CN220610817U - Combined equipment for recovering ultrafine-particle-level rare earth minerals - Google Patents

Combined equipment for recovering ultrafine-particle-level rare earth minerals Download PDF

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CN220610817U
CN220610817U CN202321864293.9U CN202321864293U CN220610817U CN 220610817 U CN220610817 U CN 220610817U CN 202321864293 U CN202321864293 U CN 202321864293U CN 220610817 U CN220610817 U CN 220610817U
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flotation column
rare earth
desulfurization
fine
outlet
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王正华
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Sichuan Hedi Mining Development Co ltd
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Sichuan Hedi Mining Development Co ltd
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Abstract

The utility model discloses combined equipment for recovering ultrafine-particle-grade rare earth minerals, which comprises a concentrator, a concentrating cyclone, a ball mill, an ore pulp buffer box, a desulfurization stirring barrel, a desulfurization flotation column module, a fine-sweeping flotation column, a rare earth stirring barrel, a rare earth flotation column module and a fine-choosing flotation column module, wherein the concentrator is communicated with a first pump pool, the first pump pool is connected with the concentrating cyclone, the concentrating cyclone is connected with the concentrator, the concentrating cyclone is connected with the ball mill, the ball mill is communicated with a second pump pool, the ore pulp buffer box, the desulfurization stirring barrel and the desulfurization flotation column module are sequentially connected, the desulfurization flotation column module is connected with the rare earth stirring barrel, the rare earth stirring barrel is connected with the rare earth flotation column module, the rare earth flotation column module is connected with a third pump pool and the fine-sweeping flotation column module, and the fine-choosing flotation column module are connected with the fine-choosing flotation column module and the second pump pool. Has the advantage of being suitable for the ore dressing and recycling of ultrafine-particle-grade rare earth with the granularity ranging from 0.01 to 0.045 mm.

Description

Combined equipment for recovering ultrafine-particle-level rare earth minerals
Technical Field
The utility model relates to the technical field of rare earth flotation, in particular to a combination device for recovering ultrafine-particle-level rare earth minerals.
Background
The current metallurgical field generally adopts flotation method, gravity separation method, magnetic separation method and the like or the combination thereof to recover ultrafine particle grade minerals, and the main equipment of the flotation recovery process is a traditional flotation machine, a flotation column and the combination thereof, because special material characteristics or the characteristics of complex ores influence the research and development hysteresis condition limitation of novel efficient medicaments exists, the traditional flotation and gravity separation equipment has limited capability of separating and enriching ultrafine particle materials because of the structural characteristics of the traditional flotation and gravity separation equipment, and generally can not directly produce qualified concentrate products only through a single beneficiation means, and also needs to combine other beneficiation processes to produce final concentrate, so that the ultrafine particle grade minerals recovery process generally occupies large area, has more equipment quantity, needs to adopt more complex process flows, has limited recovery rate and has higher production, operation and maintenance costs.
For ultrafine rare earth with the granularity ranging from 0.01 to 0.045mm, the domestic and foreign rare earth industries have no mature beneficiation method or process for realizing ultrafine rare earth mineral recovery and industrial application production, for ultrafine rare earth minerals, the ultrafine rare earth minerals are separated and recovered by utilizing traditional beneficiation equipment, the effective enrichment recovery effect can not be obtained for fine-particle-grade materials by continuously optimizing process technical index modes such as medicament system, and the like.
The traditional rare earth recovery mainly adopts gravity separation, magnetic separation-flotation and magnetic separation-magnetic separation combined processes to realize the enrichment recovery of coarse rare earth and concentrate, while equipment such as a shaking table, a centrifuge and the like adopted in the gravity separation process is suitable for coarse mineral recovery, and traditional flotation machines-flotation columns, high gradient magnetic separators and other traditional mineral separation equipment adopted in the flotation-magnetic process have the limitations on the mineral separation efficiency and the particle size recovery of ultrafine rare earth minerals due to the structural characteristics of the process, and cannot effectively recover ultrafine rare earth minerals with the particle size ranging from 0.01 to 0.045mm, so that the ultrafine rare earth minerals are the technical problem puzzling the domestic and foreign rare earth industry for a long time
Disclosure of Invention
The utility model aims to provide a combination device for recovering ultrafine-particle-level rare earth minerals, which has the advantage of being suitable for mineral dressing recovery of ultrafine-particle-level rare earth with the granularity of 0.01-0.045 mm.
In order to achieve the above purpose, the technical scheme adopted by the utility model is as follows: the utility model provides a combination equipment that super fine particle level rare earth mineral was retrieved, includes concentrator, concentrated swirler, ball mill, ore pulp buffer tank, desulfurization agitator, desulfurization flotation column module, smart sweep flotation column, rare earth agitator, rare earth flotation column module and carefully chosen flotation column module, the concentrated underflow outlet intercommunication of concentrator has first pump basin, first pump basin through first sediment stuff pump with the access connection of concentrated swirler, the overflow outlet of concentrated swirler with the access connection of concentrator, the sediment outlet of concentrated swirler with the access connection of ball mill, the outlet intercommunication of ball mill has the second pump basin, the second pump basin through the second sediment stuff pump with the access connection of ore pulp buffer tank, the outlet of ore pulp buffer tank with the access connection of desulfurization agitator, the outlet of desulfurization agitator with desulfurization column module is connected, the first pump basin through first sediment stuff pump with the access connection of rare earth agitator, the outlet of rare earth flotation column module is connected with rare earth flotation column module, the rare earth flotation column module is connected with third pump basin and sweep sediment stuff pump with the access connection of third pump basin, the second sediment stuff pump is connected with the second pump basin through the access connection of fine flotation column.
Further, the desulfurization flotation column module includes desulfurization roughing flotation column, first desulfurization scavenging flotation column and second desulfurization scavenging flotation column, the export of thresh search desulfurization agitator with the access to desulfurization roughing flotation column, the tailing export of desulfurization roughing flotation column and the access to first desulfurization scavenging flotation column, the tailing export of first desulfurization scavenging flotation column and the access to second desulfurization scavenging flotation column, the tailing export of second desulfurization scavenging flotation column and the access to rare earth agitator, sulfur roughing flotation column, first desulfurization scavenging flotation column and second desulfurization scavenging flotation column all are equipped with sulfur concentrate export, the sulfur concentrate that desulfurization flotation column module produced is through this sulfur concentrate export direct exhaust and is abandoned.
Further, the rare earth flotation column module comprises a rare earth roughing flotation column, a first rare earth scavenging flotation column and a second rare earth scavenging flotation column, wherein an inlet of the rare earth roughing flotation column is connected with an outlet of the rare earth stirring barrel, a tailing outlet of the rare earth roughing flotation column is connected with an inlet of the first rare earth scavenging flotation column, a tailing outlet of the first rare earth scavenging flotation column is connected with an inlet of the second rare earth scavenging flotation column, a tailing outlet of the second rare earth scavenging flotation column is used for directly discharging tailings and discarding, concentrate outlets of the rare earth roughing flotation column, the first rare earth scavenging flotation column and the second rare earth scavenging flotation column are all provided with concentrate outlets, a concentrate outlet of the rare earth roughing flotation column is connected with the concentrating flotation column module, and concentrate outlets of the first rare earth scavenging flotation column and the second rare earth scavenging flotation column are all connected with the third pump pool.
Further, the fine flotation column module comprises a first fine flotation column, a second fine flotation column and a third fine flotation column, wherein the inlet of the first fine flotation column is respectively connected with the concentrate outlet of the rare earth roughing flotation column and the concentrate outlet of the rare earth sweeping flotation column, the concentrate outlet of the first fine flotation column is connected with the wellhead of the second fine flotation column, the concentrate outlet of the second fine flotation column is connected with the inlet of the third fine flotation column, the concentrate discharged from the concentrate outlet of the third fine flotation column is the final output, and the tailing outlets of the first fine flotation column, the second fine flotation column and the third fine flotation column are all connected with the third pump pool.
Compared with the prior art, the utility model has the advantages that: the flotation column adopts a machine column continuous flotation column, is suitable for ore dressing recovery of ultrafine particle grade rare earth with the granularity range of 0.01-0.045 mm, has high flotation efficiency, low installed quantity and lower installation quantity than the traditional equipment, saves investment cost of new and increased ore dressing equipment on the basis of fully utilizing on-site grading concentration equipment, and reduces equipment energy consumption in the process of generating and running.
Drawings
FIG. 1 is a device connection diagram of the present utility model;
fig. 2 is a process flow diagram of the present utility model.
Detailed Description
The present utility model will be further described below.
Examples: as shown in figures 1 and 2, the combined equipment for recycling ultrafine-particle-grade rare earth minerals comprises a concentrator, a concentrating cyclone, a ball mill, an ore pulp buffer tank, a desulfurization stirring barrel, a desulfurization flotation column module, a fine-sweeping flotation column, a rare earth stirring barrel, a rare earth flotation column module and a fine-selection flotation column module, wherein a concentrated underflow outlet of the concentrator is communicated with a first pump pond, the first pump pond is connected with an inlet of the concentrating cyclone through a first slurry pump, an overflow outlet of the concentrating cyclone is connected with an inlet of the concentrator, a sand settling outlet of the concentrating cyclone is connected with an inlet of the ball mill, an outlet of the ball mill is communicated with a second pump pond, the second pump pond is connected with an inlet of the ore pulp buffer tank through a second slurry pump, an outlet of the ore pulp buffer tank is connected with an inlet of the desulfurization stirring barrel, an outlet of the desulfurization stirring barrel is connected with the desulfurization column module, an outlet of the rare earth stirring barrel is connected with an inlet of the rare earth flotation column module, an outlet of the rare earth stirring barrel is connected with a third pump pond is connected with an inlet of the fine-sweeping flotation column module, and a third pump pond is connected with an outlet of the fine-selection column module, and the fine-selection column module is connected with an inlet of the fine-sweeping column module.
Specifically, the desulfurization flotation column module includes desulfurization roughing flotation column, first desulfurization scavenging flotation column and second desulfurization scavenging flotation column, the export of thresh search desulfurization agitator with the access to desulfurization roughing flotation column, the tailing export of desulfurization roughing flotation column and the access to first desulfurization scavenging flotation column, the tailing export of first desulfurization scavenging flotation column and the access to second desulfurization scavenging flotation column, the tailing export of second desulfurization scavenging flotation column and the access to rare earth agitator, sulfur roughing flotation column, first desulfurization scavenging flotation column and second desulfurization scavenging flotation column all are equipped with sulfur concentrate export, the sulfur concentrate that desulfurization flotation column module produced is through this sulfur concentrate export direct exhaust and is abandoned.
Specifically, the rare earth flotation column module includes rare earth roughing flotation column, first rare earth scavenging flotation column and second rare earth scavenging flotation column, the import of rare earth roughing flotation column with the exit linkage of rare earth agitator, the tailing export of rare earth roughing flotation column with the access linkage of first rare earth scavenging flotation column, the tailing export of first rare earth scavenging flotation column with the access linkage of second rare earth scavenging flotation column, the tailing export of second rare earth scavenging flotation column is abandoned the tailing direct tail, rare earth roughing flotation column, first rare earth scavenging flotation column and second rare earth scavenging flotation column all are equipped with concentrate export, wherein the concentrate export of rare earth roughing flotation column with the exit linkage of carefully selecting flotation column module, the concentrate export of first rare earth scavenging flotation column and second rare earth scavenging flotation column all with the third pump pond is connected.
Specifically, the carefully chosen flotation column module includes, first carefully chosen flotation column, second carefully chosen flotation column and third carefully chosen flotation column, the import of first carefully chosen flotation column respectively with the concentrate export of rare earth rougher flotation column and the concentrate export of rare earth finely sweep flotation column, the concentrate export of first carefully chosen flotation column with the well head of second carefully chosen flotation column is connected, the concentrate export of second carefully chosen flotation column and the import connection of third carefully chosen flotation column, the concentrate that the concentrate export of third carefully chosen flotation column was discharged is final output, the tailing export of first carefully chosen flotation column, second carefully chosen flotation column and third carefully chosen flotation column all with the third pump pond is connected.
Working principle:
the flotation column adopts a machine column continuous flotation column, can realize combined cascade intensified flotation, and aims at the defects of a flotation machine and a flotation column, a countercurrent mineralization area is arranged at the lower part of an impact stirring type flotation machine, so that a mineral discharge port of the flotation machine is far away from a strong turbulence area, the problems of ore pulp short circuit and trough phenomenon of the traditional flotation machine and low mineralization intensity of the flotation column are overcome, cascade intensified flotation is realized, and on the basis of supporting an ultra-fine particle flotation process flow, the ultra-fine particle rare earth mineral recovery application problem is solved by matching with a high-efficiency rare earth collector, and the ultra-fine particle rare earth mineral is effectively recovered and qualified rare earth concentrate products are directly produced by only using a single flotation means.
The thickener is 500m 2 Inclined plate thickener, considering that the initial concentration of the selected material is about 5-10% lower, the pulp flow and fluctuation range are larger, and 500m is utilized 2 The inclined plate thickener and the concentration cyclone form a two-stage classification loop to realize concentration classification of ultrafine rare earth materials with low concentration (5-10%), thereby playing roles in buffering pulp flow fluctuation and pre-concentration, the large-volume storage bin of the inclined plate thickener plays roles in buffering pulp, and the expansion application effect of the inclined plate reaches 500m 2 By applying the shallow layer sedimentation principle, the sedimentation time of fine-grained materials is shortened, the production continuity requirement of downstream recovery operation is met, the rapid sedimentation and concentration of the materials are realized, and the sedimentation time is 500m 2 The inclined plate concentrator can raise the concentration of material from 5-10% to 10-15%, and the specific concentration process is that the mixed ore pulp (concentration 5-10%) formed by overflow in the externally poured low-two-tail and large-intensity magnetic tailings and concentrating cyclone directly enters 500m 2 The inclined plate thickener is concentrated rapidly in one stage, overflow of the thickener is discharged to enter a water return tank for return water, tailings of an underflow outlet (concentration 10-15%) mixed fine-sweeping flotation column of the thickener are pumped into a concentration cyclone by a first slurry pump, and overflow of the concentration cyclone returns to 500m 2 The inclined plate thickener is formed into a concentrating closed circuit, the sand setting concentration of the concentrating cyclone reaches 30-35%, and the concentration requirement of the subsequent ultra-fine particle grade rare earth flotation technology on the selected materials is met.
500m 2 Inclined plate thickenerThe application of (2) provides a proper graded concentration stable flow and feed concentration for the concentrate cyclone, the concentrate cyclone separation particle size and graded concentration are mainly dependent on the concentrate cyclone diameter and feed concentration, the smaller the diameter, the smaller the separation particle size. The phi 100 or phi 75 cyclone is selected, the concentration requirement can be met under the condition of proper ore feeding pressure and feeding concentration, and the ultra-fine rare earth flotation process has good recovery effect on the fine ore with the granularity below 800 meshes, so that the property requirement on the feeding material is full-size flotation recovery, namely, the prior desliming is not needed, the 325 meshes of the feeding material account for 80 percent, and the process property has no clear requirement on the separation granularity of the concentration cyclone, so that the concentration cyclone only plays a role in concentration, has no strict requirement on the granularity separation effect, and the overflow closed loop of the concentration cyclone returns 500m 2 The inclined plate thickener overflows normally to clear backwater and returns to other processes.
The concentration of the settled sand through the concentration cyclone reaches 30-35%, the main purpose of the ball mill is to break the flocculation and the package state of the micro-particle materials, so that the micro-particle materials and the acting surface of the medicament are displayed, the flotation recovery of the downstream flotation process is facilitated, and the economic control and the on-site production condition are considered.
Before desulfurization, an ore pulp buffer box and a desulfurization stirring barrel are adopted to realize the functions of steady flow and uniform stirring and mixing of fed materials, desulfurization agents mainly comprise common sodium butyl xanthate and foaming agent sec-octyl alcohol, sulfur concentrate produced by desulfurization operation is combined through a pipeline and directly discharged to the tail, the ore pulp after desulfurization automatically flows into a rare earth stirring barrel to realize the mixing of the materials and the agents, the agents adopted by the rare earth flotation operation mainly comprise regulator sodium silicate, sodium hydroxide and collector 506-C6, and the foaming agent sec-octyl alcohol is subjected to three-time concentration to obtain rare earth concentrate which is used as a final concentrate to be pumped into dehydration operation.
In the aspects of medicament cost and environmental protection emission, because the low two-tail medicament-containing return recleaning and the improvement of the backwater utilization rate, the machine column continuous separation equipment realizes production and application in an ultra-fine rare earth flotation process, the consumption of an operation collector, a regulator and the like is reduced, the actual annual consumption of the collector is reduced by about 10%, the consumption of water glass is reduced by 12%, and in the aspect of environmental protection, the recovery of the low two-tail medicament-carrying return reduces the emission of harmful substances by 10% each year, the water glass is reduced by about 12%, and the dry ore storage amount of a tailing pond is reduced by 30% each year.
The principles and embodiments of the present utility model have been described herein with reference to specific examples, the description of which is intended only to assist in understanding the methods of the present utility model and the core ideas thereof; also, it will be apparent to those skilled in the art from this disclosure that various changes and modifications can be made herein without departing from the spirit and scope of the utility model as defined by the appended claims.

Claims (4)

1. The utility model provides a combination equipment that ultra-fine particle level rare earth mineral was retrieved which characterized in that: including concentrator, concentrated swirler, ball mill, ore pulp buffer tank, desulfurization agitator, desulfurization flotation column module, smart the flotation column of sweeping, rare earth agitator, rare earth flotation column module and carefully chosen flotation column module, the concentrated underflow outlet intercommunication of concentrator has first pump pond, first pump pond through first sediment thick liquid pump with the access to concentrated swirler, concentrated swirler overflow outlet with the access to concentrator, concentrated swirler the sand setting export with the access to ball mill, the exit intercommunication of ball mill has the second pump pond, the second pump pond through the second sediment thick liquid pump with the access to ore pulp buffer tank, the export of ore pulp buffer tank with the access to desulfurization agitator, the export of desulfurization agitator with desulfurization flotation column module is connected, desulfurization column module with the access to rare earth agitator, the export of rare earth agitator with rare earth flotation column module is connected, rare earth flotation column module is connected with third pump pond and carefully chosen flotation column module, the third sediment of sweeping sweep the clean sediment thick liquid pump with the access to ore pulp buffer tank, ore pulp buffer tank is connected with the flotation column module.
2. The combination apparatus for ultra-fine grade rare earth mineral recovery of claim 1, wherein: the desulfurization flotation column module comprises a desulfurization rougher flotation column, a first desulfurization scavenger flotation column and a second desulfurization scavenger flotation column, the outlet of the desulfurization stirring barrel is connected with the inlet of the desulfurization rougher flotation column, the tailing outlet of the desulfurization rougher flotation column is connected with the inlet of the first desulfurization scavenger flotation column, the tailing outlet of the first desulfurization scavenger flotation column is connected with the inlet of the second desulfurization scavenger flotation column, the tailing outlet of the second desulfurization scavenger flotation column is connected with the inlet of the rare earth stirring barrel, the sulfur rougher flotation column, the first desulfurization scavenger flotation column and the second desulfurization scavenger flotation column are all provided with sulfur concentrate outlets, and sulfur concentrate generated by the desulfurization flotation column module is directly discharged and discarded through the sulfur concentrate outlets.
3. The combination apparatus for ultra-fine grade rare earth mineral recovery of claim 1, wherein: the rare earth flotation column module comprises a rare earth rougher flotation column, a first rare earth scavenger flotation column and a second rare earth scavenger flotation column, wherein an inlet of the rare earth rougher flotation column is connected with an outlet of the rare earth stirring barrel, a tailing outlet of the rare earth rougher flotation column is connected with an inlet of the first rare earth scavenger flotation column, a tailing outlet of the first rare earth scavenger flotation column is connected with an inlet of the second rare earth scavenger flotation column, a tailing outlet of the second rare earth scavenger flotation column is used for directly discharging tailings and discarding the tailings, and concentrate outlets are arranged on the rare earth rougher flotation column, the first rare earth scavenger flotation column and the second rare earth scavenger flotation column, a concentrate outlet of the rare earth rougher flotation column is connected with the concentrating flotation column module, and concentrate outlets of the first rare earth scavenger flotation column and the second rare earth scavenger flotation column are connected with the third pump pool.
4. A combination apparatus for ultra-fine grade rare earth mineral recovery as claimed in claim 3, wherein: the fine flotation column module comprises a first fine flotation column, a second fine flotation column and a third fine flotation column, wherein the inlet of the first fine flotation column is respectively connected with the concentrate outlet of the rare earth roughing flotation column and the concentrate outlet of the rare earth scavenging flotation column, the concentrate outlet of the first fine flotation column is connected with the wellhead of the second fine flotation column, the concentrate outlet of the second fine flotation column is connected with the inlet of the third fine flotation column, the concentrate discharged from the concentrate outlet of the third fine flotation column is the final output, and the tailing outlets of the first fine flotation column, the second fine flotation column and the third fine flotation column are all connected with the third pump pool.
CN202321864293.9U 2023-07-14 2023-07-14 Combined equipment for recovering ultrafine-particle-level rare earth minerals Active CN220610817U (en)

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Application Number Priority Date Filing Date Title
CN202321864293.9U CN220610817U (en) 2023-07-14 2023-07-14 Combined equipment for recovering ultrafine-particle-level rare earth minerals

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321864293.9U CN220610817U (en) 2023-07-14 2023-07-14 Combined equipment for recovering ultrafine-particle-level rare earth minerals

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Publication Number Publication Date
CN220610817U true CN220610817U (en) 2024-03-19

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CN202321864293.9U Active CN220610817U (en) 2023-07-14 2023-07-14 Combined equipment for recovering ultrafine-particle-level rare earth minerals

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