CN220834837U - Separation and purification device for residual gas of canned carbon dioxide - Google Patents

Separation and purification device for residual gas of canned carbon dioxide Download PDF

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Publication number
CN220834837U
CN220834837U CN202322731640.7U CN202322731640U CN220834837U CN 220834837 U CN220834837 U CN 220834837U CN 202322731640 U CN202322731640 U CN 202322731640U CN 220834837 U CN220834837 U CN 220834837U
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air
adsorption tower
valve
gas
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金星屹
刘兹壮
雷雨
王亚军
李业
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CHONGQING RISING GAS CO LTD
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CHONGQING RISING GAS CO LTD
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
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    • Y02C20/40Capture or disposal of greenhouse gases of CO2

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Abstract

The utility model discloses a separation and purification device for residual gas of canned carbon dioxide, which comprises: a gas source tank; the air inlet end of the first booster pump is communicated with the air source pipe through the main valve; the three adsorption towers are internally provided with adsorbents; a gas storage unit; the three gas outlet control units are used for respectively connecting the three adsorption tower gas storage units in series in sequence to form a purification line; the three air outlet control units are also respectively communicated with the air source tank and the air storage unit; the air outlet of the first booster pump is communicated with the inside of the adsorption tower of the purification line source; three space replacement components are respectively arranged inside the adsorption tower; and the three filling control assemblies are communicated with the space replacement assemblies inside the three adsorption towers respectively. The utility model can reduce the consumption of high-purity carbon dioxide for flushing the dilution absorption tube and improve the yield.

Description

Separation and purification device for residual gas of canned carbon dioxide
Technical Field
The utility model relates to the field of residual gas recovery equipment, in particular to a separation and purification device for canned carbon dioxide residual gas.
Background
Carbon dioxide is very low in natural air and the cost of producing carbon dioxide is high, so the residual gas of canned carbon dioxide needs to be recovered as much as possible. At present, the canned carbon dioxide residual gas is generally concentrated in a liquid space replacement mode, but the canned residual carbon dioxide generally contains more other gases, and the purity of the carbon dioxide is not high. Currently, the main carbon dioxide recovery technologies include physical absorption technology, chemical absorption technology, membrane separation technology, pressure swing adsorption technology (PAS method), and the like.
The pressure swing adsorption timely utilizes the characteristic of selective adsorption of carbon dioxide by the solid adsorbent, carbon dioxide is adsorbed at high pressure, and the adsorbed carbon dioxide is released after depressurization, so that the purposes of purifying carbon dioxide and separating the carbon dioxide from other gases are realized. In the prior pressure swing adsorption process, after pressurizing carbon dioxide, high-purity carbon dioxide is adopted to flush and dilute unadsorbed gas in an adsorption tower until the concentration of flushed and discharged carbon dioxide reaches a certain value, flushing tail gas is recycled, so that the high-purity carbon dioxide used for flushing is wasted before the concentration of flushed and discharged carbon dioxide reaches a certain value, and the production yield is reduced.
Disclosure of utility model
In view of the above-mentioned drawbacks of the prior art, the present utility model aims to provide a separation and purification device for carbon dioxide residue in cans, which can reduce the amount of high-purity carbon dioxide used for flushing a dilution absorption tube and increase the yield.
The aim of the utility model is realized by the following technical scheme:
the utility model provides a canning carbon dioxide residual gas separation and purification device, includes:
A gas source tank;
the air inlet end of the first booster pump is communicated with the air source pipe through the main valve;
The three adsorption towers are internally provided with adsorbents;
a gas storage unit;
the three gas outlet control units are used for respectively connecting the three adsorption tower gas storage units in series in sequence to form a purification line; the three air outlet control units are also respectively communicated with the air source tank and the air storage unit; the air outlet of the first booster pump is communicated with the inside of the adsorption tower of the purification line source;
three space replacement components are respectively arranged inside the adsorption tower;
And the three filling control assemblies are communicated with the space replacement assemblies inside the three adsorption towers respectively.
Further, the outlet control unit includes:
One end of the waste gas valve is communicated with the inside of the adsorption tower, and the other end of the waste gas valve is communicated with the outside atmosphere;
One end of the air return valve is communicated with the inside of the adsorption tower, and the other end of the air return valve is communicated with the inside of the air source tank;
one end of the gas transmission valve is communicated with the inside of the adsorption tower;
one end of the flushing valve is communicated with the gas storage unit, and the other end of the flushing valve is communicated with the inside of the upstream adsorption tower;
The air inlet end of the second booster pump is communicated with the other end of the air delivery valve, and the other end of the second booster pump is communicated with the downstream adsorption tower or the air storage unit.
Further, the gas outlet control unit between the two adsorption towers at the downstream of the purification line further comprises a recoil valve, one end of the recoil valve is communicated with the output end of the second booster pump, and the other end of the recoil valve is communicated with the interior of the previous adsorption tower of the upstream adsorption tower.
Further, the outlet control unit further includes:
One end of the output bus is communicated with the inside of the adsorption tower, and the other end of the output bus is respectively communicated with the waste gas valve, the air return valve and the air transmission valve;
And the concentration sensor for detecting the concentration of the carbon dioxide is communicated with the output bus.
Further, the device also comprises a third booster pump, the air inlets are respectively communicated with the air return valves of the three air outlet control units, and the other ends of the air inlets are communicated with the air source tank.
Further, the space substitution assembly includes:
The fixed plate is arranged at the upper part in the adsorption tower;
The elastic deformation air bag is fixed on the fixed plate and forms a closed space with the fixed plate;
one end of the breather pipe passes through the adsorption tower and the fixed plate to be communicated with the inside of the air bag, and the other end of the breather pipe is communicated with a filling control assembly.
Further, the lower part of the air bag is in an inverted cone shape in a natural state, the space displacement assembly further comprises a lifting unit arranged in the air bag, and the lifting unit comprises:
one end of the pull rope is connected with the inner surface of the bottom of the air bag;
A lifting barrel with an upward opening in a box, wherein the outer surface of the bottom is connected with the other end of the pull rope; the side wall of the lifting barrel is provided with a plurality of lower air inlets;
The lower end of the elastic deformation lifting cylinder is in seamless communication with the opening of the lifting cylinder, and a plurality of totally-concave deformation guide grooves are formed in the outer surface of the lifting cylinder;
The fixed cylinder is box-shaped with a downward opening, the opening is in seamless communication with the upper end of the lifting cylinder, the outer surface of the top is fixedly connected with the fixed plate, and a plurality of upper air inlets are arranged on the side wall of the fixed cylinder; the breather pipe sequentially passes through the adsorption tower, the fixed plate and the fixed cylinder and is communicated with the interior of the lifting cylinder.
Further, the filling control assembly includes:
a media source canister;
a fourth booster pump with a one-way valve, wherein the inlet end of the fourth booster pump is communicated with the inside of the medium source tank, and the outlet end of the fourth booster pump is communicated with a vent pipe of the corresponding space replacement assembly;
And one end of the pressure release valve is communicated with the vent pipe of the space displacement assembly.
Further, the medium source tank content is a compressible gas; the outlet ends of the fourth booster pumps of the three filling control assemblies are communicated sequentially through pressure regulating valves.
Due to the adoption of the technical scheme, the utility model has the following advantages:
1. The scheme of multistage series pressure swing adsorption (three adsorption towers) can be adopted to purify the carbon dioxide to higher concentration.
2. Each adsorption tower is communicated with the downstream adsorption tower or the downstream gas storage unit through the gas outlet control unit, so that each adsorption tower only needs the next stage of carbon dioxide in the adsorption and/or gas storage unit in the flushing process, high-concentration purified carbon dioxide is not needed, the consumption of carbon dioxide is reduced, and the yield of carbon dioxide can be increased.
3. Each adsorption tower can directly discharge the gas which is not adsorbed out of the adsorption tower as far as possible through the space displacement component before flushing, but the adsorption tower is not discharged in a flushing and diluting mode, so that the consumption of using the gas with higher carbon dioxide concentration than the gas source of the adsorption tower of the present stage is reduced, and the yield of carbon dioxide can be increased.
Additional advantages, objects, and features of the utility model will be set forth in part in the description which follows and in part will become apparent to those having ordinary skill in the art upon examination of the following or may be learned from practice of the utility model.
Drawings
The drawings of the present utility model are described as follows:
Fig. 1 is a schematic structural diagram of a separation and purification apparatus for residual gas of canned carbon dioxide in this embodiment.
Fig. 2 is a schematic sectional view of the adsorption tower in this embodiment.
In the figure: 1. a gas source tank; 2. a first booster pump; 3. an adsorption tower; 31. an adsorbent; 4. a gas storage unit; 51. a waste valve; 52. an air return valve; 53. a gas transmission valve; 54. flushing the valve; 55. a second booster pump; 56. a recoil valve; 57. an output bus; 58. a concentration sensor; 61. a fixing plate; 62. an air bag; 63. a vent pipe; 64. a pull rope; 65. lifting the barrel; 651. a lower air inlet hole; 66. a lifting cylinder; 661. a deformation guide groove; 67. a fixed cylinder; 671. an upper air inlet hole; 71. a media source canister; 72. a fourth booster pump; 73. a pressure release valve; 74. a pressure regulating valve; 8. a third booster pump; 9. and a main valve.
Detailed Description
The utility model is further described below with reference to the drawings and examples.
Examples:
As shown in fig. 1 to 2, the separation and purification device for the residual gas of canned carbon dioxide comprises:
A gas source tank 1;
the air inlet end of the first booster pump 2 is communicated with an air source pipe through a main valve 9;
Three adsorption towers 3, inside which an adsorbent 31 is arranged; the carbon dioxide adsorbent 31 is zeolite, alumina, silica gel, active carbon and the like, and different adsorbents 31 can be selected according to purification requirements;
a gas storage unit 4;
The three gas outlet control units are used for respectively connecting the three gas storage units 4 of the adsorption tower 3 in series in sequence to form a purification line; the three air outlet control units are also respectively communicated with the air source tank 1 and the air storage unit 4; the air outlet of the first booster pump 2 is communicated with the inside of an adsorption tower 3 of a purification line source;
Three space replacement components are respectively arranged inside the adsorption tower 3;
and the three filling control assemblies are communicated with the space replacement assemblies inside the three adsorption towers 3 respectively.
In this embodiment, the air outlet control unit includes:
a waste gas valve 51, one end of which is communicated with the inside of the adsorption tower 3, and the other end of which is communicated with the outside atmosphere;
One end of the air return valve 52 is communicated with the inside of the adsorption tower 3, and the other end of the air return valve is communicated with the inside of the air source tank 1;
One end of the gas transmission valve 53 is communicated with the inside of the adsorption tower 3;
A flushing valve 54, one end of which is communicated with the gas storage unit 4 and the other end of which is communicated with the inside of the upstream adsorption tower 3;
The second booster pump 55 has an air inlet end connected to the other end of the air delivery valve 53 and the other end connected to the downstream adsorption tower 3 or the air storage unit 4.
In this embodiment, the gas outlet control unit between the two adsorption towers 3 downstream of the purification line further includes a recoil valve 56, one end of which is communicated with the output end of the second booster pump 55, and the other end of which is communicated with the inside of the preceding adsorption tower 3 of the upstream adsorption tower 3.
Further, the outlet control unit further includes:
An output bus 57, one end of which is communicated with the inside of the adsorption tower 3, and the other end of which is respectively communicated with the waste gas valve 51, the return air valve 52 and the gas transmission valve 53;
A concentration sensor 58 that detects the concentration of carbon dioxide is in communication with the output bus 57.
In this embodiment, the air supply tank further includes a third booster pump 8, the air inlets of which are respectively communicated with the air return valves 52 of the three air outlet control units, and the other ends of which are communicated with the air source tank 1.
The third booster pump 8 recovers the low-concentration carbon dioxide gas into the gas source tank 1, and realizes reuse.
In this embodiment, the space substitution assembly includes:
A fixing plate 61 provided at an upper portion in the adsorption tower 3;
An elastically deformable air bag 62 fixed to the fixing plate 61 and enclosing a closed space with the fixing plate 61;
one end of the vent pipe 63 passes through the adsorption tower 3 and the fixing plate 61 to communicate with the inside of the air bag 62, and the other end communicates with a filling control assembly.
The space occupied by the gas which is not adsorbed in the adsorption tower 3 is changed by the expansion and contraction of the air bag 62, so that the aim of reducing flushing is fulfilled.
In this embodiment, the lower portion of the balloon 62 is in an inverted cone shape in the natural state, and the space displacement assembly further includes a lifting unit disposed in the balloon 62, and the lifting unit includes:
A pull cord 64, one end of which is connected to the inner surface of the bottom of the airbag 62;
A lifting barrel 65 with an upward opening and a box-packed shape, the outer surface of the bottom being connected with the other end of the pull rope 64; the side wall of the lifting barrel 65 is provided with a plurality of lower air inlets 651;
The lower end of the elastic deformation lifting cylinder 66 is in seamless communication with the opening of the lifting cylinder 65, and a plurality of totally-concave deformation guide grooves 661 are formed in the outer surface of the lifting cylinder 66;
The fixed cylinder 67 is box-shaped with a downward opening, the opening is in seamless communication with the upper end of the lifting cylinder 66, the outer surface of the top is fixedly connected with the fixed plate 61, and a plurality of upper air inlets 671 are formed in the side wall of the fixed cylinder 67; the breather pipe 63 passes through the adsorption tower 3, the fixed plate 61 and the fixed cylinder 67 in sequence and is communicated with the interior of the lifting cylinder 66.
By deforming the pulling cylinder 66, the state of the air bag 62 when it is contracted is changed, so that the air bag 62 can be smoothly stretched when it is opened next time, and the stretched air bag can be completely contacted with the inner wall of the adsorption tower 3, thereby occupying the inner space as much as possible and exhausting the gas which is not adsorbed.
In this embodiment, the filling control assembly includes:
A media source tank 71;
A fourth booster pump 72 with a check valve, the inlet end of which is communicated with the inside of the medium source tank 71, and the outlet end of which is communicated with the vent pipe 63 of the corresponding space displacement assembly;
a relief valve 73, one end of which communicates with the vent pipe 63 of the space displacement assembly.
In this embodiment, the content in the medium source tank 71 is a compressible gas; the outlet ends of the fourth booster pumps 72 of the three described filling control assemblies are in turn connected by pressure regulating valves 74.
A compressible gas, such as air, is used as a medium source, and its pressure capability can be transferred to another adsorption tower 3 through the pressure regulating valve 74 during the pressure release of the air to one adsorption tower 3, so as to reduce the output power of the fourth booster pump 72 of the adsorption tower 3 and the consumption of the medium source gas.
The separation and purification apparatus for carbon dioxide residue in the canned manner of this embodiment is operated by first injecting a gas containing carbon dioxide to be purified and separated into the gas source tank 1, injecting a certain amount of high purity carbon dioxide into the gas storage unit 4, and injecting clean air into the medium source tank 71.
The main valve 9 is opened, the waste gas valve 51, the return gas valve 52 and the output valve which are communicated with the output bus 57 of the first adsorption tower 3 are closed, the first booster pump 2 is started, the gas in the gas source tank 1 is injected into the first adsorption tower 3 until the pressure in the adsorption tower 3 reaches a preset value, and a large amount of carbon dioxide is absorbed by the adsorbent 31.
At this time, the fourth booster pump 72 corresponding to the first adsorption tower 3 is started to inject air into the air bag 62, and at the same time, the waste gas valve 51 communicated with the first adsorption tower 3 is opened to keep the pressure in the first adsorption tower 3 stable and not to decrease until the pressure in the air bag 62 reaches a predetermined value, the air bag 62 is fully opened, and at this time, the fourth booster pump 72 stops working. The unadsorbed gas in the first adsorption tower 3 is discharged through the waste gate 51.
The purge valve 54 in communication with the first adsorption column 3 is opened again so that the high purity di-oxidation column enters the first adsorption column 3 to dilute the unabsorbed other gas while reading the value of the concentration sensor 58 in communication with the first adsorption column 3. If the carbon dioxide concentration is low and does not have value for reuse, the exhaust valve 51 is kept open; if the concentration of the carbon dioxide rises to have the value of reuse, the waste gas valve 51 is closed, the air return valve 52 is opened, and the third booster pump 8 is opened at the same time, so that the air flows back into the air source tank 1; if the carbon dioxide concentration is raised to a value that can be purified again, the return valve 52 is closed, and the output valve opens the second booster pump 55 that is in communication therewith, and the carbon dioxide gas of a certain concentration is injected into the second adsorption tower 3.
The second adsorption tower 3 operates in substantially the same manner as the first adsorption tower 3. When the first adsorption tower 3 and the second adsorption tower 3 wash and dilute the unabsorbed gas, the back flush valve 54 on the downstream adsorption tower 3 is opened first to guide the purified dioxide tower in the downstream adsorption tower 3 to wash and dilute, so as to reduce the consumption of high-concentration carbon dioxide in the gas storage unit 4. Of course, if the high concentration carbon dioxide gas in the gas storage unit 4 is used for flushing in order not to waste the dioxide gas at all, that is, not to discharge the low concentration carbon dioxide gas through the waste gas valve 51, the gas after the flushing dilution can be reused directly through the return gas valve 52.
When the other three adsorption towers 3 are operated simultaneously, before the pressure release is started after the pressurization of the first adsorption tower 3 is completed, the second adsorption tower 3 can be controlled to be in a preparation working stage before flushing, namely before the air bag 62 in the second adsorption tower 3 is pressurized, and the air and pressure of the air bag 62 in the first adsorption tower 3 can be partially transferred into the air bag 62 in the second adsorption tower 3 by opening the pressure regulating valve 74 communicated with the first adsorption tower 3 and the second adsorption tower 3. When the air pressure of the air bag 62 in the first adsorption tower 3 is the same as the air pressure of the air bag 62 in the second adsorption tower 3, the pressure regulating valve 74 is closed, and the pressure relief valve 73 communicated with the first air bag 62 is opened to empty the air in the air bag 62.
Finally, it is noted that the above embodiments are only for illustrating the technical solution of the present utility model and not for limiting the same, and although the present utility model has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications and equivalents may be made thereto without departing from the spirit and scope of the present utility model, which is intended to be covered by the claims of the present utility model.

Claims (9)

1. The utility model provides a canning carbon dioxide residual gas separation purification device which characterized in that includes:
A gas source tank;
the air inlet end of the first booster pump is communicated with the air source pipe through the main valve;
The three adsorption towers are internally provided with adsorbents;
a gas storage unit;
the three gas outlet control units are used for respectively connecting the three adsorption tower gas storage units in series in sequence to form a purification line; the three air outlet control units are also respectively communicated with the air source tank and the air storage unit; the air outlet of the first booster pump is communicated with the inside of the adsorption tower of the purification line source;
three space replacement components are respectively arranged inside the adsorption tower;
And the three filling control assemblies are communicated with the space replacement assemblies inside the three adsorption towers respectively.
2. The apparatus according to claim 1, wherein the gas outlet control unit comprises:
One end of the waste gas valve is communicated with the inside of the adsorption tower, and the other end of the waste gas valve is communicated with the outside atmosphere;
One end of the air return valve is communicated with the inside of the adsorption tower, and the other end of the air return valve is communicated with the inside of the air source tank;
one end of the gas transmission valve is communicated with the inside of the adsorption tower;
one end of the flushing valve is communicated with the gas storage unit, and the other end of the flushing valve is communicated with the inside of the upstream adsorption tower;
The air inlet end of the second booster pump is communicated with the other end of the air delivery valve, and the other end of the second booster pump is communicated with the downstream adsorption tower or the air storage unit.
3. The apparatus according to claim 2, wherein the gas outlet control unit between the two adsorption towers downstream of the purifying line further comprises a recoil valve having one end connected to the output end of the second booster pump and the other end connected to the inside of the preceding adsorption tower of the upstream adsorption tower.
4. The apparatus according to claim 2, wherein the gas outlet control unit further comprises:
One end of the output bus is communicated with the inside of the adsorption tower, and the other end of the output bus is respectively communicated with the waste gas valve, the air return valve and the air transmission valve;
And the concentration sensor for detecting the concentration of the carbon dioxide is communicated with the output bus.
5. The apparatus according to claim 2, further comprising a third booster pump having air inlets respectively connected to the air return valves of the three air outlet control units and the other ends connected to the air source tank.
6. The apparatus for separating and purifying residual carbon dioxide in cans of claim 1, wherein the space substitution assembly comprises:
The fixed plate is arranged at the upper part in the adsorption tower;
The elastic deformation air bag is fixed on the fixed plate and forms a closed space with the fixed plate;
one end of the breather pipe passes through the adsorption tower and the fixed plate to be communicated with the inside of the air bag, and the other end of the breather pipe is communicated with a filling control assembly.
7. The apparatus according to claim 6, wherein the lower portion of the air bag is in an inverted cone shape in a natural state, the space substitution assembly further comprises a lifting unit provided in the air bag, and the lifting unit comprises:
one end of the pull rope is connected with the inner surface of the bottom of the air bag;
A lifting barrel with an upward opening in a box, wherein the outer surface of the bottom is connected with the other end of the pull rope; the side wall of the lifting barrel is provided with a plurality of lower air inlets;
The lower end of the elastic deformation lifting cylinder is in seamless communication with the opening of the lifting cylinder, and a plurality of totally-concave deformation guide grooves are formed in the outer surface of the lifting cylinder;
The fixed cylinder is box-shaped with a downward opening, the opening is in seamless communication with the upper end of the lifting cylinder, the outer surface of the top is fixedly connected with the fixed plate, and a plurality of upper air inlets are arranged on the side wall of the fixed cylinder; the breather pipe sequentially passes through the adsorption tower, the fixed plate and the fixed cylinder and is communicated with the interior of the lifting cylinder.
8. The apparatus of claim 6, wherein the fill control assembly comprises:
a media source canister;
a fourth booster pump with a one-way valve, wherein the inlet end of the fourth booster pump is communicated with the inside of the medium source tank, and the outlet end of the fourth booster pump is communicated with a vent pipe of the corresponding space replacement assembly;
And one end of the pressure release valve is communicated with the vent pipe of the space displacement assembly.
9. The apparatus of claim 8, wherein the medium source tank contents are compressible gases; the outlet ends of the fourth booster pumps of the three filling control assemblies are communicated sequentially through pressure regulating valves.
CN202322731640.7U 2023-10-11 2023-10-11 Separation and purification device for residual gas of canned carbon dioxide Active CN220834837U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202322731640.7U CN220834837U (en) 2023-10-11 2023-10-11 Separation and purification device for residual gas of canned carbon dioxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202322731640.7U CN220834837U (en) 2023-10-11 2023-10-11 Separation and purification device for residual gas of canned carbon dioxide

Publications (1)

Publication Number Publication Date
CN220834837U true CN220834837U (en) 2024-04-26

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ID=90773883

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202322731640.7U Active CN220834837U (en) 2023-10-11 2023-10-11 Separation and purification device for residual gas of canned carbon dioxide

Country Status (1)

Country Link
CN (1) CN220834837U (en)

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