SUMMERY OF THE UTILITY MODEL
The application provides a wastewater purification device, which comprises a rectifying tower, wherein one side of the rectifying tower is connected with a feeding pipeline, the bottom of the rectifying tower is connected with a reboiler, the top of the rectifying tower is connected with the reboiler through a first pipeline, the first pipeline is connected with a compressor, the reboiler is connected with a separator through a second pipeline, the separator is connected with a treatment device, and the separator is also connected with the top of the rectifying tower through a third pipeline and a backflow pipeline; and the bottom of the rectifying tower is connected with a waste water pipeline.
As a preferred scheme, processing apparatus includes the condenser of being connected with the separator through pipeline four, the condenser is connected with the exhaust emission pipeline, the condenser passes through pipeline five and is connected with the oil phase jar, the oil phase jar pass through pipeline six with the exhaust emission pipeline is connected, the oil phase jar passes through pipeline seven and is connected with the pipeline of drawing, the oil phase jar passes through pipeline seven, pipeline eight and is connected with the separator.
Preferably, the separator is an oil-water-gas three-phase separator.
As a preferred scheme, a feeding preheater is arranged on the feeding pipeline.
Preferably, the third pipeline is connected with an adsorption device.
As a preferred scheme, the adsorption device comprises a first adsorption tank connected with a third pipeline, the first adsorption tank is connected with a second adsorption tank through a connecting pipeline, and a purified water outlet pipeline is arranged at the bottom of the second adsorption tank.
As a preferable scheme, the pipeline three is connected with the feed preheater, and the feed preheater is connected with the adsorption tank I.
As a preferred scheme, the second adsorption tank is connected with the desorption device, the desorption device comprises a feeding pipeline connected with the second adsorption tank, the top of the second adsorption tank is connected with the second feeding pipeline through a ninth pipeline, and a steam condensate cooler is arranged at the joint of the ninth pipeline and the feeding pipeline.
The utility model adopts a closed circulation evaporation purification device, raw materials and a water phase extracted from the top of the tower are subjected to sufficient heat exchange and then enter a rectifying tower, a gas phase at the top of the rectifying tower is pressurized and heated by a compressor and then enters a reboiler heat exchanger, and the gas phase is condensed and then enters a separator; part of the water phase separated by the separator flows back to enter a rectifying tower; the uncondensed light components after heat exchange and condensation by the reboiler enter a treatment device for further condensation to obtain a liquid-phase hydrocarbon product; preferably, the other part of the water phase separated by the separator enters an adsorption tank to adsorb and remove light impurities and the like after heat exchange of the raw material preheater so as to ensure that the effluent reaches the discharge standard.
This application possesses following advantage:
(1) compared with the traditional wastewater treatment method, the method can effectively reduce energy consumption and realize multiple-effect utilization of energy;
(2) compared with multiple-effect evaporation, the method can effectively reduce energy consumption, has the economic efficiency equivalent to 30 effects of the multiple-effect evaporation, and has less equipment investment and operation risk.
(3) The utility model can also set a compressor, the compressor compresses the steam at low temperature, the temperature and pressure are increased, the enthalpy is increased, then the steam enters the heat exchanger for condensation, so as to fully utilize the latent heat of the steam; except for starting, secondary steam which is generated from an evaporator is not needed in the whole evaporation process, the secondary steam is compressed by a compressor, the pressure and the temperature are increased, the enthalpy is increased, and then the secondary steam is sent to a heating chamber of the evaporator to be used as heating steam, so that the feed liquid is kept in a boiling state, and the heating steam is condensed into water; therefore, the steam which is originally discarded is fully utilized, latent heat is recovered, the heat efficiency is improved, and the economic efficiency of the raw steam is equivalent to 30 effects of multi-effect evaporation.
Detailed Description
The following describes in detail a specific embodiment of the present invention with reference to fig. 1 and 2. It should be noted that the specific embodiments described herein are only for illustrating and explaining the present invention and are not to be construed as limiting the present invention.
The first embodiment is as follows:
the embodiment provides a wastewater purification device, which comprises a rectifying tower 1, wherein the rectifying tower 1 only needs to adopt a rectifying tower in the prior art, the wastewater purification device is not improved, one side of the rectifying tower 1 is connected with a feeding pipeline 2, industrial wastewater enters the rectifying tower 1 through the feeding pipeline 2, the bottom of the rectifying tower 1 is connected with a reboiler 3, the top of the rectifying tower 1 is connected with the reboiler 3 through a pipeline I4, the pipeline I4 is connected with a compressor 11, the compressor 11 only needs to adopt a compressor in the prior art, the compressor 11 is arranged to pressurize and heat a gas phase at the top of the tower, the gas phase at the top of the tower is compressed by the reboiler 11, the temperature and the pressure are increased, the heat enthalpy is increased, and then the gas phase enters the reboiler 3 to serve as a heat source; to further meet the heat source grade requirements of the reboiler 3; the reboiler 3 is connected with a separator 6 through a second pipeline 5, preferably, the separator 6 is a prior art oil-water-gas three-phase separator, the separator 6 is connected with a treatment device, and the treatment device is used for treating the gas phase and the liquid phase separated by the separator 6; the separator 6 is also connected with the top of the rectifying tower 1 through a third pipeline 7 and a reflux pipeline 8, and a reflux pump 10 is arranged on the third pipeline 7; the bottom of the rectifying tower 1 is connected with a waste water pipeline 9; the vast majority of light components of the industrial wastewater entering the rectifying tower 1 are separated from the top of the tower, and the materials discharged from the tower kettle through a wastewater pipeline 9 enter an incinerator for further treatment; the gas phase at the top of the tower is pressurized and heated by a compressor and then enters a reboiler heat exchanger 3 to be used as a reboiler heat source, a liquid phase is obtained after heat exchange and enters an oil-water-gas three-phase separation tank for separation, wherein the gas phase enters a treatment device for treatment, the water phase enters a rectifying tower 1 to be used as reflux, and the oil phase is extracted and treated.
Preferably, in order to complete the purification of the wastewater more smoothly and improve the wastewater purification rate, the feeding pipe 2 is provided with the feeding preheater 12, the feeding preheater 12 is a feeding preheater in the prior art, the structure of the utility model is not improved, and the feeding preheater 12 preheats the industrial wastewater entering the rectifying tower 1.
Example two:
the present embodiment specifically defines the treatment device, specifically, the treatment device includes a condenser 14 connected to the separator 6 through a line four 13, and the condenser 14 may be a condenser in the prior art; the condenser 14 is connected with a tail gas discharge pipeline 15, the condenser 14 is connected with an oil phase tank 17 through a pipeline five 16, the oil phase tank 17 is connected with the tail gas discharge pipeline 15 through a pipeline six 18, the oil phase tank 17 is connected with a production pipeline 20 through a pipeline seven 19, a light hydrocarbon pump 21 is arranged between the pipeline seven 19 and the production pipeline 20, and the light hydrocarbon pump 21 can be a light hydrocarbon pump in the prior art; the oil phase tank 17 is connected with the separator 6 through a pipeline seven 19 and a pipeline eight 22; the gas phase at the top of the rectifying tower 1 enters a compressor 11 for pressurization and temperature increase, enters a reboiler 3 as a reboiler heat source, obtains a liquid phase after heat exchange, enters an oil-water-gas three-phase separation tank for separation, wherein the water phase enters the rectifying tower 1 as reflux, the separated gas phase enters a condenser 14 for further cooling to be a liquid phase and then enters an oil phase tank 17, and the gas phase which enters the condenser 14 and is not condensed is discharged through a tail gas discharge pipeline 15; the oil phase separated by the oil-water-gas three-phase separation tank and the oil phase collected by the oil phase tank 17 are collected by a collecting pipeline 20.
Example three:
this embodiment has further improved the efficiency of water purification, has improved the utilization ratio of water, specifically, pipeline three is connected with adsorption equipment, and in the aqueous phase that oil gas three-phase knockout drum separated partly got into rectifying column 1 as the backward flow, another part gets into adsorption equipment and adsorbs the organic substance of desorption light component, obtains the purified water that satisfies emission standard to can regard as the water source of boiler feedwater.
More specifically, the adsorption device comprises a first adsorption tank 23 connected with a pipeline III 7, the first adsorption tank 23 is connected with a second adsorption tank 25 through a connecting pipeline 24, and the bottom of the second adsorption tank 25 is provided with a purified water outlet pipeline 26; special substances such as activated carbon, resin and the like are filled in the adsorption tank I23 and the adsorption tank II 25; through the double adsorption of the first adsorption tank 23 and the second adsorption tank 25, organic substances of light components in the industrial wastewater are more fully absorbed, and purified water meeting the emission standard is further obtained and can be used as a water source for boiler water supply.
Preferably, the line three 7 is connected with a feed preheater 12, and the feed preheater 12 is connected with a first adsorption tank 23; the water phase separated by the separating tank is preheated by the feed preheater 12 before entering the adsorption device, so that the adsorption effect is better, and organic substances of light components are adsorbed and removed more easily.
The adsorption device is not limited to two adsorption tanks, and can also be one adsorption tank or more than two adsorption tanks, such as three adsorption tanks, five adsorption tanks and the like, without specific limitation, and technicians can select the adsorption tanks according to conditions.
Example four:
in this embodiment, an adsorption tank saturated in adsorption can be treated, specifically, the second adsorption tank 25 is connected to a desorption device, the desorption device includes a second feed pipe 27 connected to the second adsorption tank 25, the top of the second adsorption tank 25 is connected to the second feed pipe 27 through a ninth pipeline 28, and a vapor-condensate cooler 29 is disposed at a connection between the ninth pipeline 28 and the second feed pipe 27; and after the second adsorption tank 25 is saturated in adsorption, introducing substances such as steam, methanol and ethanol as carriers for desorption of the adsorption device, heating the carriers, and then introducing the heated carriers into the adsorption device for desorption regeneration, wherein if steam desorption is adopted, the steam enters the second adsorption tank 25 through the second feeding pipeline 27, the desorbed steam is cooled and separated from the adsorbed organic substances through the steam condensate cooler 29, and the steam condensate enters the rectifying tower 1 again to remove a small amount of organic substances in water.
Desorption apparatus still includes the charge-in pipeline 30 of being connected with adsorption tank 23, adsorption tank 23's top is passed through ten 31 of pipeline and is connected with nine 28 of pipeline, and adsorption tank 33 adsorbs the carrier that lets in steam, methyl alcohol, ethanol etc. material as adsorption apparatus desorption after saturation and gets into adsorption apparatus after heating and carry out desorption regeneration, if adopt steam desorption, steam enters into adsorption tank 23 through charge-in pipeline 30 in, and the steam after the desorption cools off the separation with the organic substance of absorption through steam condensate cooler 29, and the steam condensate enters into a small amount of organic substance in the desorption aquatic in rectifying column 1 once more.
Preferably, in order to improve the working efficiency, the desorption device may further include a third adsorption tank, and through the cooperation of the pipeline and the valve, two of the adsorption tanks are in an adsorption working state, and the other adsorption tank is in a desorption state, so that the adsorption tanks can be desorbed without stopping working, and the working efficiency is improved; the bottom of the adsorption tank I23 can also be provided with a purified water outlet pipeline 26, so that when the adsorption tank II 25 is desorbed, the adsorption tank I23 continues to perform adsorption work, and the work efficiency is improved.
Desorption apparatus is not only limited to above-mentioned structure, and the technical staff can carry out the arbitrary combination of adsorption tanks, pipeline, valve according to specific circumstances, also can adopt other desorption apparatus can realize carrying out the desorption to the adsorption tanks can.
The working principle of the utility model is as follows: separating certain industrial wastewater, feeding the industrial wastewater into a rectifying tower, wherein the operating pressure of a rectifying tower 1 is 0-101 kpa, most of light components in the industrial wastewater are separated in the rectifying tower 1, and the materials discharged from a tower kettle through a wastewater pipeline 9 are fed into an incinerator for further treatment; the gas phase at the top of the tower enters a compressor 11 for pressurization and temperature rise, then enters a reboiler 3 as a reboiler heat source, obtains a liquid phase after heat exchange, enters an oil-water-gas three-phase separation tank for separation, wherein one part of the water phase enters a rectifying tower 1 as reflux, and the other part of the water phase enters an adsorption tank filled with special substances for adsorption and removal of organic substances with light components, so that purified water meeting the discharge standard is obtained and can be used as a water source for boiler water supply; the separated gas phase enters a condenser 14 for further cooling to be a liquid phase and then enters an oil phase tank 17, and the oil phase tank 17 collects the liquid phase and then extracts the liquid phase together with the oil phase of the oil-water-gas three-phase separator through an extraction pipeline 20; the gas phase not condensed by the condenser 14 is discharged through a tail gas discharge pipe 15; and after the adsorption tank is saturated, introducing substances such as steam, methanol and ethanol as carriers desorbed by the adsorption device, heating the heated substances, allowing the heated substances to enter the adsorption device for desorption and regeneration, if steam desorption is adopted, cooling and separating adsorbed organic substances by the desorbed steam through a steam condensate cooler 29, and allowing the steam condensate to enter the rectifying tower 1 again to remove a small amount of organic substances in water.
The utility model adopts a closed circulating evaporation purification device, raw materials and a water phase extracted from the top of the tower are subjected to sufficient heat exchange and then enter a rectifying tower, and a gas phase at the top of the rectifying tower enters a reboiler heat exchanger for condensation and then enters a separator; part of the water phase separated by the separator flows back to enter a rectifying tower; the uncondensed light components after heat exchange and condensation by the reboiler enter a treatment device for further condensation to obtain a liquid-phase hydrocarbon product; preferably, the other part of the water phase separated by the separator enters an adsorption tank to adsorb and remove light impurities and the like after heat exchange of the raw material preheater so as to ensure that the effluent reaches the discharge standard.
This application possesses following advantage:
(1) compared with the traditional wastewater treatment method, the method can effectively reduce energy consumption and realize multiple-effect utilization of energy;
(2) compared with multiple-effect evaporation, the method can effectively reduce energy consumption, has the economic efficiency equivalent to 30 effects of the multiple-effect evaporation, and has less equipment investment and operation risk;
(3) the utility model can also set a compressor, the compressor compresses the steam at low temperature, the temperature and pressure are increased, the enthalpy is increased, then the steam enters the heat exchanger for condensation, so as to fully utilize the latent heat of the steam; except for starting, secondary steam which is generated from an evaporator is not needed in the whole evaporation process, the secondary steam is compressed by a compressor, the pressure and the temperature are increased, the enthalpy is increased, and then the secondary steam is sent to a heating chamber of the evaporator to be used as heating steam, so that the feed liquid is kept in a boiling state, and the heating steam is condensed into water; therefore, the steam which is originally discarded is fully utilized, latent heat is recovered, the heat efficiency is improved, and the economic efficiency of the raw steam is equivalent to 30 effects of multi-effect evaporation.
The power source, the valve and other structures are set on each pipeline as required in the figure, the structures are the prior art, and technicians can select the structures according to conditions; and will not be described in detail herein.
The devices and connection relationships that are not described in detail above all belong to the prior art, and the present invention is not described in detail herein.
The preferred embodiments of the present invention have been described in detail with reference to the accompanying drawings, but the present invention is not limited to the details of the above embodiments, and various simple modifications can be made to the technical solution of the present invention within the technical idea of the present invention, and these simple modifications are included in the scope of protection of the present invention.
It should be noted that, in the foregoing embodiments, various features described in the above embodiments may be combined in any suitable manner, and in order to avoid unnecessary repetition, various combinations that are possible in the present application will not be described separately.
In addition, any combination of the various embodiments of the present application can be made, and the present application should be considered as disclosed in the present application as long as the combination does not depart from the spirit of the present application.