CN218951510U - Electrolytic tank for producing hydrogen by water electrolysis and water electrolysis hydrogen production equipment - Google Patents

Electrolytic tank for producing hydrogen by water electrolysis and water electrolysis hydrogen production equipment Download PDF

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Publication number
CN218951510U
CN218951510U CN202223251428.2U CN202223251428U CN218951510U CN 218951510 U CN218951510 U CN 218951510U CN 202223251428 U CN202223251428 U CN 202223251428U CN 218951510 U CN218951510 U CN 218951510U
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polar
frame
polar plate
electrolysis
plate
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巨攀龙
朱琛
廖多香
崔少平
李丰博
朱金超
桓佳君
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Xi'an Longji Hydrogen Energy Technology Co ltd
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Wuxi Longji Hydrogen Energy Technology Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The utility model relates to an electrolysis trough and electrolysis water hydrogen manufacturing equipment for electrolysis water hydrogen manufacturing, including a plurality of cyclic annular polar frames that pile up the setting along electrolysis trough axis direction to and set up diaphragm and the gasket between two adjacent polar frames, the inner periphery space of polar frame is provided with disk-shaped polar plate, and the polar plate is located the intermediate position along the thickness direction of polar frame inner peripheral face, and the interval of two adjacent polar plates is 11-12mm, and the thickness of polar plate is 0.5mm-1.5mm. Through the technical scheme, the temperature of the electrolyte in the accommodating cavity is more balanced, the heating time is saved, and the electricity consumption is reduced. The same volume of the accommodating cavities at the two sides of the polar plate ensures that the electrolytic efficiency of the accommodating cavities is the same respectively. The thickness of the thinner polar plate can reduce the influence of the polar plate resistance on the electrolytic operation, reduce the power consumption of the electrolytic operation, reduce the axial size of the electrolytic tank, facilitate reducing the weight of the electrolytic tank and the axial installation size, and can not influence the structural strength of the polar plate.

Description

Electrolytic tank for producing hydrogen by water electrolysis and water electrolysis hydrogen production equipment
Technical Field
The present disclosure relates to the field of alkaline water electrolysis hydrogen production, and in particular, to an electrolytic cell and an electrolytic water hydrogen production apparatus for producing hydrogen by electrolysis of water.
Background
Currently, filter-pressing bipolar electrolytic tanks are generally adopted in the field of alkaline water electrolysis hydrogen production. The electrolytic tank comprises a plurality of electrode frames which are stacked and arranged and electrode plates which are arranged in the electrode frames, wherein the electrode frames and the electrode plates enable a plurality of accommodating cavities which are formed in the electrolytic tank and are used for accommodating electrolyte and carrying out electrolytic operation, the electrolyte is required to be controlled at a certain temperature to realize the highest efficiency of the electrolytic operation, but in the current electrolytic operation, the temperature of the electrolyte is difficult to be balanced, the electrolytic tank has higher electricity consumption in the electrolytic process, and the electrolytic cost is also improved while the electrolytic efficiency is reduced.
Disclosure of Invention
It is a first object of the present disclosure to provide an electrolyzer for producing hydrogen by electrolysis of water to at least partially solve the problems of the related art.
In order to achieve the above purpose, the disclosure provides an electrolytic tank for producing hydrogen by electrolyzing water, which comprises a plurality of annular polar frames stacked along the axial direction of the electrolytic tank, and gaskets arranged between two adjacent polar frames, wherein a round-plate polar plate is arranged in the inner peripheral space of each polar frame, the polar plate is positioned at the middle position of the inner peripheral surface of each polar frame along the thickness direction, the distance between the two adjacent polar plates is 11mm-12mm, and the thickness of each polar plate is 0.5mm-1.5mm.
Optionally, an annular tongue plate is protruding inwards in the radial direction of the inner peripheral surface of the pole frame, and the pole plate is fixedly connected with the tongue plate.
Optionally, the polar plate is connected with the tongue plate by welding.
Optionally, the width of the welding seam at the connecting position of the polar plate and the tongue plate is more than or equal to 0.5mm.
Optionally, the first side of the pole frame is provided with a first step part for installing the diaphragm and a second step part for installing the first electrode in a gradually decreasing height from outside to inside, and the second side of the pole frame is provided with a third step part for installing the second electrode.
Optionally, the pole frame is provided with a liquid inlet and a liquid outlet, two sides of the pole plate and the inner peripheral space of the pole frame are provided with a liquid storage cavity for storing electrolyte, and the liquid outlet and the liquid inlet are respectively communicated with the liquid storage cavity.
Optionally, the liquid outlet hole and the liquid inlet hole are radially symmetrically arranged relative to the polar frame, and the liquid outlet hole and the liquid inlet hole are respectively provided with a plurality of liquid outlet holes and liquid inlet holes.
Optionally, a notch capable of being matched with the gasket is formed on the first side surface of the pole frame and/or the second side surface of the pole frame, so as to avoid radial displacement of the gasket along the pole frame.
Optionally, the outer surfaces of the polar frame and the polar plate are provided with nickel layers.
Optionally, the difference between the radius of the outer ring of the polar frame and the radius of the inner ring of the polar frame ranges from 72mm to 102mm, and the diameter of the polar plate ranges from 1795mm to 1835mm.
A second object of the present disclosure is to provide an apparatus for producing hydrogen from electrolyzed water comprising an electrolyzer as described in any one of the above.
Through the technical scheme, the temperature of the electrolyte in the accommodating cavity can be more balanced and the heating time of the electrolyte is saved by adjusting the distance between the two adjacent polar plates, and the power consumption is reduced by saving the heating time. In the electrolytic tank, the accommodating cavity capable of accommodating electrolyte is formed by enclosing the side surfaces of two adjacent polar plates and the inner peripheral space of the polar frame, so that one polar frame can form two accommodating cavities, if the distance between two adjacent polar plates is too large, the volumes of the electrolyte accommodated in the two adjacent accommodating cavities are different, the temperature of the electrolyte in the central position of the accommodating cavity with the larger volume of the electrolyte is difficult to reach the temperature required by the electrolysis operation standard in time when the accommodating cavity is heated, and the electrolysis efficiency is further influenced. The polar plate sets up in the middle position along thickness direction of polar plate inner peripheral face can make the volume of the holding chamber of polar plate both sides the same, and the required heating time of a plurality of holding chambers is also the same, has guaranteed that the electrolysis efficiency in a plurality of holding chambers in the electrolysis trough is the same respectively. Meanwhile, in the electrolysis process, current is lost when flowing through the polar plate due to the existence of the polar plate resistor, so that the electricity consumption in the electrolysis process is increased, and the thickness of the polar plate is configured to be between 0.5mm and 1.5mm, so that the influence of the polar plate resistor on the electrolysis operation can be effectively reduced, the electricity consumption of the electrolysis operation is further reduced, meanwhile, the axial size of the electrolytic tank is reduced due to the thinner polar plate thickness, the weight of the electrolytic tank is reduced, the axial installation size is reduced, and meanwhile, the structural strength of the polar plate is not influenced.
Additional features and advantages of the present disclosure will be set forth in the detailed description which follows.
Drawings
The accompanying drawings are included to provide a further understanding of the disclosure, and are incorporated in and constitute a part of this specification, illustrate the disclosure and together with the description serve to explain, but do not limit the disclosure. In the drawings:
FIG. 1 is a schematic diagram of an electrolyzer for producing hydrogen by electrolysis of water provided in an exemplary embodiment of the present disclosure;
FIG. 2 is a schematic illustration of the structure of a pole frame and pole plates in an electrolyzer for producing hydrogen by electrolysis of water provided in an exemplary embodiment of the present disclosure;
fig. 3 is a cross-sectional view taken along line X in fig. 2.
Description of the reference numerals
1-a pole frame, 11-a first side surface, 12-a first step part, 13-a second step part, 14-a second side surface, 15-a third step part, 16-a liquid inlet hole, 17-a liquid outlet hole, 18-a liquid storage cavity, 19-a notch, 2-a pole plate, 21-a welding seam, 3-a tongue plate and 4-a gasket.
Detailed Description
Specific embodiments of the present disclosure are described in detail below with reference to the accompanying drawings. It should be understood that the detailed description and specific examples, while indicating and illustrating the disclosure, are not intended to limit the disclosure.
In this disclosure, unless otherwise indicated, the term "inside" and "outside" refer generally to the orientation of the relevant components in the actual state of use, and to the inside and outside of the contours of the corresponding components. In addition, when the following description refers to the accompanying drawings, the same numbers in different drawings refer to the same or similar elements unless otherwise indicated. The terms "first," "second," and the like, as used in this disclosure, are used for distinguishing one element from another and not necessarily for order or importance.
The present disclosure provides an electrolytic cell for producing hydrogen by electrolyzing water, as shown in fig. 1 to 3, including a plurality of annular electrode frames 1 stacked along an axis direction of the electrolytic cell, and a gasket 4 disposed between two adjacent electrode frames 1, and the gasket 4 may be disposed between two electrode frames 1, to play a sealing role, to ensure that the electrolytic cell does not leak electrolyte. The space of the inner periphery of the pole frame 1 is provided with a circular-plate-shaped pole plate 2, the pole plate 2 is positioned at the middle position of the inner periphery of the pole frame 1 along the thickness direction, the distance between two adjacent pole plates 2 is 11mm-12mm, and the thickness of the pole plate 2 is 0.5mm-1.5mm. The above-mentioned thicknesses refer to the left-right direction in the direction of the drawing of fig. 1 in fig. 1, and refer to the up-down direction in the direction of the drawing of fig. 3 in fig. 3.
Through the technical scheme, the temperature of the electrolyte in the accommodating cavity can be more balanced and the heating time of the electrolyte is saved by adjusting the distance between the two adjacent polar plates 2, and the power consumption is reduced by saving the heating time. In the electrolytic tank, the accommodating cavity capable of accommodating electrolyte is formed by enclosing the side surfaces of two adjacent polar plates 2 and the inner peripheral space of the polar frame 1, so that one polar frame 1 can form two accommodating cavities, if the distance between the two adjacent polar plates 2 is too large, the volumes of the electrolyte accommodated by the two adjacent accommodating cavities are different, the temperature of the electrolyte at the central position of the accommodating cavity with larger volume of the electrolyte is difficult to reach the temperature required by the electrolytic operation standard in time when the accommodating cavity is heated, and the electrolytic efficiency is further influenced. The polar plate 2 is arranged at the middle position of the inner peripheral surface of the polar frame 1 along the thickness direction, so that the volumes of the containing cavities at the two sides of the polar plate 2 are the same, the heating time required by a plurality of containing cavities is the same, and the electrolytic efficiency of a plurality of containing cavities in the electrolytic tank is ensured to be the same respectively. Meanwhile, in the electrolysis process, the current is lost when flowing through the polar plate 2 due to the existence of the resistance of the polar plate 2, so that the electricity consumption in the electrolysis process is increased, and the thickness of the polar plate 2 is configured to be between 0.5mm and 1.5mm, so that the influence of the resistance of the polar plate 2 on the electrolysis operation can be effectively reduced, the electricity consumption of the electrolysis operation is further reduced, meanwhile, the axial size of the electrolytic tank is reduced due to the thinner polar plate 2, the weight of the electrolytic tank is reduced, the axial installation size is reduced, and meanwhile, the structural strength of the polar plate 2 is not influenced.
The inner peripheral surface of the pole frame 1 can be radially inwards provided with annular tongue plates 3 in a protruding mode, and the pole plates 2 are fixedly connected with the tongue plates 3. Because of the existence of the tongue plate 3, the distance between the polar plate 2 and the inner peripheral surface of the polar frame 1 is larger, and when the polar plate 2 is installed, an installation tool cannot be interfered by the inner peripheral surface of the polar frame 1, so that more operation space is provided during installation, and the polar frame 1 and the polar plate 2 are convenient to connect and install. In the case of welding in the connection manner mentioned below, the tongue plate 3 can also prevent thermal deformation of the pole plate 2 and the pole frame 1 due to welding.
Further, the polar plate 2 may be connected to the tongue plate 3 by welding. The sealing performance between the polar plate 2 and the polar frame 1 can be ensured by welding, and the electrolysis effect of the electrolytic tank is ensured. The width of the welding seam 21 at the connecting position of the polar plate 2 and the tongue plate 3 can be more than or equal to 0.5mm. In fig. 1 or 3, the weld 21 at the connection location of the plate 2 and the tongue plate 3 may be a butt weld 21, and with further reference to fig. 3, the width of the weld 21 is indicated by a linear distance C in fig. 3. The stress of the weld 21 having a sufficient width is more uniform to ensure the strength of the weld. If the width of the weld 21 is too small, it is difficult to ensure the connection strength between the tongue plate 3 and the electrode plate 2 and the tightness of the connection position, and the service life of the electrolytic cell is difficult to ensure.
In fig. 3, the first side 11 of the pole frame 1 may be provided with a first step 12 for mounting a separator and a second step 13 for mounting a first electrode in a height gradually decreasing from outside to inside, and the above-mentioned "from outside to inside" refers to a direction from the outer ring toward the inner ring of the pole frame 1, and in fig. 3, from left to right in the direction of the drawing of fig. 3 refers to "from outside to inside" of the pole frame 1. The second side 14 of the pole frame 1 is provided with a third step 15 for mounting the second electrode. The separator can separate hydrogen and oxygen generated in the electrolysis operation, and the electrode can provide ions required for electrolysis into the electrolyte. The step part can accommodate the diaphragm and the electrode required by electrolysis, and simultaneously further lightens the weight of the pole frame 1, and is convenient for positioning and mounting the diaphragm and the electrode. When a plurality of electrode frames 1 are required to be stacked, the adjacent electrode frames 1 are not affected by the thickness of the diaphragm and the electrode, and accordingly, the axial dimension of the electrolytic cell is reduced.
The pole frame 1 can be provided with a liquid inlet hole 16 and a liquid outlet hole 17, liquid storage cavities 18 for storing electrolyte are formed on the two side surfaces of the pole plate 2 and the inner peripheral space of the pole frame 1, and the liquid outlet hole 17 and the liquid inlet hole 16 are respectively communicated with the liquid storage cavities 18. The reservoir 18 may be formed as part of the receiving cavity, and two reservoirs 18 between adjacent plates 2 may be formed as the entire receiving cavity. Thus, the liquid inlet hole 16 can supplement electrolyte into the liquid storage cavity 18 and recover oxygen generated in the electrolysis process, and the liquid outlet hole 17 can collect hydrogen generated in the electrolysis operation and recover the electrolyzed electrolyte, so that the stable operation of the electrolytic tank is ensured. The liquid outlet hole 17 and the liquid inlet hole 16 can be arranged with specific reference to fig. 2 while ensuring the communication with the liquid storage cavity 18, namely, the liquid outlet hole 17 and the liquid inlet hole 16 can be vertically communicated with the pole frame 1, so that the liquid storage cavities 18 of the pole frames 1 can be mutually communicated when the pole frames 1 are arranged in a stacked manner, electrolyte can be simultaneously supplemented into the liquid storage cavities 18 of the pole frames 1 and oxygen generated in the electrolysis process can be recovered through the liquid inlet hole 16, and the liquid outlet hole 17 can also simultaneously collect hydrogen generated in the electrolysis operation of the liquid storage cavities 18 of the pole frames 1 and recover the electrolyzed electrolyte, so that the electrolysis efficiency of the electrolytic tank is effectively improved.
Further, the liquid outlet hole 17 and the liquid inlet hole 16 may be symmetrically arranged radially with respect to the pole frame 1, and the liquid outlet hole 17 and the liquid inlet hole 16 have a plurality of liquid outlet holes, respectively. In fig. 2, a plurality of liquid outlet holes 17 and liquid inlet holes 16 can be operated simultaneously to further improve the electrolysis efficiency, and the radial symmetrical arrangement is also more convenient for stacking and mounting the pole frame 1.
The first side 11 of the pole frame 1 and/or the second side 14 of the pole frame 1 may be provided with a notch 19 that can cooperate with the spacer 4. The displacement of the spacer 4 in the radial direction of the pole frame 1 can be avoided by the notch 19. In fig. 1, the first side 11 and the second side 14 of the pole frame 1 are both provided with notches 19. In order to enable the gasket 4 to exert a better sealing effect, the gasket 4 is generally made of elastic materials such as rubber, when the gasket 4 is installed in two adjacent pole frames 1, the gasket 4 is extruded, and due to the gap 19, the gasket 4 is partially embedded into the gap 19, so that the gasket 4 can resist displacement along the radial direction of the pole frames 1 in the use process.
In addition, the outer surfaces of the electrode frame 1 and the electrode plate 2 may be provided with a nickel layer. In the electrolytic operation, can produce a lot of alkaline ions, these alkaline ions can corrode polar frame 1 and polar plate 2, reduce polar frame 1 and polar plate 2's life, consequently can be provided with the nickel layer at polar frame 1 and polar plate 2's surface, avoid alkaline ions to the corruption of polar frame 1 and polar plate 2's surface, the nickel layer can also improve polar frame 1 and polar plate 2's surface's wearability simultaneously, improves polar frame 1 and polar plate 2 life and use intensity. The nickel layer can be arranged in a plating mode, so that the nickel layer is uniformly and firmly arranged.
In the present disclosure, the difference between the outer radius of the pole frame 1 and the inner radius of the pole frame 1 may be 72mm-102mm, and the diameter of the pole plate 2 may be 1795mm-1835mm. When the distance between two adjacent polar plates 2 is fixed, the diameter of the polar plates 2 is enlarged, so that the volume of electrolyte in the accommodating cavity can be increased, and the efficiency of electrolytic operation is improved. The outer radius of the pole frame 1 and the inner radius of the pole frame 1 can refer to fig. 3, the outer radius of the pole frame 1 is represented by a linear distance a in fig. 3, the inner radius of the pole frame 1 is represented by a linear distance B in fig. 3, and the difference between the linear distance a and the linear distance B is 72mm-102mm, so that the electrolytic cell is convenient to install the diaphragm and the gasket 4, and the use effect of the electrolytic cell is also ensured. When the difference between the linear distance a and the linear distance B is too small, it is difficult to mount the diaphragm and the gasket 4 between the adjacent pole frames 1, and the sealing property of the electrolytic cell cannot be ensured. When the difference between the linear distance A and the linear distance B is too large, the radial dimension of the electrolytic cell is too large, more installation space is occupied, and the production cost is increased. The present disclosure is not limited to a specific limitation, and the difference between the outer radius of the pole frame 1 and the inner radius of the pole frame 1 may be adaptively adjusted according to the size of the pole plate 2, where when the size of the pole plate 2 is smaller, the smaller the difference between the outer radius of the pole frame 1 and the inner radius of the pole frame 1, and correspondingly, when the size of the pole plate 2 is larger, the larger the difference between the outer radius of the pole frame 1 and the inner radius of the pole frame 1.
A second object of the present disclosure is to provide a water electrolysis hydrogen production apparatus, including the electrolytic tank for water electrolysis hydrogen production of any one of the above embodiments, and having all the beneficial effects thereof, which are not described herein.
The preferred embodiments of the present disclosure have been described in detail above with reference to the accompanying drawings, but the present disclosure is not limited to the specific details of the above embodiments, and various simple modifications may be made to the technical solutions of the present disclosure within the scope of the technical concept of the present disclosure, and all the simple modifications belong to the protection scope of the present disclosure.
In addition, the specific features described in the foregoing embodiments may be combined in any suitable manner, and in order to avoid unnecessary repetition, the present disclosure does not further describe various possible combinations.
Moreover, any combination between the various embodiments of the present disclosure is possible as long as it does not depart from the spirit of the present disclosure, which should also be construed as the disclosure of the present disclosure.

Claims (10)

1. The utility model provides an electrolysis trough for electrolysis water hydrogen manufacturing, its characterized in that includes along a plurality of cyclic annular polar frames of electrolysis trough axis direction stack setting to and set up two adjacent between the polar frame the inner periphery space of polar frame is provided with disk-shaped polar plate, the polar plate is located the middle position along the thickness direction of polar frame inner peripheral face, two adjacent polar plate interval is 11mm-12mm, the thickness of polar plate is 0.5mm-1.5mm.
2. The electrolytic tank for producing hydrogen by water electrolysis according to claim 1, wherein the inner peripheral surface of the polar frame is provided with annular tongue plates protruding radially inwards, and the polar plate is fixedly connected with the tongue plates.
3. The electrolytic tank for producing hydrogen by electrolyzing water according to claim 2, wherein the polar plate is connected with the tongue plate by welding, and the width of the welding seam of the connecting position of the polar plate and the tongue plate is more than or equal to 0.5mm.
4. The electrolytic cell for producing hydrogen by electrolyzing water according to claim 1, wherein the first side surface of the pole frame is provided with a first step portion for mounting the diaphragm and a second step portion for mounting the first electrode in a height gradually decreasing from outside to inside, and the second side surface of the pole frame is provided with a third step portion for mounting the second electrode.
5. The electrolytic tank for producing hydrogen by electrolyzing water according to claim 1, wherein the polar plate frame is provided with a liquid inlet hole and a liquid outlet hole, liquid storage cavities for storing electrolyte are formed on both sides of the polar plate and in the inner peripheral space of the polar plate frame, and the liquid outlet hole and the liquid inlet hole are respectively communicated with the liquid storage cavities.
6. The electrolytic cell for producing hydrogen by water electrolysis according to claim 5, wherein the liquid outlet hole and the liquid inlet hole are arranged radially symmetrically with respect to the polar frame, and the liquid outlet hole and the liquid inlet hole are provided in plurality, respectively.
7. The electrolyzer for the production of hydrogen by the electrolysis of water according to claim 1, characterized in that the first side of the polar frame and/or the second side of the polar frame are provided with notches capable of cooperating with the gaskets.
8. The electrolyzer for the production of hydrogen by electrolysis of water according to claim 1, wherein the outer surfaces of the polar frame and the polar plates are provided with a nickel layer.
9. The electrolyzer for the production of hydrogen by electrolysis of water according to claim 1, wherein the difference between the radius of the outer ring of the polar plate and the radius of the inner ring of the polar plate ranges from 72mm to 102mm, and the diameter of the polar plate ranges from 1795mm to 1835mm.
10. An apparatus for producing hydrogen by electrolysis of water, comprising an electrolytic cell for producing hydrogen by electrolysis of water as claimed in any one of claims 1 to 9.
CN202223251428.2U 2022-12-05 2022-12-05 Electrolytic tank for producing hydrogen by water electrolysis and water electrolysis hydrogen production equipment Active CN218951510U (en)

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CN202223251428.2U CN218951510U (en) 2022-12-05 2022-12-05 Electrolytic tank for producing hydrogen by water electrolysis and water electrolysis hydrogen production equipment

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024078190A1 (en) * 2022-10-10 2024-04-18 无锡隆基氢能科技有限公司 Metal electrode frame for electrolyzing water to produce hydrogen, electrolysis units, electrolytic cell and assembly jig

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024078190A1 (en) * 2022-10-10 2024-04-18 无锡隆基氢能科技有限公司 Metal electrode frame for electrolyzing water to produce hydrogen, electrolysis units, electrolytic cell and assembly jig

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Effective date of registration: 20231101

Address after: C0101-1F420, No. 48 Keji Road, High tech Zone, Xi'an City, Shaanxi Province, 710075

Patentee after: Xi'an Longji Hydrogen Energy Technology Co.,Ltd.

Address before: No. 102, Ximei Road, Xinwu District, Wuxi City, Jiangsu Province, 214115

Patentee before: Wuxi Longji Hydrogen Energy Technology Co.,Ltd.

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