CN220767115U - Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust - Google Patents
Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust Download PDFInfo
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- CN220767115U CN220767115U CN202321996131.0U CN202321996131U CN220767115U CN 220767115 U CN220767115 U CN 220767115U CN 202321996131 U CN202321996131 U CN 202321996131U CN 220767115 U CN220767115 U CN 220767115U
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- 230000009467 reduction Effects 0.000 title claims abstract description 34
- 239000000428 dust Substances 0.000 title claims abstract description 28
- 239000000779 smoke Substances 0.000 title claims abstract description 25
- 238000004064 recycling Methods 0.000 title claims abstract description 21
- 238000000605 extraction Methods 0.000 claims abstract description 27
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 10
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 9
- 238000004821 distillation Methods 0.000 claims abstract description 9
- 238000002386 leaching Methods 0.000 claims abstract description 9
- 230000003647 oxidation Effects 0.000 claims abstract description 9
- 238000004062 sedimentation Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000012074 organic phase Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 239000013049 sediment Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 20
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract description 17
- 239000002893 slag Substances 0.000 abstract description 13
- 230000008569 process Effects 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 7
- 150000002739 metals Chemical class 0.000 abstract description 7
- 150000003841 chloride salts Chemical class 0.000 abstract description 5
- 238000011084 recovery Methods 0.000 abstract description 4
- 239000012043 crude product Substances 0.000 abstract description 3
- 239000013067 intermediate product Substances 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 9
- 229910052737 gold Inorganic materials 0.000 description 9
- 239000010931 gold Substances 0.000 description 9
- 239000002699 waste material Substances 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000003818 cinder Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 3
- 229910052683 pyrite Inorganic materials 0.000 description 3
- 239000011028 pyrite Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
- 239000012320 chlorinating reagent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910001710 laterite Inorganic materials 0.000 description 1
- 239000011504 laterite Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- -1 nickel-poor ore Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 1
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- Manufacture And Refinement Of Metals (AREA)
Abstract
The utility model relates to a comprehensive recycling system for cyanidation tailings, chlorination, reduction, roasting and volatilizing smoke dust, which comprises a bag type dust collector, a slag warehouse and a leaching tower, wherein the slag warehouse and the leaching tower are connected with the bag type dust collector, the leaching tower is sequentially connected with a settling tank I, a distillation tower, an oxidation tank, a settling tank II and an extraction tank, an outlet of the extraction tank is connected with inlets of a back extraction tank and a reduction tank, and an outlet of the reduction tank is connected with an inlet of a settling tank III. According to the utility model, a smoke comprehensive recovery system is designed according to the characteristics of smoke generated in the process of chloridizing reduction roasting treatment of cyanide-containing tailings, separation of volatile metal elements is realized, pb, zn, cu, au, ag is separated and comprehensively utilized, all metals are recycled in crude products or intermediate products, and the value of the smoke containing chloride salt is fully embodied.
Description
Technical Field
The utility model relates to the technical fields of mineral processing, metallurgy and chemical industry, in particular to a comprehensive recycling system for volatile smoke dust generated by chloridizing, reducing, roasting and volatilizing cyanide tailings.
Background
The full mud cyanidation method is one of the most widely used gold extraction methods for gold production enterprises at present. Since the 80 s of the last century in China, along with the increase of mineral resource exploration and the discovery of a large number of gold-containing mineral deposits, the gold extraction process technology of the full-mud cyanidation method is rapidly developed, and the full-mud cyanidation method becomes a production process which is most widely applied in the provincial gold production enterprises, and the principle flow is as follows: raw ore crushing, ore grinding, grading, thickening, cyaniding, carbon adsorption, gold-loaded carbon, analysis, electrolysis, purification and ingot forming. The process adopts sodium cyanide for cyanide reaction to produce a great amount of cyanide-containing tailing waste slag, and the cyanide-containing tailing waste slag is piled up for a long time, so that the environmental hazard is great. Therefore, cyanide-containing tailing waste residues are urgently needed to be treated, and potential hazards are eliminated.
The technology for treating the cyanide-containing tailing waste residue by an alkaline chloridizing method and an incineration method has the characteristics of simple process equipment, easy operation, intermittent treatment, continuous treatment, readily available raw materials, quick response, relatively small investment and the like, and becomes a technical method for treating the cyanide-containing tailing waste residue with practical application value at present.
The incineration method is to put the cyanide-containing tailing waste residue into an incinerator, and burn the cyanide-containing toxic substances into non-toxic products under certain high temperature conditions. During incineration, the cyanide-containing tailing waste residue, coal and clay (containing quicklime) are mixed and stirred at a ratio of 6:4:1, then are subjected to ball making by a ball making machine, are placed into a special incinerator (the furnace temperature is less than 850 ℃ and the micro negative pressure is operated), and the waste gas is discharged into a 30m high chimney by a draught fan after dust removal by a dust remover and then is discharged into the atmosphere. Wherein, the quicklime plays a role of sulfur fixation, the dust collector collects smoke dust and is used for making balls, the combustion ash slag is crushed and then used for making bricks, the removal rate of cyanide in the cyanide-containing tailing waste slag can reach more than 90% after incineration, and the removal effect is obvious.
The cyanide-containing tailings overcome the reaction activation energy at a certain temperature (600 ℃), the CN-energy of the cyanide-containing tailings is completely oxidized, and the oxidation mechanism is generally considered as follows:
the chloridizing roasting refers to a process of separating and enriching valuable metals and other components by converting certain components in materials into gas or condensed-phase chlorides under certain conditions under the action of a chloridizing agent. The chloridizing sintering process is mostly used for treating pyrite cinder, high titanium slag, nickel-poor ore, laterite ore, tin-poor ore, complex gold ore and bismuth-poor composite ore.
Chloridizing roasting is one of the most widely used chloridizing processes. In the case of direct chlorination, as mentioned earlier, it has been used in production to treat gold and silver ores as early as the eighteenth century. Since more than a century, direct chlorination has been studied for extended application in the treatment of many mineral raw materials containing heavy non-ferrous and noble metals, with the most successful comprehensive utilization of pyrite cinder. Heretofore, neither medium-temperature chloridizing roasting nor high-temperature chloridizing roasting has been successfully used for comprehensive utilization of pyrite cinder on an industrial scale. As for reductive chlorination, it is known that the use of the processes such as chlorination of titanium dioxide (the main component of rutile or high titanium slag) and chlorination of magnesium oxide (or magnesite) has been an important link in the production of metallic titanium and magnesium.
The chlorinating agents commonly used for chloridizing roasting are: cl2, HCl, naCl, caCl, etc. The main factors influencing the chloridizing roasting are temperature, chloridizing agent type and concentration, gas phase composition, gas flow speed, material granularity, void fraction, material mineral composition, chemical composition, catalysis and the like.
The waste gas generated in the process of chloridizing reduction roasting tailings mainly comes from a roasting process, a great amount of chlorine-containing flue gas and smoke dust are generated by adopting a reduction chloridizing roasting process, although hydrochloric acid and chloride salt are recovered through leaching absorption, the flue gas still contains a small amount of chlorine, standard emission can be realized after alkali absorption treatment generally, even standard non-standard conditions exist, the volatilized products mainly comprise ZnCl2, pbCl2, cuCl2, auCl, agCl and the like, the formed products are the mixture of corresponding salts of the metals, the metals are treated by the flue gas, and the metals are not recycled, so that the value of the smoke dust containing the chloride salt is not fully reflected.
Disclosure of Invention
The utility model provides a comprehensive recycling system for cyanidation tailings, chloridizing, reducing, roasting and volatilizing smoke dust.
The specific technical scheme of the utility model is as follows:
the utility model provides a comprehensive recycling system of cyanidation tailings chlorination reduction roasting volatilized smoke dust, includes pocket type dust collector and slag storehouse and the drip washing tower of being connected rather than, the drip washing tower is connected with settling tank I, distillation tower, oxidation tank, settling tank II, extraction tank in proper order, the export of extraction tank is connected with the import of back extraction tank and reduction tank, the reduction tank export is connected with the import of settling tank III.
Further, preferably, the outlet of the stripping tank is connected to the inlet of the extraction tank, so that the organic phase generated after the stripping treatment is returned to the extraction tank for recycling.
Further, preferably, the outlet of the settling tank iii is connected to the inlet of the reduction tank, so that the zinc liquid generated in the settling tank iii is returned to the reduction tank for recycling.
The beneficial effects of the utility model are as follows:
according to the utility model, a smoke comprehensive recovery system is designed according to the characteristics of smoke generated in the process of chloridizing reduction roasting treatment of cyanide-containing tailings, separation of volatile metal elements is realized, pb, zn, cu, au, ag is separated and comprehensively utilized, all metals are recycled in crude products or intermediate products, and the value of the smoke containing chloride salt is fully embodied.
Drawings
FIG. 1 is a diagram showing the relationship between the comprehensive recycling system and equipment for the cyanidation tailings chloridizing reduction roasting volatile smoke dust;
in the figure: 1-bag type dust collector, 2-slag warehouse, 3-leaching tower, 4-settling tank I, 5-distillation tower, 6-oxidation tank, 7-settling tank II, 8-extraction tank, 9-stripping tank, 10-reduction tank and 11-settling tank III.
Detailed Description
In order to make the technical problems and technical schemes solved by the utility model more clear, the utility model is further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the utility model.
In the description of the present utility model, it should be understood that the terms "longitudinal," "transverse," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like indicate or are based on the orientation or positional relationship shown in the drawings, merely to facilitate description of the present utility model, and do not indicate or imply that the devices or elements referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be construed as limiting the present utility model.
In the description of the present utility model, it should also be noted that, unless explicitly specified and limited otherwise, the terms "disposed," "mounted," and "connected" are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present utility model will be understood in specific cases by those of ordinary skill in the art.
As shown in fig. 1, this embodiment provides a comprehensive recycling system for cyanidation tailings, chlorination, reduction, roasting and volatilizing smoke dust, which comprises a bag type dust collector 1, a slag warehouse 2 and a leaching tower 3 connected with the dust collector, wherein an outlet of the leaching tower 3 is sequentially connected with a settling tank i 4, a distillation tower 5, an oxidation tank 6, a settling tank ii 7 and an extraction tank 8, an outlet of the extraction tank 8 is connected with inlets of a stripping tank 9 and a reduction tank 10, and an outlet of the reduction tank 10 is connected with an inlet of a settling tank iii 11.
The outlet of the back extraction tank 9 is connected with the inlet of the extraction tank 8, so that the organic phase generated after the back extraction treatment is returned to the extraction tank 8 for recycling.
The outlet of the settling tank III 11 is connected with the inlet of the original tank 10, so that the zinc liquid generated by the settling tank III 11 is returned to the reduction tank 10 for recycling.
In the embodiment, the smoke dust generated by chloridizing reduction roasting is firstly collected by the bag type dust collector 1, collected dust collection slag is sent to the slag warehouse 2, and the smoke gas which is not collected by the bag type dust collector 1 enters the leaching tower 3 for washing. The flue gas is washed and fused into a washing liquid, the washing liquid enters a settling tank I4 for settling treatment, a settled solid phase returns to ingredients, clear liquid is sent to a distillation tower 5 for distillation treatment, and hydrochloric acid generated by distillation is returned for chloridizing agent preparation. The concentrated phase liquid generated by distillation enters an oxidation tank 6, an oxidant is added into the oxidation tank 6 for oxidation treatment, the oxidized mixed liquid generated after oxidation enters a sedimentation tank II 7 for sedimentation treatment, the solid phase sedimentation generated by sedimentation is lead dioxide (lead product), and the clear liquid generated by sedimentation is continuously sent to an extraction tank 8. An oxidizing agent is added into the extraction tank 8 for treatment, the produced loaded organic phase enters the stripping tank 9, and the produced extract is sent to the reduction tank 10. And adding a stripping agent into the stripping tank 9 for stripping, returning an organic phase generated by the stripping treatment to the extraction tank 8 for recycling, and obtaining copper sulfate as a product after the stripping treatment. Zinc powder is added into the reduction tank 10 for reduction treatment, the reduction mixed solution generated by the reduction treatment enters the sedimentation tank III 11 for sedimentation treatment, the zinc solution generated by sedimentation returns to the reduction tank 10 for continuous recycling, the solid phase generated by sedimentation is settled into silver-containing gold mud, and the silver recovery is carried out in the chloridizing analysis procedure.
According to the utility model, a smoke comprehensive recovery system is designed according to the characteristics of smoke generated in the process of chloridizing reduction roasting treatment of cyanide-containing tailings, separation of volatile metal elements is realized, pb, zn, cu, au, ag is separated and comprehensively utilized, all metals are recycled in crude products or intermediate products, and the value of the smoke containing chloride salt is fully embodied.
While the utility model has been described in detail in connection with specific and preferred embodiments, it will be understood by those skilled in the art that the utility model is not limited to the foregoing embodiments, but is intended to cover modifications, equivalents, and alternatives falling within the spirit and principles of the utility model.
Claims (3)
1. The utility model provides a comprehensive recycling system of cyanidation tailings chlorination reduction roasting volatilized smoke and dust, includes pocket type dust collector (1) and sediment storehouse (2) and drip washing tower (3) that are connected with it, its characterized in that: the leaching tower (3) is connected with the settling tank I (4), the distillation tower (5), the oxidation tank (6), the settling tank II (7) and the extraction tank (8) in sequence, the outlet of the extraction tank (8) is connected with the inlets of the back extraction tank (9) and the reduction tank (10), and the outlet of the reduction tank (10) is connected with the inlet of the settling tank III (11).
2. The comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust according to claim 1, wherein the comprehensive recycling system is characterized in that: the outlet of the back extraction tank (9) is connected with the inlet of the extraction tank (8), so that the organic phase generated after the back extraction treatment is returned to the extraction tank (8) for recycling.
3. The comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust according to claim 1, wherein the comprehensive recycling system is characterized in that: the outlet of the sedimentation tank III (11) is connected with the inlet of the reduction tank (10), so that the zinc liquid generated by the sedimentation tank III (11) is returned to the reduction tank (10) for recycling.
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