CN216711841U - Mariculture effluent treatment plant - Google Patents

Mariculture effluent treatment plant Download PDF

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Publication number
CN216711841U
CN216711841U CN202122892376.6U CN202122892376U CN216711841U CN 216711841 U CN216711841 U CN 216711841U CN 202122892376 U CN202122892376 U CN 202122892376U CN 216711841 U CN216711841 U CN 216711841U
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plate
anode plate
mariculture
wastewater treatment
treatment device
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CN202122892376.6U
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王成达
黄潇
于江华
孙鹏飞
朱佳
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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Abstract

The utility model discloses a mariculture wastewater treatment device, and belongs to the technical field of sewage treatment. The mariculture wastewater treatment device comprises a box body and a power supply; the one end of box is equipped with the water inlet, and the other end is equipped with the delivery port, by supreme iron carbon, pyrite and the ferrihydrite of filling in proper order down in the box, in first anode plate, second anode plate and negative plate all insert in iron carbon, pyrite and the ferrihydrite, first anode plate, second anode plate and negative plate interval set up, first anode plate and second anode plate with the positive pole of power links to each other, the negative plate with the negative pole of power links to each other. The utility model provides a mariculture wastewater treatment device, which solves the technical problems of high cost and poor treatment effect of mariculture wastewater treatment in the prior art.

Description

Mariculture effluent treatment plant
Technical Field
The utility model relates to a mariculture wastewater treatment device, and belongs to the technical field of sewage treatment.
Background
With the rapid development of the mariculture industry, the discharge amount of the mariculture wastewater is remarkably increased, and the problems therewith are increasingly obvious. The direct discharge of pollutants in mariculture wastewater without effective treatment can seriously pollute the water body and even destroy the ecological balance of the ocean. Because the quality of the mariculture wastewater is complex, how to effectively treat nitrogen, phosphorus and COD in the mariculture wastewater is a hotspot and a difficulty of current research. In order to realize the continuous and healthy development of the mariculture industry, a cheap, efficient and safe mariculture wastewater treatment method is urgently needed, and the mariculture wastewater is purified and then discharged up to the standard, so that the coordinated development of mariculture and marine environment protection is realized.
At present, the conventional physicochemical combined technology is researched more, but the structure mainly based on the conventional treatment method has certain defects. For example, application No. 201920621345.7 discloses a mariculture wastewater treatment device, which utilizes microwave to promote the culture wastewater and medicament to generate flocculation and precipitation, thereby purifying the mariculture wastewater. Although the patent has good flocculation effect, the treatment method mainly relying on adding medicaments has limited effect, the effluent quality cannot be ensured, and the addition of the flocculating agent is easy to cause secondary pollution. Application patent No. 201720793806.X discloses an electrolytic nitrogen and phosphorus removal device, which has the effect of removing nitrogen, phosphorus and COD, but consumes a large amount of electric energy, and the water inlet mode is not favorable for sufficient contact of pollutants and the electrolytic device. In contrast, biological treatment is considered to be a preferred method, and although structures based on biological treatment are effective in wastewater treatment, such devices are generally complicated in structure and occupy a large area. For example, in the chinese utility model with application No. 201920172501.6, a mariculture wastewater treatment device is disclosed, which comprises a biological aerated filter, a membrane bioreactor, a first aeration component and a second aeration component, and the device has poor environmental impact resistance and membrane pollution. In the chinese utility model patent of application patent No. 201420655436.X, an artificial wetland system for mariculture waste water treatment is disclosed, it mainly includes equalizing basin, acidizing hydrolysis tank, wetland region and play pond. Although the system can effectively treat pollutants, the system has long running period and slow effect and cannot effectively treat the wastewater in a short time.
SUMMERY OF THE UTILITY MODEL
The utility model aims to overcome the defects in the prior art, provides a mariculture wastewater treatment device, and solves the technical problems of high cost and poor treatment effect of mariculture wastewater treatment in the prior art.
In order to achieve the aim, the utility model provides a mariculture wastewater treatment device, which comprises a box body and a power supply; the one end of box is equipped with the water inlet, and the other end is equipped with the delivery port, by supreme iron carbon, pyrite and the ferrihydrite of filling in proper order down in the box, in insert first anode plate, second anode plate and negative plate in iron carbon, pyrite and the ferrihydrite, first anode plate, second anode plate and negative plate interval set up, first anode plate and second anode plate with the positive pole of power links to each other, the negative plate with the negative pole of power links to each other.
Furthermore, the water inlet is positioned at the bottom of one end of the box body, and the water outlet is positioned at the top of the other end of the box body.
Furthermore, the first anode plate and the second anode plate are made of iron sheets.
Furthermore, the negative plate is made of a graphite sheet material.
The medicine tube fixing device is characterized by further comprising a support, a connecting plate and a medicine tube, wherein the support is fixedly connected with the support, an opening is formed in the inner side of the support, the connecting plate is inserted into the opening, a first through groove is formed in the connecting plate, and the medicine tube is placed in the first through groove.
Furthermore, a second through groove is further formed in the connecting plate, a containing cup is placed in the second through groove, and hydrogen peroxide solution is placed in the containing cup.
Compared with the prior art, the utility model has the following beneficial effects:
iron carbon, pyrite and ferrihydrite are sequentially filled in the box body from bottom to top, the iron carbon can effectively enhance the potential difference between the first anode plate, the second anode plate and the cathode plate so as to degrade pollutants which are difficult to degrade, and can also adsorb pollutants in the mariculture wastewater to a certain extent, the pyrite can effectively promote autotrophic denitrification of attached bacteria, the abundance of microorganisms is improved, the ferrihydrite can effectively adsorb pollutants in the mariculture wastewater and precipitates after reaction, and can catalyze hydrogen peroxide solution to remove organic matters; the first anode plate, the second anode plate and the cathode plate are inserted into the iron carbon, the pyrite and the ferrihydrite, and the electrolysis effect is further enhanced due to the double-anode structure; by adopting the mode of combining the filler and the electrolysis, the treatment cost of the mariculture wastewater is effectively reduced, and the treatment effect is obviously enhanced;
the water inlet is located the bottom of box one end, and the delivery port is located the top of the box other end, not only can make mariculture waste water fully contact with iron carbon, pyrite and ferrihydrite, can play filterable effect moreover.
Drawings
FIG. 1 is a schematic structural view of a mariculture wastewater treatment apparatus according to an embodiment of the present invention;
in the figure: 1. a water outlet; 2. a support; 3. a support; 4. ferrihydrite; 5. pyrite; 6. iron carbon; 7. a cathode plate; 8. a second anode plate; 9. a first anode plate; 10. a water inlet; 11. a medicine tube; 12. a containing cup; 13. a power source; 14. and (6) connecting the plates.
Detailed Description
The utility model is further described below with reference to the accompanying drawings. The following examples are only for illustrating the technical solutions of the present invention more clearly, and the protection scope of the present invention is not limited thereby.
In the description of the present invention, it is to be understood that the terms "center", "longitudinal", "lateral", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", and the like, indicate orientations or positional relationships based on those shown in the drawings, and are used only for convenience in describing the present invention and for simplicity in description, and do not indicate or imply that the referenced devices or elements must have a particular orientation, be constructed and operated in a particular orientation, and thus, are not to be construed as limiting the present invention. Furthermore, the terms "first", "second", etc. are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first," "second," etc. may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless otherwise specified.
In the description of the present invention, it should be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art through specific situations.
As shown in fig. 1, the device for treating mariculture wastewater provided by the embodiment of the utility model comprises a tank and a power supply 13;
iron carbon 6, pyrite 5 and ferrihydrite 4 are sequentially filled in the box body from bottom to top, a first anode plate 9, a second anode plate 8 and a cathode plate 7 are inserted into the iron carbon 6, the pyrite 5 and the ferrihydrite 4 at intervals, the first anode plate 9 and the second anode plate 8 are connected with the anode of a power supply 13 through copper wire leads, and the cathode plate 7 is connected with the cathode of the power supply 13 through the copper wire leads. Iron carbon 6 not only can effectively strengthen first anode plate 9, the potential difference between second anode plate 8 and negative plate 7, and then degrade the pollutant of difficult degradation, and also can adsorb the pollutant in the mariculture waste water to a certain extent, pyrite 5 can effectively promote the autotrophic denitrification of attached bacteria, improve microorganism abundance, ferrihydrite 4 not only can effectively adsorb the pollutant in the mariculture waste water and the sediment after the reaction, and can catalyze hydrogen peroxide solution and get rid of the organic matter, the double anode structure in the box can further strengthen the electrolysis effect, this patent is through adopting the mode that packs and electrolysis combined together, not only effectively reduced the treatment cost of mariculture waste water, and show the reinforcing treatment effeciency.
The bottom of the one end of box is provided with water inlet 10, and the other end top is provided with delivery port 1, not only can make mariculture waste water and iron carbon 6, pyrite 5 and the abundant contact of ferrihydrite 4, can play filterable effect moreover.
In one embodiment, the first anode plate 9 and the second anode plate 8 are made of iron sheets, which can increase iron ions required for reaction, and the cathode plate 7 is made of graphite sheets.
The mariculture wastewater treatment device provided by the embodiment of the utility model further comprises a support 3, a bracket 2, a connecting plate 14 and a medicine pipe 11; support 3 and support 2 weld mutually, the opening has been seted up to the inboard of support 2, fishplate bar 14 is pegged graft in the inboard opening of support 2, fishplate bar 14 is located to locate to have seted up first logical groove between first anode plate 9 and the second anode plate 8, pencil 11 is placed in first logical groove, the afterbody of pencil 11 is cavity round platform structure, can avoid pencil 11 to put into first logical groove when landing, it leads to the groove still to be equipped with the second on fishplate bar 14, place in the second logical groove and hold cup 12, it is the bowl form to hold cup 12, can avoid holding cup 12 to put into the second and lead to the groove when landing, hold the hydrogen peroxide solution of having placed in cup 12, when water inlet 10 lets in the mariculture waste water, the hydrogen peroxide solution of holding in cup 12 is poured into to pencil 11.
In the embodiment, the reaction temperature in the box body is 20-28 ℃, the conductivity of the solution is always more than 24 ms/cm in the whole reaction process, the ion reaction speed is high, and the consumed electric energy is small. The specific reaction process is as follows: the nitrate nitrogen in the seawater culture wastewater is electrolyzed to generate nitrogen and ammonia nitrogen, a large amount of sodium chloride exists in the seawater culture wastewater, hypochlorous acid generated by electrolyzing the sodium chloride can continuously react with the ammonia nitrogen to generate nitrogen, and the nitrogen is continuously generated around the negative plate 7 along with the reaction, so that the aim of denitrification is fulfilled; in addition, bacteria attached to the iron carbon 6, the pyrite 5, and the ferrihydrite 4 can remove nitrate nitrogen that has not been completely electrolyzed by autotrophic denitrification. The ionic phosphorus and iron ions in the mariculture wastewater generate complex precipitation, so that the purpose of removing phosphorus is achieved. The hypochlorous acid generated by electrolysis and the action of microorganisms can effectively degrade organic matters. Hydrogen peroxide is added between the two anode plates through the charge tube 11, and the hydrogen peroxide and ferrous ions generate Fenton oxidation reaction under the catalysis of the ferrihydrite 4, so that the removal effect on organic matters is strengthened. When the treated mariculture wastewater passes through the water body ore at the uppermost layer, the ferrihydrite 4 further adsorbs unremoved pollutants and precipitates after reaction, and finally flows out of the water outlet 1. This patent can effectually get rid of nitrogen, phosphorus and COD in the mariculture waste water, realizes the coordinated development of mariculture and environmental protection.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications and variations can be made without departing from the technical principle of the present invention, and these modifications and variations should also be regarded as the protection scope of the present invention.

Claims (6)

1. A mariculture wastewater treatment device is characterized by comprising a box body and a power supply; the one end of box is equipped with the water inlet, and the other end is equipped with the delivery port, by supreme iron carbon, pyrite and the ferrihydrite of filling in proper order down in the box, in first anode plate, second anode plate and negative plate all insert in iron carbon, pyrite and the ferrihydrite, first anode plate, second anode plate and negative plate interval set up, first anode plate and second anode plate with the positive pole of power links to each other, the negative plate with the negative pole of power links to each other.
2. The mariculture wastewater treatment device according to claim 1, wherein the water inlet is located at a bottom of one end of the tank body, and the water outlet is located at a top of the other end of the tank body.
3. The mariculture wastewater treatment device according to claim 1, wherein the first anode plate and the second anode plate are made of iron sheets.
4. The mariculture wastewater treatment device according to claim 1, wherein the cathode plate is made of a graphite sheet.
5. The mariculture wastewater treatment device according to claim 1, further comprising a support, a bracket, a connection plate and a drug tube, wherein the support is fixedly connected with the bracket, an opening is formed in the inner side of the bracket, the connection plate is inserted into the opening, a first through groove is formed in the connection plate, and the drug tube is placed in the first through groove.
6. The mariculture wastewater treatment device according to claim 5, wherein a second through groove is further formed in the connecting plate, a containing cup is placed in the second through groove, and a hydrogen peroxide solution is placed in the containing cup.
CN202122892376.6U 2021-11-24 2021-11-24 Mariculture effluent treatment plant Active CN216711841U (en)

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CN202122892376.6U CN216711841U (en) 2021-11-24 2021-11-24 Mariculture effluent treatment plant

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Application Number Priority Date Filing Date Title
CN202122892376.6U CN216711841U (en) 2021-11-24 2021-11-24 Mariculture effluent treatment plant

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115466010A (en) * 2022-09-01 2022-12-13 南京信息工程大学 Mariculture wastewater treatment system and control method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115466010A (en) * 2022-09-01 2022-12-13 南京信息工程大学 Mariculture wastewater treatment system and control method

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