CN220816017U - Centrifugal compressor unit applied to chemical absorption method CCUS device - Google Patents
Centrifugal compressor unit applied to chemical absorption method CCUS device Download PDFInfo
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- CN220816017U CN220816017U CN202322497561.4U CN202322497561U CN220816017U CN 220816017 U CN220816017 U CN 220816017U CN 202322497561 U CN202322497561 U CN 202322497561U CN 220816017 U CN220816017 U CN 220816017U
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- carbon dioxide
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- rich liquid
- lean
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- 238000010521 absorption reaction Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000000126 substance Substances 0.000 title claims abstract description 17
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 194
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 101
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 101
- 239000007788 liquid Substances 0.000 claims abstract description 42
- 238000004458 analytical method Methods 0.000 claims abstract description 9
- 239000007789 gas Substances 0.000 claims description 30
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000003546 flue gas Substances 0.000 claims description 12
- 238000000746 purification Methods 0.000 claims description 7
- 238000003860 storage Methods 0.000 claims description 7
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims 1
- 238000005265 energy consumption Methods 0.000 abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 6
- 238000006073 displacement reaction Methods 0.000 description 6
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 244000161999 Acacia greggii Species 0.000 description 2
- 235000004608 catclaw acacia Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005261 decarburization Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
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- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
The utility model discloses a centrifugal compressor unit applied to a chemical absorption method CCUS device, which comprises a power plant chimney induced draft pipe, wherein the power plant chimney induced draft pipe is connected with a feed inlet of an absorption tower through an induced draft fan, a rich liquid outlet at the bottom of the absorption tower is connected with one end of a rich liquid stroke pipeline of a lean and rich liquid heat exchanger through a rich liquid pump, and the other end of the rich liquid stroke pipeline is connected with the feed inlet of an analysis tower; the lean liquid outlet at the bottom of the analysis tower is connected with one end of a lean liquid stroke pipeline of the lean-rich liquid heat exchanger through a lean liquid pump, and the other end of the lean liquid stroke pipeline is connected with a lean liquid inlet of the absorption tower; the gas outlet at the top of the analytic tower is connected with the gas inlet of the carbon dioxide centrifugal compressor through a carbon dioxide conveying pipeline. The centrifugal compressor is more suitable for large-scale carbon capture devices, the variable efficiency of the carbon dioxide compressor is improved, and the energy consumption of the device is reduced, so that the cost of carbon dioxide capture can be greatly reduced, and the industrial development of CCUS is facilitated.
Description
Technical Field
The utility model belongs to the technical field of steam turbines, relates to upper cat claws, and in particular relates to a special screw for installing and adjusting the upper cat claw of a steam turbine.
Background
Carbon dioxide (CO 2) capture, utilization and sequestration (Carbon dioxide Capture, utilization and Storage, CCUS) refers to an industrial process in which carbon dioxide is separated from an emissions source and then utilized or sequestered to achieve carbon dioxide abatement.
The carbon dioxide compressor is used as core equipment in the trapping process, and has the functions of compressing carbon dioxide from normal pressure to about 2.6MPa, condensing and liquefying the carbon dioxide through a refrigerating system, so as to realize liquid storage of the carbon dioxide; meanwhile, a carbon dioxide compressor is also the most important power consumption equipment in the whole capturing process. Therefore, the reliability and efficiency of the carbon dioxide compressor are directly related to the reliability and cost of operation of the carbon dioxide capturing device, and may be the "heart" of the carbon dioxide capturing device. However, in recent years, since the domestic carbon dioxide capturing device has a small scale, only a positive displacement compressor can be used for the flow rate of carbon dioxide, and the efficiency of the compressor is about 60% due to the limited structure and the small flow rate, and also due to the existence of a clearance volume.
At present, there are two aspects of the current state of the domestic carbon dioxide capturing device: firstly, the scale is small, industrialization is difficult to form, and the scale is below 15 ten thousand tons/year; on the other hand, the trapping cost is higher, and the energy consumption in the trapping process is higher.
At present, the domestic CCUS device is mostly in a scale of below 15 ten thousand tons/year, the scale and the flow are smaller, and only a positive displacement compressor can be adopted. The positive displacement compressor has the characteristics of clearance volume, discontinuous exhaust and the like, so that the compressor has low variable efficiency, more vulnerable parts and higher overhauling and maintenance cost.
Disclosure of Invention
Aiming at the defects existing in the prior art, the utility model aims to provide a centrifugal compressor unit applied to a chemical absorption method CCUS device, which solves the technical problem that the efficiency of the device in the prior art is required to be further improved.
In order to solve the technical problems, the utility model adopts the following technical scheme:
The utility model provides a be applied to centrifugal compressor unit of chemical absorption method CCUS device, includes power plant's chimney induced duct, and power plant's chimney induced duct passes through the draught fan and links to each other with the feed inlet of absorption tower, and the rich liquid export at the bottom of the absorption tower passes through rich liquid pump and links to each other with the one end of the rich liquid stroke pipeline of lean and rich liquid heat exchanger, and the other end of rich liquid stroke pipeline links to each other with the feed inlet of analytic tower.
And a lean solution outlet at the bottom of the analysis tower is connected with one end of a lean solution stroke pipeline of the lean solution heat exchanger through a lean solution pump, and the other end of the lean solution stroke pipeline is connected with a lean solution inlet of the absorption tower.
And a gas outlet at the top of the analytic tower is connected with a gas inlet of the carbon dioxide centrifugal compressor through a carbon dioxide conveying pipeline.
The utility model also has the following technical characteristics:
The carbon dioxide centrifugal compressors are two carbon dioxide centrifugal compressors connected in parallel.
The gas outlet of the carbon dioxide centrifugal compressor is connected with the feed inlet of the carbon dioxide liquefying and purifying system, and the discharge outlet of the carbon dioxide liquefying and purifying system is connected with the carbon dioxide storage tank.
And the carbon dioxide centrifugal compressor is also connected with a frequency converter.
The carbon dioxide centrifugal compressor adopts dry gas seal as the shaft end seal of the carbon dioxide centrifugal compressor. And the dry gas sealed air inlet is communicated with the air outlet of the carbon dioxide centrifugal compressor.
And a flue gas outlet at the top of the absorption tower is connected with a decarburization flue gas pipeline.
Compared with the prior art, the utility model has the following technical effects:
The utility model applies the centrifugal compressor to the 50 ten thousand ton/year scale CCUS device, the centrifugal compressor is turbine machinery, and has the advantages of large flow, high efficiency, few vulnerable parts and the like, continuous exhaust can be realized, and the efficiency of the compressor can reach more than 80 percent. Therefore, the centrifugal compressor is more suitable for large-scale carbon capture devices, improves the variable efficiency of the carbon dioxide compressor, and reduces the energy consumption of the device, thereby greatly reducing the cost of carbon dioxide capture and being more beneficial to the industrialized development of CCUS.
In the prior art, the flow of the screw compressor is smaller, a plurality of parallel schemes are needed, and the overhaul and maintenance cost is increased. Therefore, the centrifugal compressor is applied to the CCUS device, so that the compression efficiency can be greatly improved, the capture cost of carbon dioxide is reduced, meanwhile, the overhaul and maintenance cost is reduced, and an effective technical support is provided for the industrialized development of the CCUS technology.
According to the utility model, the carbon dioxide compressor adopts dry gas sealing as shaft end sealing, and carbon dioxide gas at the outlet of the compressor is used as a sealing gas source, so that the leakage amount of carbon dioxide is greatly reduced, and the trapping efficiency of the device is improved.
And (IV) the carbon dioxide centrifugal compressor is driven by a frequency converter, the working condition is regulated by a rotating speed regulation mode, the rotating speed regulation within the flow range of 75-105% is realized, and 60-75% adopts a rotating speed and reflux regulation mode.
And (V) for a large-scale CCUS device, the utility model adopts a scheme of connecting two or more centrifugal compressors in parallel, and when the load of the device is less than 50%, the running efficiency of the device is improved by adopting a number adjustment mode, so that the purposes of high efficiency and energy conservation are achieved.
Drawings
Fig. 1 is a schematic diagram of the connection relationship of the centrifugal compressor unit of the present utility model.
Fig. 2 is a schematic diagram of the connection relationship of the parallel centrifugal compressor units of the present utility model.
The meaning of each reference numeral in the figures is: the device comprises a 1-power plant chimney induced duct, a 2-induced draught fan, a 3-absorption tower, a 4-rich liquid pump, a 5-lean and rich liquid heat exchanger, a 501-rich liquid stroke pipeline, a 502-lean liquid stroke pipeline, a 6-resolution tower, a 7-lean liquid pump, an 8-carbon dioxide conveying pipe, a 9-carbon dioxide centrifugal compressor, a 10-carbon dioxide liquefaction and purification system, an 11-carbon dioxide storage tank, a 12-frequency converter, a 13-dry gas seal and a 14-decarburization flue gas pipeline.
The following examples illustrate the utility model in further detail.
Detailed Description
All parts and devices in the present utility model are known in the art unless otherwise specified. For example, the carbon dioxide liquefaction and purification system 10 employs a known and commonly used carbon dioxide liquefaction and purification system; the dry gas seal 13 is a known and commonly used dry gas seal.
In the utility model, all the devices are connected through pipelines, and the pipelines are provided with valves according to the needs.
At present, the method for capturing carbon dioxide in coal-fired power plants at home and abroad mainly adopts a chemical absorption method, which utilizes the property of carbon dioxide as acid gas, uses weak alkaline substances (such as ethanolamine MEA solution) to absorb and then heats to desorb the carbon dioxide, thereby achieving the aim of separating the carbon dioxide.
After carbon dioxide in the flue gas of the power plant passes through the trapping device, carbon dioxide gas with the concentration of more than 92% can be obtained. There are generally two ways: the method comprises the steps of compressing carbon dioxide to about 26barA, liquefying, storing in a tank, transporting to the downstream by adopting a tank truck, and using the tank truck for carbon dioxide displacement, industrial utilization (urea preparation, methanol preparation by hydrogenation), food-grade carbon dioxide and the like to realize the utilization and sealing of the carbon dioxide; another way is to compress the carbon dioxide to above 7.38MPaA and send it directly to the field using pipelines. Because the CCUS technology starts later in China, the carbon dioxide pipe network is relatively less, and most of the carbon dioxide pipe networks adopt the first mode.
At present, the scale of a device for capturing carbon dioxide by adopting a chemical absorption method abroad reaches 100 ten thousand tons/year at maximum, and a centrifugal compressor is adopted as core equipment in the device. The domestic scale is 5-15 ten thousand tons/year, the flow of the compressor is smaller, and only a positive displacement compressor can be adopted.
Because of the positive displacement compressor, the centrifugal compressor has the technical advantages of large flow, high efficiency, low maintenance cost, few wearing parts and the like, thereby greatly reducing the cost of carbon dioxide capture and providing technical guarantee for the large-scale, large-scale and industrialization of the CCUS technology.
Therefore, the utility model is researched aiming at the chemical absorption method carbon dioxide capturing process system with the maximum national standard (50 ten thousand tons/year); meanwhile, a high-efficiency carbon dioxide centrifugal compressor technical scheme is developed aiming at a process system, and a system solution of a compressor unit is formed.
The following specific embodiments of the present utility model are provided, and it should be noted that the present utility model is not limited to the following specific embodiments, and all equivalent changes made on the basis of the technical scheme of the present utility model fall within the protection scope of the present utility model.
Examples:
The embodiment provides a centrifugal compressor unit applied to a chemical absorption method CCUS device, as shown in fig. 1, the centrifugal compressor unit comprises a power plant chimney induced draft tube 1, the power plant chimney induced draft tube 1 is connected with a feed inlet of an absorption tower 3 through an induced draft fan 2, a rich liquid outlet at the bottom of the absorption tower 3 is connected with one end of a rich liquid stroke pipeline 501 of a lean and rich liquid heat exchanger 5 through a rich liquid pump 4, and the other end of the rich liquid stroke pipeline 501 is connected with a feed inlet of an analysis tower 6.
The lean solution outlet at the bottom of the analysis tower 6 is connected with one end of a lean solution stroke pipeline 502 of the lean-rich solution heat exchanger 5 through a lean solution pump 7, and the other end of the lean solution stroke pipeline 502 is connected with a lean solution inlet of the absorption tower 3, so that the recycling of the absorbent is realized.
The gas outlet at the top of the analytic tower 6 is connected with the gas inlet of a carbon dioxide centrifugal compressor 9 through a carbon dioxide conveying pipe 8.
As a preferable mode of the present embodiment, the carbon dioxide centrifugal compressor 9 is two carbon dioxide centrifugal compressors 9 connected in parallel. For larger-scale CCUS units, such as those of 50 ten thousand tons/year or more, a scheme of parallel operation of 2 or more centrifugal compressors may be employed, as shown in fig. 2. When the load of the process system is required to run below 50%, the number of the process systems is adjusted, and only one of the process systems is operated.
As a preferable scheme of the embodiment, the air outlet of the carbon dioxide centrifugal compressor 9 is connected with the feed inlet of the carbon dioxide liquefaction and purification system 10, and the discharge outlet of the carbon dioxide liquefaction and purification system 10 is connected with the carbon dioxide storage tank 11.
As a preferred solution of this embodiment, the carbon dioxide centrifugal compressor 9 is also connected with a frequency converter 12. The carbon dioxide centrifugal compressor 9 is dragged by the frequency converter 12, and the working condition is adjusted by adopting a rotating speed according to the working condition and load change of a user, so that the purposes of high efficiency and energy saving are achieved.
As a preferred solution of the present embodiment, the carbon dioxide centrifugal compressor 9 employs a dry gas seal 13 as the shaft end seal of the carbon dioxide centrifugal compressor 9. The air inlet of the dry gas seal 13 is communicated with the air outlet of the carbon dioxide centrifugal compressor 9. The dry gas seal 13 takes gas from a pipeline at the outlet of the carbon dioxide centrifugal compressor 9, so that zero leakage of the carbon dioxide compressor can be realized, and the dry gas seal has an important effect on improving the energy consumption and economy of a process device.
As a preferred solution of this embodiment, the flue gas outlet at the top of the absorber 3 is connected to a decarbonizing flue gas duct 14.
The operation of the centrifugal compressor unit of the present utility model applied to the chemical absorption CCUS apparatus is as follows.
Firstly, flue gas which is led out from a power plant chimney by utilizing a power plant chimney air-guiding pipe 1 and contains 10-15% of carbon dioxide in volume concentration is sent into an absorption tower 3 through an induced draft fan 2.
Secondly, in the absorption tower 3, the flue gas is contacted with absorbent ethanolamine solution sprayed on the top of the absorption tower 3, and carbon dioxide in the flue gas and ethanolamine are subjected to chemical reaction; at this time, the absorbent having absorbed carbon dioxide is called a rich liquid, and the rich liquid is fed from the bottom of the absorption tower 3 to the desorption tower 6 by the rich liquid pump 4; and the decarbonized flue gas is discharged from the top of the absorption tower 3.
Thirdly, the rich liquid absorbs heat in the analysis tower 6 to carry out reverse reaction, carbon dioxide is discharged from the top of the analysis tower 6, the analyzed absorbent is called lean liquid, and the lean liquid is sent into the absorption tower 3 through the lean liquid pump 7 to carry out the next cycle.
Fourth, the lean liquid and the rich liquid exchange heat in the lean-rich liquid heat exchanger 5, and heat is recovered.
Fifth, the resolved carbon dioxide gas is discharged from the top of the resolving tower 6, and the concentration of the carbon dioxide in the gas can reach more than 90%.
Sixth, the carbon dioxide gas is compressed to a pressure of about 2.6MPaA by a carbon dioxide centrifugal compressor 9, and after being liquefied and purified by a carbon dioxide liquefying and purifying system 10, the carbon dioxide gas can reach a purity of over 99 percent, and then the carbon dioxide gas is sent into a carbon dioxide storage tank 11 and finally transported to various use sites by a tank car, a transport ship and the like.
Taking a 50 ten thousand ton/year CCUS unit as an example, considering 8000 hours of annual operation, carbon dioxide is compressed from 0.11MPaA to 2.6MPaA, and the inlet flow of the compressor is 65600kg/h: the screw compressor is adopted, the polytropic efficiency is about 60%, and the shaft power of the compressor is about 6700 kW; by adopting a centrifugal compressor, the polytropic efficiency can reach about 80%, and the shaft power is about 5000kW.
Compared with a screw compressor, the centrifugal compressor can save about 1700kW, 1360 ten thousand kW.h of electricity can be saved each year, and 816 ten thousand yuan of electricity can be saved each year according to 0.6 yuan of electricity per degree.
Claims (6)
1. The centrifugal compressor unit applied to the chemical absorption method CCUS device is characterized by comprising a power plant chimney induced duct (1), wherein the power plant chimney induced duct (1) is connected with a feed inlet of an absorption tower (3) through a draught fan (2), a rich liquid outlet at the bottom of the absorption tower (3) is connected with one end of a rich liquid stroke pipeline (501) of a lean and rich liquid heat exchanger (5) through a rich liquid pump (4), and the other end of the rich liquid stroke pipeline (501) is connected with a feed inlet of an analysis tower (6);
The lean solution outlet at the bottom of the analysis tower (6) is connected with one end of a lean solution stroke pipeline (502) of the lean solution heat exchanger (5) through a lean solution pump (7), and the other end of the lean solution stroke pipeline (502) is connected with the lean solution inlet of the absorption tower (3);
The gas outlet at the top of the analytic tower (6) is connected with the gas inlet of a carbon dioxide centrifugal compressor (9) through a carbon dioxide conveying pipe (8).
2. Centrifugal compressor unit for use in a chemical absorption ccs plant as claimed in claim 1, wherein said carbon dioxide centrifugal compressor (9) is two carbon dioxide centrifugal compressors (9) connected in parallel.
3. Centrifugal compressor unit for use in a chemical absorption method CCUS device according to claim 1 or 2, wherein the gas outlet of the carbon dioxide centrifugal compressor (9) is connected to the feed inlet of the carbon dioxide liquefaction and purification system (10), and the discharge outlet of the carbon dioxide liquefaction and purification system (10) is connected to the carbon dioxide storage tank (11).
4. Centrifugal compressor unit for use in a chemical absorption method CCUS device according to claim 1 or 2, wherein the carbon dioxide centrifugal compressor (9) is further connected with a frequency converter (12).
5. Centrifugal compressor unit for use in a chemical absorption method CCUS device according to claim 1 or 2, wherein the carbon dioxide centrifugal compressor (9) uses a dry gas seal (13) as a shaft end seal of the carbon dioxide centrifugal compressor (9); and an air inlet of the dry gas seal (13) is communicated with an air outlet of the carbon dioxide centrifugal compressor (9).
6. Centrifugal compressor group for use in a chemical absorption ccs installation according to claim 1 or 2, wherein the flue gas outlet at the top of the absorber tower (3) is connected to a decarbonizing flue gas duct (14).
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CN202322497561.4U CN220816017U (en) | 2023-09-14 | 2023-09-14 | Centrifugal compressor unit applied to chemical absorption method CCUS device |
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CN202322497561.4U CN220816017U (en) | 2023-09-14 | 2023-09-14 | Centrifugal compressor unit applied to chemical absorption method CCUS device |
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2023
- 2023-09-14 CN CN202322497561.4U patent/CN220816017U/en active Active
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