CN2775094Y - Anti-corrosion fire-proof cable - Google Patents
Anti-corrosion fire-proof cable Download PDFInfo
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- CN2775094Y CN2775094Y CN 200420033629 CN200420033629U CN2775094Y CN 2775094 Y CN2775094 Y CN 2775094Y CN 200420033629 CN200420033629 CN 200420033629 CN 200420033629 U CN200420033629 U CN 200420033629U CN 2775094 Y CN2775094 Y CN 2775094Y
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- cable
- anticorrosion
- protection
- anode layer
- corrosion
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Abstract
The utility model relates to a cable with a protecting layer which has a corrosion-proof function and a fireproof function. The utility model is provided with a corrosion-proof system which has a combined cathode protecting function which can be monitored, adjusted and controlled and a combined shielding protecting function; the corrosion-proof system can prevent the cable from being corroded for a long time in various moisture natural environments; when the cable encounters fires, compositions in the protecting layer can be fast expanded forming a firm thermal insulating layer with high efficiency causing the fire endurance of the cable to reach more than 2 hours. The utility model is suitable for various heavy sections structures has a need of corrosion prevention for a long time or a need of simultaneous corrosion prevention and fire prevention, such as being used as required stay cables or suspension cables and other cables for making various large bridges, heavy sections structure buildings, airport facilities, sports halls, exhibition halls and other heavy sections structure buildings.
Description
Technical field
The utility model relates to a kind of cable with overcoat, this overcoat all has the long life anti corrosion function to various forms of steel cables or has anticorrosion and the fire prevention dual-use function, the cable of making by the utility model is applicable to various large-scale steel structure buildings, cables such as suspension cable that large-scale steel structure buildings such as for example various large bridges and airport installation, gymnasium, exhibition center are required or suspension cable avoid steel building because of the security incident of corroding or fire causes.
Background technology
Development along with modern building cause, the suspension cable that suspension cable that is formed by the steel wire that kinks and parallel wire unit are formed has obtained using widely in numerous modern bridges and steel building, and the anticorrosion of cable and fire prevention become the safety that influences bridge and building and service life one a very important techniques difficult problem.Because the particularity of line structure; be difficult to adopt conventional anticorrosive coating or fireproof paint to protect; the PE resin that existing cable is most to be adopted the PE resin or be added with fire retardant is as protective layer; the PE protective layer is because of aging in long-term use; or fine gap appears in other reasons unavoidably; moisture or corrosive medium are easy to infiltrate; particularly at the easier infiltration corrosive medium of the seam crossing of ground tackle; make steel wire corrosion and cable forfeiture mechanical strength and rupturing; cause major accident; also can only self play fire retardation though added fire retardant to the PE protective layer; it does not possess effect of heat insulation; therefore the steel cables back intensity decreases of being heated causes building collapse during breaking out of fire, can not effectively prevent to corrode or destruction that fire causes, to the security of steel construction with cause service life and have a strong impact on.
Summary of the invention
The purpose of this utility model is exactly to solve above-mentioned technical barrier, seeks a kind of characteristics that can adapt to cable fully, has the technical scheme of anticorrosion and fire prevention dual-use function simultaneously, and this technical scheme must possess following three characteristics:
One, because cable belongs to flexible construction material, therefore anticorrosion and the fire proofing material that matches with it also must be flexible, can be attached to the cable surface for a long time securely.
Two, in the projected life of steel construction, can keep reliable anticorrosion and flameproof effect for a long time.
Protective layer can expand rapidly when three, meeting fire, forms the abundant firm fire proof heat-insulation layer of one deck, and fire endurance can satisfy the fire-fighting requirement.
Have now found that the corrosion proof function that having of a kind of flexibility is fabulous or have anticorrosion simultaneously and the composition of fire prevention dual-use function; it is clamp-oned it in external protection of cable with extruding or additive method; make it be coated on the appearance of cable steel wire; and in the gap of steel wire and steel wire, infiltrate anticorrosive composite (9), just can reach the purpose of this utility model.This anticorrosion fire retardant composition is to have the electrolyte ion conducting, and iron and steel is had the composition of fabulous corrosion inhibitive function, can increase substantially the anticorrosion life-span of cable, and said composition also has the fire of the chance formation fire proof heat-insulation layer that can expand simultaneously.Being burnt when soft when cable during breaking out of fire by PE or by the external protection that other resin is made; the fire retardant anticorrosion composition (2) of the inside just begins to expand; after the external protection scaling loss is broken and is come off; said composition continues to expand and forms the abundant firm fire proof heat-insulation layer of one deck, and fire endurance can reach more than 2 hours.
Below the technical solution of the utility model is described in detail: described anti-corrosive compositions or have simultaneously anticorrosion and the fire prevention dual-use function composition be selected from various types of silicate, poly silicate, various types of phosphate, polyphosphate, various types of borates, boric acid, diboron trioxide, aluminate, the part hydrolyzing ethyl silicate, waterglass, KP1, lithium silicate, aerosil, white carbon, titanium dioxide, aluminium hydroxide, aluminium oxide, zinc hydroxide, zinc oxide, magnesium hydroxide, magnesia, calcium hydroxide, zirconia, powdery waterglass, Ludox, talcum powder, organic amine is a nitrogen-containing compound, dicyandiamide, melamine, hexamethylenetetramine, urea, ammonium oxalate, ammonium carbonate, or the aqueous of above-mentioned all cpds, wherein a kind of or several.Wherein various types of silicate, poly silicate, various types of phosphate, polyphosphate, various types of borates, boric acid, diboron trioxide, aluminate, waterglass, KP1, lithium silicate, powdery waterglass, Ludox and partial hydrolysis silester all are the inorganic matters to the conducting of electrolyte ion energy, and iron and steel all had good corrosion inhibitive function, when saturation state or heating and melting state all is the jelly of thickness, under the effect of expanding gas, can both foam when being heated, these materials and point out above various two, three, the hydroxide or the oxide of tetravalent metal (or nonmetal) mix, behind the heating and melting foaming and intumescing, can form firm thermostable heat insulation layer, therefore play effectively anti-fire action.Also can add various organic amines in this external above-mentioned composition is nitrogen-containing compound, or inorganic ammonium based compound, for example dicyandiamide, melamine, hexamethylenetetramine, urea, ammonium oxalate, ammonium carbonate, ammonium phosphate, ammonium polyphosphate etc., the compound decomposes of these organic amines or inorganic ammonium generation great amount of carbon dioxide and ammonia impel the composition foaming when meeting fire, improve effect of heat insulation.In order to improve the heat insulation effect that expands, can also add other expansible fireproof composition, being selected from organic or inorganic expansion fire-proof composition, self-expanding monomer, amino phenyl sulfonyl hydrochlorate, chlorine sulphonyl is fire retardant composition, expansion type phosphor phosphate-gallate series fire retardant composition to aniline, charcoal becoming expansible fireproof composition, intumescent silicate, wherein a kind of or several.Can add various ionic conduction type corrosion inhibiter in order to improve corrosion mitigating effect, for example: chromate, bichromate, molybdate, zincate, nitrite, benzoate, carbonate, bicarbonate, citrate, tartrate, glucose, gluconate, thiocarbamide, rust resisting pigment, dicyclohexyl amine nitrite, adhesion for enhancing composition, improve the physical property of composition, Corrosion Protection and effect of heat insulation, can also add and fire resin or synthetic resin in various days, animal glue, latex, white glue with vinyl, thermosol, EVA, VAE, polyethers, polyester, polyamide, epoxy resin, polyvinyl alcohol, polyvinyl acetal resin, polyvinyl acetate emulsion, carboxymethyl cellulose, starch, ion exchange resin, glycerine, ethylene glycol, pentaerythrite, bentonite, organobentonite, attapulgite, powder coal ash glass-microballons, talcum powder, zirconia, magnesium zirconate, diatomite, mica powder, anti-settling agent, the intumescent flexibel charcoal, wherein a kind of or several.
For requiring the fireproof occasion; external protection of the present utility model should adopt when meeting fire and can soften; the material that breaks and come off is made; anticorrosion fire retardant composition inside so just can not hindering is heated outwards to expand and forms thermal insulation layer; the different temperatures that begins to expand according to different anticorrosion fire retardant compositions is selected the material of external protection for use; can adopt existing P E resin or be added with the PE resin of fire retardant; can adopt the composition of EVA resin or PE and EVA and the modifier of PE or EVA in order to reduce softening temperature; also can adopt other synthetic resin; natural resin; hot melt adhesive or rubber; or be added with the above-mentioned various resins or the rubber of fortifying fibre or plasticizer or reinforcing agent; or aluminum composite, and the above-mentioned various resins or rubber or the aluminum composite that are added with fire retardant.Described fire retardant is selected from inorganic combustion inhibitor, organic fire-retardant, halide fire retardant, phosphoric acid ester fire retardant, halophosphoric acid lipid fire retardant, chlorinated paraffin wax, chlorinated biphenyl, decabromodiphenyl oxide, tricresyl phosphate, β one trichloro-ethylene phosphate, poly-2,6 dibromobenzene aethers (PBO), tetrabromobisphenol, tetrabromoethane, antimonous oxide, and is wherein at least a.For prevent cable store, park with transportation in; the influence of invar stopper own wt is expressed to a side with anticorrosion fire retardant composition; cause the composition skewness; should in external protection, be added with supporter or support (5) by protruding supporter or spiral wire circle that external protection extends internally; thereby keep between external protection and the cable uniform spacing being arranged; make anticorrosion fire retardant composition be able to even distribution, see Fig. 1,2,3.The anticorrosion fire prevention cable of making according to such scheme proves that through simulated test fire endurance can be seen Fig. 5 more than 2 hours.The thin wall tubule (10) of easily changing in the time of also can adopting chance to go out calamity or breaking loads anticorrosion fire retardant composition, thereby anticorrosion fire retardant composition is evenly distributed, and as shown in Figure 8, this thin wall tubule preferably has semi-transparent character, make the conducting of corrosion inhibiter ion energy, thereby improve anticorrosion ability.
Occasion for the better anticorrosion ability of needs, thin plate that employing is made than the electronegative metal material of the negative at least 100mV of carbon steel by electrode potential or metal forming or wire are as the inner anode layer, method by parcel or winding, steel cables is coated, and make mutual conducting (electronic conduction) make therebetween resistance less than 1 Ω.In the PE external protection, between the slit of the inside and outside of inner anode layer and cable steel wire, all be full of can conducting to electrolyte ion anticorrosive composite (9) or anticorrosion fire retardant composition (2), thereby formed an electrochemistry closed-circuit system, see Fig. 4.Therefore the inner anode layer of this electronegative metal material making plays extremely effectively cathodic protection effect to whole steel wires of cable; the electronegative metal material of making this inner anode layer is selected from aluminium, aluminium alloy, zinc or the kirsite that is added with a kind of or several nothing elements in zinc, silicon, magnesium, mercury, indium, gallium, tin, cadmium, aluminium, manganese, titanium, carbon, nickel, bismuth, lead, calcium, beryllium, lithium, antimony, strontium, scandium, zirconium, vanadium, chromium, molybdenum, phosphorus, boron, germanium, rare earth metal or other the no elements, and is wherein at least a.With wherein a kind of aluminium alloy is example; its Main Ingredients and Appearance is to contain zinc 9~10%; contain magnesium 0.9~1%; contain zirconium 0.3~0.45%; all the other are aluminium, and the electrode potential of this metal has good plasticity again than the negative 200mV~220mV of iron; but wire drawing or be squeezed into thin plate or paper tinsel protects cable to play fabulous cathodic protection effect with it.
Anticorrosion fire prevention cable according to such scheme is made reaches as salt-fog resistant test more than 3000 hours through carving brokenly external protection, and the cable steel wire is stainless, therefore can guarantee cable not corroding for a long time in various moist natural environments.
Require higher occasion for anticorrosion; the measure of adopting controlled cathodic protection to combine with shielding protection; this cable is by one or more layers external protection (1); anticorrosive composite (9) or anticorrosion fire retardant composition (2); inner anode layer (4); electrical isolation layer (11); steel cables (3); permeating the ground tackle (13) at anticorrosive composite (9) between the cable steel wire and cable two ends forms; by conducting connecting part and external wire; with cable and inner anode layer and test instrumentation electric connection; or be connected in series a regulatable external D.C. regulated power supply (15) therebetween again and form a kind of adjustable; the corrosion protection system that the cathodic protection that can monitor combines with shielding protection or also have the cable of fire-proof function simultaneously; the material of making inner anode layer or conducting connecting part is electronegative metal material or non-sacrifice conductive material; provide cathodic protection current by the electronegative metal material or by external D.C. regulated power supply or by both actings in conjunction; cable is played the cathodic protection effect, make cathodic protection be in optimum state for a long time by regulation and control and monitoring.Described electrical isolation layer is meant rete, separation layer or the braided fabric that the various nonmetallic materials of electronic isolation are made, or refer to electronic isolation but to electrolyte ion can conducting pellicle or amberplex.
Require more to increase for anticorrosion but do not need to prevent fires or occasion that fire protection requirement is low; can adopt the measure that increases outer anode layer; this cable is by one or more layers external protection (1); outer anode layer (6); anticorrosive composite (9); inner anode layer (4); electrical isolation layer (11); steel cables (3); permeating the ground tackle (13) at anticorrosive composite (9) between the cable steel wire and cable two ends forms; by conducting connecting part and external wire; with cable and inner anode layer; outer anode layer and test instrumentation electric connection; or be connected in series a regulatable D.C. regulated power supply (15) therebetween again; form a kind of adjustable; the corrosion protection system that the cathodic protection that can monitor combines with shielding protection; the material of making inner anode layer or outer anode layer or conducting connecting part is electronegative metal material or non-sacrifice conductive material; provide cathodic protection current by the electronegative metal material or by external D.C. regulated power supply or by both actings in conjunction, cable is played the cathodic protection effect.According to different needs; also can cancel inner anode layer (4); outer anode layer directly is electrically connected with cable cathodic protection and shielding protection is provided; or outside electrical isolation layer and anticorrosive composite are isolated behind the electronics path between anode layer and the cable; again by conducting connecting part and external wire; with outer anode layer and cable and test instrumentation electrical communication; or be connected in series a regulatable D.C. regulated power supply therebetween again; form a kind of adjustable; the cathodic protection system that can monitor, the outside of anode layer (6) can add the outer layer (1) of protecting outside, plays humidification; see Fig. 7; also can not add external protection in addition, outer anode layer plays the outer layer of protecting simultaneously, sees Fig. 6.
Description of drawings:
The anticorrosion fire prevention erosion cable schematic cross-sectional view that the projection of inside extension that has Fig. 1 external protection supports.
Fig. 2 is the schematic diagram that has the anticorrosion fire prevention cable cross section of spiral wire circle support.
Fig. 3 is the schematic diagram that has the anticorrosion fire prevention cable vertical section of spiral wire circle support.
Fig. 4 is enclosed with the schematic diagram in the anticorrosion fire prevention cable cross section of electronegative metal inner protective layer.
The sectional schematic diagram of Fig. 5 cable downside of the present utility model after the flame torch firing forms the expansion thermal insulation layer.
Fig. 6 replaces high-efficiency anticorrosive (not preventing fires) the cable sectional schematic diagram of PE external protection with outer anode layer.
Fig. 7 increases the schematic diagram in the cable cross section of the external protection that one deck strengthens again outside outer anode layer shown in Figure 6.
Fig. 8 adopts thin wall tubule to load the anticorrosion fire prevention erosion cable schematic cross-sectional view of anticorrosion fire retardant composition.
The corrosion protection system schematic diagram that the cathodic protection that Fig. 9 is adjustable, can monitor combines with shielding protection.
1. external protection
2. anticorrosion fire retardant composition
3. steel cables
4. inner anode layer
5. the spirality steel traveler supports
6. outer anode layer
7. conducting connecting part
8. anticorrosion fire retardant composition is met the refractory insulating layer that forms after fire expands
9. anticorrosive composite
10. thin wall tubule
11. electrical isolation layer
12. lead
13. ground tackle
14. test instrumentation
15. regulatable D.C. regulated power supply
The specific embodiment
Illustrate embodiment of the present utility model below, they only are some examples wherein, can not represent full content of the present utility model:
One, anticorrosion fire retardant composition formula examples:
Prescription one
Waterglass 35% pentaerythrite 2%
Magnesia 8% melamine 10%
Aluminium hydroxide 30% ammonium molybdate 3%
Prescription two
Polyphosphoric acids aluminium 20% gelatin (10% liquid) 10%
Talcum powder 20% zinc yellow 3%
Sodium metasilicate 30% starch 2%
Prescription three (for soaking the anticorrosive composite that cable is used)
Waterglass 60% glucose 5%
Aluminium hydroxide 25% magnesium hydroxide 10%
Two, implementation example:
Embodiment one
At first made the plastic tube of external protection effect of the PE resin that is added with fire retardant; the internal diameter of pipe is than the big 3mm of external diameter of the steel cables (3) that will coat; appearance winding screw shape steel traveler in steel cables supports (5); the external diameter that the spirality steel traveler supports is slightly less than the internal diameter of external protection; the steel cables (3) that will be wound with spirality steel traveler support (5) is then soaked in by the anticorrosive composites (9) of prescription three preparations; make the anticorrosive composite (9) that all is full of infiltration in the slit between the cable steel wire; then steel cables (3) is filled in external protection (1) again by will fill a prescription one anticorrosion fire retardant composition (2) of fashion of extrusion and riddle in the cavity between external protection (1) and the steel cables (3); ground tackle is loaded onto at the two ends of cable; and tight sealing, guarantee that the anticorrosion fire retardant composition in the cavity can not leak.
Embodiment two
Twine or wrap up 1~2 layer of electronegative metal silk or other inner anode layers (4) in advance in the appearance of steel cables (3) by electronegative metal material system; suitably increase the internal diameter of external protection; the volume that keeps cavity is with embodiment one; other are all identical with embodiment one; better by the anticorrosion fire prevention cable decay resistance that this method is made, fire-resistant situation is the same.
Embodiment three
Adopt the PE resin to make external protection; make outer anode layer with the electronegative metal material; behind the electronics path outside electrical isolation layer and anticorrosive composite isolation between anode layer and the cable; again by conducting connecting part and external wire with outer anode layer and cable and test instrumentation electrical communication; be connected in series a regulatable D.C. regulated power supply therebetween again; form the system that a kind of cathodic protection adjustable, that can monitor combines with shielding protection; not needing to be used for fire prevention; but anticorrosion requires higher occasion, sees Fig. 9.
Claims (6)
1. anticorrosion fire prevention cable; it is characterized in that in the external protection (1) and the cavity between the steel cables (3) at cable; be full of anticorrosive composite (9) or anticorrosion fire retardant composition (2); in the gap of cable steel wire, be full of infiltration anticorrosive composite (9) therebetween; and the ground tackle of being adorned by the cable two ends (13); anticorrosive composite (9) or anticorrosion fire retardant composition (2) tightly are closed in the above-mentioned cavity, thereby form a kind of cable with anti-corrosion function or anticorrosion, fire prevention dual-use function.
2. by the described anticorrosion fire prevention of claim 1 cable; it is characterized in that within anticorrosive composite (9) or anticorrosion fire retardant composition (2) and outside steel cables (3); also increased the inner anode layer (4) of one or more layers electrode potential than the negative at least 100mV of steel; be conducting to electronics between this inner anode layer and the steel cables; resistance therebetween is less than 1 Ω, so this inner anode layer plays the cathodic protection effect to steel cables.
3. by the described anticorrosion fire prevention of claim 2 cable; it is characterized in that within the inner anode layer (4) and outside the steel cables (3); also increased one deck electrical isolation layer (11); by conducting connecting part and external wire; steel cables is connected with inner anode layer and test instrumentation; composition is to the circuit of electronic conduction; or be connected in series a regulatable D.C. regulated power supply (15) therebetween again, form a kind of the monitoring and maybe can monitor and corrosion protection system that regulatable cathodic protection combines with shielding protection or also have the cable of fire-proof function simultaneously.
4. by claim 1 or claim 2 or the described anticorrosion fire prevention of claim 3 cable; it is characterized in that within external protection (1); outside the anticorrosive composite (9); also increase outer anode layer (6) is arranged; by direct contact or by conducting connecting part and external wire; steel cables is connected with outer anode layer; composition is to the circuit of electronic conduction; form a kind of the monitoring and maybe can monitor and corrosion protection system that regulatable cathodic protection combines with shielding protection, it is high and do not need the fireproof occasion to be used for the anticorrosion requirement.
5. by claim 1 or claim 2 or the described anticorrosion fire prevention of claim 3 cable; it is characterized in that replacing external protection (1) by outer anode layer (6); by direct contact or by conducting connecting part and external wire; steel cables is connected with outer anode layer; composition is to the circuit of electronic conduction; form a kind of the monitoring and maybe can monitor and corrosion protection system that regulatable cathodic protection combines with shielding protection, it is high and do not need the fireproof occasion to be used for the anticorrosion requirement.
6. by claim 1 or claim 2 or the described anticorrosion fire prevention of claim 3 cable; it is characterized in that in described external protection, being added with supporter or support (5) by protruding supporter or spiral wire circle that external protection extends internally; thereby keep between external protection and the cable uniform spacing being arranged; or adopt thin wall tubule (10) to load anticorrosion fire retardant composition, thereby anticorrosion fire retardant composition is evenly distributed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200420033629 CN2775094Y (en) | 2004-05-20 | 2004-05-20 | Anti-corrosion fire-proof cable |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200420033629 CN2775094Y (en) | 2004-05-20 | 2004-05-20 | Anti-corrosion fire-proof cable |
Publications (1)
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CN2775094Y true CN2775094Y (en) | 2006-04-26 |
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CN 200420033629 Expired - Fee Related CN2775094Y (en) | 2004-05-20 | 2004-05-20 | Anti-corrosion fire-proof cable |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102040744A (en) * | 2010-12-10 | 2011-05-04 | 四川大学 | Mixed salt flame retardant of phosphoric acid, gluconic acid and melamine and preparation method thereof |
CN105525296A (en) * | 2015-12-24 | 2016-04-27 | 天津工业大学 | Corrosion prevention method for metal |
CN113322699A (en) * | 2021-08-03 | 2021-08-31 | 南通隆彩纺织科技有限公司 | High-strength fireproof cable rope |
FR3108913A1 (en) * | 2020-04-06 | 2021-10-08 | Nexans | Cable comprising a fire-resistant and/or retardant composition |
-
2004
- 2004-05-20 CN CN 200420033629 patent/CN2775094Y/en not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102040744A (en) * | 2010-12-10 | 2011-05-04 | 四川大学 | Mixed salt flame retardant of phosphoric acid, gluconic acid and melamine and preparation method thereof |
CN102040744B (en) * | 2010-12-10 | 2012-03-21 | 四川大学 | Mixed salt flame retardant of phosphoric acid, gluconic acid and melamine and preparation method thereof |
CN105525296A (en) * | 2015-12-24 | 2016-04-27 | 天津工业大学 | Corrosion prevention method for metal |
CN105525296B (en) * | 2015-12-24 | 2018-04-10 | 天津工业大学 | A kind of anti-corrosion method for metal |
FR3108913A1 (en) * | 2020-04-06 | 2021-10-08 | Nexans | Cable comprising a fire-resistant and/or retardant composition |
WO2021205104A1 (en) * | 2020-04-06 | 2021-10-14 | Nexans | Fire resistant and/or retardant composition |
CN115335490A (en) * | 2020-04-06 | 2022-11-11 | 耐克森公司 | Fire-resistant and/or flame-retardant composition |
CN113322699A (en) * | 2021-08-03 | 2021-08-31 | 南通隆彩纺织科技有限公司 | High-strength fireproof cable rope |
CN113322699B (en) * | 2021-08-03 | 2021-09-24 | 南通隆彩纺织科技有限公司 | High-strength fireproof cable rope |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060426 |