CN220767115U - Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust - Google Patents

Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust Download PDF

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CN220767115U
CN220767115U CN202321996131.0U CN202321996131U CN220767115U CN 220767115 U CN220767115 U CN 220767115U CN 202321996131 U CN202321996131 U CN 202321996131U CN 220767115 U CN220767115 U CN 220767115U
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tank
reduction
chloridizing
recycling system
smoke
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孙晋琳
尹福兴
潘品生
和少龙
董彬
资胡琪
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Heqing Beiya Mining Co ltd
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Heqing Beiya Mining Co ltd
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Abstract

The utility model relates to a comprehensive recycling system for cyanidation tailings, chlorination, reduction, roasting and volatilizing smoke dust, which comprises a bag type dust collector, a slag warehouse and a leaching tower, wherein the slag warehouse and the leaching tower are connected with the bag type dust collector, the leaching tower is sequentially connected with a settling tank I, a distillation tower, an oxidation tank, a settling tank II and an extraction tank, an outlet of the extraction tank is connected with inlets of a back extraction tank and a reduction tank, and an outlet of the reduction tank is connected with an inlet of a settling tank III. According to the utility model, a smoke comprehensive recovery system is designed according to the characteristics of smoke generated in the process of chloridizing reduction roasting treatment of cyanide-containing tailings, separation of volatile metal elements is realized, pb, zn, cu, au, ag is separated and comprehensively utilized, all metals are recycled in crude products or intermediate products, and the value of the smoke containing chloride salt is fully embodied.

Description

Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust
Technical Field
The utility model relates to the technical fields of mineral processing, metallurgy and chemical industry, in particular to a comprehensive recycling system for volatile smoke dust generated by chloridizing, reducing, roasting and volatilizing cyanide tailings.
Background
The full mud cyanidation method is one of the most widely used gold extraction methods for gold production enterprises at present. Since the 80 s of the last century in China, along with the increase of mineral resource exploration and the discovery of a large number of gold-containing mineral deposits, the gold extraction process technology of the full-mud cyanidation method is rapidly developed, and the full-mud cyanidation method becomes a production process which is most widely applied in the provincial gold production enterprises, and the principle flow is as follows: raw ore crushing, ore grinding, grading, thickening, cyaniding, carbon adsorption, gold-loaded carbon, analysis, electrolysis, purification and ingot forming. The process adopts sodium cyanide for cyanide reaction to produce a great amount of cyanide-containing tailing waste slag, and the cyanide-containing tailing waste slag is piled up for a long time, so that the environmental hazard is great. Therefore, cyanide-containing tailing waste residues are urgently needed to be treated, and potential hazards are eliminated.
The technology for treating the cyanide-containing tailing waste residue by an alkaline chloridizing method and an incineration method has the characteristics of simple process equipment, easy operation, intermittent treatment, continuous treatment, readily available raw materials, quick response, relatively small investment and the like, and becomes a technical method for treating the cyanide-containing tailing waste residue with practical application value at present.
The incineration method is to put the cyanide-containing tailing waste residue into an incinerator, and burn the cyanide-containing toxic substances into non-toxic products under certain high temperature conditions. During incineration, the cyanide-containing tailing waste residue, coal and clay (containing quicklime) are mixed and stirred at a ratio of 6:4:1, then are subjected to ball making by a ball making machine, are placed into a special incinerator (the furnace temperature is less than 850 ℃ and the micro negative pressure is operated), and the waste gas is discharged into a 30m high chimney by a draught fan after dust removal by a dust remover and then is discharged into the atmosphere. Wherein, the quicklime plays a role of sulfur fixation, the dust collector collects smoke dust and is used for making balls, the combustion ash slag is crushed and then used for making bricks, the removal rate of cyanide in the cyanide-containing tailing waste slag can reach more than 90% after incineration, and the removal effect is obvious.
The cyanide-containing tailings overcome the reaction activation energy at a certain temperature (600 ℃), the CN-energy of the cyanide-containing tailings is completely oxidized, and the oxidation mechanism is generally considered as follows:
the chloridizing roasting refers to a process of separating and enriching valuable metals and other components by converting certain components in materials into gas or condensed-phase chlorides under certain conditions under the action of a chloridizing agent. The chloridizing sintering process is mostly used for treating pyrite cinder, high titanium slag, nickel-poor ore, laterite ore, tin-poor ore, complex gold ore and bismuth-poor composite ore.
Chloridizing roasting is one of the most widely used chloridizing processes. In the case of direct chlorination, as mentioned earlier, it has been used in production to treat gold and silver ores as early as the eighteenth century. Since more than a century, direct chlorination has been studied for extended application in the treatment of many mineral raw materials containing heavy non-ferrous and noble metals, with the most successful comprehensive utilization of pyrite cinder. Heretofore, neither medium-temperature chloridizing roasting nor high-temperature chloridizing roasting has been successfully used for comprehensive utilization of pyrite cinder on an industrial scale. As for reductive chlorination, it is known that the use of the processes such as chlorination of titanium dioxide (the main component of rutile or high titanium slag) and chlorination of magnesium oxide (or magnesite) has been an important link in the production of metallic titanium and magnesium.
The chlorinating agents commonly used for chloridizing roasting are: cl2, HCl, naCl, caCl, etc. The main factors influencing the chloridizing roasting are temperature, chloridizing agent type and concentration, gas phase composition, gas flow speed, material granularity, void fraction, material mineral composition, chemical composition, catalysis and the like.
The waste gas generated in the process of chloridizing reduction roasting tailings mainly comes from a roasting process, a great amount of chlorine-containing flue gas and smoke dust are generated by adopting a reduction chloridizing roasting process, although hydrochloric acid and chloride salt are recovered through leaching absorption, the flue gas still contains a small amount of chlorine, standard emission can be realized after alkali absorption treatment generally, even standard non-standard conditions exist, the volatilized products mainly comprise ZnCl2, pbCl2, cuCl2, auCl, agCl and the like, the formed products are the mixture of corresponding salts of the metals, the metals are treated by the flue gas, and the metals are not recycled, so that the value of the smoke dust containing the chloride salt is not fully reflected.
Disclosure of Invention
The utility model provides a comprehensive recycling system for cyanidation tailings, chloridizing, reducing, roasting and volatilizing smoke dust.
The specific technical scheme of the utility model is as follows:
the utility model provides a comprehensive recycling system of cyanidation tailings chlorination reduction roasting volatilized smoke dust, includes pocket type dust collector and slag storehouse and the drip washing tower of being connected rather than, the drip washing tower is connected with settling tank I, distillation tower, oxidation tank, settling tank II, extraction tank in proper order, the export of extraction tank is connected with the import of back extraction tank and reduction tank, the reduction tank export is connected with the import of settling tank III.
Further, preferably, the outlet of the stripping tank is connected to the inlet of the extraction tank, so that the organic phase generated after the stripping treatment is returned to the extraction tank for recycling.
Further, preferably, the outlet of the settling tank iii is connected to the inlet of the reduction tank, so that the zinc liquid generated in the settling tank iii is returned to the reduction tank for recycling.
The beneficial effects of the utility model are as follows:
according to the utility model, a smoke comprehensive recovery system is designed according to the characteristics of smoke generated in the process of chloridizing reduction roasting treatment of cyanide-containing tailings, separation of volatile metal elements is realized, pb, zn, cu, au, ag is separated and comprehensively utilized, all metals are recycled in crude products or intermediate products, and the value of the smoke containing chloride salt is fully embodied.
Drawings
FIG. 1 is a diagram showing the relationship between the comprehensive recycling system and equipment for the cyanidation tailings chloridizing reduction roasting volatile smoke dust;
in the figure: 1-bag type dust collector, 2-slag warehouse, 3-leaching tower, 4-settling tank I, 5-distillation tower, 6-oxidation tank, 7-settling tank II, 8-extraction tank, 9-stripping tank, 10-reduction tank and 11-settling tank III.
Detailed Description
In order to make the technical problems and technical schemes solved by the utility model more clear, the utility model is further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the utility model.
In the description of the present utility model, it should be understood that the terms "longitudinal," "transverse," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like indicate or are based on the orientation or positional relationship shown in the drawings, merely to facilitate description of the present utility model, and do not indicate or imply that the devices or elements referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be construed as limiting the present utility model.
In the description of the present utility model, it should also be noted that, unless explicitly specified and limited otherwise, the terms "disposed," "mounted," and "connected" are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; can be directly connected or indirectly connected through an intermediate medium, and can be communication between two elements. The specific meaning of the above terms in the present utility model will be understood in specific cases by those of ordinary skill in the art.
As shown in fig. 1, this embodiment provides a comprehensive recycling system for cyanidation tailings, chlorination, reduction, roasting and volatilizing smoke dust, which comprises a bag type dust collector 1, a slag warehouse 2 and a leaching tower 3 connected with the dust collector, wherein an outlet of the leaching tower 3 is sequentially connected with a settling tank i 4, a distillation tower 5, an oxidation tank 6, a settling tank ii 7 and an extraction tank 8, an outlet of the extraction tank 8 is connected with inlets of a stripping tank 9 and a reduction tank 10, and an outlet of the reduction tank 10 is connected with an inlet of a settling tank iii 11.
The outlet of the back extraction tank 9 is connected with the inlet of the extraction tank 8, so that the organic phase generated after the back extraction treatment is returned to the extraction tank 8 for recycling.
The outlet of the settling tank III 11 is connected with the inlet of the original tank 10, so that the zinc liquid generated by the settling tank III 11 is returned to the reduction tank 10 for recycling.
In the embodiment, the smoke dust generated by chloridizing reduction roasting is firstly collected by the bag type dust collector 1, collected dust collection slag is sent to the slag warehouse 2, and the smoke gas which is not collected by the bag type dust collector 1 enters the leaching tower 3 for washing. The flue gas is washed and fused into a washing liquid, the washing liquid enters a settling tank I4 for settling treatment, a settled solid phase returns to ingredients, clear liquid is sent to a distillation tower 5 for distillation treatment, and hydrochloric acid generated by distillation is returned for chloridizing agent preparation. The concentrated phase liquid generated by distillation enters an oxidation tank 6, an oxidant is added into the oxidation tank 6 for oxidation treatment, the oxidized mixed liquid generated after oxidation enters a sedimentation tank II 7 for sedimentation treatment, the solid phase sedimentation generated by sedimentation is lead dioxide (lead product), and the clear liquid generated by sedimentation is continuously sent to an extraction tank 8. An oxidizing agent is added into the extraction tank 8 for treatment, the produced loaded organic phase enters the stripping tank 9, and the produced extract is sent to the reduction tank 10. And adding a stripping agent into the stripping tank 9 for stripping, returning an organic phase generated by the stripping treatment to the extraction tank 8 for recycling, and obtaining copper sulfate as a product after the stripping treatment. Zinc powder is added into the reduction tank 10 for reduction treatment, the reduction mixed solution generated by the reduction treatment enters the sedimentation tank III 11 for sedimentation treatment, the zinc solution generated by sedimentation returns to the reduction tank 10 for continuous recycling, the solid phase generated by sedimentation is settled into silver-containing gold mud, and the silver recovery is carried out in the chloridizing analysis procedure.
According to the utility model, a smoke comprehensive recovery system is designed according to the characteristics of smoke generated in the process of chloridizing reduction roasting treatment of cyanide-containing tailings, separation of volatile metal elements is realized, pb, zn, cu, au, ag is separated and comprehensively utilized, all metals are recycled in crude products or intermediate products, and the value of the smoke containing chloride salt is fully embodied.
While the utility model has been described in detail in connection with specific and preferred embodiments, it will be understood by those skilled in the art that the utility model is not limited to the foregoing embodiments, but is intended to cover modifications, equivalents, and alternatives falling within the spirit and principles of the utility model.

Claims (3)

1. The utility model provides a comprehensive recycling system of cyanidation tailings chlorination reduction roasting volatilized smoke and dust, includes pocket type dust collector (1) and sediment storehouse (2) and drip washing tower (3) that are connected with it, its characterized in that: the leaching tower (3) is connected with the settling tank I (4), the distillation tower (5), the oxidation tank (6), the settling tank II (7) and the extraction tank (8) in sequence, the outlet of the extraction tank (8) is connected with the inlets of the back extraction tank (9) and the reduction tank (10), and the outlet of the reduction tank (10) is connected with the inlet of the settling tank III (11).
2. The comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust according to claim 1, wherein the comprehensive recycling system is characterized in that: the outlet of the back extraction tank (9) is connected with the inlet of the extraction tank (8), so that the organic phase generated after the back extraction treatment is returned to the extraction tank (8) for recycling.
3. The comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust according to claim 1, wherein the comprehensive recycling system is characterized in that: the outlet of the sedimentation tank III (11) is connected with the inlet of the reduction tank (10), so that the zinc liquid generated by the sedimentation tank III (11) is returned to the reduction tank (10) for recycling.
CN202321996131.0U 2023-07-27 2023-07-27 Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust Active CN220767115U (en)

Priority Applications (1)

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CN202321996131.0U CN220767115U (en) 2023-07-27 2023-07-27 Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321996131.0U CN220767115U (en) 2023-07-27 2023-07-27 Comprehensive recycling system for cyanidation tailings chloridizing reduction roasting volatile smoke dust

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CN220767115U true CN220767115U (en) 2024-04-12

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