CN217855586U - Horizontal stirring machine for protein powder - Google Patents

Horizontal stirring machine for protein powder Download PDF

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Publication number
CN217855586U
CN217855586U CN202222325527.4U CN202222325527U CN217855586U CN 217855586 U CN217855586 U CN 217855586U CN 202222325527 U CN202222325527 U CN 202222325527U CN 217855586 U CN217855586 U CN 217855586U
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CN
China
Prior art keywords
stirring
sampling
seats
pipe
positioning
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Expired - Fee Related
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CN202222325527.4U
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Chinese (zh)
Inventor
刘明新
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Shandong Dongheng Biotechnology Co ltd
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Shandong Dongheng Biotechnology Co ltd
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Priority to CN202222325527.4U priority Critical patent/CN217855586U/en
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Publication of CN217855586U publication Critical patent/CN217855586U/en
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Abstract

The utility model relates to the technical field of protein powder production, in particular to a horizontal protein powder stirrer, the angle of a stirring blade of which is adjustable, has a multi-sampling function, and improves the stirring and mixing effects by matching with professional mixing degree detection; the stirring device comprises a stirring box, a feeding hopper, a discharging pipe, a stirring pipe and a plurality of stirring blades, wherein the feeding hopper is arranged at the upper part of the stirring box, the discharging pipe is arranged at the lower part of the stirring box, the stirring pipe is rotatably arranged in the stirring box, and a driving motor is in transmission connection with the stirring pipe; still include two sample seats, gear motor, sampler and angle modulation mechanism, a plurality of stirring leaves rotate to be installed on the agitator pipe, angle modulation mechanism is connected with a plurality of stirring leaf transmissions, both ends about the upper portion at the agitator tank are installed to two sample seats, the sampler is installed to gear motor's lower extreme, the sampler stretches into in the agitator tank through the slide opening of sample seat, the sampler is provided with three sample cell, three sample cell is located the bottom of the stirring chamber of agitator tank respectively, middle part and top.

Description

Horizontal stirring machine for protein powder
Technical Field
The utility model relates to a technical field of albumen powder production especially relates to albumen powder horizontal mixer.
Background
In order to improve the comprehensiveness and the proportion balance of amino acids in protein powder and enable the types and proportions of the amino acids in the protein powder to meet the requirements of a human body better, multiple kinds of protein powder need to be mixed and stirred, for example, soybean protein powder and egg white protein powder are added into a horizontal stirrer according to a certain proportion, the horizontal stirrer is started to uniformly stir the two kinds of protein powder, most horizontal stirrers in the prior art do not have the function of uniform sampling, the angles of stirring blades are fixed, a small amount of protein powder needs to be stirred for a long time, and the discharge port discharges a small amount of protein powder.
SUMMERY OF THE UTILITY MODEL
In order to solve the technical problem, the utility model provides an angularly adjustable of stirring leaf has many places sample function, and the degree of mixing of cooperation specialty detects, improves the stirring and mixes the protein powder horizontal mixer of effect.
The utility model discloses a horizontal mixer for protein powder, including agitator tank, loading hopper, discharging pipe, agitator tube and a plurality of stirring leaf, the lower part of agitator tank is provided with a plurality of landing legs, the inside of agitator tank is provided with the stirring cavity, the upper portion of agitator tank is provided with the loading hopper, the lower part of agitator tank is provided with the discharging pipe, loading hopper and discharging pipe all communicate with the stirring cavity of agitator tank, the agitator tube rotates to be installed in the stirring cavity of agitator tank, the agitator tube horizontal arrangement, driving motor installs in the external world of agitator tank, driving motor passes through the transmission assembly and is connected with the agitator tube transmission; the device comprises a stirring box, a plurality of stirring blades, a speed reducing motor, a sampler and an angle adjusting mechanism, wherein the stirring blades are rotatably arranged on the outer wall of the stirring pipe, the angle adjusting mechanism is arranged in the stirring pipe and is in transmission connection with the stirring blades, the two sampling seats are respectively arranged at the left end and the right end of the upper part of the stirring box, vertical sliding holes are respectively arranged in the middle parts of the two sampling seats, the two sliding holes are communicated with a stirring chamber of the stirring box, the sampler is arranged at the lower end of the speed reducing motor, the sampler extends into the stirring chamber of the stirring box through the sliding holes of the sampling seats, the speed reducing motor is located on the sampling seats, the sampler is provided with three sampling units, and the three sampling units are respectively located at the bottom, the middle part and the top part of the stirring chamber of the stirring box; adding two or more different protein powders into a stirring chamber of a stirring box through a hopper according to a certain proportion, adjusting the angles of a plurality of stirring blades through an angle adjusting mechanism, starting a driving motor, driving the stirring pipe and the stirring blades to rotate by the driving motor, stirring the protein powders by the stirring blades, stirring for a period of time, reversely adjusting the angles of the stirring blades by the adjusting mechanism, so that the protein powders are stirred in different directions by the stirring blades, after stirring for a plurality of times, respectively inserting a sampler into slide holes of two sampling seats, starting a speed reduction motor to drive the sampler to operate for sampling, obtaining the bottoms of the front part of the stirring chamber of the stirring box, the middle part and the top part of the stirring chamber and the bottom of the rear part of the stirring chamber, obtaining six samples in the total parts of the middle part and the top part, sending the six samples into an infrared spectrum analyzer to determine the mixing proportion of the multiple protein powders in the samples, when the mixing proportion of the multiple protein powders in the six samples is consistent with the total proportion of the input, judging that all the protein powders in the stirring chamber are uniformly mixed, adjusting mechanism at the angle of the stirring blades at the stirring chamber, opening the discharging pipe, enabling the stirring pipe to meet the requirement of the stirring blade of the stirring mechanism, and improving the effect of the stirring discharge of the stirring pipe, and promoting the stirring blade of the stirring chamber.
Preferably, the sampler comprises a sampling tube, three partition plates, a screw rod, three screw augers and a cover plate, wherein the upper end of the sampling tube is concentrically connected with the lower end face of a gear motor, the front side wall of the sampling tube is provided with a sampling notch, the three partition plates are uniformly arranged in the sampling tube, the three partition plates and the bottom wall of the sampling tube form three sampling spaces, the upper end of the screw rod is concentrically and drivingly connected with an output shaft of the gear motor, the lower end of the screw rod penetrates through the three partition plates to be rotatably connected with the bottom wall of the sampling tube, the contact surfaces of the screw rod and the three partition plates are provided with wear-resistant sealing rings, the three screw augers are arranged on the screw rod, the three screw augers are respectively positioned at the bottoms of the three sampling spaces, the cover plate is buckled on the sampling notch of the sampling tube, the cover plate is provided with three feeding square holes, and the three feeding square holes are respectively aligned with the three screw augers; when taking a sample, the slide opening that passes the sampling tube sample seat stretches into in the stirring cavity of agitator tank, with gear motor on the sample seat, open gear motor, gear motor drive auger pole and three auger rotate, the albumen powder of the sampling tube that three feeding side hole that pivoted three auger will get into through the apron promotes the upper portion in three sample space, when the lower terminal surface contact of albumen powder and three baffle is filled up three sample space, stop gear motor, take out the sampling tube from the sample seat, open the apron, take out the triplicate sample, accomplish sample work, it is convenient to take a sample, and is fast, because the sampling tube avoids a plurality of stirring leaves, need not shut down during the sample, and the practicality is high.
Preferably, the device also comprises three pressure sensors, wherein the three pressure sensors are respectively arranged on the lower end surfaces of the three partition plates, and are electrically connected with a controller of the speed reducing motor; during the sample, when albumen powder got into the sampling tube and when three baffle contact, pressure sensor detected albumen powder to the pressure of baffle, and when pressure reached a definite value, three pressure sensor signals made the controller stop gear motor, conveniently controlled the quantity of sample, made the sample compact simultaneously, improve equipment's practicality.
Preferably, the sampling device further comprises a plurality of positioning columns and a plurality of column holes, the upper end surfaces of the two sampling seats are respectively provided with the plurality of positioning columns, the lower end surface of the speed reducing motor is provided with the plurality of column holes, and the plurality of column holes are respectively matched and aligned with the plurality of positioning columns on the sampling seats; when gear motor is located on the sample seat, during a plurality of reference columns inject a plurality of post holes respectively, fix a position gear motor, stability when improving the sample.
Preferably, the sampling device further comprises two closed cover plates, one ends of the two closed cover plates are respectively rotatably installed on the side walls of the two sampling seats through rotating shafts, and the two closed cover plates respectively shield the sliding holes of the two sampling seats; during the stirring work, two close the apron cover the slide opening of two sample seats, avoid the albumen powder to spill, and the sample during operation promotes two close the apron and rotates, rotates two sample seats's the outside with two close the apron, opens the slide opening of two sample seats, makes things convenient for the sample, improve equipment's practicality.
Preferably, the angle adjusting mechanism comprises a plurality of gear shafts, a shaft lever and a plurality of driving bevel gears, the gear shafts are arranged at the inner ends of the stirring blades, the middle parts of the gear shafts are respectively and rotatably connected with the outer wall of the stirring pipe through bearings, the bevel gears are arranged at the inner ends of the gear shafts, the shaft lever is concentrically and rotatably arranged in the stirring pipe, the driving bevel gears are arranged on the shaft lever, the driving bevel gears are respectively in meshing transmission with the bevel gears of the gear shafts, the outer end of the shaft lever extends out of the stirring pipe, and a square block is arranged at the outer end of the shaft lever; when adjusting the angle of a plurality of stirring leaves, use instrument centre gripping squares such as spanner to rotate the axostylus axostyle for the axostylus axostyle drives a plurality of drive bevel gear and rotates certain angle, and a plurality of drive bevel gears rotate certain angle through a plurality of gear shafts of a plurality of bevel gear synchronous drive together with a plurality of stirring leaves in step, realize the synchronous angle regulation of a plurality of stirring leaves, conveniently carry out multi-directional stirring and push away the material when arranging the material, improve equipment's work efficiency.
Preferably, the stirring device further comprises a plurality of positioning seats and a positioning swing arm, the outer end face of the stirring pipe is circularly and uniformly provided with the plurality of positioning seats, the plurality of positioning seats are respectively provided with a positioning hole, one end of the positioning swing arm is connected with the shaft rod, the other end of the positioning swing arm is provided with a plug pin hole, the plug pin hole is aligned with the positioning hole of the positioning seat, and the positioning pin penetrates through the plug pin hole of the positioning swing arm and is inserted into the positioning hole of the positioning seat; after the angle of a plurality of stirring leaves is adjusted to the rotation axostylus axostyle, pass the bolt hole of location swing arm with the locating pin and insert corresponding initiative bevel gear's locating hole, with the position locking of axostylus axostyle, when avoiding the stirring, a plurality of stirring leaf angles change, improve equipment's stability.
Compared with the prior art, the beneficial effects of the utility model are that: adding two or more different protein powders into a stirring chamber of a stirring box through a hopper according to a certain proportion, adjusting the angles of a plurality of stirring blades through an angle adjusting mechanism, starting a driving motor, driving the stirring pipe and the stirring blades to rotate by the driving motor, stirring the protein powders by the stirring blades, stirring for a period of time, reversely adjusting the angles of the stirring blades by the adjusting mechanism, so that the protein powders are stirred in different directions by the stirring blades, after stirring for a plurality of times, respectively inserting a sampler into slide holes of two sampling seats, starting a speed reduction motor to drive the sampler to operate for sampling, obtaining the bottoms of the front part of the stirring chamber of the stirring box, the middle part and the top part of the stirring chamber and the bottom of the rear part of the stirring chamber, obtaining six samples in the total parts of the middle part and the top part, sending the six samples into an infrared spectrum analyzer to determine the mixing proportion of the multiple protein powders in the samples, when the mixing proportion of the multiple protein powders in the six samples is consistent with the total proportion of the input, judging that all the protein powders in the stirring chamber are uniformly mixed, adjusting mechanism at the angle of the stirring blades at the stirring chamber, opening the discharging pipe, enabling the stirring pipe to meet the requirement of the stirring blade of the stirring mechanism, and improving the effect of the stirring discharge of the stirring pipe, and promoting the stirring blade of the stirring chamber.
Drawings
FIG. 1 is a schematic view of the present invention;
FIG. 2 is a schematic view of a half-section axial structure of the present invention;
FIG. 3 is an enlarged schematic structural view of the structure of the stirring tube, the stirring blade, the angle adjusting mechanism and the like;
FIG. 4 is an exploded and enlarged view of the reduction motor and the sampler;
in the drawings, the reference numbers: 1. a stirring box; 2. a hopper; 3. a discharge pipe; 4. a stirring pipe; 5. stirring blades; 6. a sampling seat; 7. a reduction motor; 8. a sampler; 9. a sampling tube; 10. a partition plate; 11. a screw rod; 12. a packing auger; 13. a cover plate; 14. a pressure sensor; 15. a positioning column; 16. a post hole; 17. closing the cover plate; 18. a gear shaft; 19. a shaft lever; 20. a drive bevel gear; 21. positioning seats; 22. and positioning the swing arm.
Detailed Description
In order to facilitate understanding of the present invention, the present invention will be described more fully hereinafter with reference to the accompanying drawings. The present invention may be embodied in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Examples
As shown in fig. 4, the sampler 8 includes a sampling tube 9, three partition plates 10, a sampling rod 11, three packing augers 12 and a cover plate 13, the upper end of the sampling tube 9 is concentrically connected with the lower end face of the gear motor 7, the front side wall of the sampling tube 9 is provided with a sampling notch, the three partition plates 10 are uniformly arranged in the sampling tube 9, the three partition plates 10 and the bottom wall of the sampling tube 9 form three sampling spaces, the upper end of the packing auger rod 11 is concentrically connected with the output shaft of the gear motor 7 in a transmission manner, the lower end of the packing auger rod 11 passes through the three partition plates 10 to be rotatably connected with the bottom wall of the sampling tube 9, the contact surfaces of the packing auger rod 11 and the three partition plates 10 are provided with wear-resistant sealing rings, the three packing augers 12 are mounted on the packing auger rod 11, the three packing augers 12 are respectively located at the bottoms of the three sampling spaces, the cover plate 13 is buckled on the sampling notch of the sampling tube 9, the cover plate 13 is provided with three feeding square holes, and the three feeding square holes are respectively aligned with the three packing augers 12; the three pressure sensors 14 are respectively arranged on the lower end faces of the three partition plates 10, and the three pressure sensors 14 are electrically connected with a controller of the speed reducing motor 7; the threshold values of three pressure sensors 14 are set before sampling, when sampling is carried out in the stirring process, the sampling tube 9 penetrates through a sliding hole of a sampling seat 6 and extends into a stirring chamber of a stirring box 1, a speed reduction motor 7 is located on the sampling seat 6, the speed reduction motor 7 is started, the speed reduction motor 7 drives a screw rod 11 and three screw conveyors 12 to rotate, protein powder of the sampling tube 9 entering through three feeding square holes of a cover plate 13 is pushed to the upper parts of three sampling spaces by the rotating three screw conveyors 12, the protein powder is in contact with the lower end faces of three partition plates 10, the pressure sensors 14 detect the pressure of the protein powder on the partition plates 10, when the pressure reaches a certain value, the three pressure sensors 14 send signals to enable a controller to stop the speed reduction motor 7, after the speed reduction motor 7 stops, the sampling tube 9 is taken out from the sampling seat 6, the cover plate 13 is opened, three samples are taken out, or the sampling tube 9 is directly extended into an infrared spectrum analyzer, composition analysis is carried out on the three samples in the sampling tube 9, and the samples taken out are put back into the stirring box 1 again after the analysis is finished.
As shown in fig. 1 to 4, the utility model discloses a protein powder horizontal mixer, it is at the during operation, at first add the stirring cavity of agitator tank 1 through loading hopper 2 with two kinds or multiple different protein powder according to certain proportion, use instrument centre gripping squares such as spanner to rotate axostylus axostyle 19, make a plurality of stirring leaf 5 synchronous rotation certain angle, later start driving motor, driving motor drive stirring pipe 4 and a plurality of stirring leaf 5 rotate, a plurality of stirring leaf 5 stir the protein powder, after stirring a period, the angle of a plurality of stirring leaf 5 of reverse regulation of reverse axostylus axostyle 19, make a plurality of stirring leaf 5 carry out the stirring of equidirectional to the protein powder, after stirring many times, then inject sampler 8 respectively in the slide opening of two sample holders 6, start gear motor 7 drive sampler 8 operation and take a sample, gain the anterior bottom of stirring cavity of agitator tank 1 altogether, middle part and top and the bottom at stirring cavity rear portion, middle part and top are total six sample altogether, open apron 13 and send into this six sample's sample the mixing proportion of the mixture powder in the infrared spectroscopy survey sample, the stirring powder, the stirring leaf can drive the stirring leaf 3 the stirring leaf in the stirring discharge pipe 3 all the stirring leaf of stirring leaf 5 of stirring leaf in the stirring discharge pipe, the stirring box 5 the stirring leaf of the stirring leaf can drive the stirring leaf when the stirring leaf 5 unanimity, make the stirring leaf 3 total stirring leaf of the stirring leaf of stirring leaf in the stirring leaf 5 unanimous stirring discharge pipe, the stirring leaf of the stirring powder.
The utility model discloses the main function who realizes does: the angle of the stirring blade is adjustable, the stirring blade has a multi-sampling function, and is matched with professional mixing degree detection, so that the proportion of various amino acids in a product meets the requirement, and the stirring and mixing effect is improved.
The installation mode, the connection mode or the arrangement mode of the horizontal protein powder stirrer of the utility model are common mechanical modes, and the horizontal protein powder stirrer can be implemented as long as the beneficial effects can be achieved; the utility model discloses a protein powder horizontal mixer's agitator tank 1, loading hopper 2, discharging pipe 3, stirred tubular 4, a plurality of stirring leaf 5, gear motor 7, auger 12, pressure sensor 14, gear shaft 18, initiative bevel gear 20, positioning seat 21 are purchase on the market, this industry technical staff only need according to its subsidiary operating specification install and operate can, and need not the technical staff in the field and pay out creative work.
All technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, a plurality of modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.

Claims (7)

1. The horizontal protein powder stirring machine comprises a stirring box (1), a feeding hopper (2), a discharging pipe (3), a stirring pipe (4) and a plurality of stirring blades (5), wherein a plurality of supporting legs are arranged at the lower part of the stirring box (1), a stirring cavity is arranged inside the stirring box (1), the feeding hopper (2) is arranged at the upper part of the stirring box (1), the discharging pipe (3) is arranged at the lower part of the stirring box (1), the feeding hopper (2) and the discharging pipe (3) are both communicated with the stirring cavity of the stirring box (1), the stirring pipe (4) is rotatably arranged in the stirring cavity of the stirring box (1), the stirring pipe (4) is horizontally arranged, a driving motor is arranged outside the stirring box (1), and the driving motor is in transmission connection with the stirring pipe (4) through a transmission assembly; the device is characterized by further comprising two sampling seats (6), a speed reducing motor (7), a sampler (8) and an angle adjusting mechanism, wherein the stirring blades (5) are rotatably installed on the outer wall of the stirring pipe (4), the angle adjusting mechanism is installed in the stirring pipe (4) and is in transmission connection with the stirring blades (5), the two sampling seats (6) are respectively installed at the left end and the right end of the upper portion of the stirring box (1), vertical sliding holes are formed in the middle of the two sampling seats (6), the sliding holes are communicated with the stirring cavity of the stirring box (1), the sampler (8) is installed at the lower end of the speed reducing motor (7), the sampler (8) extends into the stirring cavity of the stirring box (1) through the sliding holes of the sampling seats (6), the speed reducing motor (7) is located on the sampling seats (6), the sampler (8) is provided with three sampling units, and the three sampling units are respectively located at the bottom, the middle and the top of the stirring cavity of the stirring box (1).
2. The horizontal protein powder stirring machine according to claim 1, wherein the sampler (8) comprises a sampling tube (9), three partition plates (10), an auger rod (11), three augers (12) and a cover plate (13), the upper end of the sampling tube (9) is concentrically connected with the lower end face of the gear motor (7), the front side wall of the sampling tube (9) is provided with a sampling notch, the three partition plates (10) are uniformly arranged in the sampling tube (9), the three partition plates (10) and the bottom wall of the sampling tube (9) form three sampling spaces, the upper end of the auger rod (11) is concentrically connected with the output shaft of the gear motor (7) in a transmission manner, the lower end of the auger rod (11) penetrates through the three partition plates (10) to be rotatably connected with the bottom wall of the sampling tube (9), the contact faces of the auger rod (11) and the three partition plates (10) are provided with wear-resistant sealing rings, the three augers (12) are mounted on the auger rod (11), the three augers (12) are respectively located at the bottoms of the three sampling spaces, the cover plate (9) is buckled on the cover plate (9), and the cover plate (13) is provided with three sampling notches (13) aligned with three square feeding holes (12).
3. The horizontal protein powder stirring machine according to claim 2, further comprising three pressure sensors (14), wherein the three pressure sensors (14) are respectively installed on the lower end faces of the three partition plates (10), and the three pressure sensors (14) are electrically connected with a controller of the speed reducing motor (7).
4. The horizontal protein powder stirring machine according to claim 1, further comprising a plurality of positioning posts (15) and a plurality of post holes (16), wherein the plurality of positioning posts (15) are disposed on the upper end surfaces of the two sampling seats (6), the plurality of post holes (16) are disposed on the lower end surface of the speed reduction motor (7), and the plurality of post holes (16) are respectively aligned with the plurality of positioning posts (15) on the sampling seats (6).
5. The horizontal type protein powder stirring machine as claimed in claim 1, further comprising two closed cover plates (17), wherein one ends of the two closed cover plates (17) are rotatably mounted on the side walls of the two sampling seats (6) through rotating shafts respectively, and the two closed cover plates (17) shield the sliding holes of the two sampling seats (6) respectively.
6. The horizontal protein powder stirring machine as claimed in claim 1, wherein the angle adjusting mechanism comprises a plurality of gear shafts (18), a shaft rod (19) and a plurality of driving bevel gears (20), the gear shafts (18) are mounted at the inner ends of the stirring blades (5), the middle parts of the gear shafts (18) are respectively rotatably connected with the outer wall of the stirring pipe (4) through bearings, the bevel gears are arranged at the inner ends of the gear shafts (18), the shaft rod (19) is concentrically and rotatably mounted in the stirring pipe (4), the driving bevel gears (20) are arranged on the shaft rod (19), the driving bevel gears (20) are respectively in meshing transmission with the bevel gears of the gear shafts (18), the outer end of the shaft rod (19) extends out of the stirring pipe (4), and the outer end of the shaft rod (19) is provided with a square block.
7. The horizontal protein powder stirring machine according to claim 6, further comprising a plurality of positioning seats (21) and a positioning swing arm (22), wherein the plurality of positioning seats (21) are uniformly arranged on the outer end surface of the stirring pipe (4) in a circular shape, positioning holes are formed in each of the plurality of positioning seats (21), one end of the positioning swing arm (22) is connected with the shaft rod (19), a pin hole is formed in the other end of the positioning swing arm (22), the pin hole is aligned with the positioning hole of the positioning seat (21), and the positioning pin penetrates through the pin hole of the positioning swing arm (22) and is inserted into the positioning hole of the positioning seat (21).
CN202222325527.4U 2022-09-01 2022-09-01 Horizontal stirring machine for protein powder Expired - Fee Related CN217855586U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202222325527.4U CN217855586U (en) 2022-09-01 2022-09-01 Horizontal stirring machine for protein powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202222325527.4U CN217855586U (en) 2022-09-01 2022-09-01 Horizontal stirring machine for protein powder

Publications (1)

Publication Number Publication Date
CN217855586U true CN217855586U (en) 2022-11-22

Family

ID=84080680

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202222325527.4U Expired - Fee Related CN217855586U (en) 2022-09-01 2022-09-01 Horizontal stirring machine for protein powder

Country Status (1)

Country Link
CN (1) CN217855586U (en)

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20221122

CF01 Termination of patent right due to non-payment of annual fee