CN220277259U - Acid mist environment-friendly absorption device for cobalt production - Google Patents

Acid mist environment-friendly absorption device for cobalt production Download PDF

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Publication number
CN220277259U
CN220277259U CN202321795741.4U CN202321795741U CN220277259U CN 220277259 U CN220277259 U CN 220277259U CN 202321795741 U CN202321795741 U CN 202321795741U CN 220277259 U CN220277259 U CN 220277259U
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acid mist
electrode tube
assembly
waste gas
control module
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CN202321795741.4U
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卢相军
邓昌奋
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Kelixin Zhuhai New Energy Co ltd
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Kelixin Zhuhai New Energy Co ltd
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Abstract

The utility model relates to an acid mist environment-friendly absorption device for cobalt production, which belongs to the technical field of waste gas treatment and comprises a waste gas collection assembly, an electrostatic absorption assembly, an absorption assembly, a spray tower and a waste gas emission assembly which are sequentially connected, wherein the waste gas collection assembly is connected with cobalt production equipment, the waste gas emission assembly is communicated with the atmosphere, the absorption assembly is an activated carbon absorption layer, the electrostatic absorption assembly comprises a shell, a control module, a positive electrode tube and a negative electrode tube, the input end and the output end of the shell are respectively connected with the waste gas collection assembly and the absorption assembly, the positive electrode tube and the negative electrode tube are arranged in the shell, the control module is electrically connected with the positive electrode tube and the negative electrode tube to form a circuit, and the control module is used for introducing high-voltage direct current to the two electrode tubes; the acid mist absorption effect is good.

Description

Acid mist environment-friendly absorption device for cobalt production
Technical Field
The utility model belongs to the technical field of waste gas treatment, and particularly relates to an acid mist environment-friendly absorption device for cobalt production.
Background
Cobalt is a metal which can be used for manufacturing alloys, permanent magnets, precise alloys, electricity storage materials and the like, waste gas is generated in the production process of cobalt, and the waste gas contains acid mist mainly formed by mixing sulfuric acid, phosphoric acid, nitric acid, nitrous acid and water, and the acid mist is directly discharged without absorption to pollute the environment.
To this end, a general solution, such as an acid mist absorbing device for swinging cobalt production disclosed in chinese patent CN206965448U, includes a frame, a support plate is provided at the bottom of the frame, a circulating water tank is provided at the top surface of the support plate, a fixed water outlet pipe is provided at the top center of the circulating water tank, the fixed water outlet pipe penetrates through the frame and extends to the center of the inner side of the bottom of the absorbing tower, the absorbing tower is provided on the top surface of the frame, an exhaust gas input pipe is provided at the bottom side of the absorbing tower, a gas output pipe is provided at the top of the absorbing tower, a spray packing layer is symmetrically provided on the inner side wall of the absorbing tower, and the spray packing layer is located above the gas output pipe, an adsorption layer is provided above the spray packing layer, and a mist removing layer is provided above the adsorption layer, which has a strong acid mist absorbing effect on absorbing exhaust gas; however, the above proposal only uses adsorption and spraying method to absorb acid mist, and has limited effect on acid mist absorption, therefore, an acid mist with good acid mist absorption effect, an acid mist environment-friendly absorption device for cobalt production, is needed.
Disclosure of Invention
In order to solve the problems in the prior art, the utility model provides an environment-friendly treatment device for waste gas and dust of cobaltosic oxide, which has the characteristic of good acid mist absorption effect.
The aim of the utility model can be achieved by the following technical scheme:
the utility model provides an acid mist environmental protection absorbing device for cobalt production, includes waste gas collection subassembly, static absorption subassembly, adsorption subassembly, spray column and the exhaust emission subassembly that connects gradually, waste gas collection subassembly is connected with cobalt production facility, exhaust emission subassembly and atmosphere intercommunication, adsorption subassembly is active carbon adsorption layer.
As a preferred technical scheme of the utility model, the electrostatic absorption assembly comprises a shell, a control module, a positive electrode tube and a negative electrode tube, wherein the input end and the output end of the shell are respectively connected with the waste gas collecting assembly and the adsorption assembly, the positive electrode tube and the negative electrode tube are arranged in the shell, the control module is electrically connected with the positive electrode tube and the negative electrode tube and forms a circuit, and the control module is used for supplying high-voltage direct current to the two electrode tubes.
As a preferable technical scheme of the utility model, the air outlet end of the electrostatic absorption assembly is provided with an acid mist detector, the acid mist detector is electrically connected with a control module, the acid mist detector is used for detecting acid mist at the output end and uploading acid mist concentration data to the control module, and the control module changes the voltage between the positive electrode tube and the negative electrode tube according to the acid mist concentration data
As a preferable technical scheme of the utility model, a spray head is arranged at the inner top of the shell of the electrostatic absorption component.
As a preferable aspect of the present utility model, the positive electrode tube and the negative electrode tube are each composed of carbon fibers.
As a preferable technical scheme of the utility model, the spray tower comprises a cylinder body, a spray assembly and a neutralization liquid tank, wherein the air inlet end of the spray tower is arranged at the lower part of the cylinder body, the air outlet end of the spray tower is arranged at the upper part of the cylinder body, the spray assembly is arranged at the top part in the cylinder body, the neutralization liquid tank is filled with alkaline neutralization liquid, and the spray assembly is connected with the neutralization liquid tank and is used for spraying the neutralization liquid into the cylinder body.
The beneficial effects of the utility model are as follows:
(1) Through setting up static absorbing assembly in the upper reaches of spray column, can make whole absorbing device absorb more acid mist, improved the absorption effect.
(2) Through setting up the adsorption component, when can strengthen the absorption to the acid mist, prevent that electrified acid mist granule from getting into the adsorption tower, strengthened the absorption effect.
Drawings
The present utility model is further described below with reference to the accompanying drawings for the convenience of understanding by those skilled in the art.
FIG. 1 is a schematic diagram of the structure of the present utility model;
FIG. 2 is a schematic cross-sectional view of an electrostatic absorption assembly according to the present utility model;
FIG. 3 is a schematic diagram of a control loop of the control module of the present utility model.
Description of main reference numerals:
in the figure: 1. an exhaust gas collection assembly; 2. an electrostatic absorption assembly; 21. a housing; 22. a control module; 23. a positive electrode tube; 24. a negative electrode tube; 25. an acid mist detector; 26. a settling tank; 3. an adsorption assembly; 4. a spray tower; 5. an exhaust emission assembly.
Detailed Description
In order to further describe the technical means and effects adopted by the utility model for achieving the preset aim, the following detailed description is given below of the specific implementation, structure, characteristics and effects according to the utility model with reference to the attached drawings and the preferred embodiment.
Referring to fig. 1-3, an acid mist environment-friendly absorbing device for cobalt production comprises an exhaust gas collecting component 1 and an exhaust gas discharging component 5, wherein one end of the exhaust gas collecting component 1 is connected with cobalt production equipment, one end of the exhaust gas discharging component 5 is communicated with the atmosphere, meanwhile, as the exhaust gas can be generated in the cobalt production process, the exhaust gas contains acid mist mainly comprising sulfuric acid, phosphoric acid, nitric acid, nitrous acid and water, and the acid mist can pollute the environment after being directly discharged without absorption, the acid mist environment-friendly absorbing device further comprises a spray tower 4, the spray tower 4 comprises a barrel, a spray component and a neutralization liquid tank, the gas inlet end of the spray tower 4 is arranged at the lower part of the barrel, the gas outlet end of the spray tower 4 is arranged at the upper part of the barrel, the spray component is arranged at the inner top of the barrel, the spray component is connected with the neutralization liquid tank and used for spraying the neutralization liquid into the barrel, when in use, the waste gas containing acid mist discharged from cobalt production equipment flows into the cylinder from the lower end of the spray tower 4 and continuously moves to the air outlet end above the cylinder, meanwhile, the spray component positioned at the upper part of the cylinder continuously extracts the neutralization liquid in the neutralization liquid tank and sprays the neutralization liquid to the space below the cylinder in an atomizing way, the neutralization liquid continuously moves downwards, and the neutralization liquid and the waste gas flow direction are opposite to each other and can be fully contacted with each other, in the embodiment, the neutralization liquid at least comprises distilled water, in the contact process, the acid mist formed by mixing sulfuric acid, phosphoric acid and other substances in the waste gas and water is dissolved in the neutralization liquid comprising distilled water, and falls into the bottom of the cylinder along with the downward movement of the neutralization liquid, the residual waste gas is continuously conveyed upwards to the air outlet end, the dissolution and separation of the acid mist from the gas by using the liquid are completed through the arrangement of the spray tower 4, the acid mist is prevented from being discharged into the atmosphere, and (5) carrying out environment-friendly treatment on the acid mist waste gas.
Preferably, because the absorption efficiency of common distilled water to acid mist is lower, in order to improve the absorption efficiency of neutralization liquid in spray tower 4 to acid mist in waste gas in the above-mentioned process, the neutralization liquid tank is filled with alkaline neutralization liquid, when the alkaline neutralization liquid is sprayed onto tail gas with acid mist, part of acid mist is dissolved in the neutralization liquid, when the alkaline in the neutralization liquid is neutralized by acid mist, part of acid mist is continuously dissolved in water until the upper limit of dissolution, compared with common distilled water, the alkaline neutralization liquid in unit volume can absorb more acid mist, the spray tower 4 is improved, only spray tower 4 which actually plays the role of acid mist absorption in the above-mentioned process, the absorption means is single, and in order to further improve the absorption effect to acid mist, the utility model further comprises an electrostatic absorption component 3, the gas inlet end and the gas outlet end of the electrostatic absorption component 2 are respectively connected with waste gas collection component 1 and spray tower 4, the electrostatic absorption assembly 2 comprises a shell 21, a control module 22, a positive electrode tube 23 and a negative electrode tube 24, wherein the input end and the output end of the shell 21 are respectively connected with the waste gas collection assembly 1 and the adsorption assembly 3, the positive electrode tube 23 and the negative electrode tube 24 are arranged in the shell 21, the control module 22 is electrically connected with the positive electrode tube 23 and the negative electrode tube 24 and forms a circuit, the control module 22 is used for supplying high-voltage direct current to the two electrode tubes, in the embodiment, the control module 22 at least comprises a control circuit, an alternating current-direct current converter and a transformer, the converter is started under the control of the control module 22 and supplies alternating current to the transformer after rectification and filtration, the transformer supplies the direct current to the positive electrode tube 23 and the negative electrode tube 24 after boosting the direct current, and then a high-voltage electrostatic field is formed between the positive electrode tube 23 and the negative electrode tube 24, in this embodiment, the two electrode tubes are respectively disposed at two sides of the air flowing space in the housing 21, and the axial directions of the two electrode tubes are perpendicular to the ground, at this time, the electrostatic field coincides with the air flowing space, when the waste gas of the cobalt production device flows into the housing 21 of the electrostatic absorption assembly 2 from the waste gas collecting assembly 1, the waste gas passes through the electrostatic field between the two electrode tubes, at this time, the negative electrode tube 24 continuously emits electrons, the gas passing through the electrode tubes is ionized into dust and acid mist particles in the positive and negative ion waste gas, and the dust and acid mist particles in the waste gas are charged together, because the electric field has adsorption or repulsion effect on charged objects, the dust and acid mist particles continuously move to the positive electrode tube 23 or the negative electrode tube 24 until the acid mist particles adsorbed on one of the electrode tubes lose charges, then flow down along the wall of the electrode tube perpendicular to the ground, and the residual gas continues to the air outlet end of the housing 21 without being affected by the electric field, thereby completing the separation of the acid mist or dust and the rest of the waste gas, and the electrostatic absorption assembly 2 is disposed at the upstream of the spray tower 4, so that the whole absorption device absorbs more acid mist and improves the absorption effect.
Because above-mentioned static absorbing device mainly relies on adsorbing charged acid mist particle to the electrode pipe in the absorption process of acid mist, the acid mist particle has probability and can't leave along the pipe wall and stay on the pipe wall after adsorbing, can have more acid mist particle to adhere to on the electrode pipe after long-term absorption, cause corrosive damage to the electrode pipe, in order to avoid the emergence of this kind of circumstances, static absorbing component 2 casing 21 top is equipped with the shower nozzle, in this embodiment, the shower nozzle is connected with arbitrary pure water source, the shower nozzle sets up in two electrode pipes top simultaneously, spray water to the electrode pipe wall of below on, spray water is along electrode pipe downwardly flowing down along with the attached acid mist on the pipe wall, avoided the long-term influence to the electrode pipe on the electrode pipe of acid mist adhesion.
In the process of absorbing the structure, although the spray head is used for cleaning the electrode tube, the short-time adhesion of the acid mist to the tube wall still can lead to the corrosion of the electrode tube, and in order to further reduce the occurrence of the situations, the positive electrode tube 23 and the negative electrode tube 24 are both composed of carbon fibers, so that compared with a metal material electrode, the acid mist is more difficult to corrode the carbon fibers, and the influence of the acid mist on the electrode tube is further reduced.
In the absorption process of the electrostatic absorption assembly 2, when the voltage of the electrostatic field is too large, oxygen in the tail gas generates ozone with the probability of being directly discharged under the action of a high-voltage electric field, pollution can be caused to the air, when the voltage is too small, enough electrons cannot be generated to ionize acid mist, absorption efficiency is insufficient, in order to ensure absorption efficiency and avoid generating new pollutants, an acid mist detector 25 is arranged at an air outlet end of the electrostatic absorption assembly 2, the acid mist detector 25 is electrically connected with a control module 22, the acid mist detector 25 is used for detecting acid mist at an output end and uploading acid mist concentration data to the control module 22, in the embodiment, after the control module 22 receives the acid mist concentration data, the control module is compared with the concentration threshold, the control module 22 indicates that the current adsorption capacity to acid mist particles is insufficient when the comparison result shows that the acid mist concentration is higher than the concentration upper concentration threshold, the control module 22 instructs a transformer to enable the voltage output by the transformer to be higher, a stronger electrostatic field is manufactured, when the comparison result shows that the concentration is lower than the concentration of the acid mist, the comparison result indicates that the required concentration is lower than the concentration, the control module is required to be manufactured, the ozone concentration is prevented from being changed by the control module, and the ozone concentration is required to be changed according to the comparison result, and the concentration of the comparison result is guaranteed.
After the acid liquor flows downwards along the pipe wall and leaves the electrode pipe, the liquid containing acid mist is deposited at the position near the electrode pipe at the bottom of the shell 21, and flows to other positions with probability, for carrying out centralized treatment on the flowing acid mist liquid, the sedimentation tank 26 is arranged at the bottom of the shell 21 around the positive electrode pipe 23 and the negative electrode pipe 24, in the embodiment, the sedimentation tank 26 is annular, the inner wall of the sedimentation tank is tightly attached to the electrode pipe, when the acid mist liquid flows downwards and leaves the electrode pipe, the acid mist liquid directly flows into the inner ring surface of the annular sedimentation tank 26 and is deposited at the bottom of the sedimentation tank 26, and the centralized treatment on the flowing acid mist liquid is completed.
Preferably, the inner wall of the settling tank 26 is subjected to passivation treatment, in this embodiment, the inner wall of the settling tank 26 is coated with an inert material layer, and when the acid mist-containing liquid is deposited in the settling tank 26, the inert material prevents the erosion of the housing 21 by the acid mist
In order to further improve the absorption effect of the absorption device on acid mist, simultaneously, because the two electrode pipes have probability that all charged acid mist cannot be absorbed to the electrode pipes through electrostatic field particles, the charged acid mist has probability that acid liquor with stronger acidity is generated after being combined with water in the spray tower 4, the probability of corrosiveness caused to the spray tower 4 is higher, the absorption component 3 is arranged between the electrostatic absorption component 2 and the spray tower 4, the absorption component 3 is an active carbon absorption layer, after the waste gas passes through the electrostatic absorption component 2, the acid mist which is not absorbed and the charged particles are absorbed by active carbon, the absorption of the acid mist can be enhanced, the charged acid mist particles are prevented from entering the absorption tower, and the absorption effect is enhanced.
The working principle and the using flow of the utility model are as follows:
when the waste gas of the cobalt production equipment flows into the shell 21 of the electrostatic absorption assembly 2 from the waste gas collection assembly 1, the waste gas passes through the electrostatic field between the two electrode pipes, at the moment, the negative electrode pipe 24 continuously emits electrons, the gas passing through the electrode pipes is ionized into dust and acid mist particles in the waste gas with positive and negative ions, the dust and the acid mist particles after being charged are continuously moved to the positive electrode pipe 23 or the negative electrode pipe 24 until being adsorbed on one of the electrode pipes, the acid mist particles adsorbed on the electrode pipe lose charges, then flow down along the pipe wall of the electrode pipe vertical to the ground, and the residual gas is continuously moved to the air outlet end of the shell 21 without being influenced by the electric field, so that the separation of the acid mist or the dust and the rest of the waste gas is completed;
when the exhaust gas passes through the electrostatic absorption component 2, the unabsorbed acid mist and the charged particles are absorbed by the activated carbon;
then, the waste gas flows into the cylinder from the lower end of the spray tower 4 and continuously moves to the air outlet end above the cylinder, and meanwhile, the spray assembly at the upper part of the cylinder continuously extracts the neutralization liquid in the neutralization liquid tank and sprays the neutralization liquid into the space below the cylinder in an atomization way, and the neutralization liquid continuously moves downwards.
The present utility model is not limited to the above embodiments, but is capable of modification and variation in detail, and other modifications and variations can be made by those skilled in the art without departing from the scope of the present utility model.

Claims (6)

1. An acid mist environment-friendly absorption device for cobalt production, which is characterized in that: including waste gas collection subassembly, electrostatic absorption subassembly, adsorption subassembly, spray column and the exhaust emission subassembly that connects gradually, waste gas collection subassembly is connected with cobalt production facility, exhaust emission subassembly and atmosphere intercommunication, adsorption subassembly is active carbon adsorption layer.
2. The acid mist environment-friendly absorption device for cobalt production according to claim 1, wherein: the static absorbing assembly comprises a shell, a control module, a positive electrode tube and a negative electrode tube, wherein the input end and the output end of the shell are respectively connected with the waste gas collecting assembly and the adsorption assembly, the positive electrode tube and the negative electrode tube are arranged in the shell, the control module is electrically connected with the positive electrode tube and the negative electrode tube and forms a circuit, and the control module is used for supplying high-voltage direct current to the two electrode tubes.
3. The acid mist environment-friendly absorption device for cobalt production according to claim 1, wherein: the acid mist detector is electrically connected with the control module, and is used for detecting acid mist at the output end and uploading acid mist concentration data to the control module, and the control module changes the voltage between the positive electrode tube and the negative electrode tube according to the acid mist concentration data.
4. The acid mist environment-friendly absorption device for cobalt production according to claim 1, wherein: the top in the static electricity absorbing assembly shell is provided with a spray head.
5. The acid mist environment-friendly absorption device for cobalt production according to claim 2, wherein: the positive electrode tube and the negative electrode tube are each composed of carbon fibers.
6. The acid mist environment-friendly absorption device for cobalt production according to claim 1, wherein: the spray tower comprises a barrel, a spray assembly and a neutralization liquid tank, wherein the air inlet end of the spray tower is arranged at the lower part of the barrel, the air outlet end of the spray tower is arranged at the upper part of the barrel, the spray assembly is arranged at the inner top of the barrel, the neutralization liquid tank is filled with alkaline neutralization liquid, and the spray assembly is connected with the neutralization liquid tank and is used for spraying the neutralization liquid into the barrel.
CN202321795741.4U 2023-07-10 2023-07-10 Acid mist environment-friendly absorption device for cobalt production Active CN220277259U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202321795741.4U CN220277259U (en) 2023-07-10 2023-07-10 Acid mist environment-friendly absorption device for cobalt production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321795741.4U CN220277259U (en) 2023-07-10 2023-07-10 Acid mist environment-friendly absorption device for cobalt production

Publications (1)

Publication Number Publication Date
CN220277259U true CN220277259U (en) 2024-01-02

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Application Number Title Priority Date Filing Date
CN202321795741.4U Active CN220277259U (en) 2023-07-10 2023-07-10 Acid mist environment-friendly absorption device for cobalt production

Country Status (1)

Country Link
CN (1) CN220277259U (en)

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