that the dividing plate of 100mm records index:
Sound insulation: R
w〉=40dB, thermal conductivity factor: 0.07W/MK, refractory slab limit 〉=1.5h (GB9978-99) bending resistance load are 12.5 times of plate deadweight.Single-point hanging force load-bearing 800N * 24h, the plate face does not have damaged crack, lateral load 4.26KN/m
2
Embodiment 5:
According to the method for embodiment 2, utilize the utility model goods for the sandwich complex makes the clean engineering composite plate of color steel, sandwich complex thickness 50mm, coating panel is the color steel of 0.476mm.The key technical indexes that records: thermal conductivity factor 0.075W/MK, fire line: compound A level (sandwich) incombustible material GB8624, oxygen index (OI) 〉=70, smoke density grade SDR≤6, compression strength: 3.05mpa, core density: 160kg/m
3
Embodiment 6:
According to the method for embodiment 2, adopt water-based flame-stabilizing by weight percentage: ammonium phosphate or ammonium sulfate 10%, boric acid 2%, borax 2%, water 86%.Make the utility model goods, its thickness 100mm, density is 200kg/m
3Test plane compression strength 3.0mpa, thermal conductivity factor: 0.054W/MK, sound insulation R
w〉=36dB meets A level (sandwich) incombustible material GB8624 standard.
Claims (5)
1, a kind of fire-proof high strength heat insulating multi-layer honeycomb corrugated board, it is characterized in that it being to be compounded to form core successively by adhesive by single face corrugated board, core outermost layer composite panel, described single face corrugated board has passed through following processing: dipping or spraying water-based flame-stabilizing, pass through dipping or spray coating one deck refractory adhesive again after the drying.
2, multi-layer honeycomb corrugated board according to claim 1 is characterized in that the water-based flame-stabilizing of described single face corrugated board dipping or spraying is water base fire-retardant mould inhibitor.
3, multi-layer honeycomb corrugated board according to claim 1 is characterized in that single face corrugated board can be compound successively according to the identical mode of cellular direction, also can be that the mode of cellular direction intersection is compound layer by layer.
4, multi-layer honeycomb corrugated board according to claim 1 is characterized in that the edge honeycomb face of described core seals honeycomb hole with organic foam class material.
5, multi-layer honeycomb corrugated board according to claim 1 is characterized in that being filled with inorganic heat-insulating and sound-proof material in the honeycomb of described core, and edge honeycomb face is with organic foam class material sealing honeycomb hole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200620080220 CN2873482Y (en) | 2006-01-13 | 2006-01-13 | Fire-proof type high strength heat insulation multilayer honeycomb corrugate board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200620080220 CN2873482Y (en) | 2006-01-13 | 2006-01-13 | Fire-proof type high strength heat insulation multilayer honeycomb corrugate board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN2873482Y true CN2873482Y (en) | 2007-02-28 |
Family
ID=37780072
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200620080220 Expired - Fee Related CN2873482Y (en) | 2006-01-13 | 2006-01-13 | Fire-proof type high strength heat insulation multilayer honeycomb corrugate board |
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| CN (1) | CN2873482Y (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105800024A (en) * | 2016-03-21 | 2016-07-27 | 南通市东方包装有限公司 | Production method for fireproof and flame-retardant corrugated paper box |
| CN106183232A (en) * | 2015-04-29 | 2016-12-07 | 廖树汉 | The aluminium alloy paper composite corrugated paper fireguard that subduction fire occurs |
| CN106494764A (en) * | 2016-06-30 | 2017-03-15 | 天津宏达鑫盛科技有限公司 | A kind of moistureproof carton |
| CN111775517A (en) * | 2020-06-03 | 2020-10-16 | 航天材料及工艺研究所 | Light honeycomb sandwich structure integrating structure and biological safety and preparation method thereof |
| CN113183540A (en) * | 2021-05-17 | 2021-07-30 | 浙江希望包装有限公司 | Production process of high-flame-retardant corrugated paper |
-
2006
- 2006-01-13 CN CN 200620080220 patent/CN2873482Y/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106183232A (en) * | 2015-04-29 | 2016-12-07 | 廖树汉 | The aluminium alloy paper composite corrugated paper fireguard that subduction fire occurs |
| CN105800024A (en) * | 2016-03-21 | 2016-07-27 | 南通市东方包装有限公司 | Production method for fireproof and flame-retardant corrugated paper box |
| CN106494764A (en) * | 2016-06-30 | 2017-03-15 | 天津宏达鑫盛科技有限公司 | A kind of moistureproof carton |
| CN111775517A (en) * | 2020-06-03 | 2020-10-16 | 航天材料及工艺研究所 | Light honeycomb sandwich structure integrating structure and biological safety and preparation method thereof |
| CN113183540A (en) * | 2021-05-17 | 2021-07-30 | 浙江希望包装有限公司 | Production process of high-flame-retardant corrugated paper |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20090213 Address after: Room 316, block A, Pioneer Road, 135, Zibo hi tech Development Zone, Shandong, China, 255086 Patentee after: Zibo HaoTe Integrated House Making Co., Ltd. Address before: Room 301, building 255400, West Bank Commercial Bank, Zibo Road, Linzi District, Shandong, China Patentee before: Xu Gang |
|
| ASS | Succession or assignment of patent right |
Owner name: ZIBO HAOTE INTEGRATED HOUSE MANUFACTURING CO., LTD Free format text: FORMER OWNER: XU GANG Effective date: 20090213 |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070228 Termination date: 20100219 |