CN216808706U - Catalytic diesel oil hydrogenation modification system - Google Patents
Catalytic diesel oil hydrogenation modification system Download PDFInfo
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- CN216808706U CN216808706U CN202122741986.6U CN202122741986U CN216808706U CN 216808706 U CN216808706 U CN 216808706U CN 202122741986 U CN202122741986 U CN 202122741986U CN 216808706 U CN216808706 U CN 216808706U
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Abstract
The utility model discloses a catalytic diesel oil hydro-upgrading system, and belongs to the field of petroleum processing. The device comprises a heating furnace, a first reactor, a second reactor, a first heat exchanger, a second heat exchanger, a third heat exchanger, a fourth heat exchanger, a reaction product air cooler, a high-pressure separator, a low-pressure separator, a desulfurizing tower and a circulating hydrogen compressor, wherein a cold liquid inlet of the first heat exchanger is connected with a catalytic diesel oil supply system, a cold liquid outlet of the first heat exchanger is connected with an inlet of cold liquid of the second heat exchanger, the second heat exchanger is connected with the heating furnace, and an outlet of the heating furnace is connected with a liquid inlet of the first reactor. The utility model optimizes the flow of the diesel-catalytic hydro-upgrading system, greatly reduces the construction cost of the diesel-catalytic hydro-upgrading system, and greatly reduces the operation cost of the diesel-catalytic hydro-upgrading system.
Description
Technical Field
The utility model belongs to the field of petroleum processing, and particularly relates to a catalytic diesel hydro-upgrading system.
Background
In recent years, as the quality of the processed crude oil in China is more and more emphasized, the catalytic cracking raw material is gradually developed to be heavy and inferior, and the upgrading pressure of the product quality faced by enterprises is gradually increased along with the increasing perfection of environmental protection regulations. In China, due to severe shortage of petroleum resources, catalytic diesel is mainly used for blending diesel products after oxygen refining or hydro-upgrading, and a catalytic cracking (fcc) technology is one of main process means for heavy oil lightening and plays an important role in oil refining enterprises of various countries in the world.
The traditional diesel hydrogenation device has a hot high-split flow: raw oil enters a raw oil buffer tank after exchanging heat with refined diesel oil, is mixed with mixed hydrogen after being boosted by a hydrogenation feed pump, and then enters a reactor after exchanging heat of reaction effluent and heating by a heating furnace. The reaction effluent enters a hot high-pressure separator after exchanging heat with raw oil, and hot high-pressure gas enters a cold high-pressure separator after exchanging heat and cooling in air. And (4) the cold high-molecular gas enters a recycle hydrogen desulfurization system, and is used as recycle hydrogen after desulfurization. The cold high-fraction oil enters a cold low-fraction device after being decompressed, cold low-fraction gas is subjected to PSA hydrogen extraction, and the cold low-fraction oil is combined with hot low-fraction oil after heat exchange. The hot low-fraction oil and the cold low-fraction oil are combined and then enter a product fractionating tower. The crude naphtha is produced from the top of the tower. Refined diesel oil is produced from the bottom of the tower, exchanges heat with raw oil, is cooled in air and is discharged out of the device.
SUMMERY OF THE UTILITY MODEL
The utility model aims to provide a catalytic diesel hydro-upgrading system, which can optimize the flow of the catalytic diesel hydro-upgrading system, greatly reduce the construction cost of the catalytic diesel hydro-upgrading system and greatly reduce the operation cost of the catalytic diesel hydro-upgrading system.
In order to achieve the purpose, the technical scheme adopted by the utility model is as follows:
a catalytic diesel hydro-upgrading system comprises a heating furnace, a first reactor, a second reactor, a first heat exchanger, a second heat exchanger, a third heat exchanger, a fourth heat exchanger, a reaction product air cooler, a high-pressure separator, a low-pressure separator, a desulfurizing tower and a circulating hydrogen compressor, wherein a cold liquid inlet of the first heat exchanger is connected with a catalytic diesel supply system, a cold liquid outlet of the first heat exchanger is connected with a cold liquid inlet of the second heat exchanger, an outlet of the second heat exchanger is connected with the heating furnace, an outlet of the heating furnace is connected with a liquid inlet of the first reactor, a liquid outlet of the first reactor is connected with a hot liquid inlet of the second heat exchanger, a hot liquid outlet of the second heat exchanger is connected with a liquid inlet of the second reactor, a liquid outlet of the second reactor is communicated with a hot liquid inlet of the first heat exchanger, the first heat exchanger is connected with the third heat exchanger, the third heat exchanger is connected with the fourth heat exchanger, and a hot liquid outlet of the fourth heat exchanger is connected with a liquid inlet of the reaction product air cooler; the liquid outlet of the reaction product air cooler is connected with the liquid inlet of the high-pressure separator; an upper outlet of the high-pressure separator is connected with an air inlet of the desulfurizing tower, a lean amine liquid inlet of the desulfurizing tower is communicated with a lean amine liquid system, an air outlet of the desulfurizing tower is communicated with an inlet of a circulating hydrogen compressor, and an amine-rich liquid outlet of the desulfurizing tower is communicated with a sulfur recovery system; the bottom exit linkage of high pressure separator the inlet of low pressure separator, the drain of high pressure separator even adds hydrogen and contains sour water system, the upper portion export intercommunication circulating hydrogen compressor of low pressure separator, circulating hydrogen compressor is connected with first reactor and second reactor respectively, the drain of low pressure separator even adds hydrogen and contains sour water system, the cold fluid entry of fourth heat exchanger of lower part exit linkage of low pressure separator, the cold fluid exit linkage catalytic cracking system of fourth heat exchanger, the cold fluid exit linkage of fourth heat exchanger removes the filter oil inlet.
Furthermore, a filter, a buffer tank and a feeding pump are arranged between a cold liquid inlet of the first heat exchanger and the catalytic diesel oil supply system, the filter, the buffer tank and the feeding pump are sequentially connected, an oil outlet of the feeding pump is communicated with the cold liquid inlet of the first heat exchanger, an oil inlet of the filter is communicated with the catalytic diesel oil supply system, and an oil inlet of the filter is communicated with a cold liquid outlet of the fourth heat exchanger.
Further, the inlet of the hot reactant air cooler is communicated with a desalted water supply pipeline of the hydrogenation system.
Furthermore, the circulating hydrogen compressor is connected with a third heat exchanger, the third heat exchanger is connected with a pipeline between the first heat exchanger and the second heat exchanger, and a pipeline between the circulating hydrogen compressor and the third heat exchanger is connected with a cold low-pressure gas discharge pipeline of a hydrogen supply system.
Further, the second heat exchanger is a heat exchanger with a winding pipe type structure.
Further, the recycle hydrogen compressor is a rotary circulator driven by 3.5MPa steam.
Further, the feed pump is a high-pressure centrifugal pump.
Due to the adoption of the technical scheme, the utility model has the following beneficial effects:
the device takes mixed catalytic diesel oil of a catalytic cracking unit in a catalytic cracking device and an LTAG combined device as a raw material, mainly produces hydrogenated diesel oil components meeting the requirements of the catalytic unit of the LTAG combined device through reactions of polycyclic aromatic hydrocarbon hydrogenation saturation, desulfurization, denitrification and the like, and finally converts the hydrogenated diesel oil into high-octane gasoline or light aromatic hydrocarbon and the like through catalysis. The bottom outlet of the low-pressure separator of the catalytic diesel oil upgrading system directly enters the catalytic cracking system through the fourth heat exchanger, so that the whole fractionation system is reduced, the energy consumption of the system is reduced, the construction cost of the catalytic diesel oil upgrading system is greatly reduced, and products obtained by the improved system have no great influence on the whole catalytic unit of the LTAG integrated device.
Drawings
Fig. 1 is a schematic structural view of the present invention.
In the attached figure, 1-raw oil filter, 2-raw material tank, 3-feeding pump, 4-second reactor, 5-first reactor, 6-first heat exchanger, 7-second heat exchanger, 8-third heat exchanger, 9-heating furnace, 10-fourth heat exchanger, 11-circulating hydrogen compressor, 12-reaction product air cooler, 13-a circulating hydrogen compressor inlet liquid separation tank, 14-a high-pressure separator, 15-a low-pressure separator, 16-a desulfurizing tower, 17-a lean amine liquid system, 18-a sulfur recovery system, 19-a low-pressure gas discharge pipeline, 20-a sulfur-containing sewage system, 21-a catalytic cracking system, 22-a hydrogen supply pipeline, 23-a desalted water supply pipeline and 24-a catalytic diesel oil supply system.
Detailed Description
The following detailed description of the present invention is provided in conjunction with the accompanying drawings, but it should be understood that the scope of the present invention is not limited to the specific embodiments.
Throughout the specification and claims, unless explicitly stated otherwise, the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated element or component but not the exclusion of any other element or component.
As shown in fig. 1, a catalytic diesel hydro-upgrading system comprises a heating furnace 9, a first reactor 5, a second reactor 4, a first heat exchanger 6, a second heat exchanger 7, a third heat exchanger 8, a fourth heat exchanger 10, a reaction product air cooler, a high-pressure separator 14, a low-pressure separator 15, a desulfurizing tower 16 and a recycle hydrogen compressor 11, wherein a cold liquid inlet of the first heat exchanger 6 is connected with a catalytic diesel supply system 24, a cold liquid outlet of the first heat exchanger 6 is connected with a cold liquid inlet of the second heat exchanger 7, an outlet of the second heat exchanger 7 is connected with the heating furnace 9, an outlet of the heating furnace 9 is connected with a liquid inlet of the first reactor 5, a liquid outlet of the first reactor 5 is connected with a hot liquid inlet of the second heat exchanger 7, a hot liquid outlet of the second heat exchanger 7 is connected with a liquid inlet of the second reactor 4, a liquid outlet of the second reactor 4 is communicated with a hot liquid inlet of the first heat exchanger 6, the first heat exchanger 6 is connected with a third heat exchanger 8, the third heat exchanger 8 is connected with a fourth heat exchanger 10, and a hot liquid outlet of the fourth heat exchanger 10 is connected with a liquid inlet of the reaction product air cooler; the liquid outlet of the reaction product air cooler is connected with the liquid inlet of the high-pressure separator 14; an upper outlet of the high-pressure separator 14 is connected with an air inlet of the desulfurizing tower 16, an amine-poor liquid inlet of the desulfurizing tower 16 is communicated with an amine-poor liquid system 17, an air outlet of the desulfurizing tower 16 is communicated with an inlet of the recycle hydrogen compressor 11, and an amine-rich liquid outlet of the desulfurizing tower 16 is communicated with a sulfur recovery system 18; the high-pressure separator part gas is connected with the low-pressure separator and discharged from the low-pressure separator pipeline. The bottom exit linkage of high pressure separator 14 the inlet of low pressure separator 15, the drain of high pressure separator 14 links hydrogen and contains sulphur sewage system 20, the upper portion export intercommunication circulation hydrogen compressor 11 of low pressure separator 15, circulation hydrogen compressor 11 is connected with first reactor 5 and second reactor 4 respectively, the drain of low pressure separator 15 links hydrogen and contains sulphur sewage system 20, the cold liquid entry of the lower part exit linkage fourth heat exchanger 10 of low pressure separator 15, the cold liquid exit linkage catalytic cracking system 21 of fourth heat exchanger 10, the cold liquid exit linkage of fourth heat exchanger 10 goes the filter oil inlet.
A filter, a buffer tank and a feeding pump 3 are arranged between a cold liquid inlet of the first heat exchanger 6 and the catalytic diesel oil supply system 24, the filter, the buffer tank and the feeding pump 3 are sequentially connected, an oil outlet of the feeding pump 3 is communicated with the cold liquid inlet of the first heat exchanger 6, an oil inlet of the filter is communicated with the catalytic diesel oil supply system 24, and an oil inlet of the filter is communicated with a cold liquid outlet of the fourth heat exchanger 10.
The inlet of the hot reactant air cooler 12 is communicated with a desalted water supply pipeline 23 of a hydrogenation system. The circulating hydrogen compressor 11 is connected with the third heat exchanger 8, the third heat exchanger 8 is connected with a pipeline between the first heat exchanger 6 and the second heat exchanger 7, and a pipeline between the circulating hydrogen compressor 11 and the third heat exchanger 8 is connected with a cold low-pressure gas discharge pipeline 19 of a hydrogen supply system. The second heat exchanger 7 is a heat exchanger with a winding pipe type structure. The recycle hydrogen compressor 11 is a rotary circulator driven by 3.5MPa steam. The feed pump 3 is a high-pressure centrifugal pump.
A method for upgrading a catalytic diesel hydro-upgrading system comprises the following steps: raw oil enters a raw material tank 2 through a raw oil filter, the filtered raw oil enters a first heat exchanger 6 through a feed pump 3, the raw oil is mixed with mixed hydrogen and then enters a reaction feed heating furnace 9 through a second heat exchanger 7, heated media sequentially enter a first reactor 5 and a second reactor 4, the first reactor 5 and the reaction furnace mainly undergo sulfur removal, nitrogen removal and polycyclic aromatic hydrocarbon saturation reactions of oil gas, reaction effluents sequentially pass through the first heat exchanger 6, a third heat exchanger 8, a fourth heat exchanger 10 and a reactant air cooler 12, the first heat exchanger 6, the third heat exchanger 8 and the fourth heat exchanger 10 respectively recover heat, the cooled reactants enter a high-pressure separator 14 for gas and liquid separation, liquid discharged from the bottom of the high-pressure separator 14 enters a low-pressure separator 15, gas separated by the low-pressure separator 15 is discharged from a low-pressure gas discharge pipeline 19, sulfur-containing sewage separated by the low-pressure separator 15 is discharged from a sulfur-containing sewage system 20, one path of the oil separated by the low-pressure separator 15 returns to the raw material filter through the fourth heat exchanger 10 for a circulating reaction, and the other path of the oil directly flows to the catalytic cracking system 21; the hydrogen sulfide is removed after the lower part of the high-pressure separator 14 which enters the desulfurizing tower 16 and is separated from the top of the high-pressure separator contacts lean amine liquid, the desulfurized circulating hydrogen is discharged from the top of the circulating hydrogen desulfurizing tower 16 and is subjected to pressure rise by a circulating hydrogen compressor 11 and then is divided into two paths, one path is used as quenching hydrogen to be sent to the first reactor 5 and the second reactor 4 to control the temperature of the reactors, and the other path is mixed with hydrogen provided by a hydrogen supply pipeline 22 to form mixed hydrogen which is mixed with the raw oil through a third heat exchanger 8.
The utility model reduces the whole fractionation system, optimizes the flow of the diesel-catalytic hydro-upgrading system, greatly reduces the construction cost of the diesel-catalytic hydro-upgrading system and greatly reduces the operation cost of the diesel-catalytic hydro-upgrading system.
The above description is directed to the preferred embodiments of the present invention, but the embodiments are not intended to limit the scope of the claims of the present invention, and all equivalent changes and modifications made within the technical spirit of the present invention shall fall within the scope of the claims of the present invention.
Claims (7)
1. A catalytic diesel hydro-upgrading system is characterized by comprising a heating furnace, a first reactor, a second reactor, a first heat exchanger, a second heat exchanger, a third heat exchanger, a fourth heat exchanger, a reaction product air cooler, a high-pressure separator, a low-pressure separator, a desulfurizing tower and a circulating hydrogen compressor, wherein a cold liquid inlet of the first heat exchanger is connected with a catalytic diesel supply system, a cold liquid outlet of the first heat exchanger is connected with a cold liquid inlet of the second heat exchanger, an outlet of the second heat exchanger is connected with the heating furnace, an outlet of the heating furnace is connected with a liquid inlet of the first reactor, a liquid outlet of the first reactor is connected with a hot liquid inlet of the second heat exchanger, a hot liquid outlet of the second heat exchanger is connected with a liquid inlet of the second reactor, a liquid outlet of the second reactor is communicated with a hot liquid inlet of the first heat exchanger, the first heat exchanger is connected with the third heat exchanger, the third heat exchanger is connected with the fourth heat exchanger, and a hot liquid outlet of the fourth heat exchanger is connected with a liquid inlet of the reaction product air cooler; the liquid outlet of the reaction product air cooler is connected with the liquid inlet of the high-pressure separator; an upper outlet of the high-pressure separator is connected with an air inlet of the desulfurizing tower, a lean amine liquid inlet of the desulfurizing tower is communicated with a lean amine liquid system, an air outlet of the desulfurizing tower is communicated with an inlet of a circulating hydrogen compressor, and an amine-rich liquid outlet of the desulfurizing tower is communicated with a sulfur recovery system; the bottom exit linkage of high pressure separator the inlet of low pressure separator, the drain of high pressure separator links to add hydrogen and contains the sour water system, the upper portion export intercommunication low branch gas discharge line of low pressure separator, the circulating hydrogen compressor is connected with first reactor and second reactor respectively, the drain of low pressure separator links to add hydrogen and contains the sour water system, the cold liquid entry of the lower part exit linkage fourth heat exchanger of low pressure separator, the cold liquid exit linkage catalytic cracking system of fourth heat exchanger, the cold liquid exit linkage of fourth heat exchanger goes the filter oil inlet.
2. The catalytic diesel hydro-upgrading system of claim 1, wherein a filter, a buffer tank and a feed pump are arranged between the cold liquid inlet of the first heat exchanger and the catalytic diesel supply system, the filter, the buffer tank and the feed pump are sequentially connected, the oil outlet of the feed pump is communicated with the cold liquid inlet of the first heat exchanger, the oil inlet of the filter is communicated with the catalytic diesel supply system, and the oil inlet of the filter is communicated with the cold liquid outlet of the fourth heat exchanger.
3. The catalytic diesel hydro-upgrading system of claim 1, wherein the inlet of the reaction product air cooler is in communication with a demineralized water supply line of the hydrogenation system.
4. The catalytic diesel hydro-upgrading system of claim 1, wherein the recycle hydrogen compressor is connected to a third heat exchanger, the third heat exchanger is connected to the pipeline between the first heat exchanger and the second heat exchanger, and the pipeline between the recycle hydrogen compressor and the third heat exchanger is connected to a hydrogen supply pipeline of a hydrogen supply system.
5. The catalytic diesel hydro-upgrading system of claim 1, wherein the second heat exchanger is a wound tubular structure heat exchanger.
6. The catalytic diesel hydro-upgrading system of claim 1, wherein the recycle hydrogen compressor is a 3.5MPa steam driven rotary circulator.
7. The catalytic diesel hydro-upgrading system of claim 2, wherein the feed pump is a high pressure centrifugal pump.
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| CN202122741986.6U CN216808706U (en) | 2021-11-10 | 2021-11-10 | Catalytic diesel oil hydrogenation modification system |
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| CN202122741986.6U CN216808706U (en) | 2021-11-10 | 2021-11-10 | Catalytic diesel oil hydrogenation modification system |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114133957A (en) * | 2021-11-10 | 2022-03-04 | 中国石油化工股份有限公司 | Catalytic diesel oil hydrogenation modification system and modification method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114133957A (en) * | 2021-11-10 | 2022-03-04 | 中国石油化工股份有限公司 | Catalytic diesel oil hydrogenation modification system and modification method thereof |
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