CN215161830U - Blue charcoal waste water supersound catalytic purification device - Google Patents
Blue charcoal waste water supersound catalytic purification device Download PDFInfo
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- CN215161830U CN215161830U CN202121648211.8U CN202121648211U CN215161830U CN 215161830 U CN215161830 U CN 215161830U CN 202121648211 U CN202121648211 U CN 202121648211U CN 215161830 U CN215161830 U CN 215161830U
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Abstract
The utility model is suitable for a blue charcoal industry professional equipment field provides a blue charcoal waste water ultrasonic catalytic purification device, still include the raw water storage tank, dissolve gas self priming pump, ultraviolet irradiator, pipe-line mixer, ultrasonic catalytic purifier, oxygen cylinder, ozone generater and medicament dissolving tank, ultrasonic catalytic purifier includes liquid sediment isolating port and overflow board, the oxygen cylinder passes through ozone generater and raw water storage tank level setting and links to each other with dissolving the gas self priming pump, it links to each other with ultrasonic catalytic purifier through ultraviolet irradiator and pipe-line mixer to dissolve the gas self priming pump, ultrasonic catalytic purifier passes through the liquid sediment isolating port and links to each other with the entry of dissolving the gas self priming pump, the entry of medicament dissolving tank links to each other with the liquid outlet of overflow board, the export of medicament dissolving tank links to each other with the entry of dissolving the gas self priming pump. The utility model discloses having reinforceed the complicated reaction efficiency of purification, having realized the catalytic purification function, can practice thrift the equipment investment, reduced the use management degree of difficulty and improve the security, do benefit to the trade and promote.
Description
Technical Field
The utility model belongs to blue charcoal industry professional equipment field especially relates to a blue charcoal waste water ultrasonic catalysis purifier.
Background
The semi-coke wastewater is also called semi-coke wastewater, and is industrial wastewater formed by low-metamorphic coal (non-caking coal, weakly caking coal and long flame coal) in the medium-low temperature dry distillation (about 600-800 ℃) process, coal gas purification and semi-coke steam quenching process. The wastewater has complex components, contains a large amount of pollutants which are difficult to degrade and have high toxicity, such as organic pollutants of benzene series, phenols, polycyclic aromatic hydrocarbons, nitrogen-oxygen heterocyclic compounds and the like and inorganic pollutants of heavy metals and the like, and is typical industrial wastewater with high pollution and high toxicity. The method is characterized in that toxic organic matters in the semi-coke wastewater are combined with oxygen by comprehensively using a physical method, a chemical method and a biological method to generate carbon dioxide and water, mineral substances are deposited into active sludge and are safely solidified, and the activated sludge is a natural path for purifying the semi-coke wastewater by safely returning to the natural environment in a simplest form.
In order to save equipment investment and prevent the supercritical abnormal leakage danger caused by material corrosion, the device is designed to realize the liquid-phase micro-region transient supercritical reaction based on the blue carbon wastewater property and the ultrasonic technical characteristics, save energy consumption and play the actual working efficiency of the ultrasonic field effect, and has practical significance. Therefore, an ultrasonic catalytic purification device for semi-coke wastewater is provided.
SUMMERY OF THE UTILITY MODEL
An object of the embodiment of the utility model is to provide a blue charcoal waste water ultrasonic catalysis purifier, aim at solving the problem that proposes in the above-mentioned background art.
The embodiment of the utility model provides a realize like this, a blue charcoal waste water ultrasonic catalysis purifier, still include raw water storage tank, dissolve gas self priming pump, ultraviolet irradiator, pipe-line mixer, ultrasonic catalysis clarifier, oxygen cylinder, ozone generator and medicament dissolving tank, ultrasonic catalysis clarifier includes liquid sediment isolating port and overflow plate, the oxygen cylinder passes through ozone generator and raw water storage tank level setting and links to each other with dissolving the gas self priming pump, it links to each other with ultrasonic catalysis clarifier through ultraviolet irradiator and pipe-line mixer to dissolve the gas self priming pump, ultrasonic catalysis clarifier passes through the liquid sediment isolating port and links to each other with the entry of dissolving the gas self priming pump, the entry of medicament dissolving tank links to each other with the liquid outlet of overflow plate, the export of medicament dissolving tank links to each other with the entry of dissolving the gas self priming pump.
Further, raw water storage tank includes bottom manhole, top manhole, light oil recovery mouth, raw water delivery port and heavy oil recovery mouth, one side from the top down of raw water storage tank is equipped with light oil recovery mouth and heavy oil recovery mouth in proper order, the opposite side bottom of raw water storage tank is located to the bottom manhole, the upper end of raw water storage tank is equipped with the top manhole.
Furthermore, the dissolved air self-priming pump is at least provided with two groups.
Further, a stainless steel baffle plate is arranged in the pipeline mixer.
Further, supersound catalytic converter still includes ultrasonic wave oscillator, gas separation mouth and magnetism float level gauge, the ultrasonic wave oscillator is located in the supersound catalytic converter, the lower extreme central point of supersound catalytic converter puts and is equipped with the liquid sediment separation mouth, the liquid outlet upper end of overflow plate is located to the gas separation mouth, liquid outlet one side of overflow plate is located to the magnetism float level gauge.
Furthermore, at least two groups of oxygen cylinders are arranged.
Further, the medicament dissolving tank comprises a dosing funnel and a stirrer, the dosing funnel is arranged at the upper end of the medicament dissolving tank, and the stirrer is rotatably arranged in the medicament dissolving tank.
Compared with the prior art, the beneficial effects of the utility model are that:
according to the blue carbon wastewater ultrasonic catalytic purification device, a microscopic transient supercritical environment is realized under macroscopic normal temperature and normal pressure by utilizing a liquid ultrasonic cavitation principle, and the complex reaction efficiency of the whole purification is enhanced by cooperating with ultraviolet irradiation, ozone oxidation and medicament action, so that a catalytic purification function is realized; compared with a supercritical water oxidation device, the device can save equipment investment, reduce the use management difficulty and improve the safety, and is favorable for industrial popularization.
Drawings
Fig. 1 is a schematic structural diagram of an ultrasonic catalytic purification device for semi-coke wastewater.
In the figure: 1-raw water storage tank, 2-dissolved gas self-priming pump, 3-ultraviolet irradiator, 4-pipeline mixer, 5-ultrasonic catalytic purifier, 6-oxygen cylinder, 7-ozone generator, 8-medicament dissolving tank, 11-bottom manhole, 12-top manhole, 13-light oil recovery port, 14-raw water outlet, 15-heavy oil recovery port, 51-ultrasonic vibrator, 52-liquid-residue separation port, 53-gas separation port, 54-overflow plate, 55-magnetic float level gauge, 81-dosing funnel and 82-stirrer.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention will be described in further detail with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the present invention and are not intended to limit the present invention.
The following describes in detail a specific implementation of the present invention with reference to specific embodiments.
As shown in fig. 1, the device for purifying semi-coke wastewater by ultrasonic catalysis provided by an embodiment of the present invention further comprises a raw water storage tank 1, a dissolved air self-priming pump 2, an ultraviolet irradiator 3, a pipeline mixer 4, an ultrasonic catalytic purifier 5, an oxygen cylinder 6, an ozone generator 7 and a chemical dissolving tank 8, the ultrasonic catalytic purifier 5 comprises a liquid-slag separation port 52 and an overflow plate 54, the oxygen cylinder 6 is horizontally arranged with the raw water storage tank 1 through an ozone generator 7 and is connected with the dissolved air self-priming pump 2, the dissolved gas self-priming pump 2 is connected with an ultrasonic catalytic purifier 5 through an ultraviolet irradiator 3 and a pipeline mixer 4, the ultrasonic catalytic purifier 5 is connected with the inlet of the dissolved gas self-priming pump 2 through a liquid-slag separation port 52, the entry of medicament dissolving tank 8 links to each other with the liquid outlet of overflow plate 54, the export of medicament dissolving tank 8 links to each other with the entry of dissolving gas self priming pump 2.
In the embodiment of the present invention, preferably, the semi-coke wastewater fully stands and naturally stratifies in the raw water storage tank 1, only the water layer with a relatively clean middle part enters into the subsequent ultrasonic catalytic purification reaction of ozone, ultraviolet radiation and additional medicament which is prepared by matching with pure oxygen, and the ultrasonic catalytic purifier 5 has a self-circulation loop with the dissolved air self-priming pump 2, the ultraviolet irradiator 3 and the pipeline mixer 4, so that the control circulation ratio is convenient to adapt to the full degradation of the raw water with different concentrations, and the operation flexibility is good. The equipment is made of 304 stainless steel, carbon steel, copper and aluminum alloy are not selected, and metal ions are prevented from being dissolved to form a complex and metal corrosion in an ultrasonic environment is avoided.
As shown in fig. 1, as a preferred embodiment of the present invention, the raw water storage tank 1 includes a bottom manhole 11, a top manhole 12, a light oil recovery port 13, a raw water outlet 14, and a heavy oil recovery port 15, the light oil recovery port 13 and the heavy oil recovery port 15 are sequentially disposed on one side of the raw water storage tank 1 from top to bottom, the bottom manhole 11 is disposed at the bottom end of the other side of the raw water storage tank 1, and the top manhole 12 is disposed at the upper end of the raw water storage tank 1.
In the embodiment of the utility model provides an, it is preferred, light heavy oil in raw water storage tank 1 is retrieved through light oil recovery mouth 13, heavy oil recovery mouth 15 respectively, and it is retrieved through bottom manhole 11 periodical clear jar to subside fatlute, and the subsidiary spark arrester breather valve of top manhole 12 accords with static, lightning protection ground connection requirement.
As shown in fig. 1, as a preferred embodiment of the present invention, at least two sets of the dissolved air self-priming pumps 2 are provided.
In the embodiment of the present invention, preferably, the dissolved air self-priming pump 2 mixes raw water, ozone, chemicals, and backflow water in a pump inlet section in proportion, and then the impeller rotates at a high speed to break up and mix, and the high-pressure area at the pump case is fully pressurized and dissolved, so that ozone, surplus oxygen, chemicals, and raw water are fully and uniformly dispersed in a micro-emulsification manner, and the dissolved air self-priming pump 2 is at least provided with two groups and can be switched to maintain or update.
As shown in fig. 1, as a preferred embodiment of the present invention, a stainless steel baffle plate is provided in the line mixer 4.
In the embodiment of the utility model, the stainless steel baffle plate in the pipeline mixer 4 mixes the gas and the liquid without layering.
As shown in fig. 1, as a preferred embodiment of the present invention, the ultrasonic catalytic purifier 5 further includes an ultrasonic vibrator 51, a gas separation port 53 and a magnetic float level meter 55, the ultrasonic vibrator 51 is disposed in the ultrasonic catalytic purifier 5, a liquid-slag separation port 52 is disposed at a center position of a lower end of the ultrasonic catalytic purifier 5, the gas separation port 53 is disposed at an upper end of a liquid outlet of the overflow plate 54, and the magnetic float level meter 55 is disposed at one side of the liquid outlet of the overflow plate 54.
In the embodiment of the present invention, preferably, the overflow plate 54 divides the ultrasonic catalytic cleaner 5 into two regions, i.e., the working region of the ultrasonic vibrator 51 and the gas-liquid separation region. The ultrasonic vibrator 51 is immersed at the bottom of the liquid, and has a medium-high strength effect on the liquid inlet of the ultrasonic catalytic purifier 5, so that the degradation effect of ozone, rich residual oxygen and a medicament on organic impurities in water is enhanced; the liquid-residue separation port 52 automatically reflows the solid-phase suspension with the density larger than that of water generated after reaction according to a proportion to repeat the catalytic degradation process, and controls the reflux ratio according to the degradation difficulty and easiness degree to ensure the catalytic purification quality; a steel wire mesh for defoaming is arranged in the gas separation port 53, liquid drops in the gas flow are condensed and returned, and the gas after being dewatered is discharged at a high position through a discharge pipe; the liquid behind the overflow plate 54 is the liquid that purifies up to standard, and through magnetic float level gauge 55 automatic control discharge, the intermittent type of one way gets into medicament dissolving tank 8 and disposes the medicament of suitable concentration, and the rest is discharged, sends into the biodegradable unit and simply handles the back promptly and is up to standard reclaimed water.
As shown in fig. 1, as a preferred embodiment of the present invention, at least two groups of oxygen cylinders 6 are provided.
In the embodiment of the utility model, preferably, ozone generator 7 adopts the pure oxygen that oxygen cylinder 6 provided to prepare ozone, and this method can effectively increase ozone concentration, reinforce the degradation reaction, and surplus oxygen is favorable to ultrasonic catalysis purification's combined effect, and the oxygen cylinder is convenient for incessantly to be changed by two groups at least, avoids using air compressor machine system can also simplify the flow, practices thrift the energy consumption, reduces comprehensive cost.
As shown in fig. 1, as a preferred embodiment of the present invention, the chemical dissolving tank 8 includes a dosing funnel 81 and a stirrer 82, the dosing funnel 81 is disposed at the upper end of the chemical dissolving tank 8, and the stirrer 82 is rotatably disposed in the chemical dissolving tank 8.
In the embodiment of the present invention, preferably, the drug dissolving tank 8 can dissolve and mix the fenton reagent, the acid-base regulator, and the flocculation adsorption drug in advance to a qualified solution, and then accurately add the solution in proportion, so as to improve the sensitivity of the ultrasonic catalytic purification reaction; under a good working condition, the COD removal rate is more than or equal to 95 percent, the residual organic matter is well adapted to organisms, high-toxicity residues do not exist, and deep purification can be carried out through a biochemical treatment unit.
The working principle of the utility model is as follows:
this blue charcoal waste water ultrasonic catalysis purifier adopts raw water storage tank 1 to stew the branch liquid, adopts the pure oxygen to prepare ozone, the dissolved medicament of cooperation, dissolves through dissolving 2 pressurization of gas self priming pump, and ultraviolet radiation carries out the acoustic wave cavitation by ultrasonic catalysis clarifier 5 after follow-up mixtures, realizes microcosmic transient state supercritical degradation at macroscopic normal atmospheric temperature, strengthens reaction efficiency, through adjusting ozone, medicament, reflux ratio, illumination energy, ultrasonic frequency and input energy control reaction depth and best efficiency ratio.
The above is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, many variations and modifications can be made without departing from the spirit of the present invention, and these should be considered as the protection scope of the present invention, which will not affect the effect of the embodiments of the present invention and the practicability of the patent.
Claims (7)
1. The utility model provides a blue charcoal waste water supersound catalytic purification device, its characterized in that includes raw water storage tank, dissolves gas self priming pump, ultraviolet irradiator, pipeline mixer, supersound catalytic purifier, oxygen cylinder, ozone generater and medicament dissolving tank, supersound catalytic purifier includes liquid sediment isolating port and overflow board, the oxygen cylinder passes through ozone generater and raw water storage tank level setting and links to each other with dissolving the gas self priming pump, it links to each other with supersound catalytic purifier through ultraviolet irradiator and pipeline mixer to dissolve the gas self priming pump, supersound catalytic purifier passes through liquid sediment isolating port and links to each other with the entry of dissolving the gas self priming pump, the entry of medicament dissolving tank links to each other with the liquid outlet of overflow board, the export of medicament dissolving tank links to each other with the entry of dissolving the gas self priming pump.
2. The ultrasonic catalytic purification device for semi-coke wastewater as claimed in claim 1, wherein the raw water storage tank comprises a bottom manhole, a top manhole, a light oil recovery port, a raw water outlet and a heavy oil recovery port, the light oil recovery port and the heavy oil recovery port are sequentially arranged on one side of the raw water storage tank from top to bottom, the bottom manhole is arranged at the bottom end of the other side of the raw water storage tank, and the top manhole is arranged at the upper end of the raw water storage tank.
3. The semi-coke wastewater ultrasonic catalytic purification device according to claim 1, wherein at least two groups of dissolved gas self-priming pumps are provided.
4. The semi-coke wastewater ultrasonic catalytic purification device as claimed in claim 1, wherein a stainless steel baffle plate is arranged in the pipeline mixer.
5. The semi-coke wastewater ultrasonic catalytic purification device according to claim 1, wherein the ultrasonic catalytic purifier further comprises an ultrasonic vibrator, a gas separation port and a magnetic float level meter, the ultrasonic vibrator is arranged in the ultrasonic catalytic purifier, the liquid-slag separation port is arranged at the central position of the lower end of the ultrasonic catalytic purifier, the gas separation port is arranged at the upper end of the liquid outlet of the overflow plate, and the magnetic float level meter is arranged on one side of the liquid outlet of the overflow plate.
6. The semi-coke wastewater ultrasonic catalytic purification device as claimed in claim 1, wherein at least two groups of oxygen cylinders are provided.
7. The semi-coke wastewater ultrasonic catalytic purification device as claimed in any one of claims 1 to 6, wherein the chemical dissolving tank comprises a dosing funnel and a stirrer, the dosing funnel is arranged at the upper end of the chemical dissolving tank, and the stirrer is rotatably arranged in the chemical dissolving tank.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202121648211.8U CN215161830U (en) | 2021-07-20 | 2021-07-20 | Blue charcoal waste water supersound catalytic purification device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202121648211.8U CN215161830U (en) | 2021-07-20 | 2021-07-20 | Blue charcoal waste water supersound catalytic purification device |
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| CN215161830U true CN215161830U (en) | 2021-12-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202121648211.8U Active CN215161830U (en) | 2021-07-20 | 2021-07-20 | Blue charcoal waste water supersound catalytic purification device |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115650489A (en) * | 2022-10-24 | 2023-01-31 | 上海熊猫机械(集团)有限公司 | Water quality lifting device with water diversion function |
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2021
- 2021-07-20 CN CN202121648211.8U patent/CN215161830U/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115650489A (en) * | 2022-10-24 | 2023-01-31 | 上海熊猫机械(集团)有限公司 | Water quality lifting device with water diversion function |
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Address after: 710000 room 1902, unit 4, building 1, No. 31, zhangba'er Road, hi tech Zone, Xi'an City, Shaanxi Province Patentee after: XI'AN BAITERUI CHEMICAL ENGINEERING CO.,LTD. Address before: 710000 Room 802, unit 6, building 1, No. 31, zhangba'er Road, high tech Zone, Xi'an City, Shaanxi Province Patentee before: XI'AN BAITERUI CHEMICAL ENGINEERING CO.,LTD. |