CN217972654U - Horizontal water treatment facilities of kind fluidized bed - Google Patents

Horizontal water treatment facilities of kind fluidized bed Download PDF

Info

Publication number
CN217972654U
CN217972654U CN202222303562.6U CN202222303562U CN217972654U CN 217972654 U CN217972654 U CN 217972654U CN 202222303562 U CN202222303562 U CN 202222303562U CN 217972654 U CN217972654 U CN 217972654U
Authority
CN
China
Prior art keywords
fluidized bed
water treatment
cylinder
horizontal water
water inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202222303562.6U
Other languages
Chinese (zh)
Inventor
钟辉
孙豪
赖先熔
汪文成
阳超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Panyu Lithium Energy New Material Technology Co ltd
Original Assignee
Sichuan Panyu Lithium Energy New Material Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Panyu Lithium Energy New Material Technology Co ltd filed Critical Sichuan Panyu Lithium Energy New Material Technology Co ltd
Priority to CN202222303562.6U priority Critical patent/CN217972654U/en
Application granted granted Critical
Publication of CN217972654U publication Critical patent/CN217972654U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Treatment Of Liquids With Adsorbents In General (AREA)

Abstract

The utility model belongs to the technical field of water treatment, and discloses a fluidized bed-like horizontal water treatment device, which comprises a cylinder body and a bracket, wherein the cylinder body is horizontally arranged on the bracket and can rotate on the bracket; the barrel is provided with a water inlet and outlet valve, and at least one draining groove is arranged in the barrel. The device has the characteristic of mutual flow of liquid phase and solid phase similar to a fluidized bed, can keep high mass transfer rate and high adsorbent utilization rate, and overcomes the defect of large abrasion of adsorbent particles of the fluidized bed.

Description

Horizontal water treatment facilities of class fluidized bed
Technical Field
The utility model belongs to the technical field of water treatment facilities, a adsorption method water treatment facilities is related to.
Background
With the increase of population and the rapid development of modern industry, the problem of environmental pollution is increasingly serious, particularly the heavy metal pollution of water bodies directly endangers the health of human beings. According to the report issued by the world health organization, 300 to 400 million people die each year from diseases related to water pollution. The treatment of water pollution has become an important strategic target for the sustainable utilization of global water resources and the sustainable development of national economy at present.
The adsorption method is one of the main technical branches of water treatment technology, and has a wide application range, such as the fields of chemical industry, resource utilization, medicine and the like. The adsorption method for treating sewage is mainly to treat sewage by using an adsorbent (such as activated carbon) in a production process, and a corresponding adsorption device is usually required to be equipped. According to the difference of the working characteristics of the adsorption devices, the currently common adsorption water treatment devices can be divided into two types: fixed bed, fluidized bed.
The fixed bed is the most applied equipment in the water treatment device of the adsorption method at present, such as an adsorption tower, an adsorption bed and the like, but has the following defects:
(1) The adsorption column has large loading amount of the adsorbent, but the utilization rate is low. Because only the adsorbent in the working layer is undergoing adsorption or ion exchange reaction when the fixed bed is in operation, most of the remaining adsorbent can only serve as a "support", but when the adsorbent in the fixed bed needs to be regenerated, the upper adsorbent is in a failure state, and it is difficult to regenerate and recover the activity.
(2) Along with the increase of the height of the adsorption tower, the pressure drop of the fixed bed layer is increased, the adsorbent at the middle and lower parts is easy to break and pulverize, the water permeability at the bottom of the fixed bed is deteriorated after the adsorbent particles are broken, the full contact between target ions in water and the adsorbent is not facilitated, and the mass transfer efficiency is reduced.
As a supplement to a fixed bed adsorption water treatment device, although a fluidized bed has the advantages of sufficient solid-liquid phase contact and high mass transfer speed, the problems of violent friction and collision exist between adsorbent particles and between adsorbent particles and fluid, so that the particle adsorbent is broken, pulverized and abraded, and further fails.
Therefore, aiming at the problems of the existing water treatment device, the development and design of the novel water treatment device adopting the adsorption method, which is not only beneficial to the efficient utilization of the adsorbent, but also can avoid the massive abrasion of the adsorbent, have important significance.
SUMMERY OF THE UTILITY MODEL
The utility model aims to overcome the defects of low utilization efficiency and easy failure of the fixed bed adsorbent in the prior art; the fluidized bed adsorbent particles are easy to collide, break and lose efficacy, and the like, and the fluidized bed-like horizontal water treatment device is provided.
In order to achieve the above object, the present invention provides the following technical solutions:
the fluidized bed-like horizontal water treatment device comprises a cylinder and a bracket, wherein the cylinder is horizontally arranged on the bracket and can rotate on the bracket;
the barrel is provided with a water inlet and outlet valve, and at least one draining groove is arranged in the barrel.
The utility model discloses horizontal water treatment facilities has solved the big scheduling problem of current fixed bed adsorbent effective utilization low, fluidized bed equipment mechanical wear. Before the equipment works, adsorbent particles or porous filter media are added into the cylinder, then liquid to be treated flows into the cylinder through the water inlet and outlet valve, and the rotating motor or other power devices are started to drive the cylinder to rotate. In the rotating process of the cylinder, the adsorbent particles or the porous filter medium are fully contacted and reacted with liquid, and meanwhile, the draining tank forces the adsorbent particles or the porous filter medium to turn over, so that the adsorption reaction speed is higher and more uniform. Because the cylinder rotates to ensure that all the adsorbents can exchange positions and fully act with liquid, the adsorption efficiency and the adsorption speed of the adsorbents are higher and are superior to the adsorbents filled in the adsorption column; meanwhile, although the adsorbents move or fall off in the rotation process of the cylinder, strong collision cannot occur among the adsorbents, so that the damage failure proportion of the adsorbent particles is extremely low, and the collision, damage and failure of the adsorbent particles are avoided.
Preferably, all advance the drainage valve and all avoid the support position, when guaranteeing the barrel rotation, advance the drainage valve can not take place the conflict with the support.
Furthermore, the water inlet and outlet valve is connected with a metering pump. The metering pump is used for accurately feeding, and detecting and recording the liquid amount input or discharged by water feeding and discharging.
Further, the barrel is a cylindrical barrel. The cylindrical barrel has the advantages of good structural strength, light weight and low energy consumption during rotary operation.
Furthermore, the tip of barrel still is provided with in side feed inlet, gas vent, the supplementary outlet. And are all closable structures.
The side feed inlet can be used for filling adsorbent particles, and the exhaust port can be used for exhausting gas in the cylinder body and keeping the internal and external pressure of the cylinder body stable, and is particularly used for exhausting bubbles generated in the feeding or reaction process; the auxiliary drain port may be used for draining water during maintenance or malfunction of the cartridge. Preferably, the side feeding port, the exhaust port and the auxiliary water outlet can be merged into a single valve or channel to realize different functions according to requirements.
Preferably, the side feeding hole is also connected with a metering pump.
Further, the water inlet and outlet valve is arranged on the side surface of the cylindrical barrel. When cylindrical barrel rotated and made the position change, water inlet and outlet valve was used for intaking and drainage respectively, was used for intaking when water inlet and outlet valve was located upper portion, was used for the drainage when water inlet and outlet valve was located the lower part, and is integrative multi-purpose.
Further, the barrel is internally provided with a cylindrical cavity, and the draining groove is arranged on the side wall of the cylindrical cavity.
Furthermore, an adsorbent or a porous medium for water treatment is filled in the cylinder. Preferably, the porous medium is a porous filter medium.
Preferably, the adsorbent is packed in an amount of 0 to 60% (volume percent) of the volume of the cavity inside the cartridge. Preferably, the adsorbent is packed in an amount of 10% to 50% (volume percentage) of the volume of the cavity inside the cartridge. For example, the adsorbent loading may be 20%, 30%, 40%, etc. of the volume of the interior cavity of the cartridge.
The adsorbent is added into the barrel according to a certain filling rate, so that the barrel can rotate, and meanwhile, adsorbent particles can keep a certain degree of freedom in the barrel, and the efficiency of mutual reaction between the adsorbent particles and liquid is improved. Liquid to be treated is added into the cylinder body through the water inlet, the motor is started to enable the cylinder body to rotate at a certain rotating speed, so that the adsorbent is fully contacted with the solution, and adsorption mass transfer is carried out.
Further, the adsorbent may be in the form of particles or powder, and in the case of powder, vacuum filtration is preferable so that the liquid outflow rate is increased greatly.
Furthermore, the at least two water leaching grooves are respectively arranged on the side wall of the cylindrical cavity and are symmetrically arranged or uniformly distributed. If two waterlogging caused by excessive rainfall grooves then can symmetrical arrangement, if three and above then can the hoop evenly arrange for when the barrel rotated, porous filter medium was thrown away in succession, promoted adsorption efficiency.
Furthermore, at least one of the water leaching tanks is a V-shaped mesh structure, and the water inlet and outlet valves are communicated to the cavity between the V-shaped mesh structure and the barrel body. The water inlet and outlet valve and the draining tank are mutually matched, and filtering and protecting functions are formed through the V-shaped net structure, so that the porous filtering medium is prevented from flowing into the water inlet and outlet valve when the barrel rotates.
The height of the draining groove from the inner wall of the cylinder body is 0-2 times of the height of the filling material of the porous filtering medium filled in the cylinder body. Preferably, the height of the draining groove from the inner wall of the cylinder body is larger than the height of the porous filtering medium filled in the draining groove. Preferably 1-2 times, such as 1.3 times, 1.5 times, 1.7 times the stacking height of the porous filter medium inside the cylinder.
Preferably, the height of the draining tank from the inner wall of the barrel is 10-50cm.
The height of the water leaching tank is the closest distance between the top end of the V-shaped net structure and the inner wall of the cylinder body.
Furthermore, the outside of the draining tank is also connected with a vacuum pump, and the liquid in the rotary drum is subjected to vacuum filtration through the draining tank and the filter cloth, so that the outflow speed of the liquid is greatly increased.
Furthermore, the water inlet and outlet valve is provided with a filter screen or filter cloth, the aperture of the water inlet and outlet valve is 0.001-5mm, and the water inlet and outlet valve can be used for vacuum filtration to accelerate the water outlet rate. The aperture of the filter screen or the filter cloth can be 0.01mm, 0.1mm, 0.2mm, 0.4mm, 0.8mm, 1.5mm, 3mm and the like, and the appropriate aperture parameter of the filter screen or the filter cloth is selected according to the particle size of the adopted adsorbent or the porous medium, or the filter screen or the filter cloth is arranged on the surface of the draining tank, so that the filter screen or the filter cloth can be ensured to filter and prevent the adsorbent or the porous medium from penetrating.
Further, a filter screen or filter cloth is installed at the side feeding hole, or the filter screen or filter cloth is installed on the draining tank; the aperture of the filter screen or the filter cloth is 0.001-5mm, and the water drainage rate can be increased by vacuum filtration.
Further, a circular riding wheel shaft is sleeved outside the cylinder body, or the riding wheel shaft is integrally formed on the outer surface of the cylinder body. The riding wheel shaft is matched with the support, so that the cylinder body can rotate on the support.
Further, the support has at least two, and the barrel sets up between two supports. Preferably, each support comprises two bearings, on which the cartridge is arranged horizontally. Two bearings included by each bracket are mutually contacted with a riding wheel shaft of the cylinder body, a structure similar to a V-shaped groove is formed between the two brackets, and the riding wheel shaft is arranged in the V-shaped groove.
Preferably, at least one of the bearings has a motive mechanism that can drive the barrel in rotation. Preferably, the power mechanism is an adjustable speed motor.
The utility model has the characteristics of the double-phase flow each other of fluidized bed liquid phase, solid phase, can keep high mass transfer rate and high adsorbent utilization ratio, overcome the big shortcoming of fluidized bed adsorbent granule wearing and tearing again. The adsorbent is added into the cylinder body according to a certain filling rate, the liquid to be treated is added into the cylinder body through the water inlet, the motor is started to enable the cylinder body to rotate according to a certain rotating speed, the adsorbent is enabled to be fully contacted with the solution, and adsorption mass transfer is carried out.
Compared with the prior art, the beneficial effects of the utility model are that:
1. the device of the utility model is simple in structure, convenient operation, equipment investment is little, and the double-phase contact of solid-liquid is more abundant, and mass transfer efficiency is high, and adsorbent mechanical wear is little, is favorable to improving the production efficiency of adsorption process water treatment process.
2. The utility model discloses water treatment facilities rotational speed is decided according to actual filler and operation, has the high mass transfer rate and the high adsorbent utilization ratio of similar fluidized bed, and granule mechanical wear greatly reduced has overcome the big shortcoming of fluidized bed adsorbent granule wearing and tearing.
3. The utility model discloses water treatment facilities's waterlogging caused by excessive rainfall groove outside joinable vacuum pump, liquid carries out vacuum filtration through waterlogging caused by excessive rainfall groove and filter cloth in the rotary drum, makes liquid outflow speed greatly increased.
4. The utility model discloses water treatment facilities's adsorbent can make the graininess, also can be the powder, when being the powder, preferred vacuum filtration to make liquid outflow speed greatly increased.
5. The utility model discloses water treatment facilities is through adjusting variable speed motor, and whole barrel rotates, and the adsorbent is driven by the rotary drum wall, can not maintain the stationary state, is kicked up when the adsorbent is through the waterlogging caused by excessive rainfall groove, presents type fluidization state, makes adsorbent and liquid fully contact, improves mass transfer efficiency greatly.
6. The utility model discloses supplementary outlet is installed to water treatment facilities barrel one end, and the rotary drum stops the back adsorbent and subsides naturally, and supplementary outlet accounts for 70-90% of total liquid volume's liquid because of the pressure differential discharge, has significantly reduced the liquid volume through drip groove filter medium, makes the solid-liquid separation time shorten, has improved the work efficiency of this device.
7. The device can be used in the field of wastewater treatment and the field of metal ion recovery in water bodies.
Drawings
FIG. 1 is a schematic view of a front view of a horizontal water treatment apparatus according to the present invention;
FIG. 2 is a schematic sectional view of the horizontal water treatment device of the present invention in the front view direction;
FIG. 3 is a schematic left side sectional view of the horizontal water treatment apparatus of the present invention;
fig. 4 is a schematic left view of the horizontal water treatment device of the present invention.
FIG. 5 is an enlarged view of section A-A of FIG. 3.
The labels in the figure are: 1-a drum body; 2-a first set of riding wheels; 3-a second set of riding wheels; 4-a first idler shaft; 5-a second riding wheel shaft; 6-a feed inlet; 7-auxiliary water outlet; 8-exhaust port; 9-a first water inlet and outlet valve; 10-a second water inlet and outlet valve; 11-a third water inlet and outlet valve; 12-a fourth water inlet and outlet valve and 13-a water draining tank.
Detailed Description
The present invention will be described in further detail with reference to test examples and specific embodiments. However, it should be understood that the scope of the present invention is not limited to the following embodiments, and all the technologies realized based on the contents/concepts of the present invention belong to the protection scope of the present invention.
The utility model discloses horizontal water treatment facilities of class fluidized bed includes that the big riding wheel and the buncher etc. of basin, porous filter medium, supplementary outlet, barrel side are equipped with to the advancing/ejection of compact valve, the barrel of cylindrical barrel, support, bearing, bottom gas vent, barrel side.
Example 1
The fluidized bed horizontal water treatment device comprises a cylindrical drum body 1 and a support, wherein the support comprises two groups of tugs, namely a first group of tug 2 and a second group of tug 3. The barrel 1 is horizontally arranged on the support, and the barrel can rotate on the support. The cylinder is provided with four water inlet and outlet valves, namely a first water inlet and outlet valve 9, a second water inlet and outlet valve 10, a third water inlet and outlet valve 11 and a fourth water inlet and outlet valve 12. All water inlet and outlet valves are provided with filter screens, and the aperture of each filter screen is 0.05mm. All advance the drainage valve and all avoid the support position, when guaranteeing that the barrel rotates, advance the drainage valve can not take place the conflict with the support, simultaneously advance drainage valve interface connection and have the measuring pump to be used for accurate feeding.
As shown in fig. 1, the left end of the cylinder is further provided with an exhaust port 8 for exhausting air bubbles generated during the feeding or reaction process, and an auxiliary water discharge port 7. As shown in fig. 4, the auxiliary drain port 7 is provided at one end of the drum body, and is used for draining water in case of maintenance or malfunction of the drum body. As shown in fig. 1, a side inlet 6 is provided at the right end of the cylinder 1, and the side inlet is used for filling adsorbent particles.
As shown in fig. 2-3, two draining tanks 13 are provided inside the barrel, and are symmetrically arranged at symmetrical positions on the side wall inside the barrel. As shown in figure 5, one of the draining tanks is a V-shaped mesh structure, a filter screen is arranged on the V-shaped mesh structure, and a water inlet and outlet valve is communicated to a cavity between the V-shaped mesh structure and the cylinder body. The V-shaped mesh structure has the filtering and protecting functions, and the porous filtering medium is prevented from flowing into the water inlet and outlet valve when the cylinder rotates. The height of the two draining tanks is 30cm (adjustable as required, for example 25cm, 40cm, etc.). When the cylinder rotates, the adsorbent particles roll along with the cylinder, and when the adsorbent particles pass through the draining tank, the adsorbent particles are forced to roll, so that the particles are prevented from being adhered to the inner wall of the cylinder.
As shown in fig. 1, two annular idler shafts 4 are sleeved outside the cylinder, and as shown in fig. 4, each support comprises two bearings, and the cylinder is horizontally arranged between the two bearings of the two supports. One of the bearings is connected with a speed regulating motor as a motive mechanism, and can drive the cylinder body to rotate (or two bearings are connected with the motor, so that the total driving force of the device is enhanced).
The utility model discloses a concrete embodiment case of device system, when class fluidized bed horizontal water treatment facilities uses:
s1, adding the adsorbent into the rotary drum 1, wherein the filling rate is 35% (volume percentage).
And S2, rotating the cylinder body to enable the inlet and outlet valves 9, 10, 11 and 12 to be positioned at the upper part of the cylinder body, connecting a liquid conveying pipeline, and conveying the liquid to be treated into the cylinder body from the inlet and outlet valves 9, 10, 11 and 12 until the cylinder body is full (or not full).
S3, closing the inlet and outlet valves 9, 10, 11 and 12, removing the liquid conveying pipeline, starting the speed regulating motor, and enabling the rotary drum to rotate at the set rotating speed (0-30 rpm, usually not containing the condition that the rotating speed is 0) to perform adsorption.
And S4, after adsorption is finished, rotating the cylinder body to enable the positions of the water inlet and outlet valves 9, 10, 11 and 12 to be adjusted to a certain angle (such as 20-60 degrees in the radial direction of the bottommost part of the cylinder body), stopping rotating, standing for 1-20 minutes, and opening the water inlet and outlet valves 9, 10, 11 and 12 to enable supernatant to be discharged (accounting for 70-90 percent of the total volume of the liquid) after the adsorbent in the cylinder is naturally settled.
S5, then, adjusting and rotating the cylinder body to enable the water inlet and outlet valve to be positioned at the bottommost part (namely radial 0 degrees), and enabling residual liquid to pass through a porous medium of the water draining tank for filtering, so that the adsorbent is separated from the liquid.
S6, then adding the liquid to be treated, and circulating the processes from S2 to S5.

Claims (10)

1. The fluidized bed-like horizontal water treatment device is characterized by comprising a cylinder and a support, wherein the cylinder is horizontally arranged on the support and can rotate on the support;
the barrel is provided with a water inlet and outlet valve, and at least one draining groove is arranged in the barrel.
2. The fluidized bed-like horizontal water treatment apparatus as claimed in claim 1, wherein all of the water inlet and outlet valves are kept out of position with respect to the bracket.
3. The fluidized bed-like horizontal water treatment device according to claim 1, wherein the water inlet and outlet valve is connected with a metering pump.
4. The fluidized bed-like horizontal water treatment device according to claim 1, wherein at least one of a side feed port, an exhaust port and an auxiliary drain port is further provided at the end of the cylinder; and are all closable structures.
5. The fluidized bed-like horizontal water treatment apparatus as claimed in claim 1, wherein the inside of the cylinder is filled with an adsorbent or porous medium for water treatment.
6. The fluidized bed-like horizontal water treatment device as claimed in claim 1, wherein at least two of the water leaching tanks are respectively disposed on the side wall of the cylindrical cavity and are symmetrically arranged or uniformly distributed.
7. The fluidized bed-like horizontal water treatment apparatus as claimed in claim 1, wherein at least one of said draining tanks is a V-shaped mesh structure, and said water inlet and outlet valves are connected to a position of a cavity between the V-shaped mesh structure and the cylinder; the water inlet and outlet valve and the draining tank are matched with each other.
8. The fluidized bed-like horizontal water treatment apparatus as claimed in claim 1, wherein a vacuum pump is further connected to the exterior of the draining tank.
9. The fluidized bed-like horizontal water treatment device as claimed in claim 1, wherein the water inlet and outlet valves are provided with a filter screen or a filter cloth, or a water draining tank is provided with a filter screen or a filter cloth; the aperture of the filter screen or the filter cloth is 0.001-5mm.
10. The fluidized bed-like horizontal water treatment device according to claim 1, wherein a ring-shaped idler shaft is sleeved outside the cylinder body, or the idler shaft is integrally formed on the outer surface of the cylinder body; the riding wheel shaft is matched with the support, so that the cylinder body can rotate on the support.
CN202222303562.6U 2022-08-31 2022-08-31 Horizontal water treatment facilities of kind fluidized bed Active CN217972654U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202222303562.6U CN217972654U (en) 2022-08-31 2022-08-31 Horizontal water treatment facilities of kind fluidized bed

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202222303562.6U CN217972654U (en) 2022-08-31 2022-08-31 Horizontal water treatment facilities of kind fluidized bed

Publications (1)

Publication Number Publication Date
CN217972654U true CN217972654U (en) 2022-12-06

Family

ID=84262339

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202222303562.6U Active CN217972654U (en) 2022-08-31 2022-08-31 Horizontal water treatment facilities of kind fluidized bed

Country Status (1)

Country Link
CN (1) CN217972654U (en)

Similar Documents

Publication Publication Date Title
CN111729350B (en) Equipment for extracting lithium from brine by adsorption method
CN108002587A (en) A kind of sewage water treatment method of sewage-treatment plant and the application sewage-treatment plant
CN101474504A (en) Activated carbon fiber filter and regeneration method thereof
CN217972654U (en) Horizontal water treatment facilities of kind fluidized bed
CN110272134A (en) It is a kind of to accelerate active carbon to the coupling device of landfill leachate adsorption cleaning
CN104843819B (en) A kind of method of continuous processing heavy metal liquid
CN212700660U (en) Equipment for extracting lithium from brine by adsorption method
CN102489347B (en) Powder resin desorption regeneration reactor
CN207468314U (en) A kind of efficient sewage treatment installation
CN215465884U (en) Active carbon screening separation cooling device
CN207337948U (en) A kind of radioactivity seawater treatment apparatus
CN206232536U (en) Efficiently remove the sewage disposal system of heavy metal cadmium
CN210764749U (en) Factory sewage treatment tank capable of preventing peculiar smell
CN205973880U (en) Sewage treatment plant based on agent of chitosan infusibility humic acid adsorption
CN203183795U (en) Pressure tilting-pan filter
CN208562015U (en) A kind of water purifying device
CN112705451A (en) Active carbon screening separation cooling device
CN209317127U (en) A kind of vehicle-mounted multi-medium filtering purifier
CN202277745U (en) Centrifugal type sewage filter
CN207734701U (en) A kind of high-purity filter device for fine chemistry industry
CN207361812U (en) A kind of efficiently water purification quartz filter
CN102580370A (en) Quartz sand cushion active carbon filter with active carbon powder leakage preventing function
CN207361813U (en) A kind of efficiently water purification quartz filter
CN206262558U (en) A kind of high speed reactor equipment based on planting method fluorine removal water process
CN110002623A (en) A kind of dye wastewater treatment precipitation adsorption purification device

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant