CN219811533U - Lithium ion battery capable of increasing inner reserved space and preventing explosion by pressure - Google Patents

Lithium ion battery capable of increasing inner reserved space and preventing explosion by pressure Download PDF

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Publication number
CN219811533U
CN219811533U CN202321079213.9U CN202321079213U CN219811533U CN 219811533 U CN219811533 U CN 219811533U CN 202321079213 U CN202321079213 U CN 202321079213U CN 219811533 U CN219811533 U CN 219811533U
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diaphragm
lithium ion
ion battery
explosion
width
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CN202321079213.9U
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Chinese (zh)
Inventor
师贵荣
杨凯鑫
肖利隆
吴银华
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Shenzhen Honcell Energy Co ltd
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Shenzhen Honcell Energy Co ltd
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Abstract

The utility model discloses a lithium ion battery capable of increasing an inner reserved space and preventing explosion by pressure, which comprises a battery cell body and an aluminum plastic film shell, wherein the battery cell body is packaged in the aluminum plastic film shell, the battery cell body comprises a positive plate, a negative plate and a diaphragm, an inner reserved space is formed between the battery cell body and the aluminum plastic film shell, the width of the inner reserved space is the width of a female die, the height of the inner reserved space is the height of the female die of the aluminum plastic film, the height of the female die is equal to +0.2mm, and the width of the female die is equal to +0.2mm. The lithium ion battery provided by the utility model has the characteristics of providing a discharge channel for gas or liquid generated by internal reaction, preventing battery explosion, improving displacement, being good in quality stability and convenient to process.

Description

Lithium ion battery capable of increasing inner reserved space and preventing explosion by pressure
Technical Field
The utility model relates to the technical field of lithium ion batteries, in particular to a lithium ion battery capable of increasing an inner reserved space and preventing explosion.
Background
Energy-saving and new energy automobiles such as hybrid electric vehicles, pure electric vehicles, fuel cell vehicles and the like become a better development path. However, the rapid development of new energy automobiles is greatly limited by safety and reliability, service life, driving range, cost, public supporting facilities and the like, and the technical breakthrough and large-scale application of power batteries are particularly critical. However, in the process of process design and manufacturing of the conventional lithium battery, the height of a die of an aluminum plastic shell which is generally designed is consistent with the width of a diaphragm of a battery core body, and a reserved space in the die is not designed to serve as a gas or liquid discharge channel, so that the aluminum plastic shell is just attached to a winding core, and the winding core can be prevented from shifting. However, because the assembled aluminum-plastic shell is fully attached to the battery cell body in height, the R angle is added at the tail part to fix the battery cell body, so that the top and the bottom of the battery are in a closed state, and gas generated after the manufacturing procedures of liquid injection, formation and the like cannot be smoothly discharged to the air bag, so that the battery tab glue is easily flushed and exploded under the action of formation air pressure, the abnormal problems of poor appearance, liquid leakage and the like of the battery are caused, and the production efficiency of the lithium ion battery is influenced; in addition, because a certain gap is not provided for the residual electrolyte to provide a circulation channel, the liquid cannot be smoothly discharged to the external environment in the working procedures of two-seal air extraction and the like, and the electrolyte remained in the battery is extremely easy to generate side effects in the later use of the battery, so that the battery has poor appearance, gas expansion, influences on various performances, safety problems, yield reduction and the like of the battery, such as the cycle life and the like.
Disclosure of Invention
The utility model aims to provide a lithium ion battery capable of increasing the inner reserved space to prevent explosion, and the lithium ion battery has the characteristics of good explosion-proof effect, good displacement-proof effect, high quality stability and convenient processing.
The utility model can be realized by the following technical scheme:
the utility model discloses a battery cell body and an aluminum plastic film shell, wherein the battery cell body is packaged in the aluminum plastic film shell, the battery cell body comprises a positive plate, a negative plate and a diaphragm, an inner reserved space is formed between the battery cell body and the aluminum plastic film shell, the width of the inner reserved space is the width of a female die, the height of the inner reserved space is the height of the female die of the aluminum plastic film, the height of the female die is equal to +0.2mm of the height of the diaphragm, and the width of the female die is equal to +0.2mm of the width of the diaphragm.
Further, the positive plate, the negative plate and the diaphragm are mutually wound or laminated at intervals, and the diaphragm is arranged between the positive plate and the negative plate.
Further, the negative electrode sheet width is greater than the positive electrode sheet width, and the separator width is greater than the negative electrode sheet width.
Further, the positive active material of the positive plate is lithium manganate, lithium iron phosphate, ternary nickel cobalt lithium manganate and/or lithium cobaltate.
Further, the negative electrode active material of the negative electrode plate is natural graphite, artificial graphite or mesophase carbon microsphere.
Further, the diaphragm body is a PE diaphragm, a PP diaphragm or a PE/PP composite diaphragm.
Further, the current collector of the positive plate is aluminum foil, and the current collector of the negative plate is copper foil.
Further, the inside of the female die of the aluminum plastic film shell is provided with a round corner in a smooth transition mode.
Further, the aluminum plastic film housing comprises an aluminum foil layer, an OPP layer and an MPP layer for bonding the aluminum foil layer and the OPP layer.
Further, the aluminum-plastic film shell is formed by dry pressing or thermal pressing.
The utility model discloses a lithium ion battery capable of increasing an inner reserved space and preventing explosion, which has the following beneficial effects:
compared with the lithium ion battery in which the height of a female die is equal to that of a diaphragm in the prior art, the internal reserved space is not used as an exhaust or liquid discharge channel, so that gas remains in the battery to be flushed and exploded, and the lithium ion battery has the advantages that compared with the lithium ion battery without the reserved space, the lithium ion battery in which gas or redundant electrolyte generated by internal reaction of the lithium ion battery without the reserved space can be discharged to the external environment through the reserved channel, and the explosion prevention effect is very good; through the test, the lithium ion battery provided by the utility model has lower battery expansion rate compared with the lithium ion battery without a reserved space.
Secondly, the lithium ion battery has good anti-displacement effect, the height of the female die of the lithium ion battery is increased by 0.2mm to form a reserved channel, and after the procedures of two vacuum air extraction and the like, the battery core body is packaged in the aluminum plastic film shell;
thirdly, the quality stability is high, the lithium ion battery is disassembled by disassembling, redundant electrolyte is remained in the battery shell of the lithium ion battery without a reserved space in the prior art, and redundant electrolyte is not remained in the lithium ion battery with a reserved channel with the height of 0.2mm increased by the female die; and the appearance of the pole piece is normal.
Fourth, the utility model is convenient to process, through the high design of the size concave die of the battery shell, directly use the existing cell design, use the ready-made shell punching equipment to punch the shell and shape, do not need to set up the extra fixed structure, have reduced the difficulty of encapsulation and design limitedly, has promoted the convenience of processing.
Drawings
Fig. 1 is a schematic diagram of the internal structure of a lithium ion battery for increasing the internal reserved space and preventing explosion;
fig. 2 is a schematic diagram showing the internal dimensions of a lithium ion battery for increasing the internal headspace and preventing explosion;
fig. 3 is a side view of a lithium ion battery for increasing the internal reserved space and preventing explosion;
the labels in the drawings include:
110: an aluminum plastic film shell;
120: a cell body;
130: a tab;
h: a battery height;
t: the thickness of the battery;
w: a cell width;
w': the center distance of the pole lugs;
d: tab width;
l1: the leakage length of the tab adhesive;
l2: the exposed length of the tab (containing tab glue);
l3: top seal height;
l4: a diaphragm width;
a: the inner roof leaves a space gap.
Detailed Description
In order to better understand the technical solution of the present utility model, the following describes the product of the present utility model in further detail with reference to examples.
As shown in fig. 1, the utility model discloses a battery cell which comprises a battery cell body 120 and an aluminum plastic film shell 110, wherein the battery cell body 120 is packaged in the aluminum plastic film shell 110, the battery cell body 120 comprises a positive plate, a negative plate and a diaphragm, an inner reserved space is formed between the battery cell body 120 and the aluminum plastic film shell 110, the width of the inner reserved space is the width of a female die, the height of the inner reserved space is the height of the female die of the aluminum plastic film, the height of the female die is equal to +0.2mm of the diaphragm, namely L4+a, wherein a takes a value of 0.2mm; the width of the die is equal to the width of the diaphragm +0.2mm, i.e. the height H of the battery is at least equal to the height of the diaphragm + the thickness of the aluminium-plastic film + 2+0.2mm, i.e. the top sealing height L3 is equal to the height of the diaphragm +0.2mm.
Further, the positive plate, the negative plate and the diaphragm are mutually wound or laminated at intervals, and the diaphragm is arranged between the positive plate and the negative plate.
Further, the negative electrode sheet width is greater than the positive electrode sheet width, and the separator width is greater than the negative electrode sheet width.
Further, the positive active material of the positive plate is lithium manganate, lithium iron phosphate, ternary nickel cobalt lithium manganate and/or lithium cobaltate.
Further, the negative electrode active material of the negative electrode plate is natural graphite, artificial graphite or mesophase carbon microsphere.
Further, the diaphragm body is a PE diaphragm, a PP diaphragm or a PE/PP composite diaphragm.
Further, the current collector of the positive plate is aluminum foil, and the current collector of the negative plate is copper foil.
Further, the inside of the female die of the aluminum plastic film shell is provided with a round corner in a smooth transition mode.
Further, the aluminum plastic film housing comprises an aluminum foil layer, an OPP layer and an MPP layer for bonding the aluminum foil layer and the OPP layer.
Further, the aluminum-plastic film shell is formed by dry pressing or thermal pressing.
The utility model relates to a lithium ion battery capable of increasing an inner reserved space and preventing explosion, wherein the inner reserved space comprises an inner dimension of an aluminum plastic film shell, the inner dimension of the aluminum plastic film shell comprises a width of a female die and a height of the female die, the height of the female die is equal to the height of a diaphragm plus 0.2mm, an R angle for fixing a battery core body is arranged at the bottom of the battery during packaging, a battery core is fixed in a battery shell, the battery core consists of a positive plate, a negative plate and a diaphragm, and electrolyte is filled in the battery shell; the battery shell is externally fixed with a positive electrode lug and a negative electrode lug. The utility model has good explosion prevention and displacement change effects, the internal reserved passage can smoothly discharge gas or residual liquid generated in the lithium ion battery to the air bag, and the gas or residual liquid is discharged to the external environment from the reserved passage through two air extraction procedures, thereby ensuring the appearance of the lithium ion battery, ensuring the electrical performance problems in various aspects such as cycle life and the like; in addition, the structure has simple setting procedure, normal encapsulation and easy operation in practical application.
Example 1
The utility model discloses a lithium ion battery capable of increasing an inner reserved space and preventing explosion by pressure, which comprises a battery cell body and an aluminum plastic film shell, wherein the battery cell body is packaged in the aluminum plastic film shell, the battery cell body comprises a positive plate, a negative plate and a diaphragm, the inner reserved space comprises the inner dimension of the aluminum plastic film shell, the inner dimension of the aluminum plastic film shell comprises a female die width and a female die height, and the female die height is equal to the diaphragm height +0.2mm.
In this embodiment, the inner space comprises an inner dimension of the plastic-aluminum film housing, the inner dimension of the plastic-aluminum film housing comprises a die width and a die height, and the die height is equal to +0.2mm of the diaphragm height. The positive plate, the negative plate and the diaphragm are mutually wound or laminated at intervals, and the diaphragm is arranged between the positive plate and the negative plate. The width of the negative electrode plate is larger than that of the positive electrode plate, and the width of the diaphragm is larger than that of the negative electrode plate. The positive active material of the positive plate is lithium manganate, lithium iron phosphate, ternary nickel cobalt lithium manganate and/or lithium cobaltate. The negative electrode active material of the negative electrode plate is natural graphite, artificial graphite and mesophase carbon microspheres. The diaphragm body is a PE diaphragm, a PP diaphragm or a PE/PP composite diaphragm. The current collector of the positive plate is aluminum foil, and the current collector of the negative plate is copper foil.
Further, the inner reserved space comprises an inner dimension of an aluminum plastic film shell, and the inner dimension of the aluminum plastic film shell comprises a width of a female die and a height of the female die.
Further, the die height is equal to the diaphragm height +0.2mm.
Example 2
The utility model discloses a lithium ion battery capable of increasing an inner reserved space and preventing explosion by pressure, which comprises a battery cell body and an aluminum plastic film shell, wherein the battery cell body is packaged in the aluminum plastic film shell, the battery cell body comprises a positive plate, a negative plate and a diaphragm, the inner reserved space comprises the inner dimension of the aluminum plastic film shell, the inner dimension of the aluminum plastic film shell comprises a female die width and a female die height, and the female die height is equal to the diaphragm height +0.2mm.
In this embodiment, the inner space comprises an inner dimension of the plastic-aluminum film housing, the inner dimension of the plastic-aluminum film housing comprises a die width and a die height, and the die height is equal to +0.2mm of the diaphragm height. The positive plate, the negative plate and the diaphragm are mutually wound or laminated at intervals, and the diaphragm is arranged between the positive plate and the negative plate. The width of the negative electrode plate is larger than that of the positive electrode plate, and the width of the diaphragm is larger than that of the negative electrode plate. The positive active material of the positive plate is lithium manganate, lithium iron phosphate, ternary nickel cobalt lithium manganate and/or lithium cobaltate. The negative electrode active material of the negative electrode plate is natural graphite, artificial graphite and mesophase carbon microspheres. The diaphragm body is a PE diaphragm, a PP diaphragm or a PE/PP composite diaphragm. The current collector of the positive plate is aluminum foil, and the current collector of the negative plate is copper foil. The inner reserved space comprises an inner dimension of an aluminum plastic film shell, the inner dimension of the aluminum plastic film shell comprises a female die width and a female die height, and the female die height is equal to the height of the diaphragm plus 0.2mm.
Example 3
The utility model discloses a lithium ion battery capable of increasing an inner reserved space and preventing explosion by pressure, which comprises a battery cell body and an aluminum plastic film shell, wherein the battery cell body is packaged in the aluminum plastic film shell, the battery cell body comprises a positive plate, a negative plate and a diaphragm, the inner reserved space comprises the inner dimension of the aluminum plastic film shell, the inner dimension of the aluminum plastic film shell comprises a female die width and a female die height, and the female die height is equal to the diaphragm height +0.2mm.
In this embodiment, the inner space comprises an inner dimension of the plastic-aluminum film housing, the inner dimension of the plastic-aluminum film housing comprises a die width and a die height, and the die height is equal to +0.2mm of the diaphragm height. The positive plate, the negative plate and the diaphragm are mutually wound or laminated at intervals, and the diaphragm is arranged between the positive plate and the negative plate. The width of the negative electrode plate is larger than that of the positive electrode plate, and the width of the diaphragm is larger than that of the negative electrode plate. The positive active material of the positive plate is lithium manganate, lithium iron phosphate, ternary nickel cobalt lithium manganate and/or lithium cobaltate. The negative electrode active material of the negative electrode plate is natural graphite, artificial graphite and mesophase carbon microspheres. The diaphragm body is a PE diaphragm, a PP diaphragm or a PE/PP composite diaphragm. The current collector of the positive plate is aluminum foil, and the current collector of the negative plate is copper foil. The inner reserved space comprises an inner dimension of an aluminum plastic film shell, the inner dimension of the aluminum plastic film shell comprises a female die width and a female die height, and the female die height is equal to the height of the diaphragm plus 0.2mm.
Comparative example 1
The only difference between comparative example 1 and example 1 is that there is no empty space at the height of the die.
Comparative example 2
Comparative example 2 uses a die height equal to the diaphragm height +0.5mm.
In order to evaluate the technical effects of the present utility model, the anti-explosion and anti-displacement effects of example 1, comparative example 1 and comparative example 2 were compared, and specific results are as follows:
in terms of explosion-proof effect, when the lithium ion battery with a reserved channel is not increased in comparative example 1, the battery tab glue is easy to be exploded (the tab is exploded to cause liquid leakage during the formation of comparative example 1, and the battery expands during the formation of comparative example 1), so that the production efficiency of the battery is reduced; in addition, when the secondary sealing is performed through the working procedures such as air extraction, the redundant electrolyte cannot be smoothly discharged, and the residual electrolyte is easy to generate side reaction to generate gas so as to cause the expansion of the battery, thereby influencing the appearance, the performance, the cycle life and the like of the battery. The reserved space of the embodiment 1 and the comparative example 2 is that gas or redundant electrolyte possibly generated by side reaction of electrolyte in the battery is discharged to an air bag or an external environment (the battery is normal in the formation of the embodiment 1) through providing a reserved channel, the explosion-proof effect of the battery is very good, the battery is free from phenomena of displacement of a battery core, explosion of tab glue and the like after formation, the appearance of the battery after secondary sealing is smooth, the swelling and softening phenomena of the battery are avoided, and all performances and the cycle life of the battery are normal.
As for the battery energy density, the battery energy density of the soft pack lithium ion battery of example 1 was increased by 0.2mm without change, the battery energy density of the battery without inner space was not changed in comparative example 1, and the battery energy density of the battery was decreased by 0.5mm with increase of the battery of comparative example 2.
The above description is only of the preferred embodiments of the present utility model, and is not intended to limit the present utility model in any way; those skilled in the art will readily appreciate that the present utility model is well adapted to carry out the ends of the same out as described herein; however, those skilled in the art will appreciate that many modifications, adaptations, and variations of the present utility model are possible in light of the above teachings without departing from the scope of the utility model; meanwhile, any equivalent changes, modifications and evolution of the above embodiments according to the essential technology of the present utility model still fall within the scope of the present utility model.

Claims (9)

1. The utility model provides an increase interior headspace explosion-proof lithium ion battery, includes electric core body and plastic-aluminum membrane shell, electric core body encapsulation is in inside the plastic-aluminum membrane shell, electric core body includes positive plate, negative plate and diaphragm, its characterized in that: an inner reserved space is formed between the battery cell body and the aluminum plastic film shell, the width of the inner reserved space is the width of the female die, the height of the inner reserved space is the height of the female die of the aluminum plastic film, the height of the female die is equal to the height of the diaphragm plus 0.2mm, and the width of the female die is equal to the width of the diaphragm plus 0.2mm.
2. The increased internal headspace explosion-proof lithium ion battery of claim 1, wherein: the width of the negative electrode plate is larger than that of the positive electrode plate, and the width of the diaphragm is larger than that of the negative electrode plate.
3. The increased internal headspace explosion-proof lithium ion battery of claim 2, wherein: the positive electrode active material of the positive electrode plate is lithium manganate, lithium iron phosphate, ternary nickel cobalt lithium manganate and/or lithium cobaltate.
4. The increased internal headspace explosion-proof lithium ion battery of claim 3, wherein: the negative electrode active material of the negative electrode plate is natural graphite, artificial graphite or mesophase carbon microsphere.
5. The increased internal headspace explosion-proof lithium ion battery of claim 4, wherein: the diaphragm body is a PE diaphragm, a PP diaphragm or a PE/PP composite diaphragm.
6. The increased internal headspace explosion-proof lithium ion battery of claim 5, wherein: the current collector of the positive plate is aluminum foil, and the current collector of the negative plate is copper foil.
7. The increased internal headspace explosion-proof lithium ion battery of claim 6, wherein: the inside of die of plastic-aluminum membrane shell is fillet smooth transition setting.
8. The increased internal headspace explosion-proof lithium ion battery of claim 7, wherein: the aluminum plastic film housing comprises an aluminum foil layer, an OPP layer and an MPP layer for bonding the aluminum foil layer and the OPP layer.
9. The increased internal headspace explosion-proof lithium ion battery of claim 8 or claim 7, wherein: the aluminum-plastic film shell is formed by dry pressing or thermal pressing.
CN202321079213.9U 2023-05-08 2023-05-08 Lithium ion battery capable of increasing inner reserved space and preventing explosion by pressure Active CN219811533U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202321079213.9U CN219811533U (en) 2023-05-08 2023-05-08 Lithium ion battery capable of increasing inner reserved space and preventing explosion by pressure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321079213.9U CN219811533U (en) 2023-05-08 2023-05-08 Lithium ion battery capable of increasing inner reserved space and preventing explosion by pressure

Publications (1)

Publication Number Publication Date
CN219811533U true CN219811533U (en) 2023-10-10

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