CN218677175U - Subassembly that contains UV light conversion glued membrane - Google Patents

Subassembly that contains UV light conversion glued membrane Download PDF

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CN218677175U
CN218677175U CN202222306463.3U CN202222306463U CN218677175U CN 218677175 U CN218677175 U CN 218677175U CN 202222306463 U CN202222306463 U CN 202222306463U CN 218677175 U CN218677175 U CN 218677175U
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adhesive film
light conversion
light
film
back plate
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闫烁
王磊
韩晓航
胡求学
陈蕊
戴建方
陈洪野
吴小平
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Cybrid Technologies Inc
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Cybrid Technologies Inc
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Abstract

The utility model discloses a subassembly that contains UV light conversion glued membrane. The utility model discloses a subassembly that contains UV light conversion glued membrane, include from last front bezel, upper rubber membrane, battery piece, lower floor's glued membrane and the back plate that sets gradually extremely down, wherein, the upper rubber membrane is UV light conversion glued membrane, UV light conversion glued membrane is the UV light conversion glued membrane that converts the light below 380nm into the light more than 380 nm. The utility model discloses a subassembly that contains UV light conversion glued membrane has high luminousness, and excellent light conversion performance and high subassembly power can convert the light below 380nm to the light above 380 nm.

Description

Subassembly that contains UV light conversion glued membrane
Technical Field
The utility model belongs to the photovoltaic module field, concretely relates to subassembly that contains UV light conversion glued membrane.
Background
In recent years, the photovoltaic industry is rapidly developed, technology updating is gradually accelerated, the photovoltaic industry is developing towards product diversification, and research and development of various functional components with high reliability, high conversion rate, high power and low installation cost are becoming a direction for development of photovoltaic components.
The common photovoltaic module with the crystalline silicon solar cell as a power generation core comprises a glass front plate, an encapsulation adhesive film, a solar crystalline silicon cell, an encapsulation adhesive film and a solar cell back plate which are laminated at high temperature to form a sandwich-like structure from top to bottom.
The packaging adhesive film plays roles of bonding protection and the like in the assembly, more and more battery pieces are used in the photovoltaic assembly, the performances of various battery pieces are different, and the requirements on the packaging adhesive film are different; for example, the P-type cell needs a glue film with high PID resistance; the heterojunction battery piece provided with the circular welding strip needs an adhesive film with a non-slip surface, the CIGS battery piece is not sensitive to heat and needs low-temperature lamination, and the like, so that the requirement on the packaging adhesive film is higher and higher. In the field of solar cells, some cells are not resistant to UV light, so a UV cut-off type adhesive film is required to protect the cells. UV light can generate electricity but can damage polymer materials such as adhesive films, backing sheets, and the like. From the EQE curves of the various cells, the EQE response in the UV light band is small, and the EQE response in the visible light region is large. Therefore, if the UV light harmful to the high polymer material is converted into visible light, the material can be protected from the UV light, and the power of the component can be improved. After the UV light is converted into visible light, the EQE response is high, and the power of the component is high.
CN212323012U discloses a photovoltaic module containing a multilayer packaging adhesive film. The photovoltaic module with the multilayer packaging adhesive films comprises a front plate, an upper adhesive film, a battery piece, a lower adhesive film and a rear plate which are sequentially arranged from top to bottom, wherein at least one layer of the upper adhesive film and the lower adhesive film is the multilayer packaging adhesive film, and the multilayer packaging adhesive film comprises at least two layers of packaging adhesive films. The utility model discloses a photovoltaic module who contains multilayer encapsulation glued membrane has excellent anti PID performance, can satisfy the demand to the encapsulation glued membrane of different functions. However, the utility model discloses a glued membrane among photovoltaic module can not satisfy the demand of resistant UV light.
CN108003801A discloses a light conversion POE adhesive film and a photovoltaic module packaged by the light conversion POE adhesive film, wherein the light conversion POE adhesive film is prepared from the following components in parts by weight: 100 parts of POE resin, 0.5-2.0 parts of organic peroxide initiator, 0.5-2.5 parts of crosslinking assistant, 0.3-1.5 parts of tackifying coupling agent, 0.1-0.6 part of light stabilizer, 0.1-0.6 part of ultraviolet absorber and 0.05-0.2 part of light conversion additive. The light conversion additive added into the POE adhesive film has the function of converting ultraviolet short wave bands into blue light with longer wave bands, overcomes the defect that a photovoltaic module under a conventional packaging material has low response to the short wave bands, greatly improves the photoelectric conversion efficiency of the module, and improves the benefit of the photovoltaic module. However, the addition of an ultraviolet absorber to the adhesive film results in a reduction in the power of the assembly, and the adhesive film has poor long-term weatherability of the UV light conversion function and poor surface adhesion.
Therefore, it is necessary to develop a module having high light transmittance, resistance to UV light, and high module power.
SUMMERY OF THE UTILITY MODEL
To the deficiency of the prior art, the present invention provides a module with a UV light conversion coating, which has high transmittance, excellent light conversion performance and high module power, and can convert light below 380nm into light above 380 nm.
To achieve the purpose, the utility model adopts the following technical proposal:
the utility model provides a subassembly that contains UV light conversion glued membrane, includes from last front bezel, upper rubber membrane, battery piece, lower floor's glued membrane and the back plate that sets gradually down, wherein, upper rubber membrane is the UV light conversion glued membrane, the UV light conversion glued membrane is the UV light conversion glued membrane that converts the light below 380nm into the light above 380 nm.
The utility model discloses a subassembly that contains UV light conversion glued membrane has high luminousness, and excellent light conversion performance and high subassembly power can convert the light below 380nm to the light above 380 nm.
The UV light conversion adhesive film is any one of a UV light conversion EVA/POE co-extrusion adhesive film, a UV light conversion EVA adhesive film, a UV light conversion POE adhesive film, a UV light conversion TPO adhesive film, a UV light conversion PVB adhesive film, a UV light conversion SGP adhesive film and a UV light conversion organic silica gel film. It should be noted that, the utility model provides a UV light conversion glued membrane is the UV light conversion glued membrane among the prior art, the utility model discloses do not relate to the improvement to glued membrane material, other UV light conversion glued membranes on the market or among the prior art also can regard as the glued membrane material of this application, for example contain organic fluorescent pigment, tombarthite organic complex, tombarthite inorganic compound, cdSe quantum dot or perovskite quantum dot etc. as the UV light conversion glued membrane of light conversion material, all kinds of UV light conversion glued membranes and other glued membranes that have UV light conversion function that do not list of above-mentioned all belong to the protection scope of the utility model.
Preferably, the UV light conversion adhesive film is selected from any one of a UV light conversion adhesive film with a model number of WT 22h, a UV light conversion adhesive film with a model number of WT 11, a UV light conversion adhesive film with a model number of WT 22, a UV light conversion adhesive film with a model number of WT 34, a UV light conversion adhesive film with a model number of WT 26, a UV light conversion adhesive film with a model number of WT 27, and a UV light conversion adhesive film with a model number of WT 28, which are manufactured by suzhou sai. The upper adhesive film is selected from the adhesive films, so that the adhesive film has good light conversion performance, and can convert light with the wavelength of 380nm or less into light with the wavelength of 380nm or more.
The lower adhesive film is selected from any one of an ethylene-alpha-olefin copolymer film, an ethylene-acrylic acid copolymer film, an ethylene-ethyl acrylate copolymer film, an ethylene-methyl methacrylate copolymer film, an ethyl-methacrylate copolymer film, an ethylene-butyl acrylate copolymer film, a polyvinyl butyral film, an ionomer film and an organic silicon film. Specifically, the lower adhesive film may be selected from high-transparency adhesive films such as POE with the type of T22, EVA with the type of T11, and the like, or selected from high-cut adhesive films such as POE with the type of C22, EVA with the type of C11, and the like, or selected from white adhesive films such as POE with the type of W22, EVA with the type of W11, or black adhesive films, and the like.
Wherein the upper adhesive film and the lower adhesive film are independently selected from a single-layer adhesive film or a multi-layer adhesive film. The single-layer adhesive film refers to an adhesive film which is a single-layer film, and the multi-layer adhesive film is an adhesive film which comprises two or more layers.
Wherein the number of the layers of the multilayer adhesive film is 2-5. When the adhesive film has a multilayer structure, the matrix resins of two adjacent layers may be the same or different.
Wherein, the subassembly is single glass assembly or dual glass assembly.
Wherein, the front plate is a glass plate.
Wherein, the back plate is any one in backplate, the glass, the backplate can be for in KPF backplate, PPF backplate, CPC backplate, KPK backplate, KPO backplate, TPO backplate, the TPC backplate, other backplates that field is commonly used also all belong to the utility model discloses a scope of protection.
The solar cell comprises a solar cell body, a solar cell body and a solar cell panel, wherein the solar cell panel is any one of a P-type cell panel, an N-type cell panel, a heterojunction cell panel, an IBC cell panel, a TOPCon cell panel, an MWT cell, a perovskite cell, a CIGS cell or an amorphous silicon cell panel.
Compared with the prior art, the beneficial effects of the utility model are that:
the utility model discloses a subassembly that contains UV light conversion glued membrane has high luminousness, and excellent light conversion performance and high subassembly power can convert the light below 380nm to the light above 380 nm. Specifically, the light transmittance of a UV waveband (280-380 nm) is 11.42-12.97%, the light transmittance of a visible light waveband (380-1100 nm) is 91.99-92.18%, the initial UV light conversion efficiency is 97.53-98.02%, the UV light conversion efficiency after UV300kwh is 93.04-94.95%, the power of an initial assembly is 339.72-343.17W, and the power of an assembly after UV300kwh is 332.74-337.42W.
Drawings
Fig. 1 is a schematic structural view of an assembly of the present invention including a UV light conversion coating;
the reference numbers are as follows:
1-a front plate; 2-upper glue film; 3, a battery piece; 4-lower layer of glue film; 5-back plate.
Detailed Description
The technical solution of the present invention is further explained by the specific implementation way with reference to fig. 1.
As shown in fig. 1, the utility model discloses a subassembly that contains UV light conversion glued membrane, include from last front bezel 1, upper rubber membrane 2, battery piece 3, lower floor's glued membrane 4 and the back plate 5 that sets gradually extremely down. The upper adhesive film is a UV light conversion adhesive film (wherein, when not specifically stated, the adhesive film is a single-layer adhesive film), and the upper adhesive film enables the adhesive film to have good light conversion performance and can convert light below 380nm into light above 380 nm.
Example 1
The module that contains UV light conversion glued membrane of this embodiment includes from last front bezel 1, upper rubber membrane 2, battery piece 3, lower floor glued membrane 4 and the back plate 5 that sets gradually down, and wherein, front bezel 1 is glass, and upper rubber membrane 2 is the UV light conversion glued membrane that the model of suzhou saiwu produced is WT 34, and battery piece 3 is the heterojunction battery piece, and lower floor glued membrane 4 is ethylene-alpha-olefin copolymer glued membrane (the model of suzhou saiwu produced is the POE glued membrane of T22), and back plate 5 is glass.
Example 2
The module containing the UV light conversion adhesive film of this embodiment includes front bezel 1, upper rubber membrane 2, battery piece 3, lower rubber membrane 4 and back plate 5 that set gradually from top to bottom, wherein, front bezel 1 is glass, and upper rubber membrane 2 is the UV light conversion adhesive film that the model of suzhou saiwu produced is WT 11, and battery piece 3 is the heterojunction battery piece, and lower rubber membrane 4 is ethylene-alpha-olefin copolymer adhesive film (the model of suzhou saiwu produced is POE adhesive film of T22), and back plate 5 is glass.
Example 3
The module that contains UV light conversion glued membrane of this embodiment includes from last front bezel 1, upper rubber membrane 2, battery piece 3, lower floor glued membrane 4 and the back plate 5 that sets gradually down, and wherein, front bezel 1 is glass, and upper rubber membrane 2 is the UV light conversion glued membrane that the model of suzhou saiwu produced is WT 22, and battery piece 3 is the heterojunction battery piece, and lower floor glued membrane 4 is ethylene-alpha-olefin copolymer glued membrane (the model of suzhou saiwu produced is the POE glued membrane of T22), and back plate 5 is glass.
Example 4
The module that contains UV light conversion glued membrane of this embodiment includes from last front bezel 1, upper rubber membrane 2, battery piece 3, lower floor glued membrane 4 and the back plate 5 that sets gradually down, and wherein, front bezel 1 is glass, and upper rubber membrane 2 is the UV light conversion glued membrane that the model of suzhou saiwu produced is WT 22h, and battery piece 3 is P type battery piece, and lower floor glued membrane 4 is ethylene-alpha-olefin copolymer glued membrane (the model of suzhou saiwu produced is the POE glued membrane of T22), and back plate 5 is glass.
Example 5
The module containing the UV light conversion adhesive film of this embodiment includes front bezel 1, upper rubber membrane 2, battery piece 3, lower rubber membrane 4 and back plate 5 that set gradually from top to bottom, and wherein, front bezel 1 is glass, and upper rubber membrane 2 is the UV light conversion adhesive membrane that suzhou saiwu produced the model be WT 22h, and battery piece 3 is TOPCon battery piece, and lower rubber membrane 4 is ethylene-alpha-olefin copolymer adhesive membrane (the POE adhesive membrane that suzhou saiwu produced the model be T22), and back plate 5 is glass.
Example 6
The subassembly that contains UV light conversion glued membrane of this embodiment includes from last front bezel 1, upper rubber membrane 2, battery piece 3, lower floor glued membrane 4 and the back plate 5 that sets gradually down, and wherein, front bezel 1 is glass, and upper rubber membrane 2 is the UV light conversion glued membrane that the model of Suzhou saiwu produced is WT 22h, and battery piece 3 is heterojunction battery piece, and lower floor glued membrane 4 is the EVA glued membrane that the model is C11, and back plate 5 is glass.
Example 7
The module containing the UV light conversion adhesive film of the embodiment includes a front plate 1, an upper adhesive film 2, a battery piece 3, a lower adhesive film 4 and a back plate 5 which are sequentially arranged from top to bottom, wherein the front plate 1 is glass, and the upper adhesive film 2 is made of WT 22h produced by suzhou saiwuA UV light conversion adhesive film, wherein the cell sheet 3 is a heterojunction cell sheet, and the lower adhesive film 4 is a polyvinyl butyral adhesive film (
Figure BDA0003825614350000071
PA 41), the rear plate 5 is glass.
Example 8
The difference between this example and example 1 is that the upper adhesive film is a three-layer adhesive film, specifically, the model number of suzhou saiwu is WT 22h, and the specific structure includes an upper EVA layer (in contact with glass and having a light conversion function), an intermediate layer POE (having a light conversion function), and a lower EVA layer (in contact with a cell and having a UV light cut-off function), and the thickness is the same as that of example 1.
Comparative example 1
The comparative example is different from example 1 in that the upper adhesive film is different.
The assembly containing the UV light conversion adhesive film comprises a front plate 1, an upper adhesive film 2, a battery piece 3, a lower adhesive film 4 and a rear plate 5 which are sequentially arranged from top to bottom, wherein the front plate 1 is made of glass, the upper adhesive film 2 is an ethylene-alpha-olefin copolymer adhesive film (POE adhesive film with the model of T22 produced by Suzhou saiwu), the battery piece 3 is a heterojunction battery piece, the lower adhesive film 4 is an ethylene-alpha-olefin copolymer adhesive film (POE adhesive film with the model of T22 produced by Suzhou saiwu), and the rear plate 5 is made of glass.
Comparative example 2
The comparative example is different from example 1 in that the upper adhesive film is different and the battery piece is different.
The assembly containing the UV light conversion adhesive film comprises a front plate 1, an upper adhesive film 2, a battery piece 3, a lower adhesive film 4 and a rear plate 5 which are sequentially arranged from top to bottom, wherein the front plate 1 is made of glass, the upper adhesive film 2 is an ethylene-alpha-olefin copolymer adhesive film (POE adhesive film with the model of T22 produced by Suzhou saiwu), the battery piece 3 is a P-type battery piece, the lower adhesive film 4 is an ethylene-alpha-olefin copolymer adhesive film (POE adhesive film with the model of T22 produced by Suzhou saiwu), and the rear plate 5 is made of glass.
Comparative example 3
The comparative example is different from example 1 in that the upper adhesive film is different and the battery piece is different.
The assembly containing the UV light conversion adhesive film comprises a front plate 1, an upper adhesive film 2, a battery piece 3, a lower adhesive film 4 and a rear plate 5 which are sequentially arranged from top to bottom, wherein the front plate 1 is made of glass, the upper adhesive film 2 is an ethylene-alpha-olefin copolymer adhesive film (POE adhesive film with the model of T22 produced by Suzhou saiwu), the battery piece 3 is a TOPCON battery piece, the lower adhesive film 4 is an ethylene-alpha-olefin copolymer adhesive film (POE adhesive film with the model of T22 produced by Suzhou saiwu), and the rear plate 5 is made of glass.
The assemblies obtained in examples 1 to 8 and comparative examples 1 to 3 were subjected to performance tests, the results of which are shown in Table 1.
The test standard of the transmittance is carried out according to GB/T29848-2018, the light transmittance test is carried out by adopting a specific ultraviolet-visible spectrophotometer (Perkinelmer LAMBDA 950), and the test standard of the module power is carried out according to IEC 61215.
TABLE 1
Figure BDA0003825614350000081
The utility model discloses a subassembly that contains UV light conversion glued membrane has high luminousness, and excellent light conversion performance and high subassembly power can convert the light below 380nm to the light above 380 nm. Specifically, the light transmittance of a UV waveband (280-380 nm) is 11.42-12.97%, the light transmittance of a visible light waveband (380-1100 nm) is 91.99-92.18%, the initial UV light conversion efficiency is 97.53-98.02%, the UV light conversion efficiency after UV300kwh is 93.04-94.95%, the power of an initial assembly is 339.72-343.17W, and the power of an assembly after UV300kwh is 332.74-337.42W.
As can be seen from the data in fig. 1, the module fabricated using the UV light conversion adhesive film has high light conversion efficiency, higher initial power than the module without the light conversion adhesive film, and higher power after UV aging.
The present invention is described in detail by the above embodiments, but the present invention is not limited to the above detailed process equipment and process flow, i.e. not meaning the present invention must rely on the above detailed process equipment and process flow to implement. It should be clear to those skilled in the art that any improvement of the present invention, to the equivalent replacement of each raw material of the present invention, the addition of auxiliary components, the selection of specific modes, etc., all fall within the protection scope and disclosure scope of the present invention.
The above detailed description describes the preferred embodiments of the present invention, but the present invention is not limited to the details of the above embodiments, and the technical idea of the present invention can be within the scope of the present invention, and can be right to the technical solution of the present invention, and these simple modifications all belong to the protection scope of the present invention.
It should be noted that the various technical features described in the above embodiments can be combined in any suitable manner without contradiction, and in order to avoid unnecessary repetition, the present invention does not need to describe any combination of the features.
In addition, various embodiments of the present invention can be combined arbitrarily, and the disclosed content should be regarded as the present invention as long as it does not violate the idea of the present invention.

Claims (9)

1. The component is characterized by comprising a front plate, an upper-layer adhesive film, a battery piece, a lower-layer adhesive film and a rear plate which are sequentially arranged from top to bottom, wherein the upper-layer adhesive film is a UV light conversion adhesive film, and the UV light conversion adhesive film is a UV light conversion adhesive film for converting light below 380nm into light above 380 nm.
2. The assembly of claim 1, wherein the UV light conversion adhesive film is selected from any one of UV light conversion EVA/POE co-extrusion adhesive film, UV light conversion EVA adhesive film, UV light conversion POE adhesive film, UV light conversion TPO adhesive film, UV light conversion PVB adhesive film, UV light conversion SGP adhesive film, and UV light conversion organic silicone adhesive film.
3. The UV light converting adhesive film containing assembly according to claim 1, wherein the lower adhesive film is selected from any one of an ethylene- α -olefin copolymer film, an ethylene-acrylic acid copolymer film, an ethylene-ethyl acrylate copolymer film, an ethylene-methyl methacrylate copolymer film, an ethyl-methacrylate copolymer film, an ethylene-butyl acrylate copolymer film, a polyvinyl butyral film, an ionomer film, and a silicone film.
4. The UV light-converting adhesive film-containing assembly according to claim 1, wherein the upper adhesive film and the lower adhesive film are independently selected from a single-layer adhesive film or a multi-layer adhesive film.
5. The assembly of claim 4, wherein the number of layers of the multilayer adhesive film is 2-5.
6. The assembly of claim 1, wherein the assembly is a single glass assembly or a dual glass assembly.
7. The UV light-converting adhesive film-containing assembly according to claim 1, wherein the front sheet is a glass sheet.
8. The assembly of claim 1, wherein the back plate is selected from one of a KPF back plate, a PPF back plate, a CPC back plate, a KPK back plate, a KPO back plate, a TPO back plate, a TPC back plate, or glass.
9. The UV light-converting adhesive film-containing module according to claim 1, wherein the cell sheet is any one of a P-type cell sheet, an N-type cell sheet, a heterojunction cell sheet, an IBC cell sheet, a TOPCon cell sheet, an MWT cell, a perovskite cell, a CIGS cell, and an amorphous silicon cell sheet.
CN202222306463.3U 2022-08-31 2022-08-31 Subassembly that contains UV light conversion glued membrane Active CN218677175U (en)

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