CN215882663U - Processing equipment of fiber reinforced polyester composite material - Google Patents
Processing equipment of fiber reinforced polyester composite material Download PDFInfo
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- CN215882663U CN215882663U CN202121612101.6U CN202121612101U CN215882663U CN 215882663 U CN215882663 U CN 215882663U CN 202121612101 U CN202121612101 U CN 202121612101U CN 215882663 U CN215882663 U CN 215882663U
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Abstract
The utility model discloses processing equipment of a fiber reinforced polyester composite material, which comprises a first conveyor belt, a fiber mixing device, a second conveyor belt and a double-screw extruder which are sequentially arranged; a cutting mechanism for cutting the inorganic fiber yarns and the polyester fiber yarns into preset lengths is arranged above the first conveyor belt; the fiber mixing device comprises a driving roller, a driving roller cavity and a driving roller position regulator, wherein the surface of the driving roller is fully distributed with barbs; and a powder scattering device is arranged above the second conveying belt and comprises a feeding screw and an oscillator. The inorganic fiber and the polyester fiber are mixed and dispersed through a specific device, then are dispersed and mixed with the lubricant, the antioxidant and other auxiliary agents, and finally are conveyed to a screw extruder for extrusion molding to prepare the fiber reinforced polyester composite material, and the fiber reinforced polyester composite material can be continuously produced.
Description
Technical Field
The utility model relates to the field of composite material preparation equipment, in particular to processing equipment for a fiber reinforced polyester composite material.
Background
Polyester is a high molecular material prepared by the polycondensation reaction of polyhydric alcohol and polybasic acid. In general, polyesters mainly refer to linear thermoplastic resins such as polyethylene terephthalate (PET) and polybutylene terephthalate (PBT). The high-melting-point high-temperature-resistant heat-resistant insulating material has the characteristics of high melting point, excellent heat resistance, electric insulating property, dimensional stability and the like, and is widely applied to the fields of electronic appliances, automobiles, household appliances and the like.
At present, in order to further improve the strength and heat resistance of polyester materials and exert the advantages of high melting point and high crystallization performance of the polyester materials, a fiber reinforced polyester composite material with high strength, high modulus and high heat resistance can be prepared by generally adding a certain amount of inorganic fibers and performing a screw extrusion modification method on the inorganic fibers. In the screw extrusion modification process, the resin is usually added to the screw extruder in the form of particles or powder, and the fibers are usually added in the form of chopped fiber bundles or continuous fiber bundles, and the mutual wetting and bonding of the resin and the fibers are realized through the high-speed shearing mixing action of the screw. Due to the reasons that the retention time of materials in a screw extruder is short (usually 1-2min), fibers in a fiber bundle form (the number of the fibers is more than 1000) are difficult to uniformly disperse, good infiltration coating of the fibers and resin is difficult to form, and the like, the actual performance of the fiber reinforced polyester composite material is far lower than the theoretical value, and a great promotion space exists for the performance improvement of the composite material.
At present, the comprehensive mechanical property of the fiber reinforced polyester composite material is improved by adopting a method of surface treatment on fibers. A method for preparing a carbon fiber reinforced polyester composite is proposed in patent application 201810435929. The method comprises the steps of coating the surface of carbon fiber with a thermosetting resin sizing agent, carrying out heat treatment at the temperature of 250-350 ℃, and then carrying out screw extrusion to obtain the high-strength carbon fiber reinforced polyester composite material with the tensile strength of 160-220MPa and the bending strength of 240-290 MPa. The key point of the patent technology is that the bonding force and the infiltration effect between the fibers and the resin are improved by carrying out surface chemical modification on the carbon fibers, so that the aim of improving the comprehensive performance of the polyester composite material is fulfilled. However, the technique does not fundamentally solve the problem of good impregnation and coating between the fibers in the form of fiber bundles and the resin.
SUMMERY OF THE UTILITY MODEL
In view of the above, the present invention provides a method for preparing a fiber-reinforced polyester composite material, in which fibers and polyester resin are fully impregnated and coated, and the method can realize the preparation of the fiber-reinforced polyester composite material with higher comprehensive performance at the same density, and also discloses a processing device for implementing the method.
A processing device of a fiber reinforced polyester composite material comprises a first conveyor belt, a fiber mixing device, a second conveyor belt and a double-screw extruder which are sequentially arranged;
a cutting mechanism for cutting the inorganic fiber yarns and the polyester fiber yarns into preset lengths is arranged above the first conveyor belt;
the fiber mixing device comprises a feeding traction belt, a driving roller with barbs distributed on the surface, a driving roller cavity and a driving roller position regulator;
and a powder scattering device is arranged above the second conveying belt and comprises a feeding screw and an oscillator.
Preferably, a cutting mechanism for cutting the inorganic fiber yarns and the polyester fiber yarns into preset lengths is arranged above the first conveyor belt; the cutting mechanism comprises a traction compression roller and a cutting roller which are oppositely arranged.
Preferably, the fiber mixing device comprises a feeding traction belt, a driving roller with barbs distributed on the surface, a driving roller cavity and a driving roller position regulator; the driving roller is arranged in the driving roller cavity. In order to ensure the sufficient dispersion mixing and the dispersion mixing efficiency of the inorganic fibers and the polyester fibers, the matching between the dispersion rate and the dispersion mixing efficiency can be realized by adjusting the position adjuster of the driving roller and adjusting the distance between the driving roller and the cavity of the driving roller.
The dusting device consists of a small feeding screw and an oscillator. The material realizes measurement unloading through the rotational speed of little screw rod, and even dusting unloading is realized to rethread vibrator.
The processing equipment of the fiber reinforced polyester composite material further comprises: the cooling device, the granulator, the filter screen and the storage tank are arranged in sequence; the cooling device is connected with an extrusion opening of the double-screw extruder.
In order to achieve the purpose, the utility model provides the following technical scheme: a preparation method of a fiber reinforced polyester composite material comprises the following components in percentage by weight:
more preferably:
in the above fiber-reinforced polyester composite, the polyester fiber is a polyethylene terephthalate (PET) fiber or a polybutylene terephthalate (PBT) fiber or a poly 1.3 trimethylene terephthalate (PTT) fiber; the diameter of the polyester fiber is 1-10dtex, and the fiber length is 10-100 mm.
In the fiber reinforced polyester composite material, the inorganic fibers are glass fibers, carbon fibers and basalt fibers; the diameter of the inorganic fiber is 1-20dtex, and the fiber length is 10-100 mm.
In the fiber reinforced polyester composite material, the antioxidant is any combination of hindered phenol antioxidant and phosphite antioxidant.
In the fiber reinforced polyester composite material, the lubricant is mesonic acid amide, oleic acid amide, polyethylene wax and pentaerythritol stearate.
In the above method for preparing a fiber reinforced polyester composite, the method comprises the steps of:
step 1: cutting inorganic fibers and polyester fibers into short-cut inorganic fibers and short-cut polyester fibers with preset lengths through a cutting mechanism, and then conveying the short-cut inorganic fibers and the short-cut polyester fibers through a first conveyor belt to enter a fiber mixing device for mixing to obtain a first mixture;
step 2: the first mixture enters a second conveyor belt, and a dusting device above the second conveyor belt disperses and mixes auxiliaries such as a lubricant and an antioxidant with the first mixture to obtain a second mixture;
and step 3: and conveying the second mixture to a feed inlet of a double-screw extruder, and carrying out extrusion molding to obtain the fiber reinforced polyester composite material.
In the step 1, the polyester and the inorganic continuous fibers are cut into preset lengths by a cutting machine, and then the two fibers are added into a fiber mixing device to be fully fluffed and dispersed to form a fiber mixture.
The cutting conditions of the cutting mechanism are as follows: the yarn cutting speed is 2-8 Hz, and the yarn cutting time is 0.3-3 min; the length of the cut yarn is: 10-60 mm; most preferably, the yarn cutting speed is 5Hz, and the yarn cutting time is 1 min; the length of the cut yarn is: 30 mm.
The mixing conditions of the fiber mixing device are as follows: the speed of the driving roll is 1000-3000 r/min, the distance between the driving roll and the driving roll cavity is 5-30 mm, and preferably, the speed of the driving roll is 1500 r/min, and the distance between the driving roll and the driving roll cavity is 10 mm.
And 2, enabling the fiber mixture to pass through a conveyor belt device, arranging a powder scattering machine above the middle of the conveyor belt, and uniformly scattering the auxiliary agent system in the fiber mixture to form a mixture. The dusting and blanking conditions of the dusting device are as follows: controlling the powder spreading and blanking speed to be 20-100 g/min and the vibrator frequency to be 2-8 Hz, further preferably controlling the powder spreading and blanking speed to be 50g/min and the vibrator frequency to be 5Hz,
in step 3, the temperature of the rear part (i.e. one end of the feed port) of the cylinder of the double-screw extruder is 160-220 ℃, the temperature of the middle part of the cylinder is 220-260 ℃, the temperature of the front part (i.e. one end of the discharge port) of the cylinder is 200-240 ℃, the temperature of the head is 250-270 ℃, and the rotation speed of the screw is 100-300 r/min (most preferably 150 r/min).
In the present invention, the purpose of step 1 is to enable the inorganic fibers and polyester fibers in the form of fiber bundles (thousands of single fibers) to be sufficiently broken into single fibers or a dispersion level of a plurality of single fibers, so that the inorganic fibers and polyester fibers are sufficiently dispersed and mixed, and the polyester fibers and the inorganic fibers are sufficiently contacted and dispersed on a micrometer scale.
In the preparation method of the fiber reinforced polyester composite material, the step 2 aims to enable the lubricant and the antioxidant to be dispersed in the fiber mixture in a powder form to realize basic pre-dispersion, and is beneficial to realizing the sufficient dispersion of three phases of the resin, the fiber and the auxiliary agent in the subsequent extrusion plasticizing process.
Compared with the prior art, the utility model has the following advantages:
according to the processing equipment of the fiber reinforced polyester composite material, the inorganic fiber and the polyester fiber are mixed and dispersed through a specific device, then are dispersed and mixed with the lubricant, the antioxidant and other auxiliaries, and finally are conveyed to the screw extruder to be extruded and molded to obtain the fiber reinforced polyester composite material.
The method adopts the inorganic fiber and polyester fiber mixing pretreatment procedure and the auxiliary agent dusting dispersion procedure, can realize micron-size dispersion of the inorganic fiber and the polyester resin before the extrusion molding procedure, greatly improves the contact area of the polyester resin and the inorganic fiber, can effectively avoid the problem of uniform dispersion of inorganic fiber bundles and a resin system due to short extrusion residence time and difficulty in fully scattering the inorganic fiber bundles in the extrusion molding process, and fundamentally solves the problem of fiber and resin dispersion under high fiber filling content. Thus, the utility model has the following advantages:
1. the composite material has higher comprehensive mechanical property.
2. The product has good surface appearance quality, high gloss and no floating fiber.
3. The screw extrusion processing conditions are milder and controllable.
4. The screw extrusion processing with higher fiber content can be realized, and the wear to screw extrusion equipment is small.
Drawings
Fig. 1 is a schematic structural diagram of an embodiment of a processing apparatus according to the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Working apparatus embodiment
This example mainly illustrates processing equipment for achieving the objects of the present invention, and the following examples describe specific composite materials and methods for making the same.
The processing apparatus of the present invention is as follows (see fig. 1):
as shown in fig. 1, a processing device of a fiber reinforced polyester composite material comprises a cutting device 2, a conveyor belt 1, a fiber mixing device 3, a conveyor belt 4, a dusting device 5, a twin-screw extruder 6, a cooling device 7, a granulator 8, a filter screen 9 and a storage tank 10 which are arranged in sequence;
a cutting mechanism 2 for cutting the inorganic fiber yarn A and the polyester fiber yarn B into preset lengths is arranged above the conveyor belt 1;
the cutting mechanism 2 comprises a traction compression roller 21 and a cutting roller 22 which are oppositely arranged;
the fiber mixing device 3 mainly comprises a feeding traction belt, a driving roller 32 with barbs distributed on the surface, a driving roller cavity 33 and a driving roller position regulator 34; in order to ensure sufficient dispersion mixing and dispersion mixing efficiency of the inorganic fibers and the polyester fibers, the distance between the driving roll 32 and the driving roll cavity 33 can be adjusted by adjusting the driving roll position adjuster 34 to match the dispersion rate and the dispersion mixing efficiency.
The powdering device 5 is composed of a small feeding screw 51 and an oscillator 52. The material is metered and discharged through the rotating speed of the small screw 51, and then uniform powder spreading and discharging are realized through the vibrator 52.
Inventive examples and comparative examples are shown in table 1 below:
table 1 example materials recipe table (mass percent)
In examples 1-3 and comparative example 2, the polyester used PBT continuous fiber, the fiber diameter is 5.5 dtex; in examples 4 to 6 and comparative examples 1 and 3, PET continuous fibers were used as the polyester, and the fiber diameter was 5.5 dtex; in comparative example 4, the polyester was PET polyester chip characterized by chemical fiber and having a BG802 designation; the carbon fiber is T300 of Nippon Dongli chemical, and the glass fiber is alkali-free glass fiber EDR14-2000 of Chongqing megalite.
The material formulations for examples 1-6 and comparative examples 1-3 are shown in Table 1.
Preparation of examples 1 to 6:
step 1: cutting and mixing inorganic fibers and polyester fibers to obtain a first mixture;
the step 1 specifically comprises the following substeps:
step 1-1: cutting the filamentous inorganic fibers A and the filamentous polyester fibers B in a certain proportion into short-cut inorganic fibers and short-cut polyester fibers with preset lengths through a cutting mechanism 2 by a compression roller; adjusting the yarn cutting speed of the cutting mechanism to be 5Hz, and the yarn cutting time to be 1 min; the length of the cut yarn is: 30 mm.
Step 1-2: the chopped carbon fibers and the chopped polyester fibers enter a fiber mixing device 3 through a conveyor belt, active mixing is set, the speed of a roller is 1500 rpm, and the distance between the active mixing roller and a cavity is 10 mm; a fiber mixture (i.e., a first mixture) can be prepared.
Step 2: and (3) enabling the fiber mixture to pass through a powdering device 5 through a conveyor belt 4, controlling the powder spreading and blanking speed to be 50g/min and the vibrator frequency to be 5Hz, and obtaining a second mixture.
And step 3: and (3) feeding the second mixture into a double-screw extruder through a feeding port, carrying out extrusion molding to obtain fiber reinforced polyester composite particles, and carrying out performance detection by preparing standard sample strips through injection molding. Wherein the temperature of the rear part of the extruder cylinder is 160-220 ℃, the temperature of the middle part of the cylinder is 220-260 ℃, the temperature of the front part of the cylinder is 200-240 ℃, the temperature of the head is 250-270 ℃, and the rotating speed of the screw is 150 r/min.
The preparation method of comparative examples 1 to 3 was:
(1) cutting the filamentous inorganic fibers and the filamentous polyester fibers in a certain proportion into short-cut inorganic fibers and short-cut polyester fibers with preset lengths through a cutting mechanism by a compression roller; adjusting the yarn cutting speed of the cutting mechanism to be 5Hz, and the yarn cutting time to be 1 min; the length of the cut yarn is: 30 mm;
(2) and (2) mixing the mixed fiber obtained in the step (1), an antioxidant and a lubricant by a high-speed dispersion machine, performing melt extrusion by a double-screw extruder to obtain fiber reinforced polyester composite material particles, and performing injection molding to prepare a standard sample strip for detection. Wherein the temperature of the rear part of the extruder cylinder is 160-220 ℃, the temperature of the middle part of the cylinder is 220-260 ℃, the temperature of the front part of the cylinder is 200-240 ℃, the temperature of the head is 250-270 ℃, and the rotating speed of the screw is 300 r/min.
The preparation method of comparative example 4 was:
(1) adding the glass fiber, the PET slices and the auxiliary agent into a high-speed mixer, and fully and uniformly mixing;
(2) and (2) melting and extruding the uniform mixture obtained in the step (1) through a double-screw extruder, carrying out traction, cooling, granulating and drying to obtain fiber reinforced polyester composite particles, and carrying out injection molding to prepare standard sample strips for detection. Wherein the temperature of the rear part of the charging barrel of the extruder is 200-220 ℃, the temperature of the middle part of the charging barrel is 240-265 ℃, the temperature of the front part of the charging barrel is 230-240 ℃, the temperature of the head is 260 ℃, and the rotating speed of the screw is 300 r/min.
The test items and test methods and results are shown in table 2 below:
TABLE 2
The surface appearance was evaluated by observing the gloss of the 100mm by 2mm disk appearance and the presence of floating fibers. The evaluation criteria are specifically: 1: worst (large amount of floating fiber, rough surface); 2: poor (floating fiber, rough surface); 3: general (small amount of floating fiber); 4: better (no floating fiber); 5: most preferred is (no fiber floating, glossy surface).
From the data of examples 1-6 and comparative examples 1-4, it can be seen that compared with the conventional technology (comparative example 4) of using screw extrusion to realize blending and dispersion of inorganic fibers and resin fibers (comparative example 1-3) and blending and dispersion of inorganic fibers and resin chips, the glass fiber reinforced and carbon fiber polyester composite material (examples 1-6) prepared by the process route (fiber-containing mixing device) of the present invention has the advantages of improved tensile strength, bending strength and modulus by more than 25% and improved notch impact strength by about 30% under the premise of equal fiber filling amount and density, meanwhile, the surface quality is remarkably improved, the surface quality of 50% and 60% of the fiber reinforced polyester composite material adopting the technology can achieve the effect of no floating fiber, and the technical problem that the fiber is easy to separate out in the process of high-fiber reinforced composite material is solved.
From the above examples and comparative examples, it can be concluded that: the method adopts the step of mixing and pretreating the inorganic fiber and the polyester fiber, so that the inorganic fiber and the polyester resin are dispersed in a micron size before the extrusion molding step, the problem of fiber and resin dispersion under high fiber filling content is solved essentially, and tests prove that the fiber reinforced composite material prepared by the method has better comprehensive mechanical property and does not have the problems of surface fiber precipitation and the like.
It will be evident to those skilled in the art that the utility model is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the utility model being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Claims (6)
1. The processing equipment of the fiber reinforced polyester composite material is characterized by comprising a first conveyor belt, a fiber mixing device, a second conveyor belt and a double-screw extruder which are sequentially arranged;
a cutting mechanism for cutting the inorganic fiber yarns and the polyester fiber yarns into preset lengths is arranged above the first conveyor belt;
the fiber mixing device comprises a driving roller, a driving roller cavity and a driving roller position regulator, wherein the surface of the driving roller is fully distributed with barbs;
and a powder scattering device is arranged above the second conveying belt and comprises a feeding screw and an oscillator.
2. The apparatus for processing fiber reinforced polyester composite material according to claim 1, wherein the fiber mixing device further comprises a feeding pulling belt.
3. The apparatus for processing fiber reinforced polyester composite material according to claim 1, wherein the cutting mechanism comprises a drawing press roll and a cutting roll which are oppositely arranged.
4. The apparatus of claim 1, wherein the drive roll is disposed within the drive roll cavity.
5. The apparatus for processing fiber reinforced polyester composite material according to claim 1, further comprising: cooling device, pelleter, filter screen and the storage tank that sets gradually.
6. The apparatus for processing fiber reinforced polyester composite material according to claim 5, wherein the cooling device is connected to the extrusion outlet of the twin-screw extruder.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117207485A (en) * | 2023-11-09 | 2023-12-12 | 四川中科航宇新材料有限公司 | Glass fiber reinforced polyarylene sulfide material extrusion pretreatment screw device and installation method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117207485A (en) * | 2023-11-09 | 2023-12-12 | 四川中科航宇新材料有限公司 | Glass fiber reinforced polyarylene sulfide material extrusion pretreatment screw device and installation method |
| CN117207485B (en) * | 2023-11-09 | 2024-03-12 | 四川中科航宇新材料有限公司 | Glass fiber reinforced polyarylene sulfide material extrusion pretreatment screw device and installation method |
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