CN215102562U - Organic pollution groundwater prosthetic devices - Google Patents

Organic pollution groundwater prosthetic devices Download PDF

Info

Publication number
CN215102562U
CN215102562U CN202023284961.XU CN202023284961U CN215102562U CN 215102562 U CN215102562 U CN 215102562U CN 202023284961 U CN202023284961 U CN 202023284961U CN 215102562 U CN215102562 U CN 215102562U
Authority
CN
China
Prior art keywords
photocatalytic reaction
wall
photocatalytic
light source
filter layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202023284961.XU
Other languages
Chinese (zh)
Inventor
王永剑
单广波
王山榕
徐佰青
赵一山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Dalian Petrochemical Research Institute Co ltd
China Petroleum and Chemical Corp
Original Assignee
China Petroleum and Chemical Corp
Sinopec Dalian Research Institute of Petroleum and Petrochemicals
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp, Sinopec Dalian Research Institute of Petroleum and Petrochemicals filed Critical China Petroleum and Chemical Corp
Priority to CN202023284961.XU priority Critical patent/CN215102562U/en
Application granted granted Critical
Publication of CN215102562U publication Critical patent/CN215102562U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Catalysts (AREA)
  • Physical Water Treatments (AREA)

Abstract

The utility model provides an organic pollution groundwater remediation device, which comprises a photocatalysis unit, a precipitation treatment unit and a waste gas treatment unit; the photocatalytic unit comprises a guide wall, a filter layer and a photocatalytic reaction wall, wherein the filter layer is arranged between the guide wall and the photocatalytic reaction wall, the photocatalytic reaction wall is formed by stacking and arranging a plurality of photocatalytic reaction monomers, each photocatalytic reaction monomer comprises a shell, a photocatalytic reaction net and a light source, the photocatalytic reaction net and the light source are arranged in the shell, a photocatalyst is attached to the photocatalytic reaction net, and the photocatalytic reaction monomers are connected through a buckle; the bottom of the photocatalytic reaction wall is also provided with an aeration pipe communicated with the bottom of the photocatalytic reaction monomer. The utility model discloses a device treatment effeciency is high, can make the free equipment of photocatalytic reaction module, is applicable to the place of the different degree of depth, and can repeat recycle, is an environment-friendly normal position prosthetic devices.

Description

Organic pollution groundwater prosthetic devices
Technical Field
The utility model relates to a groundwater remediation technical field, concretely relates to organic pollution groundwater prosthetic devices.
Background
Groundwater, which is an important component of water resources, is one of the main water sources for urban and industrial and agricultural water, and also is the material basis for maintaining human survival and development. However, with the continuous development of the industrialization process of the modern society and the increasingly strengthened development and utilization activities of human beings on natural resources, a large amount of pollutants (such as heavy metals, persistent organic matters and the like) enter a soil system through different ways and then enter the underground water environment through migration, diffusion and infiltration, so that the problem of underground water pollution is increasingly serious, and the human health is threatened gradually. In recent years, the pollution degree of underground water in China gradually increases, the pollution range gradually spreads from cities to the periphery and from shallow layers to deep layers, the underground water pollution situation is more and more severe, and the pollution gradually becomes a prominent environmental problem influencing the national economic development and the health of people in China.
The types of organic pollutants in underground water are more, and the content of the organic pollutants changes along with the water solubility, the pollution degree and the migration distance of the organic matters. Typical organic pollutants in the groundwater in China at present comprise benzene series, polycyclic aromatic hydrocarbon, organic chlorine, organic phosphorus, polychlorinated biphenyl, polybrominated diphenyl ether, perfluorinated compounds, triazine pesticides, pyrethroid pesticides and hormone substances in daily cosmetics. Many organic pollutants have serious influence on human health, and have three causes, namely teratogenesis, mutagenesis and carcinogenesis. In addition, different organic compounds have different hazards to the organs and systems of the human body. Such as: trichloroethylene stimulates the skin and has damage to internal organs such as lung, liver, kidney and the like; benzene stimulates the skin and eyes and has damage to the nervous system, immune function and gastrointestinal tract.
Groundwater remediation is a challenging task. From the aspect of remediation mode, groundwater pollution remediation technologies can be divided into two main categories, namely ex-situ remediation and in-situ remediation. The in-situ remediation technology has less interference on the environment of soil and underground water, does not need to pump out the underground water, reduces the exposure of pollutants, has low cost and is concerned and applied more. The existing in-situ remediation technology has the problems that various medicaments are required to be added to increase the risk of secondary pollution and the process is complicated, the photocatalytic technology can decompose various organic compounds, the medicaments are not required to be added, the photocatalytic technology is a green, efficient and secondary pollution-free advanced oxidation technology, and can be applied to in-situ remediation of underground water in principle.
CN109970258A discloses a modular groundwater remediation circulating well device, which comprises a photocatalytic reaction module unit; and the vacuum extraction unit comprises an exhaust pipe and an active carbon adsorption mechanism. A circular circulating well is excavated downwards from the ground, underground water is pretreated through a lower-layer sieve tube and is used for removing suspended matters and large granular substances in the underground water and then enters the circulating well, a photocatalytic reaction net is used for reacting under the irradiation of a visible light source to remove organic pollutants in the underground water, the treated underground water is raised under the action of negative pressure generated by a vacuum extraction unit and flows out through an upper-layer sieve tube and flows back into the stratum. The aeration unit fully aerates the underground water and is used for increasing the oxygen content of the underground water so that the subsequent photocatalytic reaction can be smoothly carried out. An underground water extraction unit can be added, underground water is extracted by a submersible pump and then is sprayed and blown off by a spray head through a water pumping pipe, volatile and semi-volatile organic pollutants finally enter an activated carbon tank through a gas pumping pipe, and the pollutants are adsorbed and removed by activated carbon in the activated carbon tank and then are discharged. However, the method needs to constantly maintain the negative pressure in the circulating well, and the energy consumption is high; the influence radius of the circulating well in the groundwater environment is limited; the groundwater is sprayed on the photocatalytic reaction net after being extracted, so that the polluted groundwater can directly flow back to the stratum through the upper-layer sieve tube without being treated.
CN109384337A discloses a remediation device and a remediation method for petroleum hydrocarbon polluted groundwater. The apparatus comprises a reactor; the ultraviolet light source is arranged in the reactor; a medicine feeding pipe; a submersible pump is used for a well. Under the action of a submersible pump for a well, the mixed solution of the underground water polluted by petroleum hydrocarbon and the additive continuously enters the inner cavity of the reactor from the water inlet; under the irradiation of an ultraviolet light source, the oxidant provided by the dosing pipe is mixed and contacted with the mixed solution of the petroleum hydrocarbon polluted underground water and the additive in the inner cavity of the reactor. The method for repairing petroleum hydrocarbon polluted underground water can improve the repairing efficiency and reduce the using amount of the oxidant.
Disclosure of Invention
To current normal position restoration technique probably exist and need add various medicaments and increase secondary pollution risk, cost-push, process complicacy, pollutant and get rid of the trailing scheduling problem, the utility model provides an organic pollution groundwater prosthetic devices can realize normal position photocatalysis restoration.
In order to achieve the technical purpose, the technical scheme of the invention is as follows:
an organic polluted groundwater remediation device comprises a photocatalysis unit, a precipitation treatment unit and a waste gas treatment unit;
the photocatalytic unit comprises a guide wall, a filter layer and a photocatalytic reaction wall, wherein the filter layer is arranged between the guide wall and the photocatalytic reaction wall, the photocatalytic reaction wall is formed by stacking and arranging a plurality of photocatalytic reaction monomers, each photocatalytic reaction monomer comprises a shell, a photocatalytic reaction net and a light source, the photocatalytic reaction net and the light source are arranged in the shell, a photocatalyst is attached to the photocatalytic reaction net, and the photocatalytic reaction monomers are connected through a buckle; the bottom of the photocatalytic reaction wall is also provided with an aeration pipe communicated with the bottom of the photocatalytic reaction monomer;
the sedimentation treatment unit is arranged at the bottom of the photocatalytic reaction wall and sequentially comprises a bearing layer, a sludge storage pool and a sludge discharge pipe from top to bottom;
the waste gas treatment unit comprises an exhaust pipe and an adsorption device which are communicated with the photocatalytic reaction wall.
Furthermore, the light source is an ultraviolet light source and is controlled by a light source control module, and organic pollutants in water are catalyzed by the photocatalyst under the irradiation of ultraviolet light. The photocatalyst is titanium dioxide P25.
Furthermore, the guide walls are fixed on two sides of the photocatalytic reaction wall, are impermeable and guide the organic polluted underground water to the filter layer.
Furthermore, the filter layer is filled with a filler, and the filler is selected from one or more of iron, activated carbon, modified zeolite and quartz sand, and is preferably quartz sand. The filtering layer intercepts impurities carried in the organic polluted underground water, and the blockage of the impurities on a reaction net in the photocatalytic reaction monomer is avoided.
Furthermore, the device also comprises necessary pumps, including an aeration pump connected with the aeration pipe, a sludge discharge pump connected with the sludge discharge pipe and an air suction pump connected with the exhaust pipe. And the exhaust pipe is also provided with a pressure gauge.
The process of repairing organically polluted groundwater by using the device is as follows: the organic polluted underground water is intercepted by the diversion wall, is drained to the filter layer, is filtered to remove impurities such as particles and the like, enters the photocatalytic reaction wall, and is subjected to catalytic reaction under the irradiation of ultraviolet light by the photocatalyst attached to the photocatalytic reaction net under the action of a plurality of photocatalytic reaction monomers to degrade and remove organic pollutants in the underground water, so that the oxygen content of the underground water can be increased by increasing aeration in the process, and the reaction is strengthened; the impurities generated in the process are settled and enter a sludge discharge pipe to be discharged; the treated underground water enters the soil through a photocatalytic reaction wall; after aeration, volatile organic compounds in the organic polluted underground water enter a gas phase and enter the adsorption device through the exhaust pipe.
Compared with the prior art, the utility model has the characteristics of it is following:
the utility model discloses an organic pollution groundwater prosthetic devices treatment effeciency is high, can make the free equipment of photocatalytic reaction module, is applicable to the place of the different degree of depth, and can repeat recycle. After the device withdraws from the field, the space where the device is located can be transformed into a PRB reaction wall, and the device is suitable for a tailing field. The groundwater remediation device is an environment-friendly in-situ remediation device.
Other features and advantages of the present invention will be described in detail in the detailed description which follows.
Description of the drawings:
FIG. 1 is a schematic view of an apparatus for remediation of organically-polluted groundwater;
FIG. 2 is a schematic diagram of a structure including guide walls, a filter layer, and a photocatalytic reaction wall.
In the figure: 1. the device comprises a guide wall, 2 parts of a filter layer, 3 parts of a photocatalytic reaction monomer, 31 parts of a shell, 32 parts of a photocatalytic reaction net, 33 parts of a lamp storage hole, 34 parts of an ultraviolet lamp, 4 parts of a buckle, 5 parts of a light source control module, 6 parts of an aeration pump, 7 parts of an aeration pipe, 8 parts of a bearing layer, 9 parts of a sludge storage tank, 10 parts of a sludge discharge pipe, 11 parts of a sludge discharge pump, 12 parts of a sludge storage device, 13 parts of an exhaust pipe, 14 parts of a pressure gauge, 15 parts of an adsorption device, 16 parts of an air suction pump, 17 parts of an aeration head and 18 parts of a sealing cover plate.
Detailed Description
The following non-limiting examples will allow one of ordinary skill in the art to more fully understand the present invention, but do not limit the invention in any way.
Example 1
Discloses an organic polluted groundwater remediation device, which comprises a photocatalytic unit, a precipitation treatment unit and a waste gas treatment unit, and the structure of the device is shown in figure 1:
the photocatalytic unit comprises a guide wall 1, a filter layer 2 and a photocatalytic reaction wall, wherein a sealing cover plate 18 is arranged at the top of the photocatalytic reaction wall to separate the photocatalytic reaction wall from upper soil, the filter layer 2 is arranged between the guide wall 1 and the photocatalytic reaction wall, and activated carbon is filled in the filter layer 2 to serve as a filler; the photocatalytic reaction wall is formed by stacking and arranging a plurality of photocatalytic reaction monomers 3 as shown in fig. 2, wherein each photocatalytic reaction monomer 3 comprises a shell 31, a photocatalytic reaction net 32, a lamp storage hole 33 and an ultraviolet lamp 34, the photocatalytic reaction net 32, the lamp storage hole 33 and the ultraviolet lamp 34 are arranged in the shell, the ultraviolet lamp 34 is connected with a light source control module 5, a photocatalyst is attached to the photocatalytic reaction net 32, and the photocatalytic reaction monomers 3 are connected through a buckle 4; the bottom of the photocatalytic reaction wall is also provided with an aeration pipe 7 communicated with the photocatalytic reaction monomer 3, an aeration head 17 of the aeration pipe 7 is arranged at the bottom of the photocatalytic reaction monomer 3, and the aeration pipe 7 is also connected with an aeration pump 6;
the sedimentation processing unit is arranged at the bottom of the photocatalytic reaction wall and sequentially comprises a bearing layer 8, a sludge storage tank 9 and a sludge discharge pipe 10 from top to bottom, the sludge discharge pipe 10 is also connected with a sludge discharge pump 11, and the tail end of the sludge discharge pipe is connected with a sludge storage device 12;
the waste gas treatment unit comprises an exhaust pipe 13 and an adsorption device 15 which are communicated with the photocatalytic reaction wall, and the exhaust pipe 13 is connected with an air suction pump 16 and a pressure gauge 14.

Claims (9)

1. The organic polluted groundwater remediation device is characterized by comprising a photocatalysis unit, a precipitation treatment unit and a waste gas treatment unit;
the photocatalytic unit comprises a guide wall, a filter layer and a photocatalytic reaction wall, wherein the filter layer is arranged between the guide wall and the photocatalytic reaction wall, the photocatalytic reaction wall is formed by stacking and arranging a plurality of photocatalytic reaction monomers, each photocatalytic reaction monomer comprises a shell, a photocatalytic reaction net and a light source, the photocatalytic reaction net and the light source are arranged in the shell, a photocatalyst is attached to the photocatalytic reaction net, and the photocatalytic reaction monomers are connected through a buckle; the bottom of the photocatalytic reaction wall is also provided with an aeration pipe communicated with the bottom of the photocatalytic reaction monomer;
the sedimentation treatment unit is arranged at the bottom of the photocatalytic reaction wall and sequentially comprises a bearing layer, a sludge storage pool and a sludge discharge pipe from top to bottom;
the waste gas treatment unit comprises an exhaust pipe and an adsorption device which are communicated with the photocatalytic reaction wall.
2. The remediation device of claim 1, wherein the light source is an ultraviolet light source and is controlled by a light source control module.
3. The apparatus for remediating organic contaminated groundwater according to claim 1, wherein the guide walls are fixed to both sides of the photocatalytic reaction wall, and are impermeable to water to guide the organic contaminated groundwater to the filter layer.
4. The remediation device of claim 1, wherein said filter layer is filled with a filler selected from the group consisting of iron, activated carbon and silica sand.
5. The apparatus for remediating organically-polluted groundwater as claimed in claim 4, wherein the filler is quartz sand.
6. The apparatus for remediating organically-polluted groundwater as claimed in claim 1, further comprising an aeration pump connected to the aeration pipe.
7. An organically-polluted groundwater remediation device as claimed in claim 1 further comprising a dredge pump connected to the dredge pipe.
8. An organically-polluted groundwater remediation device as claimed in claim 1 further comprising a suction pump connected to the exhaust pipe.
9. The remediation device of claim 1, wherein the vent pipe is further provided with a pressure gauge.
CN202023284961.XU 2020-12-31 2020-12-31 Organic pollution groundwater prosthetic devices Active CN215102562U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202023284961.XU CN215102562U (en) 2020-12-31 2020-12-31 Organic pollution groundwater prosthetic devices

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202023284961.XU CN215102562U (en) 2020-12-31 2020-12-31 Organic pollution groundwater prosthetic devices

Publications (1)

Publication Number Publication Date
CN215102562U true CN215102562U (en) 2021-12-10

Family

ID=79322371

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202023284961.XU Active CN215102562U (en) 2020-12-31 2020-12-31 Organic pollution groundwater prosthetic devices

Country Status (1)

Country Link
CN (1) CN215102562U (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114249379A (en) * 2021-12-24 2022-03-29 内蒙古工业大学 Photocatalytic pollutant degradation reaction device
CN115571973A (en) * 2022-10-09 2023-01-06 河南省地质科学研究所 Purification detection device for underground water pollution

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114249379A (en) * 2021-12-24 2022-03-29 内蒙古工业大学 Photocatalytic pollutant degradation reaction device
CN115571973A (en) * 2022-10-09 2023-01-06 河南省地质科学研究所 Purification detection device for underground water pollution
CN115571973B (en) * 2022-10-09 2023-05-16 河南省地质科学研究所 Purification detection device for groundwater pollution

Similar Documents

Publication Publication Date Title
Mukhopadhyay et al. Nanomaterials for sustainable remediation of chemical contaminants in water and soil
CN103112915B (en) Circulation well method and device for removing pollutants in underground water
CN215102562U (en) Organic pollution groundwater prosthetic devices
CN101898855B (en) Integrated ex-situ repair system for underground water polluted by volatile organic compound
CN101481171B (en) Biological treatment apparatus and method for wastewater containing volatile organic matter
CN104129877B (en) A kind ofly removably descend the device of Organic substance in water and the method for organics removal
US20150041392A1 (en) Method and system using micro/nano bubbles for enhanced in situ remediation of polluted groundwater
CN109970257A (en) A kind of groundwater remediation circulation well device
JP3728510B2 (en) Soil pollution countermeasure method and soil pollution countermeasure system
CN103086469A (en) Efficient photocatalysis water treatment method and device
CN206731796U (en) A kind of circulation well for removably descending water pollutant
CN202849190U (en) Photoelectric catalytic oxidation reaction device
CN112645542A (en) Circulating well system for in-situ remediation of organic polluted underground water
CN104773806B (en) A kind of preparation method of strong reducing property nano material and its application in underground water pollution processing
Yu et al. Hazardous wastes treatment technologies
CN103539266A (en) Structure capable of being used for treating heavy metals in bottom mud dredging tail water and construction method thereof
CN204918235U (en) Portable integration waste water treatment equipment of multimode
CN104386848B (en) A kind of method processing organotin factory effluent
CN215480219U (en) Underground water circulating well system with repair equipment
CN101090868A (en) Magneting photocatalytic compact wastewater reclamation and reuse device
CN212198810U (en) System for utilize air supporting device to restore combined pollution groundwater that contains petroleum hydrocarbon
CN204550132U (en) A kind of novel photocatalysis water treating equipment
CN103288168B (en) Multiphase vacuum suction and reinforced ultraviolet catalytic photolysis repair system and repair method thereof
CN109970258A (en) A kind of modularization groundwater remediation circulation well device
CN105502806A (en) Efficient pesticide removing system and method based on plasma and multi-group SBR (sequencing batch reactor) reaction tanks

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20240327

Address after: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen

Patentee after: CHINA PETROLEUM & CHEMICAL Corp.

Country or region after: China

Patentee after: Sinopec (Dalian) Petrochemical Research Institute Co.,Ltd.

Address before: 100728 No. 22 North Main Street, Chaoyang District, Beijing, Chaoyangmen

Patentee before: CHINA PETROLEUM & CHEMICAL Corp.

Country or region before: China

Patentee before: DALIAN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPEC Corp.