CN2417158Y - Practical Chlorine Dioxide Generator - Google Patents
Practical Chlorine Dioxide Generator Download PDFInfo
- Publication number
- CN2417158Y CN2417158Y CN 99244976 CN99244976U CN2417158Y CN 2417158 Y CN2417158 Y CN 2417158Y CN 99244976 CN99244976 CN 99244976 CN 99244976 U CN99244976 U CN 99244976U CN 2417158 Y CN2417158 Y CN 2417158Y
- Authority
- CN
- China
- Prior art keywords
- chlorine dioxide
- column plate
- adds
- practical
- generating device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 26
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 150000002978 peroxides Chemical class 0.000 claims description 12
- 239000004744 fabric Substances 0.000 claims description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 5
- 238000005276 aerator Methods 0.000 claims description 3
- 235000011149 sulphuric acid Nutrition 0.000 claims description 3
- 239000001117 sulphuric acid Substances 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 241000282414 Homo sapiens Species 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000010924 continuous production Methods 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000001143 conditioned effect Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
A practical chlorine dioxide generator is composed of a chlorine dioxide generator with a multi-stage tower plate structure, a reaction chemical dosing device, a water injector, a temperature control system, an automatic liquid drainage system and a chlorine dioxide dosing control system. The utility model has the advantages of reasonable reactor structure, stable gas output, complete raw material reaction, safe and convenient operation, high automation degree, low production cost and high purity, and the technical innovation and the reformation are carried out on the basis of the practical II type, thereby realizing the continuous production and the automatic operation of chlorine dioxide, being widely applied to water disinfection and other related fields and having profound significance for protecting the health of human beings.
Description
The utility model is a water disinfection apparatus.
The organic halogen serious harm human beings'health such as haloform that the tap water chlorine disinfectant produces, it is imperative to adopt new type of disinfectant to substitute liquid chlorine.Dioxide peroxide is a kind of high-effective broad-spectrum fungicide, and advantages such as consumption is few, effect is fast, sterilizing power is strong, longer duration that it has the more important thing is not produce organic halogen that in sterilizing process sterilizing ability is not subjected to the influence of pH value, ammonia and aminated compounds; Simultaneously, inorganic and organism has stronger removal ability to iron, manganese, sulphur, phenols, algae etc. in the water, can obviously improve water quality.Therefore, dioxide peroxide is listed in the choice drug that substitutes liquid chlorine.At present, developed country uses dioxide peroxide very extensive, but in China, does not come out owing to still there is the chlorine dioxide generating device economical and practical, that luminous efficiency is high, product purity is high, causes the application of dioxide peroxide to be greatly limited.
The purpose of this utility model just is to design a kind of practical chlorine dioxide generating device, the cost that makes it have the production dioxide peroxide is low, purity is high, pharmacy response transforms and waits advantage fully, is beneficial to popularization and the utilization of dioxide peroxide in water treatment and other association area.
According to design, the utility model mainly adds Controlling System by the chlorine dioxide generator of multistage tower plate structure, reaction administration apparatus, water sprayer, temperature control system, automatic drain system and dioxide peroxide and forms.
Compared with prior art, the utlity model has the generation technique advanced person, structure of reactor is reasonable, gas yield is stable, raw material reaction is complete, easy-to-operate, the advantage that level of automation is high.And raw material conveniently is easy to get, and the production cost of dioxide peroxide is low, purity is high, can reach more than 98%; The equipment power consumption is few, long service life.The utility model has carried out technical renovation and transformation on the basis of practical II type, thereby the continuous production of dioxide peroxide and operation have automatically been realized, its throughput can satisfy the needs of the engineering of water treatment of different scales, can replace traditional liquid chlorine disinfection technology fully.We can say that the utility model all has profound significance to promotion and application dioxide peroxide and protection human beings'health.
Provide most preferred embodiment of the present utility model below in conjunction with accompanying drawing.Accompanying drawing is the sectional view of practical chlorine dioxide generating device.
As shown in the figure, described chlorine dioxide generator (1) adopts multi-stage column plate structure (2), every one-level Column plate all is provided with micro-hole aerator (3) and overflow pipe (4), and first order column plate is provided with sodium chlorate and mixes molten The cloth stream that adds that adds cloth stream pipe (5) and sulfuric acid solution of liquid is managed (6), and the liquid that adds cloth stream pipe passes through Heater is heated after (7), and automatically regulates heated condition by temperature control instrument (18); Adjacent two-stage Column plate communicates with next stage column plate series winding by the overflow pipe (4) of upper level. On the minimum one-level column plate Reaction residue is discharged by raffinate automatic discharge system (15) and (16). Described reaction administration apparatus refers to The adding on the cloth stream pipe (6) of cloth stream pipe (5) and sulfuric acid solution that add of sodium chlorate mixed solution is respectively equipped with Flowmeter (8) and (9) and metering add pump (10) and (11), and metering adds pump (10) and (11) are subjected to The control of controller (12). Described chlorine dioxide adds control system and refers to be located at sterilization pool (13) The detection signal of chlorine dioxide detector (14) feeds back to controller (12) and metering chemicals feed pump (10) and (1 1), comes the dosage of conditioned reaction medicament, thereby guarantee stable chlorine dioxide throwing amount. Described The raffinate automatic discharge system is made up of capacitive proximity switch (15) and magnetic valve (16).
Implementing best way of the present utility model is: have the sodium chlorate mixing solutions of certain proportion relation and sulphuric acid soln and manage the first step column plate (4) that (5) and (6), well heater (7) and under meter (8) and (9) enter into chlorine dioxide generator through the castering action of metering chemicals feed pump (10) and (11) and through adding cloth stream respectively, at this, mixing by micro-hole aerator (3) and stripping effect bloat the chlorine dioxide that produces.When the reaction solution liquid level of first step column plate reached the overflow height of upflow tube (4), reaction mixture entered second stage column plate and continues to produce titanium dioxide gas through upflow tube (4).In like manner, overflow to the third stage, the fourth stage, level V and the 6th grade (minimum one-level) successively.The chlorine dioxide that is produced mixes with pressure water through the suction function of water sprayer (17) from start to finish and forms aqueous solution of chlorine dioxide and enter in the sterilization pool.The reaction residue of minimum one-level is discharged raffinate automatically through the combined action of capacitive proximity switch (15) and magnetic valve (16).
In sterilization pool (13), dioxide peroxide detector (14) feeds back to controller (12) and metering chemicals feed pump (10) and (11) with the detection signal of chlorine dioxide concentration, comes the dosage of conditioned reaction medicament, thereby guarantees stabilized chlorine dioxide throwing amount.
Claims (4)
1, this practical chlorine dioxide generating device, it is characterized in that its chlorine dioxide generator (1) by multistage tower plate structure, the reaction administration apparatus, temperature control system (18) (7) and automatic drain system (15), (16), water sprayer (17) and dioxide peroxide add Controlling System and form, it is characterized in that described chlorine dioxide generator adopts multistage tower plate structure, each grade column plate (2) all is provided with micro-hole aerator (3) and upflow tube (4), and first step column plate is provided with the cloth stream that adds that adds cloth stream pipe (5) and sulphuric acid soln of sodium chlorate mixing solutions and manages (6), two spiral pipes in the well heater (7) be attached at respectively metering add pump and under meter (10-8,11-9) between; Metering adds the liquid that pump (10,11) adds and is heated by well heater (7) time, and adjusts heated condition automatically by temperature control instrument (18), passes through under meter (8,9) and cloth stream afterwards and adds pipe (5,6) and enter first step column plate; Adjacent two-stage column plate communicates with next stage column plate polyphone by the upflow tube (4) of upper level; Magnetic valve (16) is communicated with minimum one-level column plate, and capacitive proximity switch (15) is fixed on the outer desired location of minimum one-level column plate and links composition raffinate automatic discharge system by Circuits System and magnetic valve (16).
2,, it is characterized in that concentric tubes that described well heater (7) is made up of the refractory tube of outer field stainless steel tube and internal layer, place the spiral pipe between this concentric tubes and place the thermal sensitive ceramics (PTC) of refractory tube to form as 1 described practical chlorine dioxide generating device of right.
3, as 1 described practical chlorine dioxide generating device of right, it is characterized in that described reaction administration apparatus is meant that the adding of cloth stream pipe (5) and sulphuric acid soln that add of sodium chlorate mixing solutions is respectively equipped with under meter (8) and (9) and measures and add pump (10) and (11) on the cloth stream pipe (6), and metering adds pump (10) and is connected with controller (12) respectively with (11), and controlled by it.
4,, it is characterized in that described raffinate automatic discharge system is made up of capacitive proximity switch (15) and magnetic valve (16) as 1 described practical chlorine dioxide generating device of right.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99244976 CN2417158Y (en) | 1999-09-27 | 1999-09-27 | Practical Chlorine Dioxide Generator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99244976 CN2417158Y (en) | 1999-09-27 | 1999-09-27 | Practical Chlorine Dioxide Generator |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN2417158Y true CN2417158Y (en) | 2001-01-31 |
Family
ID=34030968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99244976 Expired - Fee Related CN2417158Y (en) | 1999-09-27 | 1999-09-27 | Practical Chlorine Dioxide Generator |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN2417158Y (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100424004C (en) * | 2006-01-12 | 2008-10-08 | 王丛若 | Chlorine dioxide generator |
| CN102602893A (en) * | 2012-03-10 | 2012-07-25 | 鹤山市雷迅新农机械科技有限公司 | Chlorine dioxide liquor generator for pesticide-free crop virus killing |
| CN102892717A (en) * | 2010-05-28 | 2013-01-23 | Isia股份公司 | Apparatus for disinfecting water |
-
1999
- 1999-09-27 CN CN 99244976 patent/CN2417158Y/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100424004C (en) * | 2006-01-12 | 2008-10-08 | 王丛若 | Chlorine dioxide generator |
| CN102892717A (en) * | 2010-05-28 | 2013-01-23 | Isia股份公司 | Apparatus for disinfecting water |
| CN102602893A (en) * | 2012-03-10 | 2012-07-25 | 鹤山市雷迅新农机械科技有限公司 | Chlorine dioxide liquor generator for pesticide-free crop virus killing |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |