CN216978771U - An in-situ test system for anti-erosion-corrosion of boiler heating surface - Google Patents

An in-situ test system for anti-erosion-corrosion of boiler heating surface Download PDF

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CN216978771U
CN216978771U CN202123359625.1U CN202123359625U CN216978771U CN 216978771 U CN216978771 U CN 216978771U CN 202123359625 U CN202123359625 U CN 202123359625U CN 216978771 U CN216978771 U CN 216978771U
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corrosion
erosion
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combustion
boiler
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刘欢
李鉴全
张秀菊
李海燕
陈同舟
姚洪
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Huazhong University of Science and Technology
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Abstract

The utility model provides an erosion-corrosion resistance in-situ test system for a heating surface of a boiler, belonging to the field of test equipment, and the system comprises a combustion simulation device and an erosion-corrosion test device, wherein: the combustion simulation device comprises a feeding unit, a combustor and a combustion chamber which are sequentially connected from top to bottom; meanwhile, a combustion area electric heater and a sample area electric heater are arranged outside the combustion chamber; the erosion-corrosion device comprises an ash corrosion platform, a circulating water temperature control unit and a camera, wherein the ash corrosion platform extends into the combustion chamber; the circulating water temperature control unit is connected with the ash corrosion platform; the camera is arranged on the outer side of the combustion chamber visual window. The utility model can simulate the whole process of fuel ignition, combustion, fly ash impact, fly ash deposition and adhesion and corrosion reaction in the minimum space, realize the rapid evaluation of the erosion-corrosion resistance of the material under the complex coupling corrosion condition, and provide guidance for the optimization of corrosion-resistant materials at different parts in the boiler.

Description

一种锅炉受热面抗冲蚀-腐蚀原位试验系统An in-situ test system for the erosion-corrosion resistance of the heating surface of the boiler

技术领域technical field

本实用新型属于试验设备领域,更具体地,涉及一种锅炉受热面抗冲蚀- 腐蚀原位试验系统。The utility model belongs to the field of test equipment, and more particularly relates to an erosion-corrosion in-situ test system for a heating surface of a boiler.

背景技术Background technique

固体燃料的燃烧是火力发电的主要方式,燃料类型包括煤、生物质和固体废弃物等可以产生热能或动力的固态可燃物质。随着我国能源需求量的不断增长,新疆地区的高钠煤、西南地区的高硫煤、生物质以及固体废弃物也更为广泛地用于燃烧发电。然而,由于这些燃料中含有不同含量的钠、钾、硫、氯元素,在燃烧过程中锅炉换热面会产生冲蚀-腐蚀问题。冲蚀指的是具有一定速度的硬质颗粒与材料表面相接触并产生冲击从而导致材料出现损耗的过程。高温腐蚀主要是指金属材料在高温条件下的氧化腐蚀,导致金属材料损耗的现象。上述固体燃料在燃烧过程中产生的大量飞灰颗粒,其中一部分在高温烟气的携带下以较大的速度对锅炉受热面换热管束进行冲刷,导致换热管材不断消耗;其余的则在涡流、热泳及惯性撞击的作用下粘附沉积在换热管表面并在高温下形成熔融物质对换热管材产生腐蚀,称为沉积相腐蚀。除此之外,燃料燃烧产生的烟气中含有HCl、SO2等腐蚀性气体也将对换热管材产生腐蚀作用,称为气相腐蚀。值得注意的是,实际炉内服役环境下沉积相腐蚀和气相腐蚀同时存在,产生气固耦合腐蚀。同时受热面管束受到飞灰和烟气的冲蚀-腐蚀耦合作用,冲蚀对锅炉受热面管束表面结构的破坏会加剧灰沉积腐蚀的过程,腐蚀对管束表面粗糙度的作用也会影响飞灰的冲蚀过程。这种耦合作用对管束的破坏比单一的冲蚀或者腐蚀更严重,将会产生“爆管”等问题,极大地影响了电力生产的安全性和经济性。Combustion of solid fuels is the main way of thermal power generation. Fuel types include solid combustible substances that can generate heat or power, such as coal, biomass and solid waste. With the continuous growth of my country's energy demand, high-sodium coal in Xinjiang, high-sulfur coal in southwest China, biomass and solid waste are also more widely used for combustion power generation. However, due to the different contents of sodium, potassium, sulfur, and chlorine in these fuels, erosion-corrosion problems occur on the heat exchange surface of the boiler during the combustion process. Erosion refers to the process in which hard particles with a certain velocity come into contact with the surface of the material and produce an impact that causes the material to be lost. High temperature corrosion mainly refers to the oxidative corrosion of metal materials under high temperature conditions, resulting in the loss of metal materials. A large number of fly ash particles generated during the combustion of the above solid fuels, some of which are carried by the high-temperature flue gas, scour the heat exchange tube bundles on the heating surface of the boiler at a large speed, resulting in continuous consumption of heat exchange tubes; the rest are in the vortex flow. , under the action of thermophoresis and inertial impact, it adheres and deposits on the surface of the heat exchange tube and forms a molten material at high temperature to corrode the heat exchange tube, which is called deposition phase corrosion. In addition, the flue gas generated by fuel combustion contains corrosive gases such as HCl and SO 2 , which will also corrode the heat exchange pipes, which is called gas phase corrosion. It is worth noting that deposition phase corrosion and vapor phase corrosion coexist in the actual service environment of the furnace, resulting in gas-solid coupling corrosion. At the same time, the heating surface tube bundle is subjected to the erosion-corrosion coupling effect of fly ash and flue gas. The damage to the surface structure of the boiler heating surface tube bundle by erosion will aggravate the process of ash deposition and corrosion, and the effect of corrosion on the surface roughness of the tube bundle will also affect the fly ash. erosion process. The damage to the tube bundle caused by this coupling effect is more serious than that of single erosion or corrosion, which will cause problems such as "tube burst", which greatly affects the safety and economy of power production.

在锅炉换热管表面应用涂层技术或新型材料将有效地提高锅炉受热面换热管的抗冲蚀-腐蚀性能,延长锅炉的服役年限,具有十分广阔的应用前景。为实现优选涂层和新型材料的目的,对应用的涂层和新型材料进行抗冲蚀-腐蚀性能试验是十分有必要的。然而,在现场环境下测试材料的性能测试周期长、经济成本高、实用性较差,因此在实验室内实现材料性能的快速、准确地评估十分重要。前以述及,在实际炉内,换热面管材所处的服役环境更为复杂且恶劣,除管壁沉积相腐蚀以外,烟气中的HCl、SO2等腐蚀性气体也会对管壁造成腐蚀,同时烟气中高速流动的飞灰颗粒与受热面发生碰撞会造成管壁的冲蚀破坏。为提高测试结果的准确性和可靠性,实现为现场应用提供指导的目的,搭建原位模拟燃料飞灰对受热面的冲蚀及烟气耦合腐蚀的试验装置,实现待测材料抗冲蚀-腐蚀性能的快速评估是十分有必要的。The application of coating technology or new materials on the surface of the boiler heat exchange tube will effectively improve the erosion-corrosion resistance of the heat exchange tube on the heating surface of the boiler, prolong the service life of the boiler, and have a very broad application prospect. In order to achieve the purpose of optimizing coatings and new materials, it is necessary to conduct erosion-corrosion performance tests on applied coatings and new materials. However, the performance testing cycle of testing materials in the field environment is long, the economic cost is high, and the practicability is poor, so it is very important to realize the rapid and accurate evaluation of material performance in the laboratory. As mentioned above, in the actual furnace, the service environment of the heat exchange surface pipes is more complex and harsh. In addition to the corrosion of the pipe wall deposition phase, the corrosive gases such as HCl and SO 2 in the flue gas will also affect the pipe wall. At the same time, the collision between the high-speed flow of fly ash particles in the flue gas and the heating surface will cause erosion damage to the pipe wall. In order to improve the accuracy and reliability of the test results and provide guidance for field application, a test device was built to simulate the erosion of fuel fly ash on the heating surface and the coupled corrosion of flue gas, so as to realize the erosion resistance of the material to be tested- A rapid assessment of corrosion performance is necessary.

现有技术对腐蚀领域试验进行了不同程度的研究,CN111323364A公开了一种均匀化沉积盐热腐蚀试验装置及方法,其主要是利用雾化器将盐溶液雾化后,在材料表面沉积形成腐蚀盐膜。CN106769822A公开了一种高温腐蚀试验系统,其利用旋风混气罐和水蒸气探究仅腐蚀性气体和高温水蒸气存在条件下材料耐腐蚀性能的系统。上述研究多应用纯物质作为腐蚀介质以及在单一腐蚀条件下开展材料试验。进一步地,CN209878565U公开了一种燃烧气氛下耐热材料抗热腐蚀试验装置,通过使用燃烧器燃烧产生的烟气模拟真实气氛中的腐蚀条件,其测试样品以焊接的方式连成空心管状,内部流过烟气,通过外部流过冷却介质控制样品温度;但该试验装置无法控制燃料的充分燃烧以及烟气的温度,也无法评估材料的抗冲蚀性能。部分学者研究了冲蚀-腐蚀试验装置,例如CN109856036A公开了一种高温高压气、液、固三相冲刷腐蚀试验装置及方法,CN112284953A公开了海洋变温模拟环境下多元介质腐蚀-冲蚀耦合试验装置,着眼于研究模拟海洋变温环境下材料在盐雾气氛中抗冲蚀-腐蚀耦合性能,CN103149144A提出了一种油井管柱高温腐蚀冲蚀性能试验装置及方法,冲蚀介质为砂粒。上述试验装置主要应用于海洋环境或油田环境中,缺少可以应用于锅炉的冲蚀-腐蚀耦合试验装置。The prior art has carried out different degrees of research on corrosion field tests. CN111323364A discloses a homogenized deposition salt thermal corrosion test device and method, which mainly uses an atomizer to atomize the salt solution and deposit on the material surface to form corrosion Salt film. CN106769822A discloses a high temperature corrosion test system, which utilizes a cyclone gas mixing tank and water vapor to explore the corrosion resistance performance of materials under the condition that only corrosive gas and high temperature water vapor exist. The above studies mostly use pure substances as corrosive media and carry out material tests under single corrosive conditions. Further, CN209878565U discloses a test device for thermal corrosion resistance of heat-resistant materials in a combustion atmosphere, which simulates the corrosion conditions in the real atmosphere by using the flue gas generated by the combustion of the burner, and the test samples are connected into a hollow tube shape by welding, and the interior is hollow. The temperature of the sample is controlled by flowing through the flue gas and external cooling medium; however, the test device cannot control the sufficient combustion of the fuel and the temperature of the flue gas, nor can it evaluate the erosion resistance of the material. Some scholars have studied erosion-corrosion test devices. For example, CN109856036A discloses a high-temperature and high-pressure gas, liquid, and solid three-phase erosion corrosion test device and method, and CN112284953A discloses a multi-media corrosion-erosion coupling test device in an ocean temperature-variable simulated environment. , focusing on studying the erosion-corrosion coupling performance of materials in a salt spray atmosphere in a simulated ocean temperature environment, CN103149144A proposes a test device and method for high-temperature corrosion erosion performance of oil well pipe strings, and the erosion medium is sand. The above-mentioned test devices are mainly used in marine environment or oil field environment, and there is no erosion-corrosion coupling test device that can be applied to boilers.

综上,现有申请或授权专利主要存在以下问题:To sum up, the existing applications or granted patents mainly have the following problems:

腐蚀类型多为电化学腐蚀,腐蚀温度达不到实际炉内换热面的管壁温度且无法原位地模拟燃料从着火、燃烧、飞灰撞击、飞灰沉积到腐蚀的全过程,无法实现待测材料耐冲蚀-腐蚀性能的快速评估;The corrosion type is mostly electrochemical corrosion, the corrosion temperature cannot reach the tube wall temperature of the actual heat exchange surface in the furnace, and it is impossible to simulate the whole process of fuel from ignition, combustion, fly ash impact, fly ash deposition to corrosion in situ, which cannot be realized. Rapid evaluation of erosion-corrosion resistance of materials to be tested;

腐蚀介质多采用盐溶液等纯物质,与实际燃料飞灰成分差异巨大,且腐蚀介质较为单一,或是仅模拟了单相腐蚀介质的腐蚀,无法实现对材料在复杂耦合腐蚀条件下的耐冲蚀-腐蚀性能的合理预测;The corrosive medium mostly uses pure substances such as salt solution, which is very different from the actual fuel fly ash composition, and the corrosive medium is relatively single, or only simulates the corrosion of a single-phase corrosive medium, and cannot achieve the impact resistance of the material under complex coupled corrosion conditions. Reasonable prediction of corrosion-corrosion performance;

缺少对飞灰颗粒在试样表面沉积并发生腐蚀反应的动态过程研究,在试样温度产生较大波动的情况下无法迅速、准确地调节试样的温度,将造成待测试样冲蚀-腐蚀性能评估结果的巨大偏差。There is a lack of research on the dynamic process of fly ash particles deposited on the surface of the sample and the corrosion reaction occurs. When the temperature of the sample fluctuates greatly, the temperature of the sample cannot be adjusted quickly and accurately, which will cause the test sample to be eroded- Large deviations in corrosion performance assessment results.

实用新型内容Utility model content

针对现有技术的缺陷,本实用新型的目的在于提供一种锅炉受热面抗冲蚀-腐蚀原位试验系统,旨在解决现有的试验系统无法模拟锅炉内部各位置抗冲蚀-腐蚀性能的问题。In view of the defects of the prior art, the purpose of this utility model is to provide a boiler heating surface anti-erosion-corrosion in-situ test system, aiming to solve the problem that the existing test system cannot simulate the anti-erosion-corrosion performance of each position inside the boiler question.

为实现上述目的,本实用新型提供了一种锅炉受热面抗冲蚀-腐蚀原位试验系统,该系统包括燃烧模拟装置和冲蚀-腐蚀试验装置,其中:In order to achieve the above purpose, the utility model provides a boiler heating surface anti-erosion-corrosion in-situ test system, the system includes a combustion simulation device and an erosion-corrosion test device, wherein:

所述燃烧模拟装置包括从上至下依次连接的进料单元、燃烧器和燃烧室,以模拟实际燃烧过程的烟气环境;同时该燃烧室的外部从上至下依次设置有燃烧区电加热器和样品区电加热器,用于对烟气和待测试样进行分开加热,并且该燃烧室的下方设置有可视窗口;The combustion simulation device includes a feeding unit, a burner and a combustion chamber sequentially connected from top to bottom to simulate the flue gas environment of the actual combustion process; at the same time, the outside of the combustion chamber is sequentially provided with a combustion zone electric heater from top to bottom The heater and the sample area electric heater are used to separately heat the flue gas and the sample to be tested, and a visual window is provided under the combustion chamber;

所述冲蚀-腐蚀试验装置包括灰腐蚀平台、循环水控温单元和相机,所述灰腐蚀平台伸入所述燃烧室的内部,用于放置待测试样并进行冲蚀-腐蚀试验;所述循环水控温单元与灰腐蚀平台连接,以控制所述待测试样的温度;所述相机设置在燃烧室可视窗口的外侧,以实时观察所述待测试样的冲蚀-腐蚀过程。The erosion-corrosion test device includes an ash corrosion platform, a circulating water temperature control unit and a camera, and the ash corrosion platform extends into the interior of the combustion chamber for placing a sample to be tested and performing an erosion-corrosion test; The circulating water temperature control unit is connected to the ash corrosion platform to control the temperature of the sample to be tested; the camera is arranged outside the visible window of the combustion chamber to observe the erosion of the sample to be tested in real time- corrosion process.

作为进一步优选的,所述进料单元包括固体燃料进料斗、固体燃料进料管和燃烧气体进气管,所述固体燃料进料斗与固体燃料进料管连接,用于向所述燃烧器通入固体燃料或飞灰;所述燃烧气体进气管用于向所述燃烧器通入燃烧气体或烟气。As a further preference, the feeding unit includes a solid fuel feeding hopper, a solid fuel feeding pipe and a combustion gas intake pipe, the solid fuel feeding hopper is connected with the solid fuel feeding pipe, and is used for feeding the burner to the burner. Solid fuel or fly ash is introduced; the combustion gas inlet pipe is used for introducing combustion gas or flue gas to the burner.

作为进一步优选的,所述固体燃料进料斗包括物料加热器和给料电机,所述物料加热器用于对固体燃料或飞灰进行预热,所述给料电机用于控制所述固体燃料或飞灰的给料速率。As a further preference, the solid fuel feeding hopper includes a material heater and a feeding motor, the material heater is used to preheat the solid fuel or fly ash, and the feeding motor is used to control the solid fuel or Feed rate of fly ash.

作为进一步优选的,所述进料单元还包括第一腐蚀性气体进气管,用于向所述燃烧室通入腐蚀性气体。As a further preferred option, the feeding unit further includes a first corrosive gas inlet pipe for introducing corrosive gas into the combustion chamber.

作为进一步优选的,所述锅炉受热面抗冲蚀-腐蚀原位试验系统还包括强化腐蚀配气单元,所述强化腐蚀配气单元包括第二腐蚀性气体进气管和腐蚀性气体流量计,所述第二腐蚀性气体进气管与燃烧室连接,用于定量地通入腐蚀性气体,以进一步强化腐蚀环境;所述腐蚀性气体流量计用于控制第二腐蚀性气体进气管的开度,以调节所述腐蚀性气体的流量。As a further preference, the boiler heating surface erosion resistance-corrosion in-situ test system further includes an enhanced corrosion gas distribution unit, and the enhanced corrosion gas distribution unit includes a second corrosive gas inlet pipe and a corrosive gas flowmeter, so The second corrosive gas inlet pipe is connected to the combustion chamber for quantitatively introducing corrosive gas to further strengthen the corrosive environment; the corrosive gas flowmeter is used to control the opening of the second corrosive gas inlet pipe, to adjust the flow of the corrosive gas.

作为进一步优选的,所述灰腐蚀平台包括试样台、试样固定件、试样控温电偶、冷却水进口和冷却水出口,所述试样台和试样固定件相互作用以对待测试样进行固定,并利用所述试样台调整所述待测试样的角度;所述试样控温电偶设置在所述试样台上,用于对所述待测试样进行温度测量;所述冷却水进口和冷却水出口设置在所述试样台的两侧,并与所述循环水控温单元连接,以通过水冷的方式对待测试样进行降温。As a further preference, the ash corrosion platform includes a sample stage, a sample holder, a sample temperature control couple, a cooling water inlet and a cooling water outlet, and the sample stage and the sample holder interact with each other to be tested The sample is fixed, and the sample stage is used to adjust the angle of the sample to be tested; the sample temperature-controlling couple is set on the sample stage to measure the temperature of the sample to be tested ; The cooling water inlet and the cooling water outlet are arranged on both sides of the sample stage, and are connected with the circulating water temperature control unit to cool the test sample by means of water cooling.

作为进一步优选的,所述锅炉受热面抗冲蚀-腐蚀原位试验系统还包括烟气分析仪,所述烟气分析仪伸入所述燃烧室的内部,用于实时监测烟气成分。As a further preference, the boiler heating surface erosion-corrosion in-situ test system further includes a flue gas analyzer, the flue gas analyzer extending into the combustion chamber for real-time monitoring of flue gas components.

作为进一步优选的,所述循环水控温单元包括沿水流方向依次连接的进水管、循环水流量计、电动调节阀、循环水泵、水箱和出水管,所述进水管和出水管直接与灰腐蚀平台连接;所述循环水流量计和电动调节阀用于控制循环水的流速;所述循环水泵用于从水箱中抽水,以为所述循环水控温单元提供循环水。As a further preference, the circulating water temperature control unit includes a water inlet pipe, a circulating water flow meter, an electric regulating valve, a circulating water pump, a water tank and a water outlet pipe connected in sequence along the water flow direction, and the water inlet pipe and the water outlet pipe are directly corroded with ash The platform is connected; the circulating water flow meter and the electric regulating valve are used to control the flow rate of the circulating water; the circulating water pump is used to pump water from the water tank to provide circulating water for the circulating water temperature control unit.

作为进一步优选的,所述锅炉受热面抗冲蚀-腐蚀原位试验系统还包括计算机,所述计算机用于控制所述进料单元、燃烧区电加热器、样品区电加热器、循环水控温单元和相机。As a further preference, the boiler heating surface erosion-corrosion in-situ test system further includes a computer, and the computer is used to control the feeding unit, the electric heater in the combustion area, the electric heater in the sample area, and the circulating water control unit. temperature unit and camera.

作为进一步优选的,所述燃烧室的高度为0.6m~6m;所述燃烧区电加热器的最高加热温度为1600℃,所述样品区电加热器的最高加热温度为900℃。As a further preference, the height of the combustion chamber is 0.6m-6m; the maximum heating temperature of the electric heater in the combustion zone is 1600°C, and the maximum heating temperature of the electric heater in the sample zone is 900°C.

总体而言,通过本实用新型所构思的以上技术方案与现有技术相比,具有以下有益效果:In general, compared with the prior art, the above technical solutions conceived by the present utility model have the following beneficial effects:

1.本实用新型提供的锅炉受热面抗冲蚀-腐蚀原位试验系统具有较强的可操作性,能够以最小空间模拟燃料着火、燃烧、飞灰撞击、飞灰沉积、粘附并发生腐蚀反应的全过程,实现材料在复杂耦合腐蚀条件下耐冲蚀-腐蚀性能的快速评估,非常适用于高温环境下气相腐蚀与沉积相腐蚀耦合的材料抗冲蚀-腐蚀性能测试,其中通过设置燃烧区电加热器,能够对烟气和待测试样进行分开加热,保证燃料完全地燃烧燃尽,为后续灰颗粒在待测试样表面的沉积创造条件,同时通过设置样品区电加热器和循环水控温单元,能够单独对待测试样进行温度调控,实现对锅炉中高温受热面及尾部烟道的模拟,为锅炉内部不同部位耐腐蚀材料的优选提供指导,此外该试验系统还设置有可视窗口和相机,能够动态地记录燃料灰颗粒沉积、粘附、熔融和腐蚀的全过程并确定灰润湿角的大小,为材料抗冲蚀-腐蚀性能评估提供依据;1. The boiler heating surface anti-erosion-corrosion in-situ test system provided by the utility model has strong operability, and can simulate fuel ignition, combustion, fly ash impact, fly ash deposition, adhesion and corrosion with a minimum space The whole process of the reaction realizes the rapid evaluation of the erosion-corrosion resistance of materials under complex coupled corrosion conditions. The zone electric heater can heat the flue gas and the sample to be tested separately, to ensure that the fuel is completely burned out, and to create conditions for the subsequent deposition of ash particles on the surface of the sample to be tested. At the same time, by setting the sample zone electric heater and The circulating water temperature control unit can independently control the temperature of the test sample, realize the simulation of the high temperature heating surface and the tail flue in the boiler, and provide guidance for the selection of corrosion-resistant materials in different parts of the boiler. The viewing window and camera can dynamically record the whole process of the deposition, adhesion, melting and corrosion of fuel ash particles and determine the size of the ash wetting angle, providing a basis for the evaluation of the erosion-corrosion performance of the material;

2.同时,本实用新型通过对给料单元的结构进行优化,将固体燃料进料斗、固体燃料进料管、燃烧气体进气管和第一腐蚀性气体进气管联用,一方面能够通过固体燃料燃烧模拟实际燃烧下的烟气环境,另一方面也能通过通入烟气、飞灰和腐蚀性气体直接模拟烟气环境,具有较宽的适用范围;2. At the same time, the utility model optimizes the structure of the feeding unit, and combines the solid fuel feed hopper, the solid fuel feed pipe, the combustion gas intake pipe and the first corrosive gas intake pipe, on the one hand, it can pass the solid fuel. Fuel combustion simulates the flue gas environment under actual combustion. On the other hand, it can also directly simulate the flue gas environment by introducing flue gas, fly ash and corrosive gas, which has a wide application range;

3.此外,本实用新型通过设置第一腐蚀性气体进气管、第二腐蚀气体进气管和烟气分析仪,能够根据实验需要通入腐蚀性气体,以模拟特殊应用环境或强化腐蚀环境,实现对待测试样的耐冲蚀机烟气飞灰耦合腐蚀性能的快速评估,同时为耐冲蚀及烟气飞灰耦合腐蚀性能材料的优选提供指导。3. In addition, by setting the first corrosive gas inlet pipe, the second corrosive gas inlet pipe and the flue gas analyzer, the present invention can introduce corrosive gas according to the experimental needs to simulate a special application environment or strengthen the corrosive environment to achieve The rapid evaluation of the corrosion resistance of the test samples to the erosion machine flue gas and fly ash coupling corrosion, and also provides guidance for the selection of materials with erosion resistance and coupling corrosion resistance of flue gas and ash.

附图说明Description of drawings

图1是本实用新型实施例提供的锅炉受热面抗冲蚀-腐蚀原位试验系统的结构示意图;1 is a schematic structural diagram of a boiler heating surface erosion resistance-corrosion in-situ test system provided by an embodiment of the present invention;

图2是本实用新型实施例提供的适用于平板类待测试样的灰腐蚀平台的结构示意图,其中(a)为主视图,(b)为侧视图,(c)为俯视图;2 is a schematic structural diagram of an ash corrosion platform suitable for a flat plate type test sample provided by an embodiment of the present invention, wherein (a) is a front view, (b) is a side view, and (c) is a top view;

图3是本实用新型实施例提供的适用于筒状类待测试样的灰腐蚀平台的结构示意图,其中(a)为主视图,(b)为侧视图,(c)为俯视图;3 is a schematic structural diagram of an ash corrosion platform suitable for a cylindrical test sample provided by an embodiment of the present invention, wherein (a) is a front view, (b) is a side view, and (c) is a top view;

图4是本实用新型实施例提供的固体燃料进料斗的结构示意图;4 is a schematic structural diagram of a solid fuel feed hopper provided by an embodiment of the present invention;

图5是本实用新型实施例提供的锅炉受热面抗冲蚀-腐蚀原位试验系统的流程图。FIG. 5 is a flow chart of an in-situ test system for erosion-corrosion resistance of a heating surface of a boiler provided by an embodiment of the present invention.

在所有附图中,相同的附图标记用来表示相同的元件或结构,其中:Throughout the drawings, the same reference numbers are used to refer to the same elements or structures, wherein:

1-固体燃料进料斗,111-给料电机,112-物料加热器,2-固体燃料进料管, 3-燃烧气体进气管,4-第一腐蚀性气体进气管,5-燃烧器,6-顶端法兰,7-燃烧室,8-两级电加热单元,81-燃烧区电加热器,82-样品区电加热器,9-强化腐蚀配气单元,91-腐蚀性气体流量计,92-第二腐蚀性气体进气管,10-灰腐蚀平台,101-待测试样,102-试样台,103-试样控温电偶,104-冷却水进口, 105-冷却水出口,106-试样固定件,11-底端法兰,12-相机,13-烟气分析仪, 14-循环水控温单元,141-进水管,142-循环水流量计,143-电动调节阀,144-循环水泵,145-水箱,146-出水管,15-计算机。1-solid fuel feeding hopper, 111-feeding motor, 112-material heater, 2-solid fuel feeding pipe, 3-combustion gas inlet pipe, 4-first corrosive gas inlet pipe, 5-burner, 6- Top flange, 7- Combustion chamber, 8- Two-stage electric heating unit, 81- Electric heater in combustion area, 82- Electric heater in sample area, 9- Enhanced corrosion gas distribution unit, 91- Corrosive gas flow meter , 92- Second corrosive gas inlet pipe, 10- Ash corrosion platform, 101- Sample to be tested, 102- Sample stage, 103- Sample temperature control couple, 104- Cooling water inlet, 105- Cooling water outlet , 106-sample fixing piece, 11-bottom flange, 12-camera, 13-flue gas analyzer, 14-circulating water temperature control unit, 141-water inlet pipe, 142-circulating water flowmeter, 143-electric adjustment Valve, 144-circulating water pump, 145-water tank, 146-water outlet pipe, 15-computer.

具体实施方式Detailed ways

为了使本实用新型的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本实用新型进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本实用新型,并不用于限定本实用新型。In order to make the purpose, technical solutions and advantages of the present utility model more clearly understood, the present utility model will be further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention, and are not intended to limit the present invention.

如图1所示,本实用新型提供了一种锅炉受热面抗冲蚀-腐蚀原位试验系统,该系统包括燃烧模拟装置和冲蚀-腐蚀试验装置,其中:As shown in Figure 1, the utility model provides a boiler heating surface erosion-corrosion in-situ test system, the system includes a combustion simulation device and an erosion-corrosion test device, wherein:

燃烧模拟装置包括从上至下依次连接的进料单元、燃烧器5、顶端法兰6、燃烧室7和底端法兰11,以模拟实际燃烧过程的烟气环境;同时该燃烧室7 的外部设置有两级电加热单元8,分别为燃烧区电加热器81和样品区电加热器82,用于对烟气和待测试样101进行分开加热,燃烧区电加热器81的最高加热温度可达1600℃,能够保证燃料的进一步燃烧和燃尽,为后续灰颗粒在待测试样表面的沉积创造条件,样品区电加热器82的最高加热温度可达900℃,能够实现对锅炉中高温受热面及尾部烟道的模拟,并且该燃烧室7的下方设置有可视窗口,以实现待测试样101的实时观察;The combustion simulation device includes a feed unit, a burner 5, a top flange 6, a combustion chamber 7 and a bottom flange 11 sequentially connected from top to bottom to simulate the flue gas environment of the actual combustion process; A two-stage electric heating unit 8 is provided outside, which are the electric heater 81 in the combustion area and the electric heater 82 in the sample area, which are used to separately heat the flue gas and the sample to be tested 101. The highest heating of the electric heater 81 in the combustion area is The temperature can reach 1600°C, which can ensure the further combustion and burnout of the fuel, and create conditions for the subsequent deposition of ash particles on the surface of the sample to be tested. Simulation of the medium and high temperature heating surface and the tail flue, and a visual window is provided below the combustion chamber 7 to realize real-time observation of the sample 101 to be tested;

冲蚀-腐蚀试验装置包括灰腐蚀平台10、循环水控温单元14、烟气分析仪 13和相机12,灰腐蚀平台10伸入燃烧室7的内部,用于放置待测试样101 并进行冲蚀-腐蚀试验;循环水控温单元14与灰腐蚀平台10连接,以控制待测试样101的温度,通过样品区电加热器82和循环水控温单元14的相互作用,能够将待测试样101的温度控制在100℃~750℃之内,模拟锅炉内不同部位的温度,以为耐腐蚀材料的优选提供指导;烟气分析仪13伸入燃烧室7的内部,用于实时监测烟气成分,进一步提高锅炉受热面抗冲蚀-腐蚀原位试验的准确度;相机12设置在燃烧室7中可视窗口的外侧,以实时观察待测试样101的冲蚀-腐蚀过程,相机12优选采用CCD相机,可动态地记录燃料灰颗粒沉积、粘附、熔融并腐蚀的全过程,以确定灰润湿角的大小,从而为材料耐冲蚀-腐蚀性能评估提供依据。The erosion-corrosion test device includes an ash corrosion platform 10, a circulating water temperature control unit 14, a flue gas analyzer 13 and a camera 12. The ash corrosion platform 10 extends into the interior of the combustion chamber 7 for placing the sample 101 to be tested and conducting Erosion-corrosion test; the circulating water temperature control unit 14 is connected to the ash corrosion platform 10 to control the temperature of the sample 101 to be tested. Through the interaction between the electric heater 82 in the sample area and the circulating water temperature control unit 14, the The temperature of the test sample 101 is controlled within 100°C to 750°C, simulating the temperature of different parts in the boiler to provide guidance for the selection of corrosion-resistant materials; the flue gas analyzer 13 extends into the interior of the combustion chamber 7 for real-time monitoring The flue gas composition further improves the accuracy of the erosion-corrosion in-situ test on the heating surface of the boiler; the camera 12 is arranged outside the visible window in the combustion chamber 7 to observe the erosion-corrosion process of the sample 101 to be tested in real time. The camera 12 preferably adopts a CCD camera, which can dynamically record the whole process of the deposition, adhesion, melting and corrosion of fuel ash particles, so as to determine the size of the ash wetting angle, so as to provide a basis for the evaluation of the erosion-corrosion resistance of the material.

进一步,如图4所示,进料单元包括固体燃料进料斗1、固体燃料进料管2、燃烧气体进气管3和第一腐蚀性气体进气管4,固体燃料进料斗1与固体燃料进料管2连接,用于向燃烧器5通入固体燃料或飞灰,该固体燃料进料斗1包括物料加热器112和给料电机111,物料加热器112用于对固体燃料或飞灰进行预热,给料电机111用于控制固体燃料或飞灰的给料速率;燃烧气体进气管3用于向燃烧器5通入燃烧气体或烟气;第一腐蚀性气体进气管4 用于向燃烧室7通入腐蚀性气体。工作时,可以通入固体燃料和燃烧气体以模拟实际燃烧环境,也可以直接通入飞灰和烟气以模拟实际燃烧环境,同时还可通入腐蚀性气体模拟腐蚀过程。Further, as shown in FIG. 4 , the feeding unit includes a solid fuel feeding hopper 1, a solid fuel feeding pipe 2, a combustion gas inlet pipe 3 and a first corrosive gas inlet pipe 4, the solid fuel feeding hopper 1 and the solid fuel feeding pipe 4. The feed pipe 2 is connected for feeding solid fuel or fly ash to the burner 5. The solid fuel feed hopper 1 includes a material heater 112 and a feeding motor 111. The material heater 112 is used for solid fuel or fly ash. For preheating, the feeding motor 111 is used to control the feeding rate of solid fuel or fly ash; the combustion gas inlet pipe 3 is used to introduce combustion gas or flue gas to the burner 5; the first corrosive gas inlet pipe 4 is used to Corrosive gas is introduced into the combustion chamber 7 . During operation, solid fuel and combustion gas can be introduced to simulate the actual combustion environment, or fly ash and flue gas can be directly introduced to simulate the actual combustion environment, and corrosive gas can also be introduced to simulate the corrosion process.

进一步,锅炉受热面抗冲蚀-腐蚀原位试验系统还包括强化腐蚀配气单元 9,用于实现待测试样101耐冲蚀及烟气飞灰耦合腐蚀性能的快速评估,该强化腐蚀配气单元9包括第二腐蚀性气体进气管92和腐蚀性气体流量计91,第二腐蚀性气体进气管92与燃烧室7连接,用于定量地通入腐蚀性气体,以进一步强化腐蚀环境;腐蚀性气体流量计91用于控制第二腐蚀性气体进气管92 的开度,以调节腐蚀性气体的流量。Further, the boiler heating surface erosion resistance-corrosion in-situ test system also includes an enhanced corrosion gas distribution unit 9, which is used to realize the rapid evaluation of the erosion resistance and flue gas fly ash coupled corrosion performance of the sample 101 to be tested. The gas unit 9 includes a second corrosive gas inlet pipe 92 and a corrosive gas flow meter 91. The second corrosive gas inlet pipe 92 is connected to the combustion chamber 7 for quantitatively introducing corrosive gas to further strengthen the corrosive environment; The corrosive gas flow meter 91 is used to control the opening of the second corrosive gas inlet pipe 92 to adjust the flow rate of the corrosive gas.

进一步,如图2、3所示,灰腐蚀平台10包括试样台102、试样固定件 106、试样控温电偶103、冷却水进口104和冷却水出口105,试样台102和试样固定件106相互作用将待测试样101进行固定,并且利用试样台102调整待测试样101的角度,以改变待测试样101表面与烟气的夹角,实现不同冲蚀角下材料耐腐蚀性能的快速评估;试样控温电偶103设置在试样台102 上,用于对待测试样101的温度进行精确测量;冷却水进口104和冷却水出口105设置在试样台102的两侧,并与循环水控温单元14连接,以通过水冷对待测试样101进行降温。当待测试样101为平板结构时,冷却水进口104 和冷却水出口105设置在试样台102的下方,冷却水通过循环流动的方式对试样台102进行冷却;当待测试样101为管状结构时,冷却水进口104和冷却水出口105与管状结构的两侧连接,冷却水通过循环流动的方式对待测试样101进行冷却。Further, as shown in FIGS. 2 and 3, the ash corrosion platform 10 includes a sample stage 102, a sample fixing member 106, a sample temperature control couple 103, a cooling water inlet 104 and a cooling water outlet 105, the sample stage 102 and the test The sample holder 106 interacts to fix the sample to be tested 101, and the sample stage 102 is used to adjust the angle of the sample to be tested 101 to change the angle between the surface of the sample to be tested 101 and the flue gas to achieve different erosion angles The rapid evaluation of the corrosion resistance of the lower material; the sample temperature control couple 103 is set on the sample stage 102 to accurately measure the temperature of the test sample 101; the cooling water inlet 104 and the cooling water outlet 105 are set on the sample stage 102 and connected to the circulating water temperature control unit 14 to cool the test sample 101 by water cooling. When the sample 101 to be tested is a flat plate structure, the cooling water inlet 104 and the cooling water outlet 105 are arranged below the sample table 102, and the cooling water cools the sample table 102 by circulating flow; In the case of a tubular structure, the cooling water inlet 104 and the cooling water outlet 105 are connected to both sides of the tubular structure, and the cooling water cools the test sample 101 by circulating flow.

进一步,循环水控温单元14包括沿水流方向依次连接的进水管141、循环水流量计142、电动调节阀143、循环水泵144、水箱145和出水管146,进水管141和出水管146直接与灰腐蚀平台10连接;循环水流量计142和电动调节阀143用于控制循环水的流速;循环水泵144用于从水箱145中抽水,以为循环水控温单元14提供循环水。Further, the circulating water temperature control unit 14 includes a water inlet pipe 141, a circulating water flow meter 142, an electric regulating valve 143, a circulating water pump 144, a water tank 145 and a water outlet pipe 146 connected in sequence along the water flow direction. The water inlet pipe 141 and the water outlet pipe 146 are directly connected to The ash corrosion platform 10 is connected; the circulating water flow meter 142 and the electric regulating valve 143 are used to control the flow rate of the circulating water;

进一步,锅炉受热面抗冲蚀-腐蚀原位试验系统还包括计算机15,用于控制进料单元、燃烧区电加热器81、样品区电加热器82、循环水控温单元14 和相机12,包括给料电机111的给料速度,燃料的预加热温度,烟气温度和待测试样温度,燃烧气体、第一腐蚀性气体和第二腐蚀性气体的流量,以及相机12的记录及分析过程等。Further, the erosion-corrosion in-situ test system for the heating surface of the boiler further includes a computer 15 for controlling the feeding unit, the electric heater 81 in the combustion area, the electric heater 82 in the sample area, the circulating water temperature control unit 14 and the camera 12, Including the feeding speed of the feeding motor 111, the preheating temperature of the fuel, the temperature of the flue gas and the sample to be tested, the flow rates of the combustion gas, the first corrosive gas and the second corrosive gas, and the recording and analysis of the camera 12 process etc.

进一步,燃烧室7的高度为0.6m~6m;燃烧区电加热器81的最高加热温度为1600℃,样品区电加热器82的最高加热温度为900℃。固体燃料可采用煤、生物质、固体再生燃料、垃圾衍生燃料中的一种或多种;燃烧气体可采用CH4、C2H4和H2中的一种或多种,并搭配助燃剂如O2或空气;腐蚀性气体可采用HCl、SO2、SO3和H2S中的一种或多种。Further, the height of the combustion chamber 7 is 0.6m-6m; the maximum heating temperature of the electric heater 81 in the combustion area is 1600°C, and the maximum heating temperature of the electric heater 82 in the sample area is 900°C. The solid fuel can be one or more of coal, biomass, solid regenerated fuel, and garbage-derived fuel; the combustion gas can be one or more of CH 4 , C 2 H 4 and H 2 , together with combustion accelerants Such as O 2 or air; the corrosive gas can be one or more of HCl, SO 2 , SO 3 and H 2 S.

如图5所示,本实用新型提供的锅炉受热面抗冲蚀-腐蚀原位试验系统的使用方法包括如下步骤:As shown in FIG. 5 , the use method of the anti-erosion-corrosion in-situ test system for the boiler heating surface provided by the present utility model includes the following steps:

S1称取一定量的固体燃料放入固体燃料进料斗1中,将待测试样101固定在灰腐蚀平台10上,并通过试样台102调节待测试样101的角度;S1 weighs a certain amount of solid fuel and puts it into the solid fuel feed hopper 1, fixes the sample to be tested 101 on the ash corrosion platform 10, and adjusts the angle of the sample to be tested 101 through the sample stage 102;

S2设定燃烧区电加热器81和样品区电加热器82的加热温度,同时设定待测试样101的温度;S2 sets the heating temperature of the electric heater 81 in the combustion area and the electric heater 82 in the sample area, and simultaneously sets the temperature of the sample to be tested 101;

S3启动循环水控温单元14的循环水泵144和加热开关;S3 starts the circulating water pump 144 and the heating switch of the circulating water temperature control unit 14;

S4接通燃烧气体进气管3、第一腐蚀性气体进气管4和第二腐蚀性气体进气管92;S4 connects the combustion gas inlet pipe 3, the first corrosive gas inlet pipe 4 and the second corrosive gas inlet pipe 92;

S5启动给料电机111使得固体燃料开始燃烧,对待测试样101进行冲蚀- 腐蚀试验,并利用相机12动态地记录燃料灰颗粒沉积并腐蚀的全过程,经过计算机15分析后确定灰润湿角的大小;S5 Start the feeding motor 111 to make the solid fuel start to burn, conduct the erosion-corrosion test on the test sample 101, and use the camera 12 to dynamically record the entire process of the deposition and corrosion of fuel ash particles, and determine the ash wetting angle after analysis by the computer 15. the size of;

S6待试验结束后,依次关闭各组件并取出试样。S6 After the test is over, turn off each component in turn and take out the sample.

接着本领域的技术人员容易理解,以上所述仅为本实用新型的较佳实施例而已,并不用以限制本实用新型,凡在本实用新型的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本实用新型的保护范围之内。Then those skilled in the art will easily understand that the above are only the preferred embodiments of the present invention, and are not intended to limit the present invention, and any modifications and equivalent replacements made within the spirit and principles of the present invention and improvements, etc., should be included within the scope of protection of the present invention.

Claims (10)

1. The anti erosion-corrosion in-situ test system for the heating surface of the boiler is characterized by comprising a combustion simulation device and an erosion-corrosion test device, wherein:
the combustion simulation device comprises a feeding unit, a combustor (5) and a combustion chamber (7) which are sequentially connected from top to bottom so as to simulate the flue gas environment in the actual combustion process; meanwhile, a combustion area electric heater (81) and a sample area electric heater (82) are sequentially arranged outside the combustion chamber (7) from top to bottom and used for separately heating smoke and a sample (101) to be tested, and a visible window is arranged below the combustion chamber (7);
the erosion-corrosion test device comprises an ash corrosion platform (10), a circulating water temperature control unit (14) and a camera (12), wherein the ash corrosion platform (10) extends into the combustion chamber (7) and is used for placing a sample (101) to be tested and carrying out an erosion-corrosion test; the circulating water temperature control unit (14) is connected with the ash corrosion platform (10) to control the temperature of the sample (101) to be tested; the camera (12) is arranged on the outer side of a visible window of the combustion chamber (7) to observe the erosion-corrosion process of the sample (101) to be measured in real time.
2. The system for in-situ testing erosion-corrosion resistance of the heating surface of the boiler as claimed in claim 1, wherein the feeding unit comprises a solid fuel feeding hopper (1), a solid fuel feeding pipe (2) and a combustion gas inlet pipe (3), the solid fuel feeding hopper (1) is connected with the solid fuel feeding pipe (2) and is used for feeding solid fuel or fly ash to the combustor (5); the combustion gas inlet pipe (3) is used for introducing combustion gas or smoke into the combustor (5).
3. The system for in-situ testing erosion-corrosion resistance of the heating surface of the boiler as claimed in claim 2, wherein the solid fuel feed hopper (1) comprises a material heater (112) and a feed motor (111), the material heater (112) is used for preheating the solid fuel or the fly ash, and the feed motor (111) is used for controlling the feed rate of the solid fuel or the fly ash.
4. The in-situ test system for erosion-corrosion resistance of the heating surface of the boiler as set forth in claim 1, wherein the feeding unit further comprises a first corrosive gas feeding pipe (4) for feeding a corrosive gas into the combustion chamber (7).
5. The system for in-situ testing erosion-corrosion resistance of the heating surface of the boiler as set forth in claim 1, characterized in that the system for in-situ testing erosion-corrosion resistance of the heating surface of the boiler further comprises an intensified corrosion gas distribution unit (9), the intensified corrosion gas distribution unit (9) comprises a second corrosive gas inlet pipe (92) and a corrosive gas flowmeter (91), the second corrosive gas inlet pipe (92) is connected with the combustion chamber (7) and is used for quantitatively introducing corrosive gas so as to further intensify a corrosive environment; the corrosive gas flowmeter (91) is used for controlling the opening degree of a second corrosive gas inlet pipe (92) so as to adjust the flow of the corrosive gas.
6. The in-situ test system for resisting erosion-corrosion of the heating surface of the boiler as claimed in claim 1, wherein the ash corrosion platform (10) comprises a sample table (102), a sample fixing member (106), a sample temperature control galvanic couple (103), a cooling water inlet (104) and a cooling water outlet (105), the sample table (102) and the sample fixing member (106) interact to fix the sample (101) to be tested, and the sample table (102) is used for adjusting the angle of the sample (101) to be tested; the sample temperature control electric couple (103) is arranged on the sample table (102) and is used for measuring the temperature of the sample (101) to be measured; the cooling water inlet (104) and the cooling water outlet (105) are arranged on two sides of the sample table (102) and are connected with the circulating water temperature control unit (14) so as to cool the sample (101) to be tested in a water cooling mode.
7. The in-situ test system for the erosion resistance and the corrosion resistance of the heating surface of the boiler as set forth in claim 1, characterized in that the in-situ test system for the erosion resistance and the corrosion resistance of the heating surface of the boiler further comprises a flue gas analyzer (13), and the flue gas analyzer (13) extends into the combustion chamber (7) and is used for monitoring the components of the flue gas in real time.
8. The in-situ test system for the erosion-corrosion resistance of the heating surface of the boiler as claimed in claim 1, wherein the circulating water temperature control unit (14) comprises a water inlet pipe (141), a circulating water flow meter (142), an electric regulating valve (143), a circulating water pump (144), a water tank (145) and a water outlet pipe (146) which are connected in sequence along the water flow direction, and the water inlet pipe (141) and the water outlet pipe (146) are directly connected with the ash corrosion platform (10); the circulating water flow meter (142) and the electric regulating valve (143) are used for controlling the flow rate of circulating water; the circulating water pump (144) is used for pumping water from the water tank (145) to provide circulating water for the circulating water temperature control unit (14).
9. The in-situ test system for resisting erosion-corrosion of the heating surface of the boiler as set forth in claim 1, characterized in that the in-situ test system for resisting erosion-corrosion of the heating surface of the boiler further comprises a computer (15), and the computer (15) is used for controlling the feeding unit, the combustion area electric heater (81), the sample area electric heater (82), the circulating water temperature control unit (14) and the camera (12).
10. The in-situ test system for erosion-corrosion resistance of the heating surface of the boiler as set forth in any one of claims 1 to 9, wherein the height of the combustion chamber (7) is 0.6m to 6 m; the highest heating temperature of the combustion area electric heater (81) is 1600 ℃, and the highest heating temperature of the sample area electric heater (82) is 900 ℃.
CN202123359625.1U 2021-12-28 2021-12-28 An in-situ test system for anti-erosion-corrosion of boiler heating surface Active CN216978771U (en)

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