CN220999764U - Silver waste sludge classification and leaching automatic treatment device - Google Patents

Silver waste sludge classification and leaching automatic treatment device Download PDF

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Publication number
CN220999764U
CN220999764U CN202323041392.XU CN202323041392U CN220999764U CN 220999764 U CN220999764 U CN 220999764U CN 202323041392 U CN202323041392 U CN 202323041392U CN 220999764 U CN220999764 U CN 220999764U
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silver
separating
tank
residue
lead
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林晖
曹镇涛
曹海宙
顾佳玉
赖东杰
赵华棣
万孟
周逸宸
林建国
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Zhejiang Suichang Huijin Non Ferrous Metal Co ltd
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Zhejiang Suichang Huijin Non Ferrous Metal Co ltd
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Abstract

The utility model relates to the technical field of smelting waste residue treatment, in particular to an automatic silver waste sludge grading and leaching treatment device. Including mud sediment inlet tube way, silver sediment separation region, no. one bottom intercommunication mouth, silver concentrate separation region, no. two bottom intercommunication mouths, lead ore separation region, no. three bottom intercommunication mouths, residue separation region and drainage valve, silver sediment separation region one side is connected with mud sediment inlet tube way, silver sediment separation region opposite side is connected with silver concentrate separation region, silver concentrate separation region opposite side is connected with lead ore separation region, lead ore separation region opposite side is connected with the residue separation region, residue separation region opposite side bottom is equipped with drainage valve. According to the utility model, lead and impurities in the silver waste sludge are gradually removed and recovered, so that the working efficiency of silver waste sludge recovery is improved.

Description

Silver waste sludge classification and leaching automatic treatment device
Technical Field
The utility model relates to the technical field of smelting waste residue treatment, in particular to an automatic silver waste sludge grading and leaching treatment device.
Background
Insoluble sludge attached to the surface of a residual anode or deposited at the bottom of an electrolytic bath in the electrolytic refining process of copper to form silver waste sludge, wherein the silver waste sludge consists of elements with higher potential than copper and various substances insoluble in electrolyte, the components of the silver waste sludge mainly depend on the composition of the copper anode, and the yield is generally 0.2-0.8%; and extracting noble metals such as gold, silver, platinum, palladium, copper, selenium, tellurium and other valuable elements from the silver waste sludge copper anode slime. In recent years, with the increase of the treatment capacity of scrap copper, the tin content of silver waste sludge is continuously increased, and the yield of the silver waste sludge is generally 50-60% of that of copper anode slime; about 750 tons of anode mud is produced from a smelting plant producing 10 ten thousand tons of electrolytic copper in one year, and 350-450 tons of silver-separated slag is produced.
At present, the existing silver waste sludge treatment method mostly adopts a method for recovering precious metals by manual operation, but chemical raw materials used by the method have great harm to human bodies, so that the respiratory system and the central nervous system of the human bodies are extremely easily damaged, and part of chemical raw materials have certain carcinogenicity, so that irreversible damage is brought to the human bodies. Meanwhile, the operation intensity is higher, the silver recovery efficiency is lower, the labor cost is higher, the recovery cost of the silver waste sludge is greatly increased, and the silver waste sludge is difficult to recycle.
Therefore, the silver waste sludge classification and leaching automatic treatment device with high metal recovery efficiency is provided without manual operation, and is a problem to be solved by those skilled in the art.
Disclosure of utility model
In order to overcome the defects of the prior art, the utility model aims to provide the silver waste sludge classification and leaching automatic treatment device which can reduce the damage of chemical raw materials to human bodies in the silver waste sludge recovery process, reduce the secondary pollution of the chemical raw materials and systematically recycle the silver waste sludge.
In order to achieve the above object, the present utility model provides the following technical solution, which mainly includes:
The utility model provides a silver waste sludge classifying and leaches automation processing device, includes mud sediment import pipeline, silver sediment separation region, a bottom intercommunication mouth, silver concentrate separation region, no. two bottom intercommunication mouths, lead ore separation region, no. three bottom intercommunication mouths, residue separation region and drainage valve, silver sediment separation region one side top and mud sediment import pipeline fixed connection, silver sediment separation region opposite side and silver concentrate separation region fixed connection, silver sediment separation region and silver concentrate separation region communicate through a bottom intercommunication mouths, silver concentrate separation region is kept away from silver sediment separation region's one side and lead ore separation region fixed connection, silver concentrate separation region and lead ore separation region communicate through a bottom intercommunication mouths No. two, lead ore separation region is kept away from silver concentrate separation region's one side and residue separation region fixed connection, lead ore separation region and residue separation region communicate through a bottom intercommunication mouths No. three, the residue separation region is kept away from lead ore separation region's one side bottom is equipped with drainage valve.
Preferably, the silver slag separation area comprises a silver slag separation tank, a first reaction tank stirrer, a sodium chloride medicament tank, a first automatic regulating valve, a hydrogen chloride medicament tank, a second automatic regulating valve, a sodium chlorate medicament tank and a third automatic regulating valve, wherein a sludge inlet pipeline is fixedly connected with the silver slag separation tank, the sodium chloride medicament tank is arranged above the silver slag separation tank, the first automatic regulating valve is arranged below the sodium chloride medicament tank, the hydrogen chloride medicament tank is arranged above the silver slag separation tank, the second automatic regulating valve is arranged below the hydrogen chloride medicament tank, the sodium chlorate medicament tank is arranged above the silver slag separation tank, the third automatic regulating valve is arranged below the sodium chlorate medicament tank, and the first reaction tank stirrer is fixedly connected above the silver slag separation tank.
Preferably, the silver concentrate separation area comprises a second reaction tank stirrer, a lead powder reagent box, a fourth automatic regulating valve and a silver concentrate separation tank, wherein the silver slag separation tank is fixedly connected with the silver concentrate separation tank, the silver slag separation tank is communicated with the silver concentrate separation tank through a first bottom communication port, the lead powder reagent box is arranged above the silver concentrate separation tank, the fourth automatic regulating valve is arranged below the lead powder reagent box, and a second reaction tank stirrer is fixedly connected above the silver concentrate separation tank.
Preferably, the lead ore separation area comprises an iron powder medicament box, a lead ore separation tank, a fifth automatic regulating valve and a third reaction tank stirrer, wherein the lead ore separation tank is fixedly connected with the silver concentrate separation tank, the lead ore separation tank is communicated with the silver concentrate separation tank through a second bottom communication port, the iron powder medicament box is arranged above the lead ore separation tank, the fifth automatic regulating valve is arranged below the iron powder medicament box, and the third reaction tank stirrer is fixedly connected above the lead ore separation tank.
Preferably, the residue separation area comprises a neutralizer medicament box, a No. six automatic regulating valve, a No. four reaction tank stirrer and a residue separation tank, wherein the residue separation tank is fixedly connected with the lead ore separation tank, the residue separation tank is communicated with the lead ore separation tank through a No. three bottom communication port, the neutralizer medicament box is arranged above the residue separation tank, the No. six automatic regulating valve is arranged below the neutralizer medicament box, and the No. four reaction tank stirrer is fixedly connected above the residue separation tank.
Preferably, a first PH meter is connected above the silver slag separation tank.
Preferably, a second PH meter is connected above the residue separation tank.
Compared with the prior art, the method has the advantages that lead and impurities in the silver waste sludge are gradually separated and recycled, the working efficiency of silver waste sludge recycling is improved, the neutralized wastewater after desorption can be repeatedly desorbed, the silver recycling efficiency is improved, the labor process of manually adding chemical raw materials is reduced, the damage of the chemical raw materials to human bodies is reduced, the process condition is mild, the high-temperature high-acid high-alkali of the traditional recycling process in the silver waste sludge is not needed, the method is favorable for industrial large-scale popularization, the environment is friendly, and the recycling and reutilization of precious metals are further ensured.
Drawings
In order to more clearly illustrate the embodiments of the present utility model or the technical solutions in the prior art, the drawings that are required to be used in the embodiments or the description of the prior art will be briefly described below, and it is obvious that the drawings in the following description are only embodiments of the present utility model, and that other drawings can be obtained according to the provided drawings without inventive effort for a person skilled in the art.
Fig. 1 is a schematic structural view of the present utility model.
Reference numerals illustrate: 1-silver slag separating tank, 2-sludge inlet pipeline, 3-reaction tank stirrer, 4-pH meter, 5-sodium chloride reagent tank, 6-automatic regulating valve, 7-hydrogen chloride reagent tank, 8-automatic regulating valve, 9-sodium chlorate reagent tank, 10-automatic regulating valve, 11-bottom communication port, 12-reaction tank stirrer, 13-lead powder reagent tank, 14-automatic regulating valve, 15-silver concentrate separating tank, 16-bottom communication port, 17-iron powder reagent tank, 18-five-automatic regulating valve, 19-three reaction tank stirrer, 20-lead ore separating tank, 21-three bottom communication port, 22-neutralizer reagent tank, 23-six automatic regulating valve, 24-four reaction tank stirrer, 25-second pH meter, 26-residue separating tank and 27-drain valve.
Detailed Description
The following description of the embodiments of the present utility model will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present utility model, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the utility model without making any inventive effort, are intended to be within the scope of the utility model.
Examples
The utility model provides a silver waste sludge classification and leaches automation processing device, is shown in fig. 1, including mud sediment import pipeline 2, silver sediment separation region, no. one bottom intercommunication mouth 11, silver concentrate separation region, no. two bottom intercommunication mouths 16, lead ore separation region, no. three bottom intercommunication mouths 21, residue separation region and drainage valve 27, silver sediment separation region one side top and mud sediment import pipeline 2 fixed connection, silver sediment separation region opposite side and silver concentrate separation region fixed connection, silver sediment separation region and silver concentrate separation region pass through No. one bottom intercommunication mouths 11 intercommunication, silver concentrate separation region is kept away from silver sediment separation region's one side and lead ore separation region fixed connection, silver concentrate separation region and lead ore separation region pass through No. two bottom intercommunication mouths 16 intercommunication, lead ore separation region is kept away from silver concentrate separation region's one side and residue separation region fixed connection, lead ore separation region and residue separation region pass through No. three bottom intercommunication mouths 21 intercommunication, one side bottom that the residue separation region kept away from the silver concentrate separation region is equipped with drainage valve 27.
In order to further optimize above-mentioned scheme, silver slag separation area is including silver slag separation pond 1, reaction tank mixer 3, sodium chloride medicament case 5, automatic regulating valve 6, hydrogen chloride medicament case 7, no. two automatic regulating valves 8, sodium chlorate medicament case 9 and No. three automatic regulating valves 10, mud slag inlet pipe 2 and silver slag separation pond 1 fixed connection, sodium chloride medicament case 5 is installed to silver slag separation pond 1's top, sodium chloride medicament case 5 below is equipped with automatic regulating valve 6, hydrogen chloride medicament case 7 is installed to silver slag separation pond 1's top, hydrogen chloride medicament case 7 below is equipped with No. two automatic regulating valves 8, sodium chlorate medicament case 9 is installed to silver slag separation pond 1's top, sodium chlorate medicament case 9 below is equipped with No. three automatic regulating valves 10, silver slag separation pond 1's top fixedly connected with reaction tank mixer 3.
In order to further optimize above-mentioned scheme, silver concentrate separation area is including No. two reaction tank mixers 12, lead powder medicament case 13, no. four automatic regulating valves 14 and silver concentrate separation tank 15, silver slag separation tank 1 and silver concentrate separation tank 15 fixed connection, silver slag separation tank 1 and silver concentrate separation tank 15 communicate through No. one bottom intercommunication mouth 11, lead powder medicament case 13 is installed to silver concentrate separation tank 15's top, lead powder medicament case 13 below is equipped with No. four automatic regulating valves 14, silver concentrate separation tank 15's top fixedly connected with No. two reaction tank mixers 12.
In order to further optimize above-mentioned scheme, lead ore separation area includes iron powder medicament case 17, lead ore separation tank 20, no. five automatic regulating valves 18 and No. three reaction tank mixer 19, lead ore separation tank 20 and silver concentrate separation tank 15 fixed connection, lead ore separation tank 20 and silver concentrate separation tank 15 are through No. two bottom intercommunication mouthfuls 16 intercommunication, iron powder medicament case 17 is installed to the top of lead ore separation tank 20, iron powder medicament case 17 below is equipped with No. five automatic regulating valves 18, no. three reaction tank mixer 19 are fixedly connected with to the top of lead ore separation tank 20.
In order to further optimize above-mentioned scheme, the residue separation area includes neutralizer medicament case 22, no. six automatically regulated valves 23, no. four reaction tank agitators 24 and residue separation tank 26, residue separation tank 26 and lead ore separation tank 20 fixed connection, residue separation tank 26 and lead ore separation tank 20 are through No. three bottom intercommunication mouths 21 intercommunication, neutralizer medicament case 22 is installed to the top of residue separation tank 26, neutralizer medicament case 22 below is equipped with No. six automatically regulated valves 23, the top fixedly connected with No. four reaction tank agitators 24 of residue separation tank 26.
In order to further optimize the scheme, a first PH meter 4 is connected above the silver slag separation tank 1.
In order to further optimize the scheme, a second PH meter 25 is connected above the residue separation tank 26.
Working principle: silver waste sludge enters a silver sludge separation tank 1 through a sludge inlet pipeline 2, and the dosing amount of a sodium chloride medicament box 5, a hydrogen chloride medicament box 7 and a sodium chlorate medicament box 9 is controlled through the linkage of a first PH instrument 4, a first automatic regulating valve 6, a second automatic regulating valve 8 and a third automatic regulating valve 10, a first reaction tank stirrer 3 is started to stir the mixed solution, so that the silver waste sludge and the medicament are fully mixed, and residues are separated; the reacted mixed solution enters a silver concentrate separation tank 15 through a first bottom communication port 11, a fourth automatic regulating valve 14 controls the dosage of a lead powder medicament box 13 according to the total amount of the mixed solution, a second reaction tank stirrer 12 is started, the mixed solution is stirred, the mixed solution and the lead powder medicament are ensured to be fully mixed, and silver ores are separated; the reacted solution enters a lead ore separating tank 20 through a second bottom communication port 16, a fifth automatic regulating valve 18 controls the dosage of the iron powder medicament box 17 according to the total amount of the mixed solution, a third reaction tank stirrer 19 is started, the mixed solution is stirred, the mixed solution and the iron powder medicament are ensured to be fully mixed, and lead ores are separated; the reacted solution enters a residue separation tank 26 through a third bottom communication port 21, is linked with a sixth automatic regulating valve 23 through a second PH instrument 25, controls the dosage of a neutralizer medicament box 22, a fourth reaction tank stirrer 24 is started, and is used for stirring the mixed solution, so that the mixed solution and the neutralizer are fully mixed, the residue is separated, the neutralized solution is discharged through a water discharge valve 27, the reacted solution can be repeatedly desorbed, and the recovery efficiency of silver and lead is improved.
In the present specification, each embodiment is described in a progressive manner, and each embodiment is mainly described in a different point from other embodiments, and identical and similar parts between the embodiments are all enough to refer to each other. For the device disclosed in the embodiment, since it corresponds to the method disclosed in the embodiment, the description is relatively simple, and the relevant points refer to the description of the method section.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present utility model. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the utility model. Thus, the present utility model is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (7)

1. Silver waste sludge classifying and leaching automatic processing device is characterized by comprising a sludge inlet pipeline (2), a silver sludge separating region, a first bottom communicating port (11), a silver concentrate separating region, a second bottom communicating port (16), a lead separating region, a third bottom communicating port (21), a residue separating region and a drainage valve (27), wherein one side upper part of the silver sludge separating region is fixedly connected with the sludge inlet pipeline (2), the other side of the silver sludge separating region is fixedly connected with the silver concentrate separating region, the silver sludge separating region is communicated with the silver concentrate separating region through the first bottom communicating port (11), one side of the silver concentrate separating region is far away from the silver sludge separating region and is fixedly connected with the lead separating region, one side of the lead separating region is far away from the silver concentrate separating region and is fixedly connected with the residue separating region through the second bottom communicating port (16), one side of the lead separating region and the residue separating region are communicated through the third bottom communicating port (21), and one side of the residue separating region is far away from the lead separating region is provided with the drainage valve (27).
2. The automatic silver residue classifying and leaching treatment device according to claim 1, wherein the silver residue separating area comprises a silver residue separating tank (1), a first reaction tank stirrer (3), a sodium chloride medicament box (5), a first automatic regulating valve (6), a hydrogen chloride medicament box (7), a second automatic regulating valve (8), a sodium chlorate medicament box (9) and a third automatic regulating valve (10), a sludge inlet pipeline (2) is fixedly connected with the silver residue separating tank (1), the sodium chloride medicament box (5) is arranged above the silver residue separating tank (1), the first automatic regulating valve (6) is arranged below the sodium chloride medicament box (5), the hydrogen chloride medicament box (7) is arranged above the silver residue separating tank (1), the second automatic regulating valve (8) is arranged below the hydrogen chloride medicament box (7), the sodium chlorate box (9) is arranged above the silver residue separating tank (1), the third automatic regulating valve (10) is arranged below the sodium chlorate box (9), and the first reaction tank (3) is fixedly connected with the silver residue stirrer.
3. The silver waste sludge classifying and leaching automatic treatment device according to claim 2, wherein the silver concentrate separating area comprises a second reaction tank stirrer (12), a lead powder medicament box (13), a fourth automatic regulating valve (14) and a silver concentrate separating tank (15), the silver sludge separating tank (1) is fixedly connected with the silver concentrate separating tank (15), the silver sludge separating tank (1) is communicated with the silver concentrate separating tank (15) through a first bottom communicating port (11), the lead powder medicament box (13) is arranged above the silver concentrate separating tank (15), the fourth automatic regulating valve (14) is arranged below the lead powder medicament box (13), and the second reaction tank stirrer (12) is fixedly connected above the silver concentrate separating tank (15).
4. The automatic silver waste sludge classifying and leaching treatment device according to claim 1, wherein the lead ore separating area comprises an iron powder medicament box (17), a lead ore separating tank (20), a fifth automatic regulating valve (18) and a third reaction tank stirrer (19), the lead ore separating tank (20) is fixedly connected with a silver concentrate separating tank (15), the lead ore separating tank (20) is communicated with the silver concentrate separating tank (15) through a second bottom communicating port (16), the iron powder medicament box (17) is arranged above the lead ore separating tank (20), the fifth automatic regulating valve (18) is arranged below the iron powder medicament box (17), and a third reaction tank stirrer (19) is fixedly connected above the lead ore separating tank (20).
5. The silver waste sludge classifying and leaching automatic treatment device according to claim 1, wherein the residue separating area comprises a neutralizer reagent box (22), a six-number automatic regulating valve (23), a four-number reaction tank stirrer (24) and a residue separating tank (26), the residue separating tank (26) is fixedly connected with a lead ore separating tank (20), the residue separating tank (26) is communicated with the lead ore separating tank (20) through a three-number bottom communicating port (21), the neutralizer reagent box (22) is arranged above the residue separating tank (26), the six-number automatic regulating valve (23) is arranged below the neutralizer reagent box (22), and the four-number reaction tank stirrer (24) is fixedly connected above the residue separating tank (26).
6. The automatic silver waste sludge classifying and leaching treatment device according to claim 2, wherein a first PH meter (4) is connected above the silver sludge separating tank (1).
7. The automatic silver waste sludge classifying and leaching treatment device according to claim 5, wherein a second PH meter (25) is connected above the residue separating tank (26).
CN202323041392.XU 2023-11-10 2023-11-10 Silver waste sludge classification and leaching automatic treatment device Active CN220999764U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202323041392.XU CN220999764U (en) 2023-11-10 2023-11-10 Silver waste sludge classification and leaching automatic treatment device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202323041392.XU CN220999764U (en) 2023-11-10 2023-11-10 Silver waste sludge classification and leaching automatic treatment device

Publications (1)

Publication Number Publication Date
CN220999764U true CN220999764U (en) 2024-05-24

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Application Number Title Priority Date Filing Date
CN202323041392.XU Active CN220999764U (en) 2023-11-10 2023-11-10 Silver waste sludge classification and leaching automatic treatment device

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CN (1) CN220999764U (en)

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