CN215527815U

CN215527815U - Battery case and battery

Info

Publication number: CN215527815U
Application number: CN202120929231.6U
Authority: CN
Inventors: 夏祖见; 张丰学; 王允
Original assignee: Guoyan Xinneng Shenzhen Technology Co ltd
Current assignee: Guoyan Xinneng Shenzhen Technology Co ltd
Priority date: 2021-04-30
Filing date: 2021-04-30
Publication date: 2022-01-14
Anticipated expiration: 2031-04-30

Abstract

The utility model discloses a battery shell and a battery, wherein the battery shell is divided into a bottom shell and a sealing cover, the sealing cover is divided into an outer contact layer, an insulating layer and an inner contact layer, wherein an electrode contact part of the outer contact layer can penetrate through the insulating layer and the inner contact layer to be electrically conducted with one pole of a battery cell, the other pole of the battery cell can be electrically conducted with the bottom shell, the battery cell can be packaged after the inner contact layer is welded with the bottom shell, and the bottom shell can be insulated with the outer contact layer due to the fact that the inner contact layer is insulated with the outer contact layer through the insulating layer, so that mutual conduction and short circuit of two electrodes of the battery cell can be prevented; because the inner contact layer and the outer contact layer of the sealing cover are insulated in advance, when the sealing cover is used for packaging the bottom shell, only the inner contact layer and the bottom shell need to be welded, an insulating film does not need to be arranged, and therefore the packaging process of the battery can be simplified, and the packaging efficiency is improved.

Description

Battery case and battery

Technical Field

The utility model relates to the technical field of batteries, in particular to a battery shell and a battery.

Background

The battery shell of the conventional button battery is formed by splicing an anode shell and a cathode shell, and the anode shell and the cathode shell need to be insulated so as to avoid short circuit of the button battery; in the related art, insulation is realized by arranging an insulating film between the anode shell and the cathode shell, the anode shell and the cathode shell are welded and fixed, the insulating film is difficult to set in a processing process, the button cell is difficult to process, and the processing efficiency is reduced.

SUMMERY OF THE UTILITY MODEL

The utility model mainly aims to provide a battery case for a button battery, and aims to solve the technical problem of how to improve the processing efficiency of the battery.

In order to achieve the above object, the present invention provides a battery case including a cup-shaped bottom case and a lid for sealing an opening of the bottom case;

the bottom shell comprises a circular or oval bottom wall and an annular side wall;

the sealing cover sequentially comprises an outer contact layer, an insulating layer and an inner contact layer from outside to inside;

the maximum outer diameter D1 of the outer contact layer is smaller than the maximum outer diameter D2 of the inner contact layer;

the external contact layer comprises an electrode contact part and a conductive bonding part;

the insulating layer comprises an insulating bonding part and an insulating opening part;

the inner contact layer comprises a welding part, a welding bonding part and a welding perforated part;

a welding supporting part is arranged on the side wall close to the opening;

the electrode contact part faces the bottom shell through the insulating perforated part and the welding perforated part and is used for being electrically connected with one of the electric cores so that the external contact layer is electrically communicated with the electric cores;

the conductive bonding part is used for being seamlessly bonded with the insulating bonding part so as to strengthen the strength of the sealing cover and prevent external water from permeating into the battery shell;

the welding part is used for being connected with the welding supporting part in a welding mode so that the sealing cover and the bottom shell are sealed;

the welding bonding part is used for being seamlessly bonded with the insulating bonding part so as to strengthen the strength of the sealing cover, reduce the direct contact area of the insulating bonding part and the inside of the battery case and prevent external water from permeating into the inside of the battery case;

before the sealing cover and the bottom shell are sealed, the insulating bonding part, the conductive bonding part and the welding bonding part are bonded in a seamless mode.

Optionally, the insulating bonding part is seamlessly bonded with the conductive bonding part and the welding bonding part after being melted by an insulating electrolyte corrosion-resistant material with a thermal shrinkage rate of 6% or less at 100 ℃.

Optionally, the thickness d3 of the insulating bonding part is 0.01mm-2.5 mm; and/or the contact area S0 between the insulation bonding part and the inside of the battery case meets S0< ═ π D2 × D3 × 1/2.

Optionally, the material of the outer contact layer is stainless steel, and the thickness d4 of the outer contact layer is 0.1mm-0.25 mm; and/or the material of the inner contact layer is stainless steel, and the thickness d5 of the inner contact layer is 0.1mm-0.25 mm.

Optionally, the insulating layer is made of one or more of PP, PFA, PVDF, PTFE, ETFE, and PVC.

Optionally, the bonding strength between the insulating bonding part and the conductive bonding part and between the insulating bonding part and the welding bonding part at a cooling normal temperature is greater than or equal to 1.0N per square millimeter and less than or equal to 5.0N per square millimeter.

Optionally, an area S1 of the insulating bonding part and an area S2 of the insulating layer satisfy S1/S2> -0.6; and/or the area S1 of the insulating bonding part and the area S3 of the outer contact layer meet the condition that S1/S3> is 0.5.

Optionally, a first adhesion enhancement layer is arranged on the first surface layer of the conductive adhesion part, which is close to the insulating adhesion part, and is used for enhancing the adhesion strength between the conductive adhesion part and the insulating adhesion part; and/or a second bonding enhancement layer is arranged on a second surface layer of the welding bonding part, which is close to the insulating bonding part, and is used for enhancing the bonding strength between the welding bonding part and the insulating bonding part.

Optionally, the side wall is further provided with an extension portion, the extension portion protrudes out of the welding support portion and extends outwards for a certain height h, and the extending height h is larger than or equal to the sum of the thickness d3 of the insulating bonding portion and the thickness d4 of the outer contact layer.

Optionally, the battery case further includes a protective member formed by curing liquid glue disposed in grooves formed at outer edge portions of the extension portion, the welding portion, the insulating adhesive portion, and the outer contact layer after the sealing of the cover with the bottom case at normal temperature.

Optionally, an insulating unit is disposed inside the welding hole part, and the insulating unit is used for preventing one pole of the battery cell from contacting the inner contact part to form a short circuit when the pole is electrically connected with the electrode contact part.

The utility model also provides a battery, which comprises a battery core and the battery shell, wherein one pole of the battery core is electrically connected with the outer contact layer of the battery shell, and the other pole of the battery core is electrically connected with the inner contact layer and/or the bottom shell of the battery shell.

The battery case is divided into the bottom case and the sealing cover, and the sealing cover is divided into the outer contact layer, the insulating layer and the inner contact layer, wherein the electrode contact part of the outer contact layer can penetrate through the insulating layer and the inner contact layer to be electrically conducted with one pole of the battery cell, the other pole of the battery cell can be electrically conducted with the bottom case, the battery cell can be packaged after the inner contact layer is welded with the bottom case, and the bottom case can be insulated with the outer contact layer due to the fact that the inner contact layer is insulated from the outer contact layer through the insulating layer, and therefore mutual conduction short circuit of two electrodes of the battery cell can be prevented; because the inner contact layer and the outer contact layer of the sealing cover are insulated in advance, when the sealing cover is used for packaging the bottom shell, only the inner contact layer and the bottom shell need to be welded, an insulating film does not need to be arranged, and therefore the packaging process of the battery can be simplified, and the packaging efficiency is improved; in addition, the contact area S0 of the insulating bonding part and the inside of the battery case is limited to S0< ═ pi. D2. D3. 1/2, and the area of the insulating bonding part exposed to the electrolyte can be reduced, so that the corrosion of the electrolyte to the insulating layer is reduced, and the bonding stability of the insulating layer to the outer contact layer and the inner contact layer is ensured.

Drawings

In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the structures shown in the drawings without creative efforts.

Fig. 1 is an exploded view of the structure of one embodiment of a battery case according to the present invention;

fig. 2 is a cross-sectional exploded view of one embodiment of a battery case according to the present invention;

FIG. 3 is a schematic cross-sectional view illustrating one embodiment of a battery case according to the present invention;

FIG. 4 is a schematic cross-sectional view of an embodiment of the closure of the present invention;

fig. 5 is an exploded view of the structure of another embodiment of the battery case according to the present invention.

The reference numbers illustrate:

reference numerals	Name (R)	Reference numerals	Name (R)	Reference numerals	Name (R)
						10	Bottom shell	20	Sealing cover	11	Bottom wall
12	Side wall	21	External contact layer	22	Insulating layer
						23	Inner contact layer	211	Electrode contact	212	Conductive adhesive part
221	Insulating adhesive part	222	Insulation opening part	231	Weld part
						232	Welding bonding part	233	Welding the opening part	121	Welding support part
213	First adhesion enhancement layer	234	Second adhesion enhancing layer	122	Extension part
						30	Protecting piece	40	Insulating unit	50	Battery cell
223	First adhesive layer	224	Conduction-proof layer	225	Second adhesive layer

The implementation, functional features and advantages of the objects of the present invention will be further explained with reference to the accompanying drawings.

Detailed Description

The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.

It should be noted that, if directional indications (such as up, down, left, right, front, and back … …) are involved in the embodiment of the present invention, the directional indications are only used to explain the relative positional relationship between the components, the movement situation, and the like in a specific posture (as shown in the drawing), and if the specific posture is changed, the directional indications are changed accordingly.

In addition, if there is a description of "first", "second", etc. in an embodiment of the present invention, the description of "first", "second", etc. is for descriptive purposes only and is not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In addition, the meaning of "and/or" appearing throughout is to include three juxtapositions, exemplified by "A and/or B," including either the A or B arrangement, or both A and B satisfied arrangement. In addition, technical solutions between various embodiments may be combined with each other, but must be realized by a person skilled in the art, and when the technical solutions are contradictory or cannot be realized, such a combination should not be considered to exist, and is not within the protection scope of the present invention.

The utility model provides a battery case for a button battery.

In the embodiment of the present invention, as shown in fig. 1 to 5, the battery case includes a cup-shaped bottom case 10 and a cover 20 for sealing an opening of the bottom case 10; the bottom shell 10 comprises a circular or oval bottom wall 11 and an annular side wall 12; the sealing cover 20 sequentially comprises an outer contact layer 21, an insulating layer 22 and an inner contact layer 23 from outside to inside; the maximum outer diameter D1 of the outer contact layer 21 is smaller than the maximum outer diameter D2 of the inner contact layer 23; the external contact layer 21 includes an electrode contact portion 211 and a conductive adhesive portion 212; the insulating layer 22 includes an insulating adhesive portion 221 and an insulating opening portion 222; the inner contact layer 23 includes a welding portion 231, a welding adhesive portion 232, and a welding opening portion 233; a welding support part 121 is arranged on the side wall 12 close to the opening; the electrode contact 211 is directed into the bottom case 10 through the insulation opening 222 and the welding opening 233, and is used for electrical connection with one of the battery cells 50 to electrically connect the external contact layer 21 with the battery cell 50; the conductive adhesive part 212 is used for being seamlessly adhered to the insulating adhesive part 221 to reinforce the strength of the cover 20 and prevent external water from penetrating into the battery case; the welding part 231 is used for welding with the welding support part 121 to seal the cover 20 with the bottom case 10; the welding bonding part 232 is used for being seamlessly bonded with the insulating bonding part 221 so as to strengthen the strength of the cover 20, reduce the direct contact area of the insulating bonding part 221 and the inside of the battery case and prevent external water from permeating into the inside of the battery case;

before the sealing cover 20 is sealed with the bottom case 10, the insulating bonding part 221 is seamlessly bonded to the conductive bonding part 212 and the welding bonding part 232 after melting an insulating electrolyte corrosion-resistant material having a thermal shrinkage rate of 6% or less at 100 ℃ or higher, the bonding strength between the insulating bonding part 212 and the welding bonding part 232 is 1.0N per square millimeter or higher at a cooling normal temperature, the thickness D3 of the insulating bonding part 221 is 0.01mm to 2.5mm, the contact area S0 of the insulating bonding part 221 and the inside of the battery case satisfies S0 ═ D2 ═ D3 ═ 1/2, specifically, for example, D3 may be 0.01mm, 0.05mm, 0.1mm, 0.15mm, 0.2mm, 0.25mm, 0.3mm, 0.35mm, 0.5mm, 1.0mm, 1.2mm, 1.4mm, 1.6mm, 1.5 mm, 2mm, and a small-sized battery is designed, the thickness d1 is preferably selected to be 0.15mm-0.25mm, it should be understood that the thickness of the specific insulating adhesive portion can be designed specifically according to the specific product, and the insulating adhesive portion and the insulating layer 22 are preferably of an integral structure.

Compared with the prior art, the battery case of this application compares with the tradition, and sealed adoption welding, fine improvement leakproofness and stability like this, but not rely on the physics atress extrusion between the casing to seal, and because closing cap 20 is done in advance, insulate through insulating bonding portion 221, can improve insulating nature, under certain condition, can play the guard action simultaneously. Furthermore, the sealing cover 20 of the battery case adopts a three-layer structure, the stability and the firmness of the structure are enhanced, the insulating bonding part is positioned between two layers of stainless steel, the waterproof and electrolyte corrosion prevention properties of the sealing cover are very strong, the contact area between the insulating bonding part and the outside of the battery case is small, external moisture can be effectively prevented from entering the battery case, meanwhile, the path length between the outside of the battery case 221 and the inside of the battery case is longer while the contact area is small, and therefore the influence of the external moisture and the like on the electric core and the electrolyte in the battery case is further avoided; similarly, for the inside of the battery case, only the inner edge of the insulating bonding part 221 can be in contact with the electrolyte in the battery case, so that the contact area between the electrolyte and the insulating bonding part 221 can be effectively reduced, the insulating bonding part 221 can be effectively protected, the influence of the electrolyte on softening, corrosion and the like of the insulating bonding part 221 is avoided, the service life of the battery is effectively prolonged, further, the path from the inside of the battery case to the outside of the battery case of the insulating bonding part 221 is longer, and the service life of the battery can be further prolonged.

The bottom case 10 may be made of a stainless steel plate, and an opening of the bottom case 10 faces upward to accommodate the battery cell 50 and the electrolyte; the bottom wall 11 and the side wall 12 may be integrally formed by injection molding, or may be fixed by welding, which is not limited herein. The outer contact layer 21 and the inner contact layer 23 of the cover 20 may be made of stainless steel plates, wherein the outer contact layer 21 is used to connect to one of the electrodes of the battery cell 50, and the inner contact layer 23 is connected to the other electrode of the battery cell 50 by being connected to the bottom case 10. Since the insulating layer 22 is disposed between the outer contact layer 21 and the inner contact layer 23, the outer contact layer 21 and the inner contact layer 23 are insulated from each other, so that the bottom case 10 and the cover 20 can be insulated from each other to prevent the two electrodes of the battery cell 50 from being conducted with each other, thereby not only enabling the cover 20 and the bottom wall 11 of the bottom case 10 to form two output electrodes of the battery, but also preventing the two output electrodes from being conducted with each other to cause a short circuit.

Compared with the prior art, casing cooperation about present button cell's casing adopts, and the centre is the plastic insulation circle, and to battery casing lateral wall, it has three layer construction, and the battery casing lateral wall 12 of this application only can be the one deck, under the condition of equidimension casing, the battery case of this application has improved the available space in inside, is favorable to improving the capacity of whole battery.

The welding portion 231, that is, the inner contact layer 23 is used at a position to be welded to the welding support portion 121, and the welding portion 231 is provided in the peripheral wall of the inner contact layer 23. The maximum outer diameter D1 of the outer contact layer 21 is smaller than the maximum outer diameter D2 of the inner contact layer 23, that is, the soldering portion 231 protrudes from the peripheral wall of the outer contact layer 21 in the radial direction, so that a space is formed between the peripheral wall of the outer contact layer 21 and the soldering support portion 121, and the outer contact layer 21 is prevented from contacting the sidewall 12. The solder opening portion 233 is a position where the inner contact layer 23 is opened, and the solder bonding portion 232 is used for bonding to the insulating layer 22. The welding portion 231 is welded to the sidewall 12, so that the cover 20 and the bottom case 10 can be fixed to each other, and the inner contact layer 23 and the sidewall 12 can be electrically connected. The insulation hole part 222 of the insulation layer 22 corresponds to the welding hole part 233 of the inner contact layer 23 so that the electrode contact part 211 of the outer contact layer 21 can face the inside of the battery case through the insulation hole part 222 and the welding hole part 233; the insulation opening portion 222 and the welding opening portion 233 may be opened at the middle portion of the cover 20 so that the electrode contact portion 211 can maintain a sufficient distance from each position of the sidewall 12.

The electrode of the battery cell 50 may extend through the insulation opening portion 222 and the welding opening portion 233 to be in contact with the electrode contact portion 211, or the electrode contact portion 211 may be protruded downward to be in electrode contact with the battery cell 50. If the electrode of the battery cell 50 extends upward to contact the electrode contact portion 211, the battery cell 50 needs to avoid the inner contact layer 23. The top and bottom surfaces of the insulating adhesive 221 are adhered to the conductive adhesive 212 and the solder adhesive 232, respectively, to achieve the insulating connection of the outer contact layer 21 and the inner contact layer 23. The inner contact layer 23 is welded and sealed with the side wall 12, and the outer contact layer 21 and the inner contact layer 23 are seamlessly bonded through the insulating layer 22, so that the cover 20 can be sealed with the bottom case 10. Here, when the inner contact layer 23 and the sidewall 12 are bonded, the inner contact layer 23 and the outer contact layer 21 are connected in advance in an insulating manner, and therefore, it is not necessary to provide an insulating film separately.

The insulating layer 22 is made of a material having insulating properties and being resistant to electrolyte corrosion, and has a heat shrinkage rate of 6% or less at 100 ℃, wherein the heat shrinkage rate refers to a volume change of a thermoplastic material due to its inherent thermal expansion rate, that is, at a temperature of 100 ℃ or more, a volume change amount of the insulating layer 22 is not more than 6% of an original volume, so that the insulating layer 22 can be sufficiently melted and then sufficiently connected with the inner contact layer 23 and the outer contact layer 21 to ensure an adhesive effect. The bonding strength between the insulating layer 22 and the conductive bonding part 212 and between the insulating layer 22 and the welding bonding part 232 is more than or equal to 1.0N per square millimeter at the cooling normal temperature, so that the bonding stability between the insulating layer 22 and the inner contact layer 23 and between the insulating layer 22 and the outer contact layer 21 can be ensured; specifically, the bonding strength between the insulating bonding portion 221 and the conductive bonding portion 212 and between the insulating bonding portion 221 and the solder bonding portion 232 is less than or equal to 5.0N/mm at a cooling normal temperature, so as to prevent an excessive internal stress in the cap 20, and thus, the cap 20 can be prevented from being damaged by an internal force during subsequent processing or use. The thickness d3 of the insulating adhesive portion 221 is set to 0.01mm-2.5mm, so that the insulating adhesive portion 221 can stably withstand changes in temperature or external force, the adhesion stability of the insulating adhesive portion 221 can be improved, and the overall thickness dimension of the cap 20 can be reasonably controlled.

The contact area S0 between the insulating bonding part 221 and the inside of the battery case satisfies S0 ═ pi × D2 × D3 × 1/2; note that the contact surface between the insulating adhesive portion 221 and the inside of the battery case is the area of the insulating open hole portion 222 exposed to the electrolyte, that is, the area of the hole wall of the insulating open hole portion 222; the aperture area S0 of insulating open cell portion 222 is pi D3 the aperture of insulating open cell portion 222, that is, the aperture of insulating open cell portion 222 should be equal to or less than D2 1/2, so that the area of insulating layer 22 exposed to the electrolyte can be effectively controlled on the basis of ensuring that the thickness D3 of insulating layer 22 is sufficient, corrosion of the electrolyte to insulating layer 22 or corrosion of the bonding surface of insulating layer 22 and inner contact layer 23 can be reduced, the structural stability and bonding strength stability of insulating layer 22 can be improved, and insulating layer 22 can be prevented from falling off from inner contact layer 23, thereby effectively improving the overall stability of the battery case.

The battery case is divided into the bottom case 10 and the cover 20, and the cover 20 is divided into an outer contact layer 21, an insulating layer 22 and an inner contact layer 23, wherein an electrode contact part 211 of the outer contact layer 21 penetrates through the insulating layer 22 and the inner contact layer 23 to be electrically conducted with one pole of the battery cell 50, the other pole of the battery cell 50 is electrically conducted with the bottom case 10, the inner contact layer 23 is welded with the bottom case 10 to realize the encapsulation of the battery cell 50, and the inner contact layer 23 is insulated from the outer contact layer 21 through the insulating layer 22, so that the bottom case 10 is also insulated from the outer contact layer 21, and the two electrodes of the battery cell 50 can be prevented from being mutually conducted and short-circuited; since the inner contact layer 23 and the outer contact layer 21 of the cover 20 are insulated in advance, when the cover 20 is used for packaging the bottom case 10, only the inner contact layer 23 and the bottom case 10 need to be welded without arranging an insulating film, so that the packaging process of the battery can be simplified, and the packaging efficiency can be improved; in addition, by defining the contact area S0 of the insulating adhesive part 221 with the inside of the battery case as S0 ═ pi × D2 × D3 × 1/2, the area of the insulating adhesive part 221 exposed to the electrolyte can be reduced, thereby reducing corrosion of the electrolyte to the insulating layer 22 to ensure adhesion stability of the insulating layer 22 to the outer contact layer 21 and the inner contact layer 23.

Specifically, the material of the outer contact layer 21 is stainless steel, and the thickness d4 of the outer contact layer 21 is 0.1mm-0.25 mm; and/or the material of the inner contact layer 23 is stainless steel, and the thickness d5 of the inner contact layer 23 is 0.1mm-0.25 mm. By way of specific illustration, d4 and d5 may be specifically designed to be 0.1mm, 0.15mm, 0.2mm, 0.25mm, 0.3mm, 0.35mm, 0.5mm, 1.0mm, 1.2mm, 1.4mm, 1.6mm, 1.8mm, 2.0mm, 2.5 mm. The stainless steel can be 304 stainless steel, contains higher nickel, is in an austenite single-phase structure at room temperature, has higher corrosion resistance, better cold forming and weldability, and has higher plasticity and toughness at low temperature, room temperature and high temperature. The provision of the external contact layer 21 and the internal contact layer 23 as SUS304 ensures structural stability of the cap 20 during processing and chemical stability when used as a battery case.

The thickness d4 of the outer contact layer 21 and the thickness d5 of the inner contact layer 23 are set to 0.1mm to 0.25mm, which not only provides the outer contact layer 21 and the inner contact layer 23 with sufficient structural strength, but also reasonably controls the overall thickness dimension of the closure 20. In practical applications, the insulating layer 22 is made of one or more of PP (polypropylene), PFA (a small amount of copolymer of perfluoropropyl perfluorovinyl ether and polytetrafluoroethylene), PVDF (polyvinylidene fluoride), PTFE (polytetrafluoroethylene), ETFE (ethylene-tetrafluoroethylene copolymer), and PVC (polyvinyl chloride).

In one embodiment, the area S1 of the insulating adhesive portion 221 and the area S2 of the insulating layer 22 satisfy S1/S2> -0.6; and/or the area S1 of the insulating bonding part 221 and the area S3 of the outer contact layer 21 satisfy S1/S3> being 0.5, thereby effectively ensuring the bonding area of the insulating layer 22 and the outer contact layer 21 and improving the connection stability of the insulating layer 22 and the outer contact layer 21; meanwhile, the size of the insulation opening part 222 can be reasonably controlled, so that the area of the electrode contact part 211 can be effectively controlled, and the area utilization rate of the outer contact layer 21 can be improved.

In one embodiment, as shown in fig. 3, a first adhesion enhancement layer 213 is disposed on the first surface of the conductive adhesion part 212 close to the insulating adhesion part 221 for enhancing the adhesion strength with the insulating adhesion part 221; and/or a second adhesion enhancement layer 234 is arranged on the second surface layer of the welding adhesion part 232 close to the insulating adhesion part 221, and is used for enhancing the adhesion strength between the welding adhesion part 232 and the insulating adhesion part 221. The specific form of the first adhesion enhancing layer 213 is not limited, and it is sufficient to increase the connection area with the insulating adhesion portion 221 to enhance the adhesion strength. For example, the first adhesion enhancing layer 213 may be provided as a protrusion. The second adhesion enhancing layer 234 can refer to the first adhesion enhancing layer 213, and it should be noted that the first adhesion enhancing layer 213 and the second adhesion enhancing layer 234 can indirectly cooperate with each other through the insulating layer 22 to further improve the combination stability of the outer contact layer 21, the insulating layer 22 and the inner contact layer 23.

Specifically, as shown in fig. 4, the first adhesion enhancement layer 213 is a first surface layer of the first stainless steel layer close to the insulating adhesion part 221, which is processed by sand blasting to form a uniform first rough surface layer; and/or the second adhesion enhancing layer 234 is a second surface layer of the second stainless steel layer close to the insulating adhesion part 221, which is processed by sand blasting to form a uniform second rough surface layer. It is understood that uniform in this embodiment does not mean absolutely uniform, but rather a natural uniform matte surface formed by grit blasting the first surface layer. The first rough surface layer enables the adhesion force between each part of the first surface layer and the insulating bonding part 221 to be more uniform, so that stress concentration is avoided. Similarly, the second rough surface layer can make the adhesion between each part of the second surface layer and the insulating adhesive part 221 more uniform. By forming the first and second

adhesion enhancing layers

213 and 234 by sand blasting, the processing of the first and second

adhesion enhancing layers

213 and 234 can be simplified to improve the processing efficiency.

In another embodiment, the first adhesion enhancing layer 213 is a first inclined plate protruding from the first surface layer and having a certain inclination angle with the first surface layer, the first inclined plate has a height smaller than the thickness of the insulating adhesive portion 221, the second adhesion enhancing layer 234 is a second inclined plate protruding from the second surface layer and having a certain inclination angle with the second surface layer, the second inclined plate has a height smaller than the thickness of the insulating adhesive portion 221, and the first inclined plate and the second inclined plate are alternately arranged in opposite directions. The number of the first inclined pieces is multiple and distributed on the first surface layer, and the melted adhesive insulating layer 22 can fill the space between two adjacent first inclined pieces so as to be adhered and connected with the side surface of each first inclined piece. The height of the first inclined sheet is the vertical distance between the tail end of the first inclined sheet and the first surface layer, and the height of the first inclined sheet is smaller than the thickness of the insulating bonding part 221, so that the first inclined sheet can be prevented from contacting the second stainless steel layer after penetrating through the insulating bonding part 221. The distribution and action of the second inclined plate can be referred to the first inclined plate. The first inclined pieces and the second inclined pieces are alternately arranged in the longitudinal direction, so that the first inclined pieces and the second inclined pieces can be adjacent to each other after the insulating adhesive part 221 is inserted, and the outer contact layer 21 and the inner contact layer 23 can be closer to each other without reducing the thickness of the insulating adhesive part 221, thereby improving the structural strength of the cap 20.

In another embodiment, the first adhesion enhancing layer 213 is a first groove recessed into the first surface layer, and the recessed direction of the first groove is away from the insulating adhesion layer; and/or the second adhesion enhancing layer 234 is a second groove recessed into the second surface layer in a direction away from the insulating adhesive layer. The quantity of first recess is a plurality of, and a plurality of first recesses distribute in first top layer, and the insulating bonding portion 221 that melts can fill in first recess to increase the area of connection with first top layer, thereby strengthen the adhesive strength of outer contact layer 21 and insulating bonding portion 221. The arrangement and function of the second groove can refer to the first groove, and are not described herein again.

In an embodiment, as shown in fig. 1 to 3, the sidewall 12 is further provided with an extension portion 122, the extension portion 122 protrudes from the soldering support portion 121 and extends outward by a certain height h, and the extending height h is equal to or greater than the sum of the thickness d3 of the insulating adhesive portion 221 and the thickness d4 of the outer contact layer 21. The extending portion 122 extends upward from the top of the welding support portion 121, and the top of the extending portion 122 protrudes above the top surface of the outer contact layer 21, so that the extending portion 122 can be connected to a protective cover covering the outer contact layer 21, thereby effectively protecting the cover 20.

Specifically, as shown in fig. 1 to 3, the battery case further includes a protective member 30, and the protective member 30 is formed by curing liquid glue disposed in grooves formed at outer edge portions of the extension part 122, the welding part 231, the insulating adhesive part 221, and the outer contact layer 21 after the sealing of the cover 20 with the bottom case 10 at normal temperature. The insulating adhesive portion 221 forms a groove bottom of the groove on the top surface of the portion protruding from the peripheral wall of the outer contact layer 21, and the peripheral wall of the outer contact layer 21 and the inner peripheral wall of the extension portion 122 form a groove wall of the groove, so that the groove extends in the circumferential direction of the outer contact layer 21. The protector 30 can cover the top surface of the protruding portion of the insulating adhesive layer and effectively isolate the outer contact layer 21 from the extension portion 122, thereby preventing the outer contact layer 21 from being electrically conducted with the inner contact layer 23 or the sidewall 12. It will be appreciated that providing the protective member 30 to be formed by curing the liquid gel can achieve both insulation of the outer contact layer 21 from the inner contact layer 23 or the extension portion 122 and also reduce the force pressure of the protective member 30 against the outer contact layer 21 or the extension portion 122, so as to facilitate deformation of the outer contact layer 21 or the extension portion 122, thereby ensuring structural stability of the battery case.

In practical applications, as shown in fig. 1 to 3, an insulating unit 40 is disposed inside the welding opening portion 233, and the insulating unit 40 is used for preventing one electrode of the battery cell 50 from contacting the inner contact layer 23 to form a short circuit when electrically connected to the electrode contact portion 211. The insulating unit 40 may be annularly disposed and extend along a circumferential direction of the welding opening portion 233, and the insulating unit 40 may be adjacent to a hole wall of the welding opening portion 233 to cover the welding opening portion 233, so that an electrode connected to the electrode contact portion 211 may be prevented from contacting the inner contact layer 23 to further avoid a short circuit between two electrodes of the battery cell 50.

In an embodiment, as shown in fig. 5, the insulating layer 22 may include a first adhesive layer 223, a conduction preventing layer 224 and a second adhesive layer 225 stacked, wherein the first adhesive layer 223 adheres the outer contact layer 21 and the conduction preventing layer 224, the second adhesive layer 225 adheres the inner contact layer 23 and the conduction preventing layer 224, and the conduction preventing layer 224 may ensure that the outer contact layer 21 and the inner contact layer 23 are insulated from each other. Thus, the first adhesive layer 223 and the second adhesive layer 225 only need to have adhesive properties, the conduction preventing layer 224 only needs to have insulating properties, two properties of the insulating layer 22 are realized through different functional levels, and the adhesive properties and the insulating properties of the corresponding levels can be enhanced to improve the overall performance of the insulating layer 22.

The present invention further provides a battery, which includes a battery core 50 and a battery case, and the specific structure of the battery case refers to the above embodiments, and since the battery employs all technical solutions of all the above embodiments, the battery at least has all beneficial effects brought by the technical solutions of the above embodiments, and details are not repeated herein. One of the poles of the battery cell 50 is electrically connected to the outer contact layer 21 of the battery case, and the other pole is electrically connected to the inner contact layer 23 and/or the bottom case 10 of the battery case. The battery can be set as a button battery which is mainly applied to electronic products to provide electric energy for the electronic products. The electronic product can be an earphone, a watch and the like, and is low in voltage.

The above description is only an alternative embodiment of the present invention, and not intended to limit the scope of the present invention, and all modifications and equivalents of the present invention, which are made by the contents of the present specification and the accompanying drawings, or directly/indirectly applied to other related technical fields, are included in the scope of the present invention.

Claims

1. A battery shell for button batteries is characterized in that,

the battery case comprises a cup-shaped bottom case and a cover for sealing an opening of the bottom case;

a welding supporting part is arranged on the side wall close to the opening;

2. The battery case according to claim 1, wherein the material of the outer contact layer is stainless steel, and the thickness d4 of the outer contact layer is 0.1mm to 0.25 mm; and/or the material of the inner contact layer is stainless steel, and the thickness d5 of the inner contact layer is 0.1mm-0.25 mm.

3. The battery case of claim 1, wherein the insulating layer is made of one of PP, PFA, PVDF, PTFE, ETFE, and PVC.

4. The battery can of claim 1, wherein the adhesive strength between the insulating adhesive part and the conductive adhesive part and the welding adhesive part at a cooling normal temperature is 1.0N/mm and 5.0N/mm.

5. The battery case of claim 1, wherein an area S1 of the insulating adhesive part and an area S2 of the insulating layer satisfy S1/S2> -0.6; and/or the area S1 of the insulating bonding part and the area S3 of the outer contact layer meet the condition that S1/S3> is 0.5.

6. The battery case according to any one of claims 1 to 5, wherein the conductive adhesive part is provided with a first adhesion enhancing layer adjacent to the first surface layer of the insulative adhesive part for enhancing the adhesive strength with the insulative adhesive part; and/or a second bonding enhancement layer is arranged on a second surface layer of the welding bonding part, which is close to the insulating bonding part, and is used for enhancing the bonding strength between the welding bonding part and the insulating bonding part.

7. The battery case according to any one of claims 1 to 5, wherein the side walls are further provided with extension portions protruding from the welding support portions and extending outward by a height h, the extended height h satisfying a requirement equal to or greater than the sum of a thickness d3 of the insulating adhesive portion and a thickness d4 of the outer contact layer.

8. The battery case of claim 7, further comprising a protective member formed by curing liquid glue disposed in grooves formed at the outer edge portions of the extension portion, the welding portion, the insulating adhesive portion, and the outer contact layer after the sealing of the cover with the bottom case at normal temperature.

9. The battery case according to any one of claims 1 to 5, wherein an insulating unit for preventing one pole of the battery cell from contacting the inner contact portion to form a short circuit when electrically connected to the electrode contact portion is provided inside the welding opening part.

10. A battery comprising a cell and a battery casing according to any one of claims 1 to 9, wherein one pole of the cell is electrically connected to the outer contact layer of the battery casing and the other pole is electrically connected to the inner contact layer and/or the bottom casing of the battery casing.