CN2735556Y - Flat type metal air battery - Google Patents

Flat type metal air battery Download PDF

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Publication number
CN2735556Y
CN2735556Y CN 200420041891 CN200420041891U CN2735556Y CN 2735556 Y CN2735556 Y CN 2735556Y CN 200420041891 CN200420041891 CN 200420041891 CN 200420041891 U CN200420041891 U CN 200420041891U CN 2735556 Y CN2735556 Y CN 2735556Y
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CN
China
Prior art keywords
negative pole
air electrode
metal
air
air cell
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Expired - Fee Related
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CN 200420041891
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Chinese (zh)
Inventor
李璐
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Individual
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Individual
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Priority to CN 200420041891 priority Critical patent/CN2735556Y/en
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Publication of CN2735556Y publication Critical patent/CN2735556Y/en
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    • Y02E60/128

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Abstract

The utility model relates to a flat type metal air battery. The first structure of the battery is that the upper bottom and the lower base of the battery are all air electrodes. The second structure of the battery is that the upper bottom or the lower base of the battery is an air electrode, and the rest part of the battery is a shell. A cathode is parallelly or aslant assembled to the air electrode. The electrolyte is filled between the air electrode and the cathode. By adopting this structure, the utility model can improve the availability ratio of the cathode materials. The problems of lower barrier and deformation of the cathode are solved. The cathode can stably output the current under the chronically hygroscopic holding state and dynamic use state. The pressure to the air electrode caused by the cathode is reduced, and the lifetime of the air electrode is prolonged.

Description

Flat metal-air cell
Technical field:
The device that it is electric energy that the utility model relates to a kind of direct transformation chemical energy, particularly flat metal-air cell.
Background technology
The at present actual chemical cell kind of using is more various, the battery of property use once, but the repeated charge battery is also arranged.These batteries have a common feature, and exactly that the both positive and negative polarity chemical reaction is required active material is stored in inside battery, and the active material that the energy of battery output all relies on inside battery to store provides, and this just makes battery output energy be restricted.
In recent years, the research of metal-air cell is comparatively active, metal-air cell and above-mentioned battery relatively, it is big, cheap to have an output energy, can utilize in the air oxygen as the active material of positive pole.Save characteristics such as earth resource.At present in the metal-air cell field, the design of patent or product structure all is to be the form on vertical base and deisgn product structure with the negative pole.With reference to Fig. 1, existing air cell generally includes air electrode 1, negative pole 2, barrier film 3 and electrolyte 5.Air electrode 1 is arranged in parallel with negative pole 2 vertical bases, and electrolyte 3 is filled in the space between air electrode and the negative pole.This structure of air cell exists in actual use builds under the negative pole or fracture, make the active material of negative pole 2 be deposited in the bottom of air cell, cause the air cell output capacity to reduce, output current density reduces, air electrode 1 bottom pressurized, the problems such as useful life of shortening air electrode.
Invention constitutes
The purpose of this utility model is to overcome the deficiencies in the prior art part, and provides a kind of metal-air cell negative pole that can solve fully the flat metal-air cell structure of base, fracture down in use to occur.The battery of this structure can guarantee that in the process of vibration, transportation, long preservation the negative pole shape that holds its shape is constant, makes battery regular picture performance, and especially the dynamic discharge performance has had sufficient assurance.
The purpose of this utility model can realize by following approach:
Flat metal-air cell comprises air electrode, negative pole, electrolyte, barrier film, housing, negative pole expansion cushion chamber, steam vent or explosionproof hole.Its main points are that the metal-air cell structure is flat shape, and the size of length or Width is greater than the size of short transverse, and air electrode is the upper base of air cell and goes to the bottom, perhaps is upper base, perhaps for going to the bottom.Negative pole is parallel to upper base or goes to the bottom at inside battery, or has certain included angle with air electrode.Like this, because negative pole is horizontal positioned basically, pass through barrier film, electrolyte closely contacts with air electrode, with regard to the problem of having avoided negative pole in transportation, use, to be out of shape owing to vibrations, negative pole is remained unchanged substantially with respect to the shape of air electrode, and making negative pole reach design capacity has had reliable basis.Because the negative pole dimensionally stable, but negative pole is with regard to stable output current.
The utility model can also further be specially:
There are multiple choices the position of air electrode in air cell, below is wherein four kinds.
Air electrode is going to the bottom of air cell, and air electrode comprises watertight composition, air-permeable layer, collector, Catalytic Layer.Upper base and side are the housing of air cell, and housing is processed by macromolecule polymer material, also can be by metal material processing.Negative pole can parallel placement with air electrode, also can have certain included angle.Negative pole closely contacts with air electrode by electrolyte or barrier film, and the parallel air electrode top that is assemblied in of negative pole just can effectively solve under the negative pole and build, is out of shape, the problem that the output energy reduces.Reserve certain space between negative pole or electrolyte and the upper base, use, steam vent or explosionproof hole are installed in a certain position of upper base or side as negative pole expansion cushion chamber.
Air electrode is the upper base of air cell, goes to the bottom to constitute the housing of air cell with the side, and housing is processed by macromolecule polymer material.Side or upper base at housing have a salient position, as negative pole expansion cushion chamber, at the top of cushion chamber steam vent or explosionproof hole are installed.Negative pole and electrolyte are filled in upper base (air electrode) and go to the bottom in the formed space, must guarantee that negative pole or electrolyte closely contact with upper base by barrier film, with the reduction internal resistance of cell.Air electrode is as the upper base of air cell, can slow down negative pole, the electrolyte pressure to air electrode, plays the effect that prolongs life of air electrode.
Air electrode is the upper base of air cell and goes to the bottom that the side is a housing, and housing is processed by macromolecule polymer material.At upper base or side negative pole expansion cushion chamber is installed, steam vent or explosionproof hole is housed at the top of cushion chamber.The air cell internal structure is that the air cell upper base is identical with air electrode.The hateful big air cell power output of this structure is effectively utilized limited space, improves the negative pole utilance.
Air electrode be air cell upper base, go to the bottom and one of them side (or several side), carry out different combinations according to the requirement of air cell power output, its internal structure and steam vent can be determined with reference to above-mentioned several forms.
The negative material of air electrode can adopt metals such as zinc, magnesium, aluminium, iron.Negative pole structure specifically can be divided into tabular negative pole, platinum shape negative pole, powder negative pole, the tabular negative pole of powder, graininess negative pole, pasty state powder negative pole.If negative pole adopts powder negative pole, the tabular negative pole of powder, graininess negative pole, pasty state powder negative pole just must insert negative current collector in negative pole, collect the electric current of metal particle output.Tabular negative pole specific area is less, occur polarization easily, but negative pole intensity is better, and the tabular negative pole specific area of powder is bigger, and the output current ability is strong, and utilance is higher, but negative pole intensity is lower.
The electrolyte form can be taked two kinds of forms, and first kind is liquid, is gel state in second.The liquid electrolyte internal resistance is less, be fit to the output high current density and use, but the cell sealing difficulty is bigger, and the gel state electrolyte internal resistance is bigger, is suitable in the output, the low current density occasion uses, and cell sealing is more or less freely, and the battery that is fit to dynamically use uses.
Description of drawings
Accompanying drawing 1 is a metal-air cell prior art structure chart described in the utility model.
Accompanying drawing 2 is the structure chart of flat type metal-air cell embodiment 1 described in the utility model.
Accompanying drawing 3 is the structure chart of flat type metal-air cell embodiment 2 described in the utility model.
Accompanying drawing 4 is the structure chart of flat type metal-air cell embodiment 3 described in the utility model.
Accompanying drawing 5 is the structure chart of flat type metal-air cell embodiment 4 described in the utility model.
Accompanying drawing 6 is the structure chart of flat type metal-air cell embodiment 5 described in the utility model.
Accompanying drawing 7 is the structure chart of flat type metal-air cell embodiment 6 described in the utility model.
The explanation of accompanying drawing code name
The 1-air electrode, 2-negative pole, 3-barrier film, 4-housing, 5-electrolyte, 6-steam vent (explosionproof hole), 7-cushion chamber, 8-negative current collector
Specific embodiment
Embodiment 1:
With reference to Fig. 2, flat metal-air cell comprises air electrode 1, negative pole 2, barrier film 3, housing 4, electrolyte 5, steam vent (or explosionproof hole) 6, and air electrode 1 is gone to the bottom for air cell, upper base and side are housing, and steam vent (or explosionproof hole) 6 is installed on housing 4.Air electrode 1 has the function of waterproof, conduction, ventilative, catalysis, is the positive pole of flat metal-air cell.Air electrode 1, housing 4, steam vent 6 constitute battery case.Internal layer near air electrode 1 posts one deck barrier film 3, and barrier film 3 can prevent air electrode and negative pole short circuit.Negative pole 2 is filled in air electrode 1 and the housing 4 formed spaces, electrolyte 5 is filled in around the negative pole 2, negative pole 2 is contacted with air electrode 1 by electrolyte, between electrolyte 5 or negative pole 2 and housing 4, reserve certain space, as negative pole 2 expansion cushion chambers 7.
Embodiment 2:
With reference to Fig. 3, Fig. 3 is the salient position that the cushion chamber among Fig. 27 is moved to housing 4, and negative pole 2 or electrolyte 5 can contact with housing 4.At the top of cushion chamber 7 steam vent 6 is arranged
It is identical with embodiment 1 that present embodiment is not stated part.
Embodiment 3:
With reference to Fig. 4, the upper base of flat metal-air cell shell is that with going to the bottom air electrode 1, remainder are housing 4 and cushion chamber 7.At the top of cushion chamber 7 steam vent 6 is arranged, negative pole 2 or electrolyte 5 contact with upper base.
It is identical with embodiment 1 that present embodiment is not stated part.
Embodiment 4:
With reference to Fig. 5, add respectively at embodiment 1, embodiment 2, the inner filling of embodiment 3 described flat air cells negative pole 2, electrolyte 5, also pasty state powder negative pole 2 can be filled separately, and not need to dose once more electrolyte 5.In the middle of pasty state powder negative pole 2, insert negative current collector 8, to play the purpose of collected current.
It is identical with embodiment 1 that present embodiment is not stated part.
Embodiment 5:
With reference to Fig. 6, structure shown in Figure 6 and structure difference shown in Figure 3 are: the upper base of structure shown in Figure 6 is an air electrode 1, and remainder is housing 4 and cushion chamber 7.
It is same with embodiment 3 that present embodiment is not stated part.
Embodiment 6:
With reference to Fig. 7, structure shown in Figure 7 and structure difference shown in Figure 4 are: the upper base of structure shown in Figure 7, go to the bottom and a side of housing 4 is made up of air electrode 1.Remainder is housing 4 and cushion chamber 7.
It is identical with embodiment 3 that present embodiment is not stated part.

Claims (6)

1. flat metal-air cell, comprise air electrode (1), negative pole (2), barrier film (3), housing (4), electrolyte (5), steam vent or explosionproof hole (6), cushion chamber (7), collector (8), it is characterized in that: air electrode (1) is for the upper base of metal-air cell and go to the bottom or upper base or go to the bottom or upper base and side or go to the bottom and the side, negative pole expansion cushion chamber (7) is arranged on housing (4), negative pole (2) is by electrolyte (5), and barrier film (3) contacts with air electrode (1).
2. flat metal-air cell according to claim 1 is characterized in that: negative pole (2) is with respect to the parallel assembling of air electrode (1) or the assembling of tilting.
3. according to the described flat metal-air cell of claim (1), it is characterized in that: the salient position of housing (4) is the expansion cushion chamber (7) of negative pole (2).
4. flat metal-air cell according to claim 1 is characterized in that: negative pole (2) comprises pasty state metal dust negative pole, the tabular negative pole of metal powder, metal plate-like negative pole, metal platinum shape negative pole, metal powder negative pole, chargeable negative pole.
5. flat metal-air cell according to claim 1 is characterized in that: the top of cushion chamber (7) is equipped with steam vent (6).
6. flat metal-air cell according to claim 1 is characterized in that; Housing (4) is formed by alkaline-resisting high molecular polymer, alkaline-resisting metal material, metal material processing with alkaline-resisting coating.
CN 200420041891 2004-05-10 2004-05-10 Flat type metal air battery Expired - Fee Related CN2735556Y (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200420041891 CN2735556Y (en) 2004-05-10 2004-05-10 Flat type metal air battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200420041891 CN2735556Y (en) 2004-05-10 2004-05-10 Flat type metal air battery

Publications (1)

Publication Number Publication Date
CN2735556Y true CN2735556Y (en) 2005-10-19

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CN 200420041891 Expired - Fee Related CN2735556Y (en) 2004-05-10 2004-05-10 Flat type metal air battery

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CN (1) CN2735556Y (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107946603A (en) * 2017-12-15 2018-04-20 刘芙蓉 A kind of double activated material cell anode chamber
CN109494431A (en) * 2018-11-12 2019-03-19 西安鸿钧睿泽新材料科技有限公司 Flexible aluminium air battery of flexible

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107946603A (en) * 2017-12-15 2018-04-20 刘芙蓉 A kind of double activated material cell anode chamber
CN109494431A (en) * 2018-11-12 2019-03-19 西安鸿钧睿泽新材料科技有限公司 Flexible aluminium air battery of flexible
CN109494431B (en) * 2018-11-12 2021-11-02 廖湘标 Flexible aluminium air battery of flexible

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C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee