CN2807241Y - Oil sampling pretreatment system - Google Patents

Oil sampling pretreatment system Download PDF

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Publication number
CN2807241Y
CN2807241Y CN 200520022808 CN200520022808U CN2807241Y CN 2807241 Y CN2807241 Y CN 2807241Y CN 200520022808 CN200520022808 CN 200520022808 CN 200520022808 U CN200520022808 U CN 200520022808U CN 2807241 Y CN2807241 Y CN 2807241Y
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pretreatment
oil
oil product
pretreatment system
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CN 200520022808
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李苏安
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ZHONGKE CHUANGYI TECH DEVELOPMENT Co Ltd
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ZHONGKE CHUANGYI TECH DEVELOPMENT Co Ltd
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Abstract

The utility model provides an oil sampling pretreatment system which comprises a first group of pretreatment units and a second group of pretreatment units which are connected in series, wherein the first group of pretreatment units are connected with oil pipes which are divided in groups via fast returning circuits, the second group of pretreatment units are connected to an on-line N. I. R. analyzer via sampling optical fiber and a detection probe, and a foam removing device for removing foam, and a primary filter for removing impurity are connected in series to pipelines of the first group of pretreatment units. The system can make sampling fully satisfy application requirements of the on-line N. I. R. analyzer, and thus, the utility model can perform positive functions of the on-line quality control of process industry which is widely developed.

Description

Oil product sampling pretreatment system
Technical field
The utility model relates to the principle of the on-line nir system sampling pretreatment system in the oil product on-line optimization blending systems such as gasoline in the refinery, kerosene or diesel oil and detailed design, particularly a kind of sampling pretreatment system that is used for the blending of lightweight oil on-line optimization.
Background technology
Modern refinery extensively adopts oil product on-line optimization blending systems such as gasoline, diesel oil.This type systematic is as the process unit of advanced technology, refinery energy-saving and cost-reducing, improve product yield, reduce cost of products, save and brought into play great role aspect refinery storage tank and the process pipeline, thereby the economic benefit of refinery is improved.As the core of this type systematic, the effect of online check and analysis instrument in whole on-line optimization blending system is extremely important, and it plays the effect of eyes in system.
On-line nir system is the very high online detection spectrophotometer of a kind of scientific and technological content, by the near infrared light sample that sends with it, can obtain the feature near infrared spectrum of sample; By being installed on the Chemical Measurement software on the dedicated analysis computing machine, can calculate the various physico-chemical properties in the tested material fast again.Its detection speed is fast, is that the other types analyser can't be compared.
But as the very high online analytical instrument of scientific and technological content, on-line nir system also demonstrates its enervated one side.For example, when containing micro-impurity or water or bubble in the sample in entering the sample detection space, because the existence of above-mentioned factor will cause the absorption spectrum of detected sample to depart from, thereby make the near infrared detection value of sample depart from, influence on-line analysis and production control.
Because the intermediate component oil in the refinery production run all contains moisture, impurity usually, and in pipeline, can produce bubble owing to the fluctuation situation of displacement and pressure when mobile, therefore, if sample is not being carried out under certain pretreated situation, just sample is introduced the sample detector space of on-line nir system, above-mentioned said moisture, impurity and bubble can influence the accuracy of detected value to a great extent.
In the production of refinery, during the light-end products (oil products such as gasoline, kerosene, diesel oil) during device light constituent outlet, petroleum products blending are produced are produced, necessary the sample pretreatment system that a cover satisfies the on-line nir system application requirements is set.The inventor furthers investigate oil product sampling pretreatment system, satisfying the on-line nir system application requirements, thus the positive effect of process industry line Quality Control performance to extensively launching.
The utility model content
The utility model provides a kind of oil product sampling pretreatment system at defective that exists in the prior art or deficiency.Adopt this system can make sampling fully satisfy the application requirements of on-line nir system, thus the positive effect of process industry line Quality Control performance to extensively launching.
Technical conceive of the present utility model is in order to guarantee the accurate measurement of near-infrared analyzer, must guarantee that the oil product that detects the space through probe is clean and does not have bubble.Therefore, when considering design sample or sampling pretreatment system, accomplish to dewater as far as possible, the removal of impurity, remove bubble, and make the oil product constant temperature that detects the space through probe as far as possible.For this reason, need in sample or sampling pretreatment system, install dehydrator, filtrator, bubble trap and thermostat.
The technical solution of the utility model is as follows:
Oil product sampling pretreatment system, first group of pretreatment unit and second group of pretreatment unit of comprising serial connection, first group of pretreatment unit is connected in the component oil pipe by quick loop, and second group of pretreatment unit is connected in on-line nir system by sampling optical fiber and detection probe.
Be serially connected with on the pipeline of described first group of pretreatment unit and be used for removing the bubble trap of bubble and be used for deimpurity grade one filter.
Described bubble trap is the minor axis bypass structure.
Be serially connected with alternative secondary filter and dehydrator on the pipeline of described second group of pretreatment unit.
The inlet end of described alternative secondary filter is serially connected with water cooler.
Also be serially connected with thermostat on the pipeline of described second group of pretreatment unit.
Described thermostat is the constant temperature oil bath device.
Described detection probe places the constant temperature oil bath device.
Technique effect of the present utility model is as follows:
Because oil product sampling pretreatment system of the present utility model, two groups of pretreatment units that comprise serial connection, make The pretreatment more abundant, can make sampling fully satisfy the application requirements of on-line nir system, thus the positive effect of process industry line Quality Control performance to extensively launching.
Because having adopted bubble trap, the effect of bubble trap is by the minor axis bypass, makes to enter pretreatment unit, but draw from the minor axis bypass by the bubble in the process sampling fluid of quick loop pump.Owing to adopted filtrator and dehydrator and thermostat, influence, impurity effect and Temperature Influence that this just can help eliminating water improve measuring accuracy greatly.
Description of drawings
Fig. 1 is the application structure synoptic diagram of near-infrared analyzer in the petroleum products blending process.
Fig. 2 is a structural principle synoptic diagram of the present utility model.
Reference numeral lists as follows:
The quick loop of 1-, 2-retracting device, 3-sample preparation sampler, 4-leads to many fibre bundles of process, the 5-near-infrared analyzer, and 6-analyzes PC, 7-process quality control parameter, 8-Process Control System, the quick loop of 9-inlet valve, the 10-retaining valve, 11-sampling pump, 12-pump discharge buffer tank, the 13-bubble trap, 14-grade one filter, the quick loop of 15-outlet valve, the quick loop of 16-bypass valve, 17-pre-service inlet valve, 18-hand valve, 19-sample collection jar, 20-collection tube, 21-nitrogen tube, the 22-recycling can, 23-reclaims pump, 24-reduction valve, the 25-tensimeter, 26-water cooler, 27-cooling water pipe, the 28-waste pipe, 29-alternative filtrator, 30-dehydrator, 31-scalable hand valve, 32-sample tap, the 33-optical fiber of sampling, the 34-constant temperature oil bath, the 35-spinner-type flowmeter.
Embodiment
Be described in further detail below in conjunction with drawings and Examples.
The sample pretreatment application system that this paper is related, the adhere rigidly to U.S. ASTM standard.
Normative reference is as follows:
1, ASTM E1655-00: near infrared multivariate quantitative test standard practices
(Standard?Practices?for?Infrared?Multivariate?Quantitative?Analysis)
2, ASTM D3764-01: process fluid analyzer system validation criteria method
(Standard?Practice?for?Validation?of?Process?Stream?Analyzer?Systems)
3, ASTM D2885-85: the standard method of test of using in-line analyzer measurement Research method octane value and motor octane number
(Standard?Test?Method?for?Research?and?Motor?Method?Octane?RatingsUsing?On-Line?Analyzers)
4, ASTM D6122-01: multivariable process near infrared spectrometer validation criteria method
(Standard?Practice?for?Validation?of?Multivariate?Process?InfraredSpectrophotometers)
5, ASTM D4177-5: the automatic sampling standard method of oil and petroleum products
(Standard?Practice?for?Automatic?Sampling?of?Petroleum?and?PetroleumProducts)
6, ASTM D4057-5; Oil and petroleum products hand sampling standard method
(Standard?Practice?for?Automatic?Sampling?of?Petroleum?and?PetroleumProducts)
7, ASTM D4053-98: the standard method of test of near-infrared spectrometers measured automobiles gasoline and aviation gasoline
(Standard?Test?Method?for?Benzene?in?Motor?and?Aviation?Gasoline?byInfrared?Spectroscopy)
Supplementary notes: owing to be generally the hazardous industry zone in the Production Regional of refinery, the electric part in the related sample pretreatment system of this paper is strict explosion-proof part, and the electrical equipment explosive-proof grade is ExdIIBT4, meets refinery and produces explosion-proof standard.
One, the analysis of oil body factor:
1, water
During refinery is produced, produce in the oil body pipeline of outlet, because distil process itself contains more water in the pipeline oil body at device.The main forms that water exists is a free water, and the sub-fraction emulsified water is arranged simultaneously.
From installing next oil product, can be temporary in the semi-manufacture jar usually.During semi-manufacture jar temporary, at the bottom of W/O can be deposited in to a certain extent according to the length of the residence time jar, but jar in oil still contain micro-moisture.
In petroleum products blending, semi-manufacture oil may be directly from device, also may be from the semi-manufacture jar.Which kind of mode no matter, the micro-moisture in the oil is always inevitable, and directly the water-in-oil content from device is a lot, contains a certain amount of moisture from the oil product of semi-manufacture jar.
In the index of dispatching from the factory of the gasoline product of GB regulation, moisture should be greater than 100ppm, and in the semi-manufacture oil in process of production, the content of moisture is higher than this far away.And water content in oil is alkalescent or strong basicity usually.
2, impurity
Impurity in the oil product mainly comes from catalyst fines in the device, pipeline inwall iron rust etc.Directly in the oil product from device, impurity content is higher, if in the semi-manufacture jar temporary a period of time, at the bottom of impurity can be deposited in jar significantly.
3, bubble
Oil product is moving, in the transfer process, because the motion of itself and the fluctuation situation of pipeline internal pressure, and the fluctuation situation of temperature, can produce more bubble.
4, temperature
Device comes the oil product temperature higher usually, be generally 30~50 ℃, and semi-manufacture jar temperature is usually near environment temperature.
Two, the oil body factor is to the influence of near infrared detection:
1, the influence of water
Near infrared detection principle fundamentally is to produce owing to the near infrared spectrum that contains H (hydrogen) group in the organism absorbs.Water contains H (hydrogen) group H-O, thereby may influence the measurement of near-infrared analyzer.In the practical application, probe is can not influence probe measurement by the emulsified water in the oil product only, because the emulsified water content in the oil product is very low under the situation of cleaning.But because the sapphire window possess hydrophilic property (comparing) on the near-infrared analysis instrument probe with the character of oil product own, therefore still easily from oil, separate and be attached on the sapphire window of probe, time has been grown, may form the very thin moisture film of one deck on the probe, thereby on slight extent, influence the detection of near-infrared analysis instrument probe.More serious situation is may have a large amount of free waters in a certain stage in the oil product to come, and is a large amount of attached on the sapphire window of popping one's head in, thereby has a strong impact on the measurement of probe.
2, impurity effect
Impurity may arrive the sample detection space of probe along with the motion of oil product, and stops at detecting head surface, thus the measurement of influence probe.
3, influence of air bubbles
In the sample detection space of probe, because the existence of bubble causes thickness of sample to reduce, thereby has a strong impact on the accuracy of measurement.
4, Temperature Influence
The conversion of temperature can make spectrum be offset along wavelength direction.Temperature raises, and spectrum moves to left; Temperature reduces, and spectrum moves to right.Because moving of spectrum generation wavelength direction, thereby the accuracy that influence is measured.
Three, pretreatment system principle of design:
In order to guarantee the accurate measurement of near-infrared analyzer, must guarantee that the oil product that detects the space through probe is clean and does not have bubble.Therefore, when considering the design sample pretreatment system, accomplish to dewater as far as possible, the removal of impurity, remove bubble, and make the oil product constant temperature that detects the space through probe as far as possible.For this reason, it is neat to install dehydrator, filtrator, bubble trap and constant temperature in sample pretreatment system.
Four, sample pretreatment system structure:
According to the above sample pretreatment thought of discussing, can make the supporting sample pretreatment system of on-line nir system that satisfies actual refinery process control and petroleum products blending production needs.The fluid factor of oil body in the pipeline of discussing at the front can design and comprises following device and structure, with the cleaning that guarantees the oil property after the pre-service with stable, thereby guarantee the accurate measurement of near-infrared analysis instrument probe.Main device and structure comprise: as depicted in figs. 1 and 2: quick loop 1, quick loop sampling pump 11, bubble trap 13, grade one filter 14, pre-service reduction valve 24, tensimeter 25, water cooler 26, alternative secondary filter 29, dehydrator 30, analyte capture jar 19, thermostat 34, adjustable rotor flowmeter 35, teletransmission tensimeter 25, recycling can 22, recovery pump 23 etc.; Process Control System 8 among Fig. 1 is connected to the scene, and the left side of on-line nir system 5 is power-on self-test and positive draft device among Fig. 2, and the whirlwind cooling is carried out in the periphery, and power-on self-test is communicated with instrument wind with the positive draft device by valve.
Five, hardware description, as depicted in figs. 1 and 2:
1. quick loop: the purpose in loop 1 is to obtain the process sample fast from the process line sampled point fast, and it is transferred to sample detection demand position fast, thereby reduces as much as possible the detection delay time of Process Control System.In the practical application, quick loop 1 can adopt 1/2, and " steel pipe, its pipeline should not surpass 30m, and is short as much as possible in practical ranges.
2. quick loop pump: only install quick loop 1 in the process sample region, may since fast the two ends in loop 1 do not have the former of enough pressure reduction thereby cause the transfer velocity of sample of process check point very slow, thereby cause very big system to delay, influence system control performance.For addressing this problem, adding quick loop pump on quick loop 1 is that sampling pump 11 is necessary.The selection principle of loop pump 11 is to guarantee that the sampling in quick loop 1 is steady fast, do not have pressure surge (because the pressure surge meeting causes a large amount of bubbles), and sampled fluid is continuous, and speed can be very not fast, but can not be very slow.Given this, suggestion selects gear-type pump to be advisable.In conjunction with the 1st, the 2nd point, be controlled at 30s and be advisable the actual sample time in loop 1 fast, and loop flow 300~800L/h is advisable fast.
3. bubble trap: the effect of bubble trap 13 is by the minor axis bypass, makes can not enter pretreatment unit by the bubble in the process sampling fluid of quick loop pump 11, but draws from the minor axis bypass.
4. grade one filter: grade one filter 14 is installed on the quick loop 1; the effect of grade one filter 14 is to stop that the large granular impurity (for example pipeline iron rust etc.) in the process line enters pretreatment system; block Φ 6 stainless-steel tubes of pretreatment system or damage cartridge or dehydrator core, thereby play the pretreated effect of protection.
5. pre-service reduction valve: pre-service reduction valve 24 is the process sample enters pretreatment system from quick loop 1 critical points.The oil product that flows in the pretreatment system needs stable and suitable pressure, because will consider the factor of three aspects: the one, the pressure surge meeting in the pretreatment system causes and produces bubble in the oil product; The 2nd, pressure surge may cause damage to secondary filter 29 and dehydrator 30 and on-line nir system 5 probes; The 3rd, the pressure surge meeting influences probe measurement.3 considerations for this reason, pretreatment system need be installed reduction valve 24 (pressure maintaining valve), and the oil product pressure in the control pre-service usually can be at 0.05~0.1Mpa in suitable scope.In the design in quick loop 1, fast aspect the selection of selection, the pre-service reduction valve 24 of loop pump 11, need consider according to the pressure matching relationship.
6. tensimeter: the tensimeter 25 after the pre-service reduction valve is used for the on-the-spot sample strain that shows after the pre-service reduction valve 24, helps on-the-spot artificial reduction valve 24 apertures of adjusting, and guarantees that pressure in the pretreatment system is in suitable scope.Usually reasonably the pressure limit of pretreatment system can be at 0.05~0.1Mpa.
7. water cooler: the oil product temperature in the process line may be than higher, for example 40~60 ℃; The effect that water cooler 26 is installed mainly is to have considered two following factors: the one, and the oil product temperature in the process line is too high, needs with water cooler it to be cooled to below 30 ℃; The 2nd, by reducing the oil body temperature significantly, help free water and emulsified water in the oil body to be condensed into bigger water droplet, thereby help to improve the water removal effect of dehydrator 30.
8. alternative filtrator: the secondary alternative filtrator 29 in pretreatment system is one of core devices in the pretreatment system, all impurity in the oil product and bulky grain water droplet all are blocked and are deposited in filter bottom (or directly emitting) during by cartridge at sample, thereby guaranteed to enter oil product clean of follow-up unit, guaranteed the accuracy of probe measurement.Alternative filtrator 29 adopts the working method of the using and the reserved, guarantees can drop into the standby filtrator of another at once, and can easily it be pulled down cleaning or the cartridge that more renews when a filtrator during because of dirty inefficacy.The strainability of cartridge can be selected different specifications for use according to actual viscosity and the particle concentration and the size of tested oil product, usually, crosses the optional 2um~20um of specification of filter core, can guarantee to filter the cleanliness factor of back sample substantially.But note that the order number of crossing filter core is close more, the effect of damming that filtrator causes is strong more; When using, should be noted that the relation of actual flow velocity and pressure.In design, filtrator 29 always is mounted in before the dehydrator 30.
9. dehydrator: the free water during dehydrator 30 is exclusively used in out and deoils, guarantee that the moisture in the sample oil is reduced to alap level, guarantee the accuracy of probe measurement.Dehydrator 30 is one of core devices in the pretreatment system.In actual applications, the dehydrator 30 bottoms outlet of releasing.Because dehydrator 30 has adopted coalescence technology, the little water droplet in the sample oil gathers into big water droplet at the outer wall of dehydrator core, and is settled down to dehydrator 30 bottoms under action of gravity, discharges the sampling system of probe by the bleed outlet of bottom.In actual applications, the hand valve 31 of dehydrator 30 belows be opened a very little angle (common 5~10 degree), thereby the coalescent moisture in assurance dehydrator 30 bottoms can be discharged dehydrator 30 at any time.
10. thermostat: temperature is had certain sensitivity because near-infrared analyzer detects, when temperature raises, near infrared spectrum can move to left along wavelength direction, therefore, design has thermostat 34 in the pretreatment system of reality, the oil product that assurance enters probe by constant temperature on a certain fixed temperature, thereby guarantee near-infrared analyzer side amount accurately.The thermostat temperature of suggestion is 30 ℃.Usually the constant temperature means that adopt are constant temperature oil bath.Sample is after entering pretreatment system, at first pass through the cooling of water cooler 26, temperature is reduced to below 30 ℃, through filtrator 29 and dehydrator 30, enter thermostat 34, electric heating unit, temperature sensor, gas cooler are arranged in the thermostat 34, both can heated sample oil, can give the cooling of sample oil to a certain extent again,, guarantee the temperature constant state of sample oil all the time by the temperature control unit of special use.
11. analyte capture jar: the effect of analyte capture jar 19 is manually to grasp sample in system in due course at the scene, uses in order to breadboard analysis.The capacity of analyte capture jar is 1 or 2L, and structure is for bearing the stainless steel component of malleation 0.05Mpa.
12. adjustable rotor flowmeter: adjustable rotor flowmeter 35 is equipped with in the pretreatment system exit below thermostat, can adjust the sample oil body flow velocity in the pretreatment system, the sample oil body flow velocity in the pretreatment system is within the reasonable range.Usually available adjustable rotor flowmeter 35 working ranges are 10~15L/h, and setting range can be 6~8L/h usually, thereby guarantee that the oil body that detects the space by probe has constant compression force and flow, guarantees measurement accuracy.
13. teletransmission tensimeter: the tensimeter of band teletransmission is used in suggestion, and remote transfer signal is sent to the surveillance of DCS, thereby the operator can see the pressure condition of pretreatment system on the DCS of pulpit picture.The pressure condition of pretreatment system is the important operating mode of pretreatment system, and it can reflect directly whether pretreatment system is working properly.If it is working properly, usually the pressure demonstration on the DCS can be a comparatively fixing value (actual size of this value depends on the design of actual sample pretreatment system), undesired if work, then the pressure demonstration on the DCS can be a undesired value, and this value can be a sound and light alarm by configuration, with notifying operation personnel recovery system as early as possible.
14. recycling can: the main effect of recycling can 22 is an outlet waste oil of collecting all pretreatment systems, thereby guarantees not waste oil product, free from environmental pollution.The stainless cylinder of steel that is designed to 2~5m3 (or cylinder of steel of similar volume) of recycling can 22, high low level level switch should be equipped with in inside, thereby when system works, can detect high liquid level and low liquid level in the recycling can, thus indication is reclaimed opening of pump 23 or is stopped.
15. recovery pump: the effect of reclaiming pump 23 is the two position indications according to recycling can, automatically
Turn on pump or close pump automatically makes that the oil body in the recycling can is pumped in the process line, thereby
Make the liquid level in the recycling can be in the safe range all the time.
Sample pretreatment system mentioned above, its design is selected with device, can change to some extent according to the variation of the application site of refinery reality and application places, but mentality of designing substantially is extensively and accurately, can detect for the in-line meter of process industry high-quality preprocessing means is provided.
Should be pointed out that the above embodiment can make those skilled in the art more fully understand the utility model, but limit the utility model never in any form.Therefore, although this instructions has been described in detail the utility model with reference to drawings and Examples,, it will be appreciated by those skilled in the art that still and can make amendment or be equal to replacement the utility model; And all do not break away from the technical scheme and the improvement thereof of spirit of the present utility model and technical spirit, and it all should be encompassed in the middle of the protection domain of the utility model patent.

Claims (8)

1. oil product sampling pretreatment system, first group of pretreatment unit and second group of pretreatment unit of comprising serial connection, it is characterized in that: first group of pretreatment unit is connected in the component oil pipe by quick loop, and second group of pretreatment unit is connected in on-line nir system by sampling optical fiber and detection probe.
2. oil product according to claim 1 sampling pretreatment system is characterized in that: be serially connected with on the pipeline of described first group of pretreatment unit and be used for removing the bubble trap of bubble and be used for deimpurity grade one filter.
3. oil product sampling pretreatment system according to claim 2, it is characterized in that: described bubble trap is the minor axis bypass structure.
4. oil product sampling pretreatment system according to claim 3 is characterized in that: be serially connected with alternative secondary filter and dehydrator on the pipeline of described second group of pretreatment unit.
5. oil product sampling pretreatment system according to claim 4, it is characterized in that: the inlet end of described alternative secondary filter is serially connected with water cooler.
6. oil product sampling pretreatment system according to claim 5 is characterized in that: also be serially connected with thermostat on the pipeline of described second group of pretreatment unit.
7. oil product sampling pretreatment system according to claim 6, it is characterized in that: described thermostat is the constant temperature oil bath device.
8. oil product sampling pretreatment system according to claim 7, it is characterized in that: described detection probe places the constant temperature oil bath device.
CN 200520022808 2005-02-04 2005-02-04 Oil sampling pretreatment system Expired - Lifetime CN2807241Y (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103575574A (en) * 2012-07-18 2014-02-12 上海宝钢工业技术服务有限公司 Cold rolling process medium on-line detection system sample pretreatment device
CN104515861A (en) * 2013-09-28 2015-04-15 中国石油化工股份有限公司 Integrated on-line measurement system for gasoline and diesel oil
CN106097162A (en) * 2016-08-19 2016-11-09 无锡蓝天燃机热电有限公司 A kind of thermal power plant's comprehensive water utilities managing and control system and method
CN104215481B (en) * 2013-06-05 2016-12-28 中国石油天然气股份有限公司 Online near-infrared analysis pretreatment device and method
CN106680037A (en) * 2017-03-01 2017-05-17 中国人民解放军空军勤务学院 Microsampling and constant temperature maintaining device applied to on-line analysis of liquid and method thereof
CN108931496A (en) * 2018-02-05 2018-12-04 北京航程迈进科技发展有限公司 A kind of modeling and method of gasoline sample
CN109297537A (en) * 2018-10-25 2019-02-01 于鲲 A kind of multifunctional vertical oil sight device
CN111948168A (en) * 2020-07-17 2020-11-17 中国神华煤制油化工有限公司 Measuring system
CN113049522A (en) * 2019-12-26 2021-06-29 中国石油天然气股份有限公司 Near-infrared analysis device capable of eliminating bubbles
CN113376096A (en) * 2021-05-26 2021-09-10 商丘睿控仪器仪表有限公司 Spectrum measurement while drilling system

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103575574B (en) * 2012-07-18 2017-10-03 上海宝钢工业技术服务有限公司 Cold-rolling process medium on-line detecting system sample pretreatment device
CN103575574A (en) * 2012-07-18 2014-02-12 上海宝钢工业技术服务有限公司 Cold rolling process medium on-line detection system sample pretreatment device
CN104215481B (en) * 2013-06-05 2016-12-28 中国石油天然气股份有限公司 Online near-infrared analysis pretreatment device and method
CN104515861A (en) * 2013-09-28 2015-04-15 中国石油化工股份有限公司 Integrated on-line measurement system for gasoline and diesel oil
CN104515861B (en) * 2013-09-28 2016-04-20 中国石油化工股份有限公司 Gasoline and diesel oil integration on-line measurement system
CN106097162A (en) * 2016-08-19 2016-11-09 无锡蓝天燃机热电有限公司 A kind of thermal power plant's comprehensive water utilities managing and control system and method
CN106680037A (en) * 2017-03-01 2017-05-17 中国人民解放军空军勤务学院 Microsampling and constant temperature maintaining device applied to on-line analysis of liquid and method thereof
CN108931496B (en) * 2018-02-05 2021-06-04 北京航程迈进科技发展有限公司 Method for modeling gasoline sample by adopting modeling system of gasoline sample
CN108931496A (en) * 2018-02-05 2018-12-04 北京航程迈进科技发展有限公司 A kind of modeling and method of gasoline sample
CN109297537A (en) * 2018-10-25 2019-02-01 于鲲 A kind of multifunctional vertical oil sight device
CN113049522A (en) * 2019-12-26 2021-06-29 中国石油天然气股份有限公司 Near-infrared analysis device capable of eliminating bubbles
CN113049522B (en) * 2019-12-26 2023-07-25 中国石油天然气股份有限公司 Near infrared analysis device capable of eliminating bubbles
CN111948168A (en) * 2020-07-17 2020-11-17 中国神华煤制油化工有限公司 Measuring system
CN111948168B (en) * 2020-07-17 2023-09-08 中国神华煤制油化工有限公司 Measuring system
CN113376096A (en) * 2021-05-26 2021-09-10 商丘睿控仪器仪表有限公司 Spectrum measurement while drilling system
CN113376096B (en) * 2021-05-26 2022-11-04 商丘睿控仪器仪表有限公司 Spectrum measurement while drilling system

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