The coke-cooling waste water cyclic processing device
Technical field
The utility model relates to the burnt water circulation treatment device technical field of System of Cool Coking of Delayed Coking in a kind of refinery.
Background technology
The coke cooling water treatment unit is to adopt traditional open type circulating disposal process in China's refinery delayed coking unit, it is the open type discharging, the parallel flow intercepter oil removal, water cooling tower cools and water pump lifting is given water-cooled Jiao's circulating disposal process and device, coke tower is given in the process of water cooling coke layer after finishing the pyrogenic reaction process, cat head high temperature overflow water and big amount temperature are being carried oil whip secretly and micro-coke powder is discharged to oil trap along upflow tube at 150 degree left and right sides high-temperature steams, a large amount of volatile organic compounds VOC evaporations enter in the air in the sewage, oil trap ingress steam fills the air, and distributes the intensive stench.All adopt the extracting of coke cooling water pump to water cooling tower air blast cooling to the cooling of coke cooling water in the world, because evaporable organism quilt stripping, evaporation, loss constantly easily in the high temperature coke cooling water, form a stench face source that range of influence is bigger, stench concentration is the highest can be reached 2000 and (presses the GB/T14675 method, surrounding enviroment are caused severe contamination down together).Its concrete problem that exists has:
1, existing circulating disposal process and device oil removing cooling-down effect are poor, China System of Cool Coking of Delayed Coking Jiao Shui adopts circulating disposal process mostly, the coke cooling water oil concentration usually is higher than 400mg/l, even above 2000mg/l, water cooling tower is adhered to and stops up by oil easily, and cooling-down effect is poor, when device go into operation to later stage coke cooling water temperature can up to 90 the degree, restrict the processing power of device, influenced normal production;
2, existing circulating disposal process and device context pollution problem are outstanding, coke cooling water is carried heavy oil secretly, coke cooling water contains big gauging, sulphur, phenol, cyanogen, heavy metal, heterocycle and condensed-nuclei aromatics compound, wherein relatively enrichment of carcinogenic substance such as heterocycle and condensed-nuclei aromatics, in the burnt water process of the cooling of water cooling tower, evaporable heavy oil oil gas and hydrogen sulfide pollute surrounding environment, and population health is constituted a threat to;
3, the intractability of coke cooling water is big, and the coke cooling water intractability is bigger, and coke cooling water is obviously different with other oily(waste)water, and in its component, the initial stage is a three-phase mixture, vapor temperature 100 the degree more than, oily(waste)water, coke powder.Oil density in the oily(waste)water therein reaches 0.9396mg/cm
3Very approaching with the density of water, in coke powder, the oil suction of porous coke powder alleviates, part coke powder proportion is less than water, mix floating in the oil, the part coke powder is deposited on the bottom greater than water, the part coke powder is identical with water proportion, mix to float in the water, these characteristics have determined the closed processes difficulty of coke cooling water, also are the roots of sedimentation oil removal facility poor effect step by step;
4, coke cooling water hot tub steam fills the air, and is seriously polluted because the coke cooling water that the cold burnt initial stage overflows from the coke cat head is carried a large amount of steam secretly, advance retention basin after, make vaporizing oil-gas with a large amount of steam raisings in atmosphere, have a strong impact on surrounding environment.
Summary of the invention
Technical problem to be solved in the utility model provides a kind of coke-cooling waste water cyclic processing device, it adopts the closed circulating disposal process, makes coke cooling water handle whole process and carries out in sealing, improves peripheral operating environment greatly, eliminate the main malodor source of refinery, improve cold burnt effect simultaneously.
The utility model solves the problems of the technologies described above the technical scheme that is adopted: this kind coke-cooling waste water cyclic processing device, its feature exists: be connected to line mixer on the connection line of coke drum connection water storing tank, also be connected with low temperature coke cooling water pipeline by line mixer from water supply pump, the outlet of water storing tank sump oil connects slop oil tank by pipeline and carries out the sump oil recovery, the outlet of water storing tank coke cooling water is connected degreaser cyclone by pipeline with hot water pump, the outlet of degreaser cyclone sump oil coke powder is by the pipeline connection and be transmitted back to water storing tank, the changeable coke cleaning of water storing tank coke powder, the degreaser cyclone water outlet is connected to water cooling pond by air cooler and pipeline, and water cooling pond is connected on the line mixer between coke drum and the water storing tank by water supply pump and pipeline.
Above-mentioned water cooling pond is also connected on the coke drum by water supply pump and pipeline;
Above-mentioned degreaser cyclone adopts the plural serial stage structure;
Above-mentioned air cooler adopts the plural serial stage structure.
Compared with prior art, advantage of the present utility model is: 1, adopt the closed circulating disposal process, making coke cooling water handle whole process carries out in sealing, improve peripheral operating environment greatly, eliminate the main malodor source of refinery, improve cold burnt effect simultaneously, before the transformation, during coke drum discharging coke cooling water, the oil trap inlet steam fills the air, and gives out the intensive stench, and odor concentration is up to 2000, after the transformation, the high temperature coke cooling water enters the sewage basin in line mixer with behind the low temperature coke cooling water hybrid cooling, the tank deck pneumostome does not have steam to overflow, and monitoring shows that the coker environmental quality obviously improves, odor concentration is not higher than 20, and operating environment meets the industrial hygiene standard; 2, adopt the cyclone deoiling technology, utilize the principle of cyclonic separation, sump oil in the water and part coke powder are removed, after the advanced water storing tank sedimentation of high temperature coke cooling water, oil, coke powder carry out flash trapping stage in the water, advance degreaser cyclone again, realize two-stage sealing oil removing, and swirler is not easy to stop up, and deoiling effect is good, and oil removing water outlet oil-contg is less than 100mg/l; 3, air cooler postposition, be not easy to stop up, good cooling effect, adopt air cooler to cool indirectly, solved and opened wide logical atmosphere in the water cooling tower process of cooling, sulfide volatilization in the water, the problem of atmosphere pollution, air cooler places after the degreaser cyclone, can make air cooler be not easy to stop up good cooling effect; 4, adopt water-water mixer water injection technology, high-temperature steam enters water storing tank in the cold burnt overflow water in order to reduce, water-water mixer technology is adopted in design, part low temperature coke cooling water is injected in the high temperature overflow water, reach the purpose of degassing cooling, this way solves the overflow coke cooling water and enters the water attack of water storing tank place, and the safety problem of wall weld seam is irritated in tube vibration, drawing crack, eliminate water storage tank deck vacuum pressure valves, liquidometer mouth and the foam producer phenomenon that steams simultaneously, the atmospheric environmental issue of contaminated solution; 5, water treatment technological process is adjustable flexibly, and the degreaser cyclone single series is handled water yield 200m
3/ h adopts many swirler series operations, but air cooler and water cooling tower isolated operation, also can parallel running, adjustable flexibly, can satisfy the requirement of industrial experiment and production simultaneously; 6, the airtight recovery of sump oil, the airtight slop oil tank that enters of sump oil that sump oil that degreaser cyclone screws out and water storing tank are separated out, through dehydration, sump oil reclaims.
Description of drawings
Fig. 1 coke-cooling waste water cyclic processing device structural principle block diagram.
Embodiment
Below in conjunction with description of drawings embodiment of the present utility model is described in further detail.
Anticipate as shown in the figure, this kind coke-cooling waste water cyclic processing device includes coke drum 1, water storing tank 2, slop oil tank 3, hot water pump 4, degreaser cyclone 5, air cooler 8, water cooling pond 7, water supply pump 6 device such as grade and parts, on the connection line of coke drum 1 connection water storing tank 2, be connected to line mixer, also be connected with low temperature coke cooling water pipeline by line mixer from water supply pump 6, the outlet of water storing tank 2 sump oils connects slop oil tank 3 by pipeline and carries out the sump oil recovery, water storing tank 2 burnt water outs are connected degreaser cyclone 5 by pipeline with hot water pump 4, the outlet of degreaser cyclone 5 sump oil coke powders is by the pipeline connection and be transmitted back to water storing tank 2, water storing tank 2 coke powders can be by switching artificial coke cleaning, perhaps be connected to contaminated-oil basin by outlet, degreaser cyclone 5 water outlets are connected to water cooling pond 7 by air cooler 8 and pipeline, and water cooling pond is connected on the line mixer between coke drum 1 and the water storing tank 2 by water supply pump 6 and pipeline.Water cooling pond 6 is also connected on the coke drum 1 by water supply pump and pipeline simultaneously.In order to improve deoiling effect, degreaser cyclone 5 adopts plural serial stage, generally adopts two-stage series connection.In order to improve cooling-down effect, air cooler 8 also can adopt the plural serial stage structure equally.
Its principle of work is as follows, mix with low temperature coke cooling water in line mixer from the high temperature overflow water of coke drum and to realize cooling degassing purpose from water supply pump, deliver to then and carry out airtight deposition in the water storing tank, part sump oil exports by sump oil, deliver in the slop oil tank through pipeline again, dewatering and recovery sump oil then, the part coke cooling water is delivered in the degreaser cyclone with pipeline by hot water pump and is separated, coke powder of separating and sump oil are transmitted back in the water storing tank by pipeline again, and after the coke cooling water that degreaser cyclone comes out cools off by air cooler, deliver to water cooling pond, the low temperature coke cooling water is delivered on the connection line between coke drum and the water storing tank in the line mixer by water supply pump and pipeline again, mix with high temperature overflow water, realize the cooling degassing from coke drum.